מידע בנושא מידע סביבתי- המשרד להגנת הסביבה
מסמך 1 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 141 KB)
פניות ציבור וחוק חופש המידע
כ"ג תשרי ,תשפ"ד
08אוקטובר 2023
מספר בקשה2023-0279 :
לכבוד
שלום רב,
הנדון :בקשתך לקבלת מידע -שכונת אלרואי
בהתייחס לבקשתך שבנדון ,להלן תבוא החלטתי:
.1בדיקות הניטור הסביבתי שנערכו בשכונת אלרואי ,הצמודה לחוות המכלים של תשתיות
נפט ואנרגיה ונמצאת בקרית טבעון .כלל תוצאות הבדיקות בין השנים ,2021-2014לרבות
תוצאות הניטור לגבי תרכובת הבנזן ( ,)Benzeneשנוסחתה הכימית היא – C6H6
מבדיקה שערכתי מול גורמי המקצוע במשרד עולה כי הניטור הסביבתי באזור ,כפי
שהתבקש ,נערך ע"י איגוד ערים חיפה בשנים 2016ו .2017-על כן ,אני מפנה אותך להגיש
בקשת חופש מידע לאיגוד ערים מפרץ חיפה בכתובת https://tinyurl.com/2p8vdehk
וזאת לפי סעיף )5(8לחוק חופש המידע ,התשנ"ח.1998 -
.2תכניות הדיגום הסביבתי של חומרים אורגניים נדיפים של חברת תשתיות נפט ואנרגיה–
מסוף אלרואי כנדרש מהם בתנאים לרישיון עסק לפי חוק רישוי עסקים ,התשכ"ח-
–1968סעיף זה נמצא בבדיקה.
.3כלל המכתבים ו/או ההתכתבויות בין המשרד לאיכות הסביבה לבין נציגי חברת תשתיות
נפט ואנרגיה בנוגע לניטור איכות האוויר בסביבת חוות אלרואי של חברת תשתיות נפט
ואנרגיה – סעיף זה נמצא בבדיקה.
החלטה זו ניתנה בירושלים .על החלטה זו ניתן להגיש עתירה מנהלית לבית המשפט המחוזי
בירושלים ,בשבתו כבית משפט לעניינים מנהליים.
בברכה
מיכל ריבלין
ראש תחום פניות הציבור
וחופש המידע
רחוב בנק ישראל ,7ירושלים 9136002
טל' 073-2733350/51 :דואר אלקטרוניmeyda@sviva.gov.il :
מסמך 2 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 137 KB)
פניות ציבור וחוק חופש המידע
ח' טבת ,תשפ"ד
20דצמבר 2023
מספר בקשה2023-0279 :
לכבוד
שלום רב,
הנדון :בקשתך לקבלת מידע -שכונת אלרואי
בהתייחס לבקשתך ובהמשך למידע שהועבר אלייך בתאריך ,8.10.23להלן החלטתי בעניין הנוסף:
.1בדיקות הניטור הסביבתי שנערכו בשכונת אלרואי ,הצמודה לחוות המכלים של תשתיות
נפט ואנרגיה ונמצאת בקרית טבעון .כלל תוצאות הבדיקות בין השנים ,2021-2014לרבות
תוצאות הניטור לגבי תרכובת הבנזן ( ,)Benzeneשנוסחתה הכימית היא – C6H6לאחר
בדיקה נוספת שערכנו ,מצ"ב דוחות שנתיים לעניין פליטות לאוויר ממסוף אלרואי,
שנמצאו ברשות המשרד.
.2תכניות הדיגום הסביבתי של חומרים אורגניים נדיפים של חברת תשתיות נפט ואנרגיה–
מסוף אלרואי כנדרש מהם בתנאים לרישיון עסק לפי חוק רישוי עסקים ,התשכ"ח-
–1968לחברת תש"ן מספר אתרים ,כאשר אתר אלרואי משמש לאחסון בלבד .באתר
קיימים תוצרי דלק מוגמרים ולא תזקיק נפט .אי לכך ,האתר נדרש בהעברת דו"ח שנתי
אודות הפליטות שבוצעו באותה השנה .הדוחות השנתיים צורפו לסעיף 1לעיל ,לא קיימות
דרישות נוספות לאתר.
.3כלל המכתבים ו/או ההתכתבויות בין המשרד לאיכות הסביבה לבין נציגי חברת תשתיות
נפט ואנרגיה בנוגע לניטור איכות האוויר בסביבת חוות אלרואי של חברת תשתיות נפט
ואנרגיה – מבדיקה שערכתי מול גורמי המקצוע לא נמצאו תכתובות כפי שהתבקשו על
ידך ,וזאת לפי סעיף )3(8לחוק חופש המידע ,התשנ"ח.1998-
החלטה זו ניתנה בירושלים .על החלטה זו ניתן להגיש עתירה מנהלית לבית המשפט המחוזי
בירושלים ,בשבתו כבית משפט לעניינים מנהליים.
בברכה
מיכל ריבלין
ראש תחום פניות הציבור
וחופש המידע
רחוב בנק ישראל ,7ירושלים 9136002
טל' 073-2733350/51 :דואר אלקטרוניmeyda@sviva.gov.il :
מסמך 3 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 1503 KB)
תשתיות נפט ואנרגיה בע"מ
מסו אלרואי
סיכו
פליטות לאוויר
שנת 2014
פרויקט3013.10 :
פברואר 2015
תוכ ענייני
.1מבוא 4.............................................................................................................................
.2נתוני מסו 5.....................................................................................................................
.2.1נתוני מיכלי 5.........................................................................................................
.2.2נתוני עבור מסו מילוי מיכליות כביש 9.....................................................................
.3חישוב פליטות 10 ..............................................................................................................
.3.1כללי 10 ...........................................................................................................................
.3.2סוגי פליטות מחושבות 11 ..................................................................................................
.3.3בחירת חומרי בתוכנת 11 ................................................................................... TANKS
.3.4נתוני מטאורולוגיי11 ....................................................................................................
.4סיכו פליטות לשנת 12 ............................................................................................. 2014
.4.1מיכלי 12 ........................................................................................................................
.4.2מסו מילוי מיכליות כביש 12 .............................................................................................
.4.3מיכל איסו תשטיפי 13 ...................................................................................................
.4.4סיכו ממצאי ניטור 13 .......................................................................................... LDAR
.4.5פליטה שנתית מכלל המתק 13 ...........................................................................................
.5פליטות לא שגרתיות במהל! שנת 13 ............................................................................2014
.6מקורות 14 .......................................................................................................................
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טבלאות
טבלה :1נתוני מיכלי – מידע כללי ,מידות ונתוני תפעול – שנת 5 .......................................... 2014
טבלה :2נתוני מעטפת וגגות – שנת 6 ................................................................................. 2014
טבלה :3נתוני אביזרי – שנת 7 ........................................................................................ 2014
טבלה :4צבעי מייצגי לצור! חישובי אקסל ותוכנת 8 .................................................. TANKS
טבלה :5נתוני עבור מסו מילוי מיכליות כביש – שנת 9 ..................................................... 2014
טבלה :6חומרי מייצגי בתוכנת 11 ........................................................................... TANKS
טבלה :7סיכו פליטות מיכלי ) שנת 12 .......................................................................... 2014
טבלה :8סיכו פליטות מסו מילוי מיכליות כביש ) שנת 12 .................................................2014
טבלה :9סיכו פליטות חומרי אורגני נדיפי עבור רכיבי בשנת 13 ................................. 2014
טבלה :10סיכו פליטות שנתי מכלל מסו אלרואי – שנת 13 ................................................2014
נספחי
נספח א'
טבלה (AP-42) 1)5.2
נספח ב'
נתוני ניטור LDARעבור מסו אלרואי – סיכו שנת 2014
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צ מס' 2המאחס בנזי
נספח ד'
דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 3של קרוסי
נספח ה'
חישוב פליטות ממיכל לאיסו תשטיפי
נעמי אלקלעי גבע
ש
עור!
יואב פיסטינר
ש
מאשר
10/02/2015
להערות
תאור
10.02.2015
תארי!
3/31
0
גרסה
3013.10-015.doc
.1מבוא
חברת תשתיות נפט ואנרגיה בע"מ )להל תש"( מפעילה את מסו אלרואי לאחסו ושינוע
דלקי .
המסו כולל:
•
מבני משרדי
•
חוות מכלי לאחסו דלקי מסוגי שוני
•
רציפי מילוי מכליות כביש )לשימוש בעת חירו בלבד(
המסו ממוק בשוליי הדרו מערביי של קריית טבעו ,בצמוד לו וממערב ממוקמת שכונת
אלרואי ומדרו לו שכונת קרית חרושת.
באתר 9מיכלי ,מתוכ 6מיכלי תפעוליי ו) 3מיכלי אסטרטגיי )מיכלי מס' .(5,6,8
מתו! המיכלי האסטרטגיי ,מיכל אחד )מס' (8הינו מיכל "רדו" שאינו ממולא באופ
שוט ,ותכולתו מוחלפת אחת לארבע שני בלבד.
מתו! המיכלי התפעוליי ,מיכל אחד )מס' (1אינו פעיל ב – .2014
מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוס קיימות מערכות תומכות כגו
מערכות כיבוי אש ומערכות פיקוד ובקרה.
כחלק מהתנאי ברישיו עסק מדצמבר ,2010בסו כל שנה קלנדרית על תש" להגיש דו"ח
סיכו פליטות שנתי לגבי השנה שחלפה.
חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקני
הקיימי במסו.
סיכו הפליטות הוכ על ידי חברת "פז" הנדסה וניהול ) (1980בע"מ )להל פז הנדסה( ,והוא
מבוסס על סקר תהליכי ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.
10/02/2015
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.2נתוני מסו
.2.1נתוני מיכלי
בטבלאות הבאות מפורט מידע טכני של המיכלי בחוות המיכלי אלרואי.
טבלה :1נתוני מיכלי – מידע כללי ,מידות ונתוני תפעול – שנת 2014
לח $אדי
כמות
בטמפ' הנוזל
צריכה
מספר סוג הדלק
הממוצעת
שנתית
המאוחס#
מיכל
)מ"ק(
)(mmHg
(1
28,768
32,056
גבעה חלקית 48.77
בנזי
1
28,637
405 @ 28°C
28,768
32,056
גבעה חלקית 48.77
14,957
קרוסי
2
0.833 @ 28°C
28,768
32,056
גבעה חלקית 48.77
140
סולר
3
0.507 @ 28°C
28,768
32,056
גבעה חלקית 48.77
0
סולר
0.507 @ 28°C
4
51,614
56,959
68.27
גבעה מלאה
8,342
סולר
5
0.507 @ 28°C
51,614
56,959
68.27
גבעה מלאה
0
סולר
6
0.507 @ 28°C
51,614
56,959
68.27
גבעה מלאה
סולר
7
40,340
0.507 @ 28°C
(2
34,228
36,547
48.8
גבעה חלקית
5,000
סולר
8
0.507 @ 28°C
(3
28,768
32,056
גבעה חלקית 48.77
קרוסי
9
14,957
0.833 @ 28°C
332,913
367,704
112,372
סה"כ
(1מיכל מס' 1מולא בפברואר 2014ואחס כמות קבועה של כ ) 28,600מ"ק בנזי.
(2מיכל מס' 8רוק במחצית הראשונה של ,2014מולא ב – 5,000מ"ק ביולי ואחס כמות קבועה ללא פעילות.
(3מיכל מס' 9לא היה פעיל במחצית הראשונה של 2014ואחס כמות קבועה של 28,768מ"ק קרוסי.
סוג ניקוז
בתחתית
מיכל
10/02/2015
קוטר
מיכל
)מטר(
נפח מיכל
)מ"ק(
5/31
נפח מיכל
פעיל
)מ"ק(
גובה /אור!
מעטפת
מיכל
)מטר(
17.16
17.16
17.16
17.16
15.56
15.56
15.56
19.54
17.16
גובה נוזל
מירבי
)מטר(
גובה נוזל
ממוצע
)מטר(
15.4
15.4
15.4
15.4
14.1
14.1
14.1
18.3
15.4
10.5
10
9.5
10.3
14.1
14.1
11.4
18.3
9.7
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טבלה :2נתוני מעטפת וגגות – שנת 2014
צורת גג
סוג
חיבורי
גג
צבע
גג
מצב
צבע
גג
צבע
מעטפת
חיצונית
מצב צבע
מעטפת
חיצונית
סוג חיבורי
מעטפת
מצב
מעטפת
פנימית
מיכל
מחומ
Pontoon
מרות!
לב
טוב
לב
טוב
מרות!
חלוד הרבה
לא
Pontoon
מרות!
לב
טוב
חאקי
טוב
מרות!
חלוד הרבה
לא
ללא
Pontoon
מרות!
לב
טוב
צהוב קר
טוב
מרות!
חלוד הרבה
לא
ללא
Pontoon
מרות!
לב
טוב
חאקי
יש
מרות!
חלוד הרבה
לא
Pontoon
מרות!
לב
טוב
צהוב קר
טוב
מרות!
חלוד הרבה
לא
Pontoon
מרות!
לב
טוב
צהוב קר
טוב
מרות!
חלוד הרבה
לא
Pontoon
מרות!
לב
טוב
צהוב קר
טוב
מרות!
חלוד הרבה
לא
Pontoon
מרות!
לב
טוב
כחול בהיר
טוב
מרות!
חלוד הרבה
לא
Pontoon
מרות!
לב
טוב
צהוב קר
טוב
מרות!
חלוד הרבה
לא
מספר
מיכל
סוג גג
אט
ראשי
אט
משני
1
גג צ
חיצוני
גג צ
חיצוני
גג צ
חיצוני
גג צ
חיצוני
גג צ
חיצוני
גג צ
חיצוני
גג צ
חיצוני
גג צ
חיצוני
גג צ
חיצוני
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Liquid
mounted
Mechanical
Shoe
Rim
mounted
Shoe
mounted
2
3
4
5
6
7
8
9
Shoe
mounted
Shoe
mounted
Shoe
mounted
Rim
mounted
ללא
סה"כ
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טבלה :3נתוני אביזרי – שנת 2014
מספר
מיכל
1
2
3
4
5
6
7
8
9
סה"כ
Pressure
]set. [psi
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
רגליי
מתכווננות התומכות
בגג צ
גובה
כמות באזור
כמות
במרכז
)(ft
pontoon
29
43
11
29
43
11
29
43
11
29
43
11
72
107
11
72
107
11
72
107
11
36
54
9
29
43
11
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שובר ואקו
כמות
2
2
2
2
2
2
2
6
2
Vacuum
]set. [psi
0
0
0
0
0
0
0
0
0
כמות
מדי
מפלס
Rim
Vent
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
כמות בוצה
בנקיו#
)מ"ק(
"גרביי
" לבאר
הדיגו
המחורצת
ולרגלי הגג הצ
70
70
70
70
150
150
150
70
70
870
יש
יש
יש
יש
יש
יש
יש
יש
יש
3013.10-015.doc
הנחות שנלקחו לצור! החישובי
.1עבור חישוב degassingבמיכל ע גג צ – הונח:
•
גג צ נח על רגליי בגובה ) 9-11 ftבהתא לטבלה לעיל( וזהו ג הגובה המרבי
של הנוזל במיכל.
•
גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.
.2הונח כי ניקיו כללי וריקו של המיכלי מתבצע אחת לכ) 15שני .הניקיו יאר! יו
אחד.
.3הונח כי אירוע של נחיתת גגות צפי מתבצע אחת לכ) 15שני .זמ נחיתת הגג
במקרה זה לא יעלה על 4ימי.
.4יחס הנוזל בבוצה הונח כ) [2] 0.8
.5בהתא לטבלה 7.1)6על פי ] ,[1נבחרו הצבעי הבאי כמייצגי את צבע מעטפת
המיכלי ,לצור! חישובי פליטות לאוויר:
טבלה :4צבעי מייצגי לצור! חישובי אקסל ותוכנת Tanks
צבע לצור! חישובי אקסל
צבע לצור! חישובי
בתוכנת
בהתא
למסמ! EPA AP-42
(*) Tanks
כחול בהיר
Gray Medium
Gray Medium
חאקי
Green Dark
Red/Primer
צהוב קר
Beige/Cream
Aluminium/Specular
צבע מעטפת
מיכל
)*( בתוכנת Tanksמבחר הצבעי מצומצ יותר מאשר בטבלה 7.1)6אשר במסמ!
.[1] EPA AP-42
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.2.2נתוני
עבור מסו מילוי מיכליות כביש
טבלה :5נתוני עבור מסו מילוי מיכליות כביש – שנת 2014
מס'
זרוע
1
2
3
4
5
6
7
8
מוצר
קרוסי
קרוסי
קרוסי
קרוסי
קרוסי
קרוסי
קרוסי
קרוסי
סה"כ
מילוי
עילי /תחתי
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
נפח ממוצע של
מיכלית )מ"ק(
30
30
30
30
30
30
30
30
נפח מילוי שנתי
)מ"ק(
0
0
400
388
0
0
0
0
788
הנחות שנלקחו צור! החישובי
.1
מקד (Tank paint solar absorptance) αממוצע עבור קרוסי חושב כדלקמ:
א .בשלב ראשו חושב המקד αעבור כל אחד ממיכלי הקרוסי:
דוגמת חישוב עבור מיכל מס' :2
0.17 + 0.89
= 0.53
2
=
α roof2 + α Shell2
2
= α tank2
ב .בשלב השני חושב מקד αממוצע עבור הקרוסי:
0.53 + 0.26
= 0.4
2
α tank2 + α tank9
=
number_of_kerosene_tanks
= α Kerosene
.2
זמ מילוי מיכלית חושב על פי נפח ממוצע של מיכלית וקצב מילוי שעתי מרבי של
1000ליטר/דקה.
.3
Vapor collection efficiency ) 70%
.4
Vapor recovery efficiency ) 0%
.5
Saturation factorהונח כ)(Submerged loading, dedicated normal service) 0.6
על פי ] .[1טבלה רלוונטית מצורפת בנספח א'.
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.3חישוב פליטות
.3.1כללי
חישובי הפליטות עבור מיכלי האחסו בוצעו בתוכנת Tanksובעזרת .[1] EPA-AP 42
הערכת פליטות כתוצאה מדליפות ציוד ואביזרי ) (LDARמצורפת בנספח ב'.
דוגמת חישוב עבור מיכל גג חיצוני צ )מיכל מס' (2המאחס קרוסי ,מצורפת כנספח ג'
למסמ! זה.
דוגמת חישוב עבור זרוע מילוי עילי של קרוסי )זרוע מס' (3מצורפת כנספח ד' למסמ! זה.
בדוגמאות אלה נית לראות את נתוני הקלט )כולל הנחות( עליה התבססו החישובי.
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.3.2סוגי פליטות מחושבות
הערכת הפליטות ממיכלי אחסו כוללת ]:[3
• פליטות בזמ אחסו )(Breathing Losses
• פליטות משינויי מפלס )(Working Losses
• פליטות כתוצאה מניקוי וריקו מיכלי )(Degassing Losses
• פליטות כתוצאה מנחיתת גגות צפי )(Roof Landing Losses
• פליטות כתוצאה מהפרשי לח(Flash Losses) 4
• פליטות בזמ מילוי מיכלי ומיכליות
בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לח4
).(Flash Losses
פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלח 4הנוזל ,נתו הגור להפרת שיווי
המשקל הקיי במיכל )בי גז לנוזל( וכתוצאה מכ! נוצר תהלי! הבזקה ,בו מרכיבי קלי
מפאזה הנוזל עוברי לפאזה הגזית .תופעות אלה מתרחשות ,בדר! כלל ,כאשר נוזל
המאוחס בלח 4נשלח לאחסו במיכל בעל לח 4נמו! יותר ].[3
פליטות אלו הוזנחו כיוו שכל החומרי מוחזקי בתנאי אטמוספריי בכל אחד
מהשלבי הנוגעי להובלת ואחסונ ,ולפיכ! לא צפויה פליטת אדי כתוצאה מתהלי!
זה.
.3.3בחירת חומרי
בתוכנת Tanks
על פי נתוני MSDSשל הדלקי במסו ,נבחרו החומרי הבאי הקיימי בתוכנת Tanks
כמייצגי של חומרי אלו:
טבלה :6חומרי מייצגי בתוכנת Tanks
דלק קיי
במסו
חומר מייצג בתוכנת Tanks
סולר )תחבורה והסקה(
Distillate fuel oil no 2
נפט )קרוסי(
Jet kerosene
בנזי
Gasoline RVP 10
.3.4נתוני
מטאורולוגיי
לצור! חישוב הנתוני בתוכנת Tanksהוגדרו נתוני מטאורולוגי המתאימי למפר4
חיפה על פי מקורות ].[4
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.4סיכו
פליטות לשנת 2014
.4.1מיכלי
סיכו חישובי פליטה עבור כל אחד ממיכלי האחסו מפורט בטבלה להל:
טבלה :7סיכו פליטות מיכלי ) שנת 2014
מיכל
חומר
1
בנזי
2
קרוסי
3
סולר
4
סולר
5
סולר
6
סולר
7
סולר
8
סולר
9
קרוסי
סה"כ
פליטות לאוויר
)ק"ג/שנה(
3775
786
816
826
1,701
1,695
1,721
800
798
12,919
.4.2מסו מילוי מיכליות כביש
להל טבלת סיכו חישובי פליטות עבור זרועות המילוי.
טבלה :8סיכו פליטות מסו מילוי מיכליות כביש ) שנת 2014
מס' זרוע
מוצר
מילוי עילי /תחתי
פליטה שנתית )ק"ג(
1
2
3
4
5
6
7
8
סה"כ
קרוסי
קרוסי
קרוסי
קרוסי
קרוסי
קרוסי
קרוסי
קרוסי
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
0.00
0.00
1.39
1.39
0.00
0.00
0.00
0.00
2.77
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.4.3מיכל איסו תשטיפי
ס! הפליטה ממיכל לאיסו תשטיפי הינה כ) 1ק"ג/שנה.
חישוב מצור בנספח ה'.
יצוי #כי החישוב מתבסס על הנחה מחמירה שהמיכל מכיל קרוסי #בלבד .מעשית ,המיכל
מכיל בעיקר ניקוז מי
מהמיכלי
.
.4.4סיכו
ממצאי ניטור LDAR
טבלה :9סיכו פליטות חומרי אורגני נדיפי עבור רכיבי בשנת 2014
סה"כ פליטות )ק"ג/שנה(
סיכו
פליטות LDAR
פליטה שנתית )ק"ג/שנה(
סה"כ
24.82
.4.5פליטה שנתית מכלל המתק#
טבלה :10סיכו פליטות שנתי מכלל מסו אלרואי – שנת 2014
סה"כ פליטות )ק"ג/שנה(
חוות מיכלי
מסו מילוי
מיכליות כביש
מיכל לאיסו
תשטיפי
12,919
2.77
1
סיכו
פליטות
רכיבי
סה"כ
)(LDAR
24.82
12,948
.5פליטות לא שגרתיות במהל! שנת 2014
במהל! שנת 2014לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.
10/02/2015
13/31
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.6מקורות
[1] EPA-AP42
[2] USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software
Version 4.0 - APPENDIX D
] [3הנחיות הממונה לטיפול בבקשה להיתר פליטה לפי סעי )9א( לתקנות אוויר נקי )היתרי
פליטה( ,התש"ע – ,2010מהדורה ,1ספטמבר 2011
] [4האטלס האקלימי לתכנו פיסי וסביבתי בישראל ,מהדורה שניה1994 ,
10/02/2015
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נספח א'
טבלה 5.2
1
AP-42
10/02/2015
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16/31
10/02/2015
נספח ב'
נתוני ניטור LDARעבור אלרואי – סיכו
שנת 2014
)מתו! דיווח שהתקבל ממעבדות אקולוגיה מתארי! (14.12.14
3013.10
002A
10/02/2015
17/31
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החברה הארצית לבדיקות ושירותי איכות הסביבה
רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.
טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),
E-mail :michael.o@ecologicalab.com
LDAR
דו"ח איתור
דליפות מרכיבי ציוד מס'
R-TASH-AL-R4-14
מפעל :תשתיות נפט ואנרגיה בע"מ
ישוב :קרית טבעון
מחוז :חיפה
מתקן :אלרואי
קטגורייה1-2 :
תקופת הניטור :סבב 5
סבב 6
סיכום שנתי
תאריך הדפסת הדו"ח14-Dec-14 :
שמות אנשי צוות :סלבה פוליק
יאן פורצלן
עורך הדו"ח :מיכאל אורייבסקי
מאשר הדו"ח :אלכסי רטנר ,מנכ"ל
This report produced using Orr LeakDAS software.
תוכן עניינים
1תיאור הפרויקט:
1.1סיכום ביצוע
3
1.2שלבי הפרויקט
3
2מתודולוגיה:
4
2.1הגדרות
2.2מתודולוגיה
4
2.3אופן ביצוע חישובים
4
3סיכום תקופת הניטור:
3.1סיכום נתונים מצטברים לתקופה
01/01/2014 - 31/12/2014
6
3.2סיכום תוצאות הניטור ,סבב 5
7
3.3סיכום תוצאות הניטור ,סבב 6
8
4סיכום שנתי 01/01/2014 - 31/12/2014
4.1טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
10
4.2פילוג לחומרים הנפלטים
11
4.3טופס תיקון דליפות שנתי
13
5תוצאות הניטור במדידה הראשונה:
5.1טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
15
5.2פילוג לחומרים הנפלטים
16
5.3טופס :15דו"ח תיקון דליפות למתקן ייצור
18
6תוצאות הניטור אחרי סבב התיקונים:
page 2 of 22
6.1טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
20
6.2פילוג לחומרים הנפלטים
21
INDEX
TASHAN-LDAR_R-TASH-AL-R4-14
1תיאור הפרוייקט:
1.1סיכום ביצוע:
הניטור בוצע לסוגי הרכיבים הבאים:
קטגוריה :1משאבות ,ציוד ערבוב וערבול ,PRD ,נקודות דגימה.
קטגוריה :2ברזים,שסתומים וצינורות פתוחים פוטנציאליים.
קטגוריה :3מחברים ואוגנים.
1.2שלבי הפרויקט:
● ניטור רכיבים
● במהלך רבעון בוצעו שני סבבי הניטור לרכיבי ציוד מקטגוריה 1במתקן אלרואי
● ניטור חוזר אחרי תיקון הדליפות.
● עדכון בסיס הנתונים.
● עדכון תזרימים .P&ID
1.3יחידות ציוד לניטור )כל המתקנים(:
מסוף
אלרואי
מסוף נמל
הדלק
מס' מיכל
מס' מיכל
מס' מיכל
מס' מיכל
מס' מיכל
מס' מיכל
T-44
T-95
T-133
T-140
T-1
T-113
T-45
T-127
T-136
קווי צנרת
קווי צנרת
T-164
T-69
T-128
T-137
T-74
T-129
T-138
T-94
T-131
T-139
טרמינל קרית חיים
T-165
קווי צנרת
בחוות
המיכלים
מערכת
VRU
הערות:
.1מתקן VRUשבמתקן נמל הדלק לא נבדק עקב חוסר הפעילות.
.2מפלס גג המיכל T-113שבנמל הדלק היה נמוך במשך תקופת הניטור ,לכן
המיכל לא נבדק מטעמי הבטיחות.
הערות כלליות:
.1חברת "מעבדות אקולוגיה א.פ .בע"מ" מוסמכת לתקן ISO-17025
ISO-17025לביצוע בדיקות LDARע"י ) ISRAQהרשות להסמכת מעבדות(.
.2הרשות להסמכת מעבדות אינה אחראית על תוצאות הבדיקות.
page 3 of 22
Project Introduction
TASHAN-LDAR_R-TASH-AL-R4-14
2מתודולוגיה:
2.1הגדרות:
נוזל קל :כל נוזל עם יותר מ 10% -נפחי של VOCהמתנדף ב 150-מעלות צלסיוס.
נוזל כבד :כל נוזל עם 10%נפחי של VOCאו פחות המתנדף ב 150-מעלות צלסיוס.
דליפה :גילוי של ריכוז TOCבפאזה גזית בסך 1,000חל"מ או יותר.
רכיב בלתי נגיש :כל רכיב הממוקם בגובה של יותר מ 5-מ' מעל הקרקע ,כאשר נדרשת גישה מהקרקע,
או כל רכיב הממוקם במרחק של יותר מ 2-מ' מפלטפורמה ,כאשר נדרשת גישה
מפלטפורמה ,ולא ניתן לגשת אליהם בצורה בטיחותית ע"י העובד ,או כל רכיב העלול
להצריך את הרתמתם של אנשי צוות ניטור לגובה של יותר מ 2-מ' מעל למשטחי
תמיכה קבועים ולא ניתן לגשת אליו בצורה בטיחותית.
2.2אופן ביצוע חישובים:
נוסחאות :חישוב הפליטות מדליפות מרכיבי ציוד נעשה בהתאם לגישת הקורלציה המפורטת
בפרוטוקול ה EPA-עבור תעשיה פטרוכימית.
US EPA "Protocol for equipment leak emission estimates",1995
"נתונים מצטברים" :בטבלאות "נתונים מצטברים" אנחנו מציגים תוצאות של כל המדידות שבוצעו מתחילת
השנה ועד סוף תקופת הניטור הנוכחית )שנה(.
חישוב הפליטה המצטברת נעשה בהתאם לModified Trapezoidal Method-
US EPA "Emission Estimation Protocol for Petroleum Refineries",Ver.2.1.1, 2011
page 4 of 22
Methodology
TASHAN-LDAR_R-TASH-AL-R4-14
- חישוב קצב פליטה שעתי ושנתי מרכיבי ציוד בוצע בהתאם ל2.3
)בהמשךProtocol for equipment leak emission estimates,2.0. (EPA,1995)
."Petroleum Industry" "פרוטוקול"( סקטור תעשייה רלוונטי הינו
: חל"מ9 ≤ דליפות
Equipment type
kg/year
Valves/all
2.29E-06 * (measured ppm value)^0.746 * production hours
Pump seals/all
5.03E-05 * (measured ppm value)^0.610 * production hours
Others/all *
1.36E-05 * (measured ppm value)^0.589 * production hours
Connectors/all
1.53E-06 * (measured ppm value)^0.735 * production hours
Flanges/all
4.61E-06 * (measured ppm value)^0.703 * production hours
Open-ended lines/all
2.20E-06 * (measured ppm value)^0.704 * production hours
. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- Others :הערה
: חל"מ9 > דליפות
Equipment type
kg/year
Valves/all
7.80E-06 * production hours
Pump seals/all
2.40E-05 * production hours
Others/all *
4.00E-06 * production hours
Connectors/all
7.50E-06 * production hours
Flanges/all
3.10E-07 * production hours
Open-ended lines/all
2.00E-06 * production hours
. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- "Others" :הערה
: חל"מ100,000 < דליפות
Equipment type
kg/year
Valves/all
0.140 * production hours
Pump seals/all
0.160 * production hours
Others/all *
0.110 * production hours
Connectors/all
0.030 * production hours
Flanges/all
0.084 * production hours
Open-ended lines/all
0.079 * production hours
. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- "Others" :הערה
:( )ק"גVOC חישוב פליטת
Evoc = Etoc * WTvoc/WTtoc
אחוז משקלי- WT כאשר
קצב פליטה- E
TASHAN-LDAR_R-TASH-AL-R4-14
Equations
page 5 of 22
01/01/2014 - 31/12/2014
3.1סיכום שנתי
סיכום לפי סוג הרכיב
סה"כ
רכיבים
אחוז רכיבים
רכיבים
רכיבים
מעל 1,000חל"מ
מעל 1,000חל"מ
לא מתוקנים
סוג
רכיב
מספר
R1
R3
R2
מספר
R5
R4
R1
R6
R3
R2
R5
R4
R1
R6
R2
מצטברת
count
%
R3
פליטה
R4
R5
R1
R6
R3
R2
ק"ג
R4
R6
R5
01/01/2014 - 31/12/2014
משאבות0 :
0
0
0
0
0
0
0
!DIV/0# !DIV/0#
0 !DIV/0#
0
0
0.000
ציוד ערבוב0 :
0
0
0
0
0
0
0
!DIV/0# !DIV/0#
0 !DIV/0#
0
0
0.000
4 :PRD
4
4
4
4
4
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
2.177
נקודות דגימה4 :
4
4
4
4
4
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
3.021
סה"כ קטגוריה 8 :1
8
8
8
8
8
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
5.197
ברזים ושסתומים0 :
0
20
20
0
0
0
0
0
0
0.0% !DIV/0# !DIV/0#
0.0%
0 !DIV/0#
0
0
0
0
1.363
צינורות פתוחים0 :
0
102
102
0
0
0
1
0
0
1.0% !DIV/0# !DIV/0#
0.0%
0 !DIV/0#
0
1
0
0
11.760
סה"כ קטגוריה 0 :2
0
122
122
0
0
0
1
0
0
!DIV/0#
0.8% !DIV/0#
0.0%
0 !DIV/0#
0
1
0
0
13.122
מחברים ואוגנים0 :
0
93
0
0
0
0
0
0.0% !DIV/0# !DIV/0#
0 !DIV/0#
0
0
0
6.501
סה"כ קטגוריה 0 :3
0
93
0
0
0
0
0
!DIV/0#
0.0% !DIV/0#
0 !DIV/0#
0
0
0
6.501
8 :Total
8
223
8
0
0
1
0
0.0%
0.4%
0
0
1
0
24.821
130
8
0
0
0.0%
0.0%
0.0%
0.0%
0
0
סיכום לפי קטגוריית הפליטה
סה"כ רכיבים
R1
#
קטגוריית פליטה
0-9חל"מ 8
R2
#
%
R3
#
%
R4
#
%
R5
#
%
R6
%
%
#
100.0%
7
87.5%
218
97.8%
7
87.5%
130
100.0%
8
100.0%
9-1,000חל"מ 0
0.0%
1
12.5%
4
1.8%
1
12.5%
0
0.0%
0
0.0%
1,000-100,000חל"מ 0
0.0%
1
12.5%
1
0.4%
0
0.0%
0
0.0%
0
0.0%
מעל 100,000חל"מ 0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
סה"כ מעל 1,000חל"מ 0
0.0%
0
0.0%
1
0.4%
0
0.0%
0
0.0%
0
0.0%
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
100.0%
8
112.5%
223
100.0%
8
100.0%
130
100.0%
8
100.0%
רכיבים בלתי נגישים 0
סה"כ8 :
הערות = "R" :מספר של סבב ניטור
page 6 of 22
Cumulative Data
TASHAN-LDAR_R-TASH-AL-R4-14
3.2סיכום תקופת הניטור :סבב 5
3.2.1תוצאות הניטור במדידה הראשונה:
סיכום לפי סוג הרכיב
סוג
סה"כ
רכיבים
רכיבים
קצב פליטה
קצב פליטה
רכיב
רכיבים
9-1000חל"מ
מעל 1,000חל"מ
שעתי
שנתי
מספר
ק"ג/שעה
מספר
משאבות0 :
ציוד ערבוב0 :
4 :PRD
נקודות דגימה4 :
ברזים ושסתומים20 :
צינורות פתוחים102 :
מחברים ואוגנים0 :
סה"כ130 :
מספר
0
0
0
0
0
0
0
0
0.00000
0.00000
0.00002
0.00002
0.00016
0.00020
0.00000
0.00039
0
0
0
0
0
0
0
0
ק"ג/שנה
0.000
0.000
0.140
0.140
1.363
1.782
0.000
3.425
סיכום לפי קטגוריית הפליטה
קטגוריית
סה"כ
אחוז מסה"כ
קצב פליטה
קצב פליטה
אחוז מסה"כ
הפליטה
רכיבים
רכיבים
שעתי
שנתי
קצב פליטה
מספר
%
ק"ג/שעה
שנתי
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
100%
0-9חל"מ 130
9-1,000חל"מ 0
1,000-100,000חל"מ 0
מעל 100,000חל"מ 0
סה"כ מעל 100,000חל"מ 0
רכיבים בלתי נגישים 0
סה"כ130 :
0.00039
0.00000
0.00000
0.00000
0.00000
0.00000
0.00039
ק"ג/שנה
3.425
0.000
0.000
0.000
0.000
0.000
3.425
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
100%
3.2.2תוצאות הניטור אחרי סבב התיקונים:
סיכום לפי סוג הרכיב
סוג
סה"כ
רכיבים
רכיבים
קצב פליטה
קצב פליטה
רכיב
רכיבים
9-1000חל"מ
מעל 1,000חל"מ
שעתי
שנתי
מספר
ק"ג/שעה
מספר
משאבות0 :
ציוד ערבוב0 :
4 :PRD
נקודות דגימה4 :
ברזים ושסתומים20 :
צינורות פתוחים102 :
מחברים ואוגנים0 :
סה"כ130 :
מספר
0
0
0
0
0
0
0
0
0.00000
0.00000
0.00002
0.00002
0.00016
0.00020
0.00000
0.00039
0
0
0
0
0
0
0
0
ק"ג/שנה
0.000
0.000
0.140
0.140
1.363
1.782
0.000
3.425
סיכום לפי קטגוריית הפליטה
קטגוריית
סה"כ
אחוז מסה"כ
קצב פליטה
קצב פליטה
אחוז מסה"כ
הפליטה
רכיבים
רכיבים
שעתי
שנתי
קצב פליטה
מספר
%
ק"ג/שעה
שנתי
0-9חל"מ 130
9-1,000חל"מ 0
1,000-100,000חל"מ 0
מעל 100,000חל"מ 0
סה"כ מעל 100,000חל"מ 0
רכיבים בלתי נגישים 0
סה"כ130 :
page 7 of 22
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
100%
0.00039
0.00000
0.00000
0.00000
0.00000
0.00000
0.00039
Summary
ק"ג/שנה
3.425
0.000
0.000
0.000
0.000
0.000
3.425
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
100%
TASHAN-LDAR_R-TASH-AL-R4-14
3.3סיכום תקופת הניטור :סבב 6
3.3.1תוצאות הניטור במדידה הראשונה:
סיכום לפי סוג הרכיב
סוג
רכיב
רכיבים
9-1000חל"מ
סה"כ
רכיבים
מספר
משאבות0 :
ציוד ערבוב0 :
4 :PRD
נקודות דגימה4 :
ברזים ושסתומים0 :
צינורות פתוחים0 :
מחברים ואוגנים0 :
סה"כ8 :
רכיבים
מעל 1,000חל"מ
קצב פליטה
שעתי
קצב פליטה
שנתי
מספר
ק"ג/שעה
ק"ג/שנה
מספר
0
0
0
0
0
0
0
0
0.00000
0.00000
0.00002
0.00002
0.00000
0.00000
0.00000
0.00003
0
0
0
0
0
0
0
0
0.000
0.000
0.140
0.140
0.000
0.000
0.000
0.280
סיכום לפי קטגוריית הפליטה
קטגוריית
הפליטה
סה"כ
רכיבים
אחוז מסה"כ
רכיבים
קצב פליטה
שעתי
קצב פליטה
שנתי
אחוז מסה"כ
קצב פליטה
שנתי
מספר
%
ק"ג/שעה
ק"ג/שנה
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
100%
0-9חל"מ 8
9-1,000חל"מ 0
1,000-100,000חל"מ 0
מעל 100,000חל"מ 0
סה"כ מעל 100,000חל"מ 0
רכיבים בלתי נגישים 0
סה"כ8 :
0.00003
0.00000
0.00000
0.00000
0.00000
0.00000
0.00003
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
100%
0.280
0.000
0.000
0.000
0.000
0.000
0.280
3.3.2תוצאות הניטור אחרי סבב התיקונים:
סיכום לפי סוג הרכיב
סוג
רכיב
רכיבים
9-1000חל"מ
סה"כ
רכיבים
מספר
משאבות0 :
ציוד ערבוב0 :
4 :PRD
נקודות דגימה4 :
ברזים ושסתומים0 :
צינורות פתוחים0 :
מחברים ואוגנים0 :
סה"כ8 :
מספר
0
0
0
0
0
0
0
0
רכיבים
מעל 1,000חל"מ
קצב פליטה
שעתי
קצב פליטה
שנתי
מספר
ק"ג/שעה
ק"ג/שנה
0.00000
0.00000
0.00002
0.00002
0.00000
0.00000
0.00000
0.00003
0
0
0
0
0
0
0
0
0.000
0.000
0.140
0.140
0.000
0.000
0.000
0.280
סיכום לפי קטגוריית הפליטה
קטגוריית
הפליטה
0-9חל"מ 8
9-1,000חל"מ 0
1,000-100,000חל"מ 0
מעל 100,000חל"מ 0
סה"כ מעל 100,000חל"מ 0
רכיבים בלתי נגישים 0
סה"כ8 :
page 8 of 22
סה"כ
רכיבים
אחוז מסה"כ
רכיבים
קצב פליטה
שעתי
קצב פליטה
שנתי
אחוז מסה"כ
קצב פליטה
שנתי
מספר
%
ק"ג/שעה
ק"ג/שנה
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
100%
0.00003
0.00000
0.00000
0.00000
0.00000
0.00000
0.00003
Summary
0.280
0.000
0.000
0.000
0.000
0.000
0.280
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
100%
TASHAN-LDAR_R-TASH-AL-R4-14
החברה הארצית לבדיקות ושירותי איכות הסביבה
רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.
טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),
E-mail :michael.o@ecologicalab.com
.4סיכום שנתי:
01/01/2014 - 31/12/2014
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
טופס תיקון דליפות שנתי
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור .נתונים מצטברים.
תאריך12/14/2014 :
שם המפעל :תשתיות נפט ואנרגיה בע"מ
דו"ח מס'R-TASH-AL-R4-14 :
סוג
סוג
רכיב
שירות
תקופת חישוב הפליטות01/01/2014 - 31/12/2014 :
שם המתקן :אלרואי
רכיבים עיקריים
סה"כ רכיבים
סה"כ רכיבים מעל 1,000חל"מ
רכיבים בלתי נגישים
רכיבים מ 0-עד 9חל"מ
רכיבים לא מתוקנים
רכיבים מ 1,000-עד 100,000חל"מ
רכיבים מ 9-עד 1,000חל"מ
פליטה משוקללת
רכיבים מעל 100,000חל"מ
תדירות
רכיבים מ 9-עד 1,000חל"מ
מדידות
מספר
R1
R3
R2
מספר
R5
R4
R6
R1
R2
R3
R4
מספר
R5
R6
R1
R2
R3
R4
מספר
R5
R6
R1
R2
R3
R4
מספר
R5
R6
R1
R2
R3
R4
מספר
R5
R6
R1
R3
R2
מספר
R5
R4
R6
R1
R2
R3
R4
מספר
R5
R6
R1
R2
R3
R4
מספר
R5
R6
R1
R2
R3
R4
ק"ג
R5
R6
סבבים/שנה
%
R1
R2
R3
R4
R6
R5
משאבות
6
גז
נוזל קל
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
גז
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
ציוד ערבוב
וערבול
נוזל קל
6
גז
6
PRD
נוזל קל
4
4
4
4
4
4
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
3
4
4
4
4
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
2.177
נקודות
6
גז
דגימה
4
4
4
4
4
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
4
4
3
4
4
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3.021
סה"כ קטגוריה 8 :1
8
8
8
8
8
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
7
8
7
8
8
0
1
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5.197
נוזל קל
6
0.0
0.0
0.0
0.0
0.0
0.0
שסתומים ,ברזים
2
גז
וציוד תלוי
20
נוזל קל
20
0
16
0
0
0
0
0
0
20
20
0
0
0
0
0
0
2
1.363
צינורות פתוחים
2
גז
פוטנציאלים
102
נוזל קל
סה"כ קטגוריה 0 :2
0
122
102
0
122
0
0
0
0
0
0 16
0
0
0
0
0
0
0
0
0
0
0
1
0
0
1
0
0
0
0
0
0
0
0
0
0
97
0
0
0
117
102
0
122
4
0
0
0
4
0
0
0
1
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
11.760
0
13.122
2
0.0
0.8 #### ####
מחברים ואוגנים
1
גז
93
נוזל קל
0
סה"כ קטגוריה 0 :3
0
93
סה"כ רכיבים8 :
8
8 223
סה"כ פליטות:
page 10 of 22
24.82
0
0
0
0
0
93
0
0
6.501
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
93
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6.501
130
8
1
1
1 17
1
1
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
8
7
218
7
130
8
0
1
4
1
0
0
0
0
1
0
0
0
0
0
0
0
0
0
24.821
1
0.0 #### ####
0.0
0.0
0.4
#### #### ####
0.0
0.0
0.0
kg
Form-07 CU
TASHAN-LDAR_R-TASH-AL-R4-14
Correlation Equations Chemical Summary by Component Class
Report Date: 12/14/2014
Calculation Period:
01/01/2014 - 31/12/2014
Units of Measurement:
KG
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
108883
Emissions
0.0000
0.0000
Cyclohexane
0.0000
MTBE
0.0000
n-Octane
Toluene
0.0000
0.0000
0.0000
Chemical Name
CAS Number
Component Class:
1-Butene
108883
Agitators
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Chemical Name
CAS Number
Component Class:
1-Butene
108883
PRD
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
Emissions
0.2177
0.0218
0.1088
0.2177
0.8706
0.7400
2.1766
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.3021
0.0302
0.1510
0.3021
1.2082
1.0270
3.0206
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1363
0.0136
0.0681
0.1363
0.5450
0.4633
1.3625
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
1.1760
0.1176
0.5880
1.1760
4.7040
3.9984
11.7599
TASHAN-LDAR_R-TASH-AL-R4-14
Chem Cu
page 11 of 22
Correlation Equations Chemical Summary by Component Class
Report Date: 12/14/2014
Calculation Period:
01/01/2014 - 31/12/2014
Units of Measurement:
KG
אלרואי
Unit
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.6501
0.0650
0.3251
0.6501
2.6005
2.2104
6.5013
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
2.4821
0.2482
1.2410
2.4821
9.9284
8.4391
24.8209
Grand Total:
24.8209
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-R4-14
Chem Cu
page 12 of 22
Leaker Detail Report
Report Parameters
Alroy
Report: R304_1
ISRAEL
All Classes
Report Date:
Compliance Leak
12/14/2014
Alroy
Details
Class
Location
Tag: 75
POE
Date
Reported
Drawing:
Top of T-1
06/22/2014
Test
Type
Leak
Def
1st Att. Due
Repair Due
Repaired
07/01/2014
07/01/2014
07/06/2014
Date
Event
Result
Technician
Instrument
Method21 Insp
Repair Attempt
Method21 Insp
12500 ppm
04
Sealing
722 ppm
polik
tva
ourievsky
tva
6006-100-007
M
999
6/22/2014 2:46:09 PM
7/6/2014 10:17:32 AM
7/6/2014 10:17:33 AM
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-R4-14
LDAR Report_015 Annual
page 13 of 22
החברה הארצית לבדיקות ושירותי איכות הסביבה
רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.
טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),
E-mail :michael.o@ecologicalab.com
סבב 5
.5תוצאות הניטור במדידה הראשונה
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
טופס :15דו"ח תיקון דליפות למתקן ייצור
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
תאריך12/14/2014 :
דו"ח מס'R-TASH-AL-R4-14 :
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מ 9-עד
1,000חל"מ
מספר
רכיבים
רכיבים
מ 1,000-עד
מעל
100,000חל"מ 100,000חל"מ
מספר
מספר
מספר
קצב
קצב
אחוז
פליטה
פליטה
רכיבים מעל
שעתי
שנתי
1,000חל"מ
ק"ג/שעה
ק"ג/שנה
%
!#DIV/0
נוזל קל
ציוד ערבור
וערבול
נוזל קל
PRD
גז
נוזל קל
נקודות דגימה
!#DIV/0
4
1
0
0
0
4
0
0
0.000016
0.140
4
0
0
0
4
0
0
0
0.000016
סה"כ קטגוריה 8 :1
1
0
0
8
0
0
0
0.000
וציוד תלוי
נוזל קל
צינורות פתוחים
גז
פוטנציאליים
נוזל קל
6
6
0.0%
2
20
0
0
0
0
20
0
0
0.000156
1.363
2
2
102
0
0
0
102
0
0
0
0.000203
1.782
סה"כ קטגוריה 122 :2
0
0
0
122
0
0
0
0.000
3.145
מחברים ואוגנים
2
0.0%
1
גז
1
נוזל קל
סה"כ קטגוריה 0 :3
סה"כ130 :
page 15 of 22
6
6
0.280
ברזים ,שסתומים
6
6
0.140
גז
סבבים/שנה
6
גז
נוזל קל
הניטור
6
גז
גז
תדירות
0
0
0
0
0
0
0
0.000
0.000
1
0
0
130
0
0
0
0.000
3.425
Form-07
!#DIV/0
0.0%
TASHAN-LDAR_R-TASH-AL-R4-14
Correlation Equations Chemical Summary by Component Class
Report Date: 12/14/2014
Units of Measurement:
KG/year
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
108883
Emissions
0.0000
0.0000
Cyclohexane
0.0000
MTBE
n-Octane
0.0000
0.0000
Toluene
0.0000
0.0000
Chemical Name
CAS Number
Component Class:
1-Butene
108883
Agitators
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1782
0.0178
0.0891
0.1782
0.7128
0.6059
1.7821
TASHAN-LDAR_R-TASH-AL-R4-14
Chem
page 16 of 22
Correlation Equations Chemical Summary by Component Class
Report Date: 12/14/2014
Units of Measurement:
KG/year
אלרואי
Unit
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.3425
0.0342
0.1712
0.3425
1.3698
1.1643
3.4245
Grand Total:
3.4245
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-R4-14
Chem
page 17 of 22
Leaker Detail Report
Report Parameters
Alroy
Report: R304_1
ISRAEL
All Classes
Report Date:
Compliance Leak
12/14/2014
Alroy
Details
Class
Location
Date
Reported
Test
Type
Leak
Def
1st Att. Due
Repair Due
Repaired
Date
Event
Result
Technician
Instrument
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-R4-14
LDAR Report_015
page 18 of 22
החברה הארצית לבדיקות ושירותי איכות הסביבה
רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.
טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),
E-mail :michael.o@ecologicalab.com
סבב 5
.6תוצאות הניטור באחרי סבב התיקונים:
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
תאריך12/14/2014 :
דו"ח מס'R-TASH-AL-R4-14 :
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מ 9-עד
1,000חל"מ
מספר
רכיבים
רכיבים
מ 1,000-עד
מעל
100,000חל"מ 100,000חל"מ
מספר
מספר
מספר
קצב
קצב
אחוז
פליטה
פליטה
רכיבים מעל
שעתי
שנתי
1,000חל"מ
ק"ג/שעה
ק"ג/שנה
%
!#DIV/0
נוזל קל
ציוד ערבור
וערבול
נוזל קל
PRD
גז
נוזל קל
נקודות דגימה
!#DIV/0
4
1
0
0
0
4
0
0
0.000016
0.140
4
0
0
0
4
0
0
0
0.000016
סה"כ קטגוריה 8 :1
1
0
0
8
0
0
0
0.000
וציוד תלוי
נוזל קל
צינורות פתוחים
גז
פוטנציאליים
נוזל קל
6
6
0.0%
2
20
0
0
0
0
20
0
0
0.000156
1.363
2
2
102
0
0
0
102
0
0
0
0.000203
1.782
סה"כ קטגוריה 122 :2
0
0
0
122
0
0
0
0.000
3.145
מחברים ואוגנים
2
0.0%
1
גז
1
נוזל קל
סה"כ קטגוריה 0 :3
סה"כ130 :
page 20 of 22
6
6
0.280
ברזים ,שסתומים
6
6
0.140
גז
סבבים/שנה
6
גז
נוזל קל
הניטור
6
גז
גז
תדירות
0
0
0
0
0
0
0
0.000
0.000
1
0
0
130
0
0
0
0.000
3.425
Form-07 Rep
!#DIV/0
0.0%
TASHAN-LDAR_R-TASH-AL-R4-14
Correlation Equations Chemical Summary by Component Class
Report Date: 12/14/2014
Units of Measurement:
KG/year
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
108883
Emissions
0.0000
0.0000
Cyclohexane
0.0000
MTBE
n-Octane
0.0000
0.0000
Toluene
0.0000
0.0000
Chemical Name
CAS Number
Component Class:
1-Butene
108883
Agitators
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1782
0.0178
0.0891
0.1782
0.7128
0.6059
1.7821
TASHAN-LDAR_R-TASH-AL-R4-14
Chem Rep
page 21 of 22
Correlation Equations Chemical Summary by Component Class
Report Date: 12/14/2014
Units of Measurement:
KG/year
אלרואי
Unit
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.3425
0.0342
0.1712
0.3425
1.3698
1.1643
3.4245
Grand Total:
3.4245
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-R4-14
Chem Rep
page 22 of 22
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צ מס' 2המאחס#
קרוסי#
3013.10-013 T2
10/02/2015
18/31
3013.10-015.doc
T2 - kerosene
External Floating roof
1. Tank data
Diameter of the tank
D
Effective height of the stock liquid (while
roof landing episode)
hle
Shell Color and condition
α
Roof color and condition
α
Tank paint solar absorptance
α
Vapor space outage (while roof landing
episode)
HVO
m
feet
m
feet
color
condition
color
condition
dimensionless
m
Tank data
--Tank data
--חאקי
טובה
לבן
טוב
48.77
160.01
11.00
0.89
Table 7.1-6
Assumption - Green Dark
0.17
Table 7.1-6
0.53
Table 7.1-6
Possible to use also equation
1-15
assumption - equal to legs height
feet
11.00
Volume of the vapor space (while roof
landing episode)
Breather vent pressure setting
VV
ft
3
VV=PI()*D /4*Hvo
221,185
Equation 1-3
∆PBP
psi
Typical value
0.50
Equation 1-11
Breather vent vacuum setting
∆PBV
psi
Typical value
0.00
Equation 1-11
Breather vent pressure setting range
∆PB
psi
∆PB = PBP − PBV
0.50
Equation 1-11
2
2. Material data - קרוסין
Stock vapor molecular weight
MV
Density of the liquid inside the tank
Wl
Vapor density
WV
True vapor pressure of the stock liquid
P
Vapor pressure at daily average liquid
surface temperature
Vapor pressure at the daily maximum
liquid surface temperature, psia
Vapor pressure at the daily minimum
liquid surface temperature
Daily vapor pressure range
3013.10-013.xls - 2
gr/gr-mole
lb/lb-mole
g/ml
lb/gal
kg/m^3
lb/ft3
msds data
130
msds data
--msds data
---
0.80
6.68
4.5
0.28
mm Hg
PEI data
0.833
psia
--הנחה:
Pv=nRT -->
P2=P1*(T2/T1)
0.02
0.02
0.02
0.00
PVA
psia
PVX
psia
PVN
psia
T1(k)=20C+273
T2(k)=37.5C+273
∆PV
psia
∆PV = PVX − PVN
1/3
0
at 20°C
0.02
Equation 1-9
02/02/2015
3. Operation data
Number of days that the tank stands idle
(on roof landing episode)
Number of degassing and cleaning
episode
Number of roof landing episode
nd
days/landing episode
site data
4
landing episode/year
site data
0.07
landing episode/year
site data
0.07
Tanks Program
--Tanks Program
---
29
13
75
34
21
Tanks Program
---
60.05
27
lb per emptying
Tanks Program
67
Kg per emptying
---
30
4. Normal operation (Tanks program)
lb per year
Kg per year
lb per year
Kg per year
Kg per year
Working (withdrawal) losses
Total emissions (Breathing & Working)
Breathing (standing) losses
5. Degassing and Cleaning (Tanks program)
Degassing: emission from one turnover of
lb per emptying
Edegass-floating
floating roof
Kg per emptying
Degassing: fixed roof with a height of roof
legs
Edegass-legs
Liquid fraction in sludge
Fliquid
Sludge volume
Sludge weight
Vs
Ws
Cleaning emissions
Ecleaning
Total Degassing and Cleaning emissions
Edegass-total
3013.10-013.xls - 2
0.8
m3 per emptying
Kg per emptying
lb per emptying
Kg per emptying
lb per emptying
Kg per emptying
Ecleaning = Ws * (1-Fliquid)
Edegass-total =
Edegass-floating + Edegass-legs + Ecleaning
2/3
T2 - B&W 2013
T2 - B&W 2013
T4 - DFloating 2014
T2- DFixed 2014
(Only working losses)
Tanks FAQ - degassing and
cleaning
70
56,000
24,692
11,200
24,818
11,257
02/02/2015
6. Roof landing
Daily average liquid surface temperature
TLA
°R
T LA = 0 . 44 T AA + 0 . 56 T B + 0 . 0079 * α * I
534.97
Equation 1-26
Daily vapor temperature range
∆TV
°R
∆ TV = 0 .72 ∆ T A + 0.028 * α * I
41.01
Equation 1-8
Daily maximum liquid surface temperature
TLX
°R
TLX = TLA + 0.25*∆TV
545.22
Figure 7.1-17
Daily minimum liquid surface temperature
TLN
°R
TLN = TLA - 0.25*∆TV
524.71
Figure 7.1-17
Liquid bulk temperature
Max standing idle losses during roof
landing
TB
°R
TB = TAA + 6α - 1
528.15
Equation 1-28
LSL-max
lb per landing episode
Kg per landing episode
dimensionless
2
LSL-max = 5.9*D *hle*W l
--0.60 for a full liquid heel
0.50 for a partial
0.15 for drain-dry
11,093,038 Equation 2-13
5,031,769
0.50
Equation 2-26
(pages No 33,35)
1
KS =
1 + 0.053 * PVA * H VO
0.5
Equation 1-20
KS is assumed to be less than
or equal to the saturation factor
during filling (S) .
∆ TV ∆ PV − ∆ PB
+
T LA
PA − PVA
0.043
Liquid stock has a true vapor
pressure greater than 0.1psia Equation 1-7.
Filling saturation factor
S
saturation factor
KS
dimensionless
Vapor space expansion factor
KE
dimensionless
Standing idle losses during roof landing
LSL
lb per landing episode
PV
L SL = n d K E V M V K S
RT AA
7
Equation 2-16
Filling losses during roof landing
LFL
lb per landing episode
P * VV
M V * S
L FL =
R * T AA
41
Equation 2-26
Total losses during roof landing
LTL
lb per landing episode
Kg per landing episode
48
22
Equation 2-10
KE =
LTL=LSL+LFL
7. Summary
Working (withdrawal) losses
Breathing (standing) losses
Kg per year
Kg per year
13
21
Total Degassing and Cleaning emissions
Kg per year
750
Total losses during roof landing
Kg per year
1
786
3013.10-013.xls - 2
3/3
Kg per year
02/02/2015
נספח ד'
דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 3של קרוסי#
3013.10-014 arm3
10/02/2015
19/31
3013.10-015.doc
Transportation - Loading losses
Loading arm #3 - Kerosene
Density
Tank paint solar absorptance
Daily average ambient temperature
Wl
α
TAA
Yearly consumption
Myear
Cargo tank volume
V
Ntrucks
t
g/ml
dimensionless
°R
ton
m3
gal
3
m
gal
1/year
min
Saturation factor
S
dimensionless
True vapor pressure of liquid
P
Number of tank trucks
Duration of road truck filling
Molecular weight of vapors
Temperature of bulk liquid loaded
M
T=TB
mmHg
psia
lb/lb-mole
°R
Controlled efficiency for the recovery
unit (vapor recovery efficiency)
eff1
%
vapor collection efficiency
eff2
%
overall reduction efficiency
eff
Total loading losses of petroleum
Annual pollutant emission during
loading
Average pollutant emission
concentration during loading
3013.10-014.xls - 3
T = TB = TAA + 6α - 1
LL
%
lb/10 gal
loaded
LL total lb / loading
lb / min
Q
Kg / min
Kg / hr
Etotal
C
0.80
0.40
525.97
318
400
105,669
30.0
7,925
13
30
0.6
Table 5.2-1
0.833
0.02
130
@ 20°C
527.34
0.000
Truck passed the NSPS-level
annual test
70.0
eff=eff1*eff2/100
0
3
Loading losses of petroleum liquids
(uncontrolled emission rate)
Flow rate of pollutant emission
during loading
msds data
site data
"Site" tab @ 3013-037
--data
--data
--Ntrucks = Myear / V
data
Submerge loading, dedicated
normal service
Kg / year
gr / m3
LL = 12.46
S *P*M
eff
1 −
T
100
0.030
LLtoatal = LL*V
Q = Lltoatal / t
-----
0.24
0.008
0.004
0.21
Etotal = LLtotal*Ntruks
1.39
C = Q *t / V
1/1
3.6
Table 7.1-2
Equation 1-28
page 5.2-6
can be 90% to over 99%
page 5.2-6
99.2- for tanker truck passed the
MACT-level annual leak test
98.7- for truck passed the NSPS-level
annual test
70 - for trucks not passing one of
these leak tests
Page 5.2-4 Equation 1
Assumption: the mass of the
pollutant is contained in the air
volume inside the tanker which is
replaced by the liquid loaded
10/02/2015
נספח ה'
חישוב פליטות ממיכל לאיסו תשטיפי
10/02/2015
20/31
3013.10-015.doc
תוכנת :Tanksחישוב פליטה כתוצאה מאחסו #ושינוי מפלס
10/02/2015
21/31
3013.10-015.doc
3013.10-015.doc
22/31
10/02/2015
3013.10-015.doc
23/31
10/02/2015
3013.10-015.doc
24/31
10/02/2015
תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקו #מיכל )שלב א'(
10/02/2015
25/31
3013.10-015.doc
3013.10-015.doc
26/31
10/02/2015
3013.10-015.doc
27/31
10/02/2015
תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקו #מיכל )שלב ב'(
10/02/2015
28/31
3013.10-015.doc
3013.10-015.doc
29/31
10/02/2015
3013.10-015.doc
30/31
10/02/2015
חישובי פליטה ממיכל תשטיפי
גיליו #חישוב זה הוכ #על ידי "פז" הנדסה וניהול ) (1980בע"מ.
אי #להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ) (1980בע"מ.
10/02/2015
31/31
3013.10-015.doc
מסמך 4 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 1430 KB)
זהו קובץ סרוק. הטקסט שלו אינו נקרא כאן, ולכן הוא מופיע בחיפוש לפי הכותרת והפרטים בלבד - הקובץ עצמו זמין בקישור שלמעלה.
מסמך 5 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 2151 KB)
תשתיות פט וארגיה בע"מ
מסוף אלרואי
סיכום פליטות לאוויר
שת 2016
פרויקט3013.12 :
פברואר 2016
תוכן עייים
.1מבוא 4.............................................................................................................................
.2תוי מסוף 5.....................................................................................................................
.2.1תוי מיכלים 5.........................................................................................................
.2.2תוים עבור מסוף מילוי מיכליות כביש 9.....................................................................
.3חישוב פליטות 10 ..............................................................................................................
.3.1כללי 10 ............................................................................................................................
.3.2סוגי פליטות מחושבות 11 ..................................................................................................
.3.3בחירת חומרים בתוכת 11 ................................................................................... TANKS
.3.4תוים מטאורולוגיים11 ....................................................................................................
.4סיכום פליטות לשת 12 ............................................................................................. 2016
.4.1מיכלים 12 ........................................................................................................................
.4.2מסוף מילוי מיכליות כביש 12 .............................................................................................
.4.3מיכל איסוף תשטיפים 13 ...................................................................................................
.4.4סיכום ממצאי יטור 13 .......................................................................................... LDAR
.4.5פליטה שתית מכלל המתקן 13 ...........................................................................................
.5פליטות לא שגרתיות במהלך שת 13 ............................................................................2016
.6מקורות 14 .......................................................................................................................
27/02/2017
2/31
3013.12-015
טבלאות
טבלה :1תוי מיכלים – מידע כללי ,מידות ותוי תפעול – שת 5 .......................................... 2016
טבלה :2תוי מעטפת וגגות – שת 6 ................................................................................. 2016
טבלה :3תוי אביזרים – שת 7 ........................................................................................ 2016
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכת 8 .................................................. TANKS
טבלה :5תוים עבור מסוף מילוי מיכליות כביש – שת 9 ..................................................... 2016
טבלה :6חומרים מייצגים בתוכת 11 ........................................................................... TANKS
טבלה :7סיכום פליטות מכלים -שת 12 ........................................................................... 2016
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שת 12 .................................................2016
טבלה :9סיכום פליטות חומרים אורגים דיפים עבור רכיבים בשת 13 ................................. 2016
טבלה :10סיכום פליטות שתי מכלל מסוף אלרואי – שת 13 ................................................2016
ספחים
ספח א'
טבלה (AP-42) 1-5.2
ספח ב'
תוי יטור LDARעבור מסוף אלרואי – סיכום שת 2016
ספח ג'
דוגמת חישוב עבור מיכל גג חיצוי צף מס' 2המאחסן קרוסין
ספח ד'
דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 3של קרוסין
ספח ה'
חישוב פליטות ממיכל לאיסוף תשטיפים
בן דות
שם עורך
27/02/2017
יואב פיסטיר
שם מאשר
להערות
תיאור
27/02/17
תאריך
3/31
0
גרסה
3013.12-015
.1מבוא
חברת תשתיות פט וארגיה בע"מ )להלן תש"ן( מפעילה את מסוף אלרואי לאחסון ושיוע
דלקים .
המסוף כולל:
•
מבי משרדים
•
חוות מכלים לאחסון דלקים מסוגים שוים
•
רציפי מילוי מכליות כביש )לשימוש בעת חירום בלבד(
המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכות
אלרואי ומדרום לו שכות קרית חרושת.
באתר 9מיכלים ,מתוכם 6מיכלים תפעוליים ו 3-מיכלי מלאי סגור )מיכלים מס' 6 ,4ו.(9-
מערכת השיוע היה באמצעות משאבות ובקרת מילוי ובוסף קיימות מערכות תומכות כגון
מערכות כיבוי אש ומערכות פיקוד ובקרה.
כחלק מהתאים ברישיון עסק מדצמבר ,2010בסוף כל שה קלדרית על תש"ן להגיש דו"ח
סיכום פליטות שתי לגבי השה שחלפה.
חישובי הפליטות בוצעו בעזרת תוכת Tanksומסמכי EPA-AP 42על פי תוי המתקים
הקיימים במסוף.
סיכום הפליטות הוכן על ידי חברת "פז" הדסה ויהול ) (1980בע"מ )להלן פז הדסה( ,והוא
מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות יטור LDARשהוגשו לרשויות.
27/02/2017
4/31
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.2תוי מסוף
.2.1תוי מיכלים
בטבלאות הבאות מפורט מידע טכי של המיכלים בחוות המיכלים אלרואי.
טבלה :1תוי מיכלים – מידע כללי ,מידות ותוי תפעול – שת 2016
מספר
מיכל
סוג הדלק
המאוחסן
1
2
בזין
קרוסין
סולר
הסקה
סולר
סולר
סולר
סולר
קרוסין
קרוסין
3
(1
(2
4
5
(4
6
7
8
(5
9
סה"כ
(3
(1
(2
(3
(4
(5
לחץ אדים
בטמפ' הוזל
הממוצעת
)(mmHg
405 @ 28°C
0.833 @ 28°C
כמות
צריכה
שתית
)מ"ק(
סוג יקוז
בתחתית
מיכל
קוטר
מיכל
)מטר(
פח מיכל
)מ"ק(
פח מיכל
פעיל
)מ"ק(
23,450
33,812
גבעה חלקית
גבעה חלקית
48.77
48.77
32,056
32,056
28,768
28,768
גובה /אורך
מעטפת
מיכל
)מטר(
17.16
17.16
15.4
15.4
0.507 @ 28°C
52,978
גבעה חלקית
48.77
32,056
28,768
17.16
15.4
0.507 @ 28°C
0.507 @ 28°C
0.507 @ 28°C
0.507 @ 28°C
0.833 @ 28°C
0.833 @ 28°C
0
19,573
0
59,137
18,516
0
גבעה חלקית
גבעה מלאה
גבעה מלאה
גבעה מלאה
גבעה חלקית
גבעה חלקית
207,465
48.77
68.27
68.27
68.27
48.8
48.77
32,056
56,959
56,959
56,959
36,547
32,056
367,704
28,768
51,614
51,614
51,614
34,228
28,768
332,913
מיכל מס' 3שופץ בחודשים יואר-פברואר.
מיכל מס' 4שימש כמיכל מלאי ,לא היו תועות במיכל בשת .2016
מיכל מס' 5וקה ובדק במשך 3שבועות במהלך חודש מרץ.
מיכל מס' 6שימש כמיכל מלאי ,לא היו תועות במיכל בשת .2016
מיכל מס' 9שימש כמיכל מלאי ,לא היו תועות במיכל בשת .2016
27/02/2017
5/31
3013.12-015
17.16
15.56
15.56
15.56
19.54
17.16
גובה וזל
מירבי
)מטר(
גובה וזל
ממוצע
)מטר(
10.5
10
9.5
15.4
14.1
14.1
14.1
18.3
15.4
10.3
14.1
14.1
11.4
18.3
9.7
טבלה :2תוי מעטפת וגגות – שת 2016
צורת גג
סוג
חיבורי
גג
צבע
גג
מצב
צבע
גג
צבע
מעטפת
חיצוית
מצב צבע
מעטפת
חיצוית
סוג חיבורי
מעטפת
מצב
מעטפת
פימית
מיכל
מחומם
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חאקי
טוב
מרותך
חלוד הרבה
לא
ללא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
ללא
Pontoon
מרותך
לבן
טוב
חאקי
ישן
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
כחול בהיר
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
מספר
מיכל
סוג גג
אטם ראשי
אטם משי
1
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Liquid
mounted
Mechanical
Shoe
Rim
mounted
Shoe
mounted
2
3
4
5
6
7
8
9
27/02/2017
Shoe
mounted
Shoe
mounted
Shoe
mounted
Rim
mounted
ללא
6/31
3013.12-015
טבלה :3תוי אביזרים – שת 2016
מספר
מיכל
1
2
3
4
5
6
7
8
9
סה"כ
27/02/2017
שובר ואקום
כמות
2
2
2
2
2
2
2
6
2
Vacuum
]set. [psi
0
0
0
0
0
0
0
0
0
Pressure
]set. [psi
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
7/31
רגליים מתכווות התומכות
בגג צף
גובה
כמות באזור
כמות
במרכז
)(ft
pontoon
29
43
11
29
43
11
29
43
11
29
43
11
72
107
11
72
107
11
72
107
11
36
54
9
29
43
11
כמות
מדי
מפלס
Rim
Vent
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
3013.12-015
כמות בוצה
בקיון
)מ"ק(
"גרביים" לבאר
הדיגום המחורצת
ולרגלי הגג הצף
70
70
70
70
150
150
150
70
70
870
יש
יש
יש
יש
יש
יש
יש
יש
יש
החות שלקחו לצורך החישובים
.1עבור חישוב degassingבמיכל עם גג צף – הוח:
•
גג צף ח על רגליים בגובה ) 9-11 ftבהתאם לטבלה לעיל( וזהו גם הגובה המרבי של הוזל
במיכל.
•
גובה ממוצע של הוזל במיכל היו 50%מגובה הוזל המרבי.
.2הוח כי יקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שים .היקיון יארך יום אחד.
.3הוח כי אירוע של חיתת גגות צפים מתבצע אחת ל 15-שים .זמן חיתת הגג במקרה זה לא
יעלה על 4ימים.
.4יחס הוזל בבוצה הוח כ[2] 0.8 -
.5בהתאם לטבלה 7.1-6על פי ] ,[1בחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,
לצורך חישובי פליטות לאוויר:
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכת Tanks
צבע מעטפת
מיכל
צבע לצורך חישובי אקסל
צבע לצורך חישובים בתוכת
בהתאם למסמך EPA AP-42
(*) Tanks
כחול בהיר
Gray Medium
Gray Medium
חאקי
Green Dark
Red/Primer
צהוב קרם
Beige/Cream
Aluminium/Specular
)*( בתוכת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך
.[1] EPA AP-42
27/02/2017
8/31
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.2.2תוים עבור מסוף מילוי מיכליות כביש
טבלה :5תוים עבור מסוף מילוי מיכליות כביש – שת 2016
מס'
זרוע
1
2
3
4
5
6
7
8
מוצר
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
סה"כ
מילוי
עילי /תחתי
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
פח ממוצע של
מיכלית )מ"ק(
30
30
30
30
30
30
30
30
פח מילוי שתי
)מ"ק(
400
100
200
200
200
100
100
83
1,383
החות שלקחו צורך החישובים
.1
מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:
א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:
דוגמת חישוב עבור מיכל מס' :2
0.17 + 0.89
= 0.53
2
=
α roof2 + α Shell2
2
= α tank2
ב .בשלב השי חושב מקדם αממוצע עבור הקרוסין:
0.53 + 0.43 + 0.26
= 0.41
3
=
α tank2 + α tank8 + α tank9
number of kerosene tanks
= α Kerosene
.2
זמן מילוי מיכלית חושב על פי פח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000
ליטר/דקה.
.3
Vapor collection efficiency - 70%
.4
Vapor recovery efficiency - 0%
.5
Saturation factorהוח כ (Submerged loading, dedicated normal service) 0.6-על פי
] .[1טבלה רלווטית מצורפת בספח א'.
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.3חישוב פליטות
.3.1כללי
חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכת Tanksובעזרת .[1] EPA-AP 42
הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ) (LDARמצורפת בספח ב'.
דוגמת חישוב עבור מיכל גג חיצוי צף )מיכל מס' (2המאחסן קרוסין ,מצורפת כספח ג' למסמך
זה.
דוגמת חישוב עבור זרוע מילוי עילי של קרוסין )זרוע מס' (2מצורפת כספח ד' למסמך זה.
בדוגמאות אלה יתן לראות את תוי הקלט )כולל החות( עליהם התבססו החישובים.
27/02/2017
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.3.2סוגי פליטות מחושבות
הערכת הפליטות ממיכלי אחסון כוללת ]:[3
• פליטות בזמן אחסון )(Breathing Losses
• פליטות משיויי מפלס )(Working Losses
• פליטות כתוצאה מיקוי וריקון מיכלים )(Degassing Losses
• פליטות כתוצאה מחיתת גגות צפים )(Roof Landing Losses
• פליטות כתוצאה מהפרשי לחץ )(Flash Losses
• פליטות בזמן מילוי מיכלים ומיכליות
בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ
).(Flash Losses
פליטות אלה רלווטיות לשיויי פתאומי\מיידי בלחץ הוזל ,תון הגורם להפרת שיווי המשקל
הקיים במיכל )בין גז לוזל( וכתוצאה מכך וצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הוזל
עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר וזל המאוחסן בלחץ שלח
לאחסון במיכל בעל לחץ מוך יותר ].[3
פליטות אלו הוזחו כיוון שכל החומרים מוחזקים בתאים אטמוספריים בכל אחד מהשלבים
הוגעים להובלתם ואחסום ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.
.3.3בחירת חומרים בתוכת Tanks
על פי תוי MSDSשל הדלקים במסוף ,בחרו החומרים הבאים הקיימים בתוכת Tanks
כמייצגים של חומרים אלו:
טבלה :6חומרים מייצגים בתוכת Tanks
דלק קיים במסוף
חומר מייצג בתוכת Tanks
סולר )תחבורה והסקה(
Distillate fuel oil no 2
פט )קרוסין(
Jet kerosene
בזין
Gasoline RVP 10
.3.4תוים מטאורולוגיים
לצורך חישוב התוים בתוכת Tanksהוגדרו תוים מטאורולוגים המתאימים למפרץ חיפה על פי
מקורות ].[4
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.4סיכום פליטות לשת 2016
.4.1מיכלים
סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:
טבלה :7סיכום פליטות מכלים -שת 2016
מיכל
חומר
1
בזין
פליטות לאוויר
)ק"ג/שה(
4,114
2
קרוסין
803
3
סולר הסקה
67
4
סולר
826
5
סולר
1,610
6
סולר
1,695
7
סולר
1,733
8
קרוסין
774
9
קרוסין
792
סה"כ
12,414
.4.2מסוף מילוי מיכליות כביש
להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שת 2016
27/02/2017
מס' זרוע
מוצר
מילוי עילי /תחתי
פליטה שתית )ק"ג(
1
2
3
4
5
6
7
8
סה"כ
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
1.39
0.32
0.75
0.75
0.75
0.32
0.32
0.32
4.91
12/31
3013.12-015
.4.3מיכל איסוף תשטיפים
סך הפליטה ממיכל לאיסוף תשטיפים היה כ 1 -ק"ג/שה.
חישוב מצורף בספח ה'.
יצוין כי החישוב מתבסס על החה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל
בעיקר יקוז מים מהמכלים.
.4.4סיכום ממצאי יטור LDAR
טבלה :9סיכום פליטות חומרים אורגים דיפים עבור רכיבים בשת 2016
סה"כ פליטות )ק"ג/שה(
סיכום פליטות LDAR
פליטה שתית )ק"ג/שה(
סה"כ
40.3
.4.5פליטה שתית מכלל המתקן
טבלה :10סיכום פליטות שתי מכלל מסוף אלרואי – שת 2016
סה"כ פליטות )ק"ג/שה(
חוות מיכלים
מסוף מילוי
מיכליות כביש
מיכל לאיסוף
תשטיפים
12,414
4.91
1
סיכום פליטות
רכיבים
סה"כ
)(LDAR
40.3
12,460
.5פליטות לא שגרתיות במהלך שת 2016
במהלך שת 2016לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמיל.
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.6מקורות
[1] EPA-AP42
[2] USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version
4.0 - APPENDIX D
] [3החיות הממוה לטיפול בבקשה להיתר פליטה לפי סעיף )9א( לתקות אוויר קי )היתרי פליטה(,
התש"ע – ,2010מהדורה ,4ספטמבר 2014
] [4האטלס האקלימי לתכון פיסי וסביבתי בישראל ,מהדורה שיה1994 ,
27/02/2017
14/31
3013.12-015
ספח א'
טבלה 5.2-1
AP-42
27/02/2017
15/31
3013.12-015
3013.12-015
16/31
27/02/2017
ספח ב'
תוי יטור LDARעבור אלרואי – סיכום שת 2016
)מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך (27.02.2016
3013.12-008A
27/02/2017
17/31
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LDAR
דו"ח איתור
דליפות מרכיבי ציוד מס'
R-TASH-AL-A-16
מפעל :תשתיות נפט ואנרגיה בע"מ
ישוב :קרית טבעון
מחוז :חיפה
מתקן :אלרואי
קטגורייה1-3 :
תקופת הניטור :סיכום 2016
תאריך הדפסת הדו"ח27-Feb-17 :
שמות אנשי צוות :מקסים טומרוב
סרגיי קוש
סלבה פוליק
יאן פורצלן
עורך הדו"ח :מיכאל אורייבסקי
מאשר הדו"ח :אלכסי רטנר ,מנכ"ל
This report produced using Orr LeakDAS software.
תוכן עניינים
1תיאור הפרויקט:
• סיכום ביצוע
• שלבי הפרויקט
2מתודולוגיה:
• הגדרות
• מתודולוגיה
• אופן ביצוע חישובים
3סיכום תקופת הניטור:
• סיכום של שנת :2016
3
3
4
4
4
01/01/2016 - 31/12/2016
4סיכום תקופה01/01/2016 - 31/12/2016 :
• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
• פילוג לחומרים הנפלטים
• טופס תיקון דליפות חצי שנתי
6
8
9
11
סבב 1
5תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:
• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
• פילוג לחומרים הנפלטים
• טופס :15דו"ח תיקון דליפות למתקן ייצור
6
סבב 2
6תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:
• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
• פילוג לחומרים הנפלטים
• טופס :15דו"ח תיקון דליפות למתקן ייצור
21
23
27
סבב 3
7תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:
• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
• פילוג לחומרים הנפלטים
• טופס :15דו"ח תיקון דליפות למתקן ייצור
29
31
35
סבב 4
8תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:
• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
• פילוג לחומרים הנפלטים
• טופס :15דו"ח תיקון דליפות למתקן ייצור
37
39
43
סבב 5
9תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:
• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
• פילוג לחומרים הנפלטים
• טופס :15דו"ח תיקון דליפות למתקן ייצור
45
47
51
סבב 6
10תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:
• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
• פילוג לחומרים הנפלטים
• טופס :15דו"ח תיקון דליפות למתקן ייצור
53
55
59
page 2 of 59
INDEX-A
13
15
19
TASHAN-LDAR_R-TASH-AL-A-16
1תיאור הפרוייקט:
1.1סיכום ביצוע:
הניטור בוצע לסוגי הרכיבים הבאים:
קטגוריה :1משאבות ,ציוד ערבוב וערבול ,PRD ,נקודות דגימה.
6סבבי הניטור בשנה.
קטגוריה :2ברזים,שסתומים וצינורות פתוחים פוטנציאליים.
2סבבי הניטור בשנה.
קטגוריה :3מחברים ואוגנים.
סבב ניטור אחד בשנה.
1.2שלבי הפרויקט:
● ניטור רכיבים
● במהלך רבעון בוצעו שני סבבי הניטור לרכיבי ציוד מקטגוריה 1במתקן אלרואי
● ניטור חוזר אחרי תיקון הדליפות.
● עדכון בסיס הנתונים.
● עדכון תזרימים .P&ID
1.3יחידות ציוד לניטור )כל המתקנים(:
מסוף
אלרואי
מסוף נמל
הדלק
מס' מיכל
מס' מיכל
מס' מיכל
מס' מיכל
מס' מיכל
מס' מיכל
T-44
T-95
T-133
T-140
T-1
T-113
T-127
T-134
T-136
קווי צנרת
קווי צנרת
T-164
T-69
T-128
T-137
T-74
T-129
T-138
T-94
T-131
T-139
טרמינל קרית חיים
T-165
קווי צנרת
בחוות
המיכלים
מערכת
VRU
הערות:
.1מתקן VRUשבמתקן נמל הדלק לא נבדק עקב חוסר הפעילות.
מפלס גג המיכל T-113שבנמל הדלק היה נמוך במשך תקופת הניטור ,לכן
המיכל לא נבדק מטעמי הבטיחות.
.3המיכל T-45במתקן טרמינל אינו פעיל ,לכן לא נבדק מ.03/08/2015-
מיכל T-134חזר לפעילות ונבדק במסגרת הסבב.
הערות כלליות:
.1חברת "מעבדות אקולוגיה א.פ .בע"מ" מוסמכת לתקן ISO-17025
ISO-17025לביצוע בדיקות LDARע"י ) ISRACהרשות להסמכת מעבדות(.
.2הרשות להסמכת מעבדות אינה אחראית על תוצאות הבדיקות.
page 3 of 59
Project Introduction
TASHAN-LDAR_R-TASH-AL-A-16
2מתודולוגיה:
2.1הגדרות:
נוזל קל :כל נוזל עם יותר מ 10% -נפחי של VOCהמתנדף ב 150-מעלות צלסיוס.
נוזל כבד :כל נוזל עם 10%נפחי של VOCאו פחות המתנדף ב 150-מעלות צלסיוס.
דליפה :גילוי של ריכוז TOCבפאזה גזית בסך 1,000חל"מ או יותר.
רכיב בלתי נגיש :כל רכיב הממוקם בגובה של יותר מ 5-מ' מעל הקרקע ,כאשר נדרשת גישה מהקרקע,
או כל רכיב הממוקם במרחק של יותר מ 2-מ' מפלטפורמה ,כאשר נדרשת גישה
מפלטפורמה ,ולא ניתן לגשת אליהם בצורה בטיחותית ע"י העובד ,או כל רכיב העלול
להצריך את הרתמתם של אנשי צוות ניטור לגובה של יותר מ 2-מ' מעל למשטחי
תמיכה קבועים ולא ניתן לגשת אליו בצורה בטיחותית.
2.2אופן ביצוע חישובים:
נוסחאות :חישוב הפליטות מדליפות מרכיבי ציוד נעשה בהתאם לגישת הקורלציה המפורטת
בפרוטוקול ה EPA-עבור תעשיה פטרוכימית.
US EPA "Protocol for equipment leak emission estimates",1995
"נתונים מצטברים" :בטבלאות "נתונים מצטברים" אנחנו מציגים תוצאות של כל המדידות שבוצעו מתחילת
השנה ועד סוף תקופת הניטור הנוכחית )שנה(.
חישוב הפליטה המצטברת נעשה בהתאם לModified Trapezoidal Method-
US EPA "Emission Estimation Protocol for Petroleum Refineries",Ver.2.1.1, 2011
page 4 of 59
Methodology
TASHAN-LDAR_R-TASH-AL-A-16
- חישוב קצב פליטה שעתי ושנתי מרכיבי ציוד בוצע בהתאם ל2.3
)בהמשךProtocol for equipment leak emission estimates,2.0. (EPA,1995)
."Petroleum Industry" "פרוטוקול"( סקטור תעשייה רלוונטי הינו
: חל"מ9 ≤ דליפות
Equipment type
kg/year
Valves/all
2.29E-06 * (measured ppm value)^0.746 * production hours
Pump seals/all
5.03E-05 * (measured ppm value)^0.610 * production hours
Others/all *
1.36E-05 * (measured ppm value)^0.589 * production hours
Connectors/all
1.53E-06 * (measured ppm value)^0.735 * production hours
Flanges/all
4.61E-06 * (measured ppm value)^0.703 * production hours
Open-ended lines/all
2.20E-06 * (measured ppm value)^0.704 * production hours
. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- Others :הערה
: חל"מ9 > דליפות
Equipment type
kg/year
Valves/all
7.80E-06 * production hours
Pump seals/all
2.40E-05 * production hours
Others/all *
4.00E-06 * production hours
Connectors/all
7.50E-06 * production hours
Flanges/all
3.10E-07 * production hours
Open-ended lines/all
2.00E-06 * production hours
. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- "Others" :הערה
: חל"מ100,000 < דליפות
Equipment type
kg/year
Valves/all
0.140 * production hours
Pump seals/all
0.160 * production hours
Others/all *
0.110 * production hours
Connectors/all
0.030 * production hours
Flanges/all
0.084 * production hours
Open-ended lines/all
0.079 * production hours
. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- "Others" :הערה
:( )ק"גVOC חישוב פליטת
Evoc = Etoc * WTvoc/WTtoc
אחוז משקלי- WT כאשר
קצב פליטה- E
TASHAN-LDAR_R-TASH-AL-A-16
Equations
page 5 of 59
31/12/2016 - 01/01/2016
סיכום התוצאות:
סוג
רכיב
R2
R1
סיכום לפי סוג הרכיב
סה"כ
רכיבים
רכיבים
מעל 1,000חל"מ
מעל 1,000חל"מ
מספר
מספר
%
R3
R5
R4
R1
R6
R3
R2
R5
R4
R1
R6
R2
אחוז רכיבים
רכיבים
לא מתוקנים
count
R3
R4
R5
R1
R6
R3
R2
פליטה
מצטברת
ק"ג
R4
R6
R5
01/01/2016 - 31/12/2016
משאבות0 :
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.000
ציוד ערבוב0 :
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.000
4 :PRD
4
4
4
4
4
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
0.198
נקודות דגימה4 :
4
4
4
4
4
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
1.389
סה"כ קטגוריה 8 :1
8
8
8
8
8
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
1.587
ברזים ושסתומים0 :
0
20
0
20
0
0
0
0
0
0
0
0.0%
0.0%
0
0
0
0
0
0
1.366
צינורות פתוחים0 :
0
102
0
102
0
0
0
0
0
0
0
0.0%
0.0%
0
0
0
0
0
0
29.041
סה"כ קטגוריה 0 :2
0
122
0
122
0
0
0
0
0
0
0
0.0%
0.0%
0
0
0
0
0
0
30.407
מחברים ואוגנים0 :
0
93
0
0
0
0
0
0
0
0
0
0.0%
0
0
0
0
0
0
8.342
סה"כ קטגוריה 0 :3
0
93
0
0
0
0
0
0
0
0
0
8 :Total
8
223
8
130
8
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
8.342
0
0
0
0
0
0
40.337
סיכום לפי קטגוריית הפליטה
סה"כ רכיבים
R1
#
קטגוריית פליטה
0-9חל"מ 8
R2
#
%
R3
#
%
R4
#
%
R5
#
%
R6
%
%
#
100.0%
7
87.5%
185
83.0%
7
87.5%
123
94.6%
8
100.0%
9-1,000חל"מ 0
0.0%
1
12.5%
38
17.0%
1
12.5%
7
5.4%
0
0.0%
1,000-100,000חל"מ 0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
מעל 100,000חל"מ 0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
סה"כ מעל 1,000חל"מ 0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
רכיבים בלתי נגישים 0
סה"כ8 :
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
0
0.0%
100.0%
8
100.0%
223
100.0%
8
100.0%
130
100.0%
8
100.0%
הערות = "R" :מספר של סבב ניטור
page 6 of 59
Cumulative Data
TASHAN-LDAR_R-TASH-AL-A-16
.4סיכום:
01/01/2016 - 31/12/2016
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
טופס תיקון דליפות
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור .נתונים מצטברים.
תאריך:
2/27/2017
שם המפעל :תשתיות נפט ואנרגיה בע"מ
דו"ח מס'R-TASH-AL-A-16 :
סוג
סוג
רכיב
שירות
סה"כ רכיבים
שם המתקן :אלרואי
רכיבים עיקריים
סה"כ רכיבים מעל 1,000חל"מ
רכיבים בלתי נגישים
תקופת חישוב הפליטות01/01/2016 - 31/12/2016 :
רכיבים מ 0-עד 9חל"מ
רכיבים לא מתוקנים
רכיבים מ 1,000-עד 100,000חל"מ
רכיבים מ 9-עד 1,000חל"מ
פליטה משוקללת
רכיבים מעל 100,000חל"מ
תדירות
רכיבים מעל 1,000חל"מ
מדידות
מספר
R1
R3
R2
מספר
R4
R6
R5
מספר
מספר
מספר
מספר
R1
R3
R2
מספר
R4
R6
R5
מספר
מספר
R1
R2
R3
R4
R5
R6
R1
R2
R3
R4
R5
R6
R1
R2
R3
R4
R5
R6
R1
R2
R3
R4
R5
R6
גז
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
נוזל קל
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
גז
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
נוזל קל
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
גז
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
נוזל קל
4
4
4
4
4
4
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
4
4
4
4
4
גז
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
נוזל קל
4
4
4
4
4
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
4
3
3
3
4
4
0
1
סה"כ קטגוריה 8 :1
8
8
8
8
8
1
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
7
7
7
8
8
0
1
1
גז
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
נוזל קל
0
0
20
0
20
0
0
0
0 16
0 16
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
20
0
20
0
0
0
0
0
0
גז
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
נוזל קל
0
0
102
0
102
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
67
0
95
0
0
0
0 35
7
0
0
סה"כ קטגוריה 0 :2
0
122
0
122
0
0
0
0 16
0 16
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
87
0
115
0
0
0
0 35
7
0
0
0
גז
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
נוזל קל
0
0
93
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
91
0
0
0
0
0
2
0
0
0
0
0
0
0
סה"כ קטגוריה 0 :3
0
93
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
91
0
0
0
0
0
2
0
0
0
0
0
0
0
0
סה"כ רכיבים8 :
8
223
8
130
8
1
1
1 17
1 17
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
7
185
7
123
8
0
1
1 38
7
0
0
0
0
0
0
סה"כ פליטות:
40.34
kg
%
ק"ג
R1
R2
R3
סבבים/שנה
R4
R6
R5
R1
R2
R3
R4
R5
R6
R1
R2
R3
R4
R5
R6
R1
R2
R3
R4
R5
R6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1.389
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1.587
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
29.041
0
0
0
0
0
0
0
0
0
0
30.407
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8.342
0
0
0
0
0
0
0
8.342
0
0
0
0
0
0
0
40.337
משאבות
ציוד ערבוב
וערבול
PRD
6
0.198
נקודות
6
דגימה
6
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
שסתומים ,ברזים
2
וציוד תלוי
2
1.366
צינורות פתוחים
2
פוטנציאלים
2
0.0%
0.0%
מחברים ואוגנים
page 8 of 59
Form-07 CU
1
1
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
TASHAN-LDAR_R-TASH-AL-A-16
Correlation Equations Chemical Summary by Component Class
Report Date: 2/27/2017
Calculation Period: 01/01/2016 - 31/12/2016
Units of Measurement:
KG
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0198
0.0020
0.0099
0.0198
0.0794
0.0675
0.1984
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1389
0.0139
0.0695
0.1389
0.5556
0.4723
1.3890
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1366
0.0137
0.0683
0.1366
0.5465
0.4645
1.3662
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
2.9041
0.2904
1.4521
2.9041
11.6164
9.8739
29.0410
TASHAN-LDAR_R-TASH-AL-A-16
Chem Cu
page 9 of 59
Correlation Equations Chemical Summary by Component Class
Report Date: 2/27/2017
Calculation Period: 01/01/2016 - 31/12/2016
Units of Measurement:
KG
אלרואי
Unit
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.8342
0.0834
0.4171
0.8342
3.3369
2.8364
8.3423
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
4.0337
0.4034
2.0168
4.0337
16.1348
13.7145
40.3369
Grand Total:
40.3369
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem Cu
page 10 of 59
Leaker Detail Report
Report Parameters
Alroy
Report: R304_1
ISRAEL
All Classes
Monitoring Period:
Compliance Leak
01/01/2016 - 31/12/2016
Alroy
Details
Class
Location
Date
Reported
Test
Type
Leak
Def
1st Att. Due
Repair Due
Repaired
Date
Event
Result
Technician
Instrument
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
LDAR Report_015 A
page 11 of 59
החברה הארצית לבדיקות ושירותי איכות הסביבה
רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.
טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),
E-mail :michael.o@ecologicalab.com
סבב 1
תוצאות הניטור:
מדידה ראשונה ואחרי סבב התיקונים
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
טופס :15דו"ח תיקון דליפות למתקן ייצור
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R1 :
שלב הניטור :מדידה ראשונה
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
0.140
גז
נוזל קל
page 13 of 59
4
1
0
0
4
0
0
0
0.000016
6
6
4
0
0
0
4
0
0
0
0.000016
6
0.140
סה"כ קטגוריה 8 :1
1
0
0
8
0
0
0
0.000
0.280
0.0%
סה"כ8 :
1
0
0
8
0
0
0
0.000
0.280
0.0%
Form-07 R1
TASHAN-LDAR_R-TASH-AL-A-16
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R1 :
שלב הניטור :אחרי סבב תיקונים
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
0.140
גז
נוזל קל
page 14 of 59
4
1
0
0
4
0
0
0
0.000016
6
6
4
0
0
0
4
0
0
0
0.000016
6
0.140
סה"כ קטגוריה 8 :1
1
0
0
8
0
0
0
0.000
0.280
0.0%
סה"כ8 :
1
0
0
8
0
0
0
0.000
0.280
0.0%
Form-07 R1
TASHAN-LDAR_R-TASH-AL-A-16
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R1
KG/year
First measurement
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
TASHAN-LDAR_R-TASH-AL-A-16
Chem R1
page 15 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
Connections & Flanges
Units of Measurement:
R1
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0280
0.0028
0.0140
0.0280
0.1118
0.0951
0.2796
Grand Total:
0.2796
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R1
page 16 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R1
KG/year
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
TASHAN-LDAR_R-TASH-AL-A-16
Chem R1
page 17 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
All
Units of Measurement:
R1
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0280
0.0028
0.0140
0.0280
0.1118
0.0951
0.2796
Grand Total:
0.2796
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R1
page 18 of 59
Leaker Detail Report
Report Parameters
Alroy
Report: R304_1
ISRAEL
All Classes
Monitoring Period:
Compliance Leak
R1
Alroy
Details
Class
Location
Date
Reported
Test
Type
Leak
Def
1st Att. Due
Repair Due
Repaired
Date
Event
Result
Technician
Instrument
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
LDAR Report_015 R1
page 19 of 59
החברה הארצית לבדיקות ושירותי איכות הסביבה
רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.
טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),
E-mail :michael.o@ecologicalab.com
סבב 2
תוצאות הניטור:
מדידה ראשונה ואחרי סבב התיקונים
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
טופס :15דו"ח תיקון דליפות למתקן ייצור
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R2 :
שלב הניטור :מדידה ראשונה
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
0.140
גז
נוזל קל
page 21 of 59
4
1
0
0
4
0
0
0
0.000016
6
6
4
0
0
0
3
1
0
0
0.000201
6
1.765
סה"כ קטגוריה 8 :1
1
0
0
7
1
0
0
0.000
1.905
0.0%
סה"כ8 :
1
0
0
7
1
0
0
0.000
1.905
0.0%
Form-07 R2
TASHAN-LDAR_R-TASH-AL-A-16
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R2 :
שלב הניטור :אחרי סבב תיקונים
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
0.140
גז
נוזל קל
page 22 of 59
4
1
0
0
4
0
0
0
0.000016
6
6
4
0
0
0
3
1
0
0
0.000201
6
1.765
סה"כ קטגוריה 8 :1
1
0
0
7
1
0
0
0.000
1.905
0.0%
סה"כ8 :
1
0
0
7
1
0
0
0.000
1.905
0.0%
Form-07 R2
TASHAN-LDAR_R-TASH-AL-A-16
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R2
KG/year
First measurement
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1765
0.0177
0.0883
0.1765
0.7060
0.6001
1.7650
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
TASHAN-LDAR_R-TASH-AL-A-16
Chem R2
page 23 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
Connections & Flanges
Units of Measurement:
R2
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1905
0.0190
0.0952
0.1905
0.7619
0.6476
1.9048
Grand Total:
1.9048
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R2
page 24 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R2
KG/year
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1765
0.0177
0.0883
0.1765
0.7060
0.6001
1.7650
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
TASHAN-LDAR_R-TASH-AL-A-16
Chem R2
page 25 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
All
Units of Measurement:
R2
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1905
0.0190
0.0952
0.1905
0.7619
0.6476
1.9048
Grand Total:
1.9048
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R2
page 26 of 59
Leaker Detail Report
Report Parameters
Alroy
Report: R304_1
ISRAEL
All Classes
Monitoring Period:
Compliance Leak
R2
Alroy
Details
Class
Location
Date
Reported
Test
Type
Leak
Def
1st Att. Due
Repair Due
Repaired
Date
Event
Result
Technician
Instrument
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
LDAR Report_015 R2
page 27 of 59
סבב 3
תוצאות הניטור:
מדידה ראשונה ואחרי סבב התיקונים
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
טופס :15דו"ח תיקון דליפות למתקן ייצור
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R3 :
שלב הניטור :מדידה ראשונה
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
מספר
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
6
4
0
0
0
3
1
0
0
0.000111
0.968
סה"כ קטגוריה 8 :1
1
0
0
7
1
0
0
0.000
1.108
ברזים ,שסתומים
גז
וציוד תלוי
נוזל קל
צינורות פתוחים
גז
פוטנציאליים
נוזל קל
6
0.0%
2
20
16
0
0
0
20
0
0
0.000156
1.363
2
2
102
0
0
0
67
35
0
0
0.004336
37.986
סה"כ קטגוריה 122 :2
16
0
0
87
35
0
0
0.004
39.349
2
0.0%
גז
93
1
93
סה"כ קטגוריה 93 :3
סה"כ223 :
page 29 of 59
4
0.140
גז
נוזל קל
מחברים ואוגנים
4
1
0
0
0
0
0
0.000016
6
0
0
0
2
91
0
0
0.001074
1
9.407
0
0
0
91
2
0
0
0.001
9.407
0.0%
17
0
0
185
38
0
0
0.006
49.864
0.0%
Form-07 R3
TASHAN-LDAR_R-TASH-AL-A-16
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R3 :
שלב הניטור :אחרי סבב תיקונים
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
מספר
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
6
4
0
0
0
3
1
0
0
0.000111
0.968
סה"כ קטגוריה 8 :1
1
0
0
7
1
0
0
0.000
1.108
ברזים ,שסתומים
גז
וציוד תלוי
נוזל קל
צינורות פתוחים
גז
פוטנציאליים
נוזל קל
6
0.0%
2
20
16
0
0
0
20
0
0
0.000156
1.363
2
2
102
0
0
0
67
35
0
0
0.004336
37.986
סה"כ קטגוריה 122 :2
16
0
0
87
35
0
0
0.004
39.349
2
0.0%
גז
נוזל קל
1
93
סה"כ קטגוריה 93 :3
סה"כ223 :
page 30 of 59
4
0.140
גז
נוזל קל
מחברים ואוגנים
4
1
0
0
0
0
0
0.000016
6
0
0
0
2
91
0
0
0.001074
1
9.407
0
0
0
91
2
0
0
0.001
9.407
0.0%
17
0
0
185
38
0
0
0.006
49.864
0.0%
Form-07 R3
TASHAN-LDAR_R-TASH-AL-A-16
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R3
KG/year
First measurement
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0968
0.0097
0.0484
0.0968
0.3873
0.3292
0.9682
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
3.7986
0.3799
1.8993
3.7986
15.1945
12.9153
37.9862
TASHAN-LDAR_R-TASH-AL-A-16
Chem R3
page 31 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
Connections & Flanges
Units of Measurement:
R3
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.9407
0.0941
0.4704
0.9407
3.7630
3.1985
9.4074
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
4.9864
0.4986
2.4932
4.9864
19.9458
16.9539
49.8644
Grand Total:
49.8644
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R3
page 32 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R3
KG/year
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0968
0.0097
0.0484
0.0968
0.3873
0.3292
0.9682
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
3.7986
0.3799
1.8993
3.7986
15.1945
12.9153
37.9862
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.9407
0.0941
0.4704
0.9407
3.7630
3.1985
9.4074
TASHAN-LDAR_R-TASH-AL-A-16
Chem R3
page 33 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
All
Units of Measurement:
R3
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
4.9864
0.4986
2.4932
4.9864
19.9458
16.9539
49.8644
Grand Total:
49.8644
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R3
page 34 of 59
Leaker Detail Report
Report Parameters
Alroy
Report: R304_1
ISRAEL
All Classes
Monitoring Period:
Compliance Leak
R3
Alroy
Details
Class
Location
Date
Reported
Test
Type
Leak
Def
1st Att. Due
Repair Due
Repaired
Date
Event
Result
Technician
Instrument
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
LDAR Report_015 R3
page 35 of 59
החברה הארצית לבדיקות ושירותי איכות הסביבה
רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.
טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),
E-mail :michael.o@ecologicalab.com
סבב 4
תוצאות הניטור:
מדידה ראשונה ואחרי סבב התיקונים
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
טופס :15דו"ח תיקון דליפות למתקן ייצור
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R4 :
שלב הניטור :מדידה ראשונה
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
0.140
גז
נוזל קל
page 37 of 59
4
1
0
0
4
0
0
0
0.000016
6
6
4
0
0
0
3
1
0
0
0.000154
6
1.350
סה"כ קטגוריה 8 :1
1
0
0
7
1
0
0
0.000
1.490
0.0%
סה"כ8 :
1
0
0
7
1
0
0
0.000
1.490
0.0%
Form-07 R4
TASHAN-LDAR_R-TASH-AL-A-16
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R4 :
שלב הניטור :אחרי סבב תיקונים
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
0.140
גז
נוזל קל
page 38 of 59
4
1
0
0
4
0
0
0
0.000016
6
6
4
0
0
0
3
1
0
0
0.000154
6
1.350
סה"כ קטגוריה 8 :1
1
0
0
7
1
0
0
0.000
1.490
0.0%
סה"כ8 :
1
0
0
7
1
0
0
0.000
1.490
0.0%
Form-07 R4
TASHAN-LDAR_R-TASH-AL-A-16
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R4
KG/year
First measurement
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1350
0.0135
0.0675
0.1350
0.5400
0.4590
1.3500
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
TASHAN-LDAR_R-TASH-AL-A-16
Chem R4
page 39 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
Connections & Flanges
Units of Measurement:
R4
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1490
0.0149
0.0745
0.1490
0.5959
0.5065
1.4898
Grand Total:
1.4898
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R4
page 40 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R4
KG/year
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1350
0.0135
0.0675
0.1350
0.5400
0.4590
1.3500
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
TASHAN-LDAR_R-TASH-AL-A-16
Chem R4
page 41 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
All
Units of Measurement:
R4
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1490
0.0149
0.0745
0.1490
0.5959
0.5065
1.4898
Grand Total:
1.4898
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R4
page 42 of 59
Leaker Detail Report
Report Parameters
Alroy
Report: R304_1
ISRAEL
All Classes
Monitoring Period:
Compliance Leak
R4
Alroy
Details
Class
Location
Date
Reported
Test
Type
Leak
Def
1st Att. Due
Repair Due
Repaired
Date
Event
Result
Technician
Instrument
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
LDAR Report_015 R4
page 43 of 59
החברה הארצית לבדיקות ושירותי איכות הסביבה
רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.
טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),
E-mail :michael.o@ecologicalab.com
סיכום 2016
תוצאות הניטור:
מדידה ראשונה ואחרי סבב התיקונים
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
טופס :15דו"ח תיקון דליפות למתקן ייצור
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R5 :
שלב הניטור :מדידה ראשונה
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
4
0.140
גז
נוזל קל
6
4
0
0
0
4
0
0
0
0.000016
0.140
סה"כ קטגוריה 8 :1
1
0
0
8
0
0
0
0.000
0.280
ברזים ,שסתומים
גז
וציוד תלוי
נוזל קל
צינורות פתוחים
גז
פוטנציאליים
נוזל קל
page 45 of 59
4
1
0
0
0
0
0
0.000016
6
6
0.0%
2
20
16
0
0
0
20
0
0
0.000156
2
1.363
2
102
0
0
0
7
95
0
0
0.001233
2
10.802
סה"כ קטגוריה 122 :2
16
0
0
115
7
0
0
0.001
12.165
0.0%
סה"כ130 :
17
0
0
123
7
0
0
0.001
12.445
0.0%
Form-07 R5
TASHAN-LDAR_R-TASH-AL-A-16
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R5 :
שלב הניטור :אחרי סבב תיקונים
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
4
0.140
גז
נוזל קל
6
4
0
0
0
4
0
0
0
0.000016
0.140
סה"כ קטגוריה 8 :1
1
0
0
8
0
0
0
0.000
0.280
ברזים ,שסתומים
גז
וציוד תלוי
נוזל קל
צינורות פתוחים
גז
פוטנציאליים
נוזל קל
page 46 of 59
4
1
0
0
0
0
0
0.000016
6
6
0.0%
2
20
16
0
0
0
20
0
0
0.000156
2
1.363
2
102
0
0
0
7
95
0
0
0.001233
2
10.802
סה"כ קטגוריה 122 :2
16
0
0
115
7
0
0
0.001
12.165
0.0%
סה"כ130 :
17
0
0
123
7
0
0
0.001
12.445
0.0%
Form-07 R5
TASHAN-LDAR_R-TASH-AL-A-16
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R5
KG/year
First measurement
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
1.0802
0.1080
0.5401
1.0802
4.3208
3.6727
10.8021
TASHAN-LDAR_R-TASH-AL-A-16
Chem R5
page 47 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
Connections & Flanges
Units of Measurement:
R5
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
1.2445
0.1244
0.6222
1.2445
4.9778
4.2311
12.4445
Grand Total:
12.4445
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R5
page 48 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R5
KG/year
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
1.0802
0.1080
0.5401
1.0802
4.3208
3.6727
10.8021
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
TASHAN-LDAR_R-TASH-AL-A-16
Chem R5
page 49 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
All
Units of Measurement:
R5
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
1.2445
0.1244
0.6222
1.2445
4.9778
4.2311
12.4445
Grand Total:
12.4445
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R5
page 50 of 59
Leaker Detail Report
Report Parameters
Alroy
Report: R304_1
ISRAEL
All Classes
Monitoring Period:
Compliance Leak
R5
Alroy
Details
Class
Location
Date
Reported
Test
Type
Leak
Def
1st Att. Due
Repair Due
Repaired
Date
Event
Result
Technician
Instrument
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
LDAR Report_015 R5
page 51 of 59
החברה הארצית לבדיקות ושירותי איכות הסביבה
רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.
טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),
E-mail :michael.o@ecologicalab.com
סבב 6
תוצאות הניטור:
מדידה ראשונה ואחרי סבב התיקונים
טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
פילוג לחומרים הנפלטים
טופס :15דו"ח תיקון דליפות למתקן ייצור
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R6 :
שלב הניטור :מדידה ראשונה
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
0.140
גז
נוזל קל
page 53 of 59
4
1
0
0
4
0
0
0
0.000016
6
6
4
0
0
0
4
0
0
0
0.000016
6
0.140
סה"כ קטגוריה 8 :1
1
0
0
8
0
0
0
0.000
0.280
0.0%
סה"כ8 :
1
0
0
8
0
0
0
0.000
0.280
0.0%
Form-07 R6
TASHAN-LDAR_R-TASH-AL-A-16
מצאי רכיבי ציוד והערכת פליטות למתקן ייצור
שם המפעל :תשתיות נפט ואנרגיה בע"מ
סבב ניטור מס'R6 :
שלב הניטור :אחרי סבב תיקונים
סוג רכיב
משאבות
שם המתקן :אלרואי
סוג
סה"כ
רכיבים
רכיבים
שירות
רכיבים
עיקריים
מספר
מספר
סה"כ
בלתי
רכיבים מעל
נגישים
1,000חל"מ
מספר
מספר
רכיבים
רכיבים
מ 0-עד 9חל"מ
מספר
רכיבים
רכיבים
קצב
קצב
אחוז
מ 9-עד
מ 1,000-עד
מעל
פליטה
פליטה
רכיבים מעל
1,000חל"מ
100,000חל"מ
100,000חל"מ
שעתי
שנתי
1,000חל"מ
מספר
מספר
מספר
ק"ג/שעה
ק"ג/שנה
%
תדירות
הניטור
סבבים/שנה
גז
6
נוזל קל
6
ציוד ערבור
גז
6
וערבול
נוזל קל
6
PRD
גז
6
נוזל קל
נקודות דגימה
0.140
גז
נוזל קל
page 54 of 59
4
1
0
0
4
0
0
0
0.000016
6
6
4
0
0
0
4
0
0
0
0.000016
6
0.140
סה"כ קטגוריה 8 :1
1
0
0
8
0
0
0
0.000
0.280
0.0%
סה"כ8 :
1
0
0
8
0
0
0
0.000
0.280
0.0%
Form-07 R6
TASHAN-LDAR_R-TASH-AL-A-16
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R6
KG/year
First measurement
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
TASHAN-LDAR_R-TASH-AL-A-16
Chem R6
page 55 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
Connections & Flanges
Units of Measurement:
R6
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
All
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0280
0.0028
0.0140
0.0280
0.1118
0.0951
0.2796
Grand Total:
0.2796
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R6
page 56 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Units of Measurement:
R6
KG/year
אלרואי
Unit
Component Class:
Pumps
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Agitators
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PRD
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Sample Points
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0140
0.0014
0.0070
0.0140
0.0559
0.0475
0.1398
Component Class:
Valves
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
PO End
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Component Class:
Connections & Flanges
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
TASHAN-LDAR_R-TASH-AL-A-16
Chem R6
page 57 of 59
Correlation Equations Chemical Summary by Component Class
Monitoring Period:
Component Class:
All
Units of Measurement:
R6
KG/year
Chemical Name
CAS Number
1-Butene
Benzene
Cyclohexane
MTBE
n-Octane
Toluene
108883
Emissions
0.0280
0.0028
0.0140
0.0280
0.1118
0.0951
0.2796
Grand Total:
0.2796
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
Chem R6
page 58 of 59
Leaker Detail Report
Report Parameters
Alroy
Report: R304_1
ISRAEL
All Classes
Monitoring Period:
Compliance Leak
R6
Alroy
Details
Class
Location
Date
Reported
Test
Type
Leak
Def
1st Att. Due
Repair Due
Repaired
Date
Event
Result
Technician
Instrument
This report produced using Orr LeakDAS software.
TASHAN-LDAR_R-TASH-AL-A-16
LDAR Report_015 R6
page 59 of 59
ספח ג'
דוגמת חישוב עבור מיכל גג חיצוי צף מס' 2המאחסן קרוסין
3013.12-025-T2
3013.12-013
27/02/2017
18/31
3013.12-015
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - B&W 2016
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.11
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Red/Primer
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock
Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
1
2
29
43
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
13/02/2017
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - B&W 2016 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
All
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
81.75
66.81
96.69
Liquid
Bulk
Temp
(deg F)
70.60
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0161
N/A
N/A
Vapor
Mol.
Weight.
130.0000
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
Liquid
Mass
Fract.
Vapor
Mass
Fract.
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
13/02/2017
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - B&W 2016 - External Floating Roof Tank
Haifa, Israel
Annual Emission Calcaulations
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
0.0161
160.0100
130.0000
1.0000
Withdrawal Losses (lb):
Annual Net Throughput (gal/yr.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
65.8011
8,932,199.0000
0.0075
7.0000
160.0100
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
5.3401
0.0003
130.0000
1.0000
150.3024
6.2000
Total Losses (lb):
111.8364
40.6952
1.6000
0.3000
6.2000
1.6000
0.0003
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock
Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
1
2
29
43
1
KFa(lb-mole/yr)
1.60
11.00
6.20
1.20
0.49
0.71
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
9.90
1.20
0.14
0.16
0.10
m
0.00
0.89
0.94
0.65
0.14
1.00
Losses(lb)
0.1705
1.6897
0.7794
1.6109
1.0488
0.0406
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TANKS 4.0 Report
Page 4 of 6
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
13/02/2017
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - B&W 2016 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
40.70
65.80
5.34
0.00
111.84
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
13/02/2017
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
13/02/2017
TANKS 4.0 Report
Page 1 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFixed 2014
Haifa
Israel
PEI
Vertical Fixed Roof Tank
kerosene
Tank Dimensions
Shell Height (ft):
Diameter (ft):
Liquid Height (ft) :
Avg. Liquid Height (ft):
Volume (gallons):
Turnovers:
Net Throughput(gal/yr):
Is Tank Heated (y/n):
N
Paint Characteristics
Shell Color/Shade:
Shell Condition
Roof Color/Shade:
Roof Condition:
Red/Primer
Good
White/White
Good
Roof Characteristics
Type:
Height (ft)
Slope (ft/ft) (Cone Roof)
Breather Vent Settings
Vacuum Settings (psig):
Pressure Settings (psig)
11.00
160.01
11.00
5.50
1,654,664.74
1.00
1,654,664.74
Cone
0.00
0.00
0.00
0.50
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
01/02/2015
TANKS 4.0 Report
Page 2 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFixed 2014 - Vertical Fixed Roof Tank
Haifa, Israel
Mixture/Component
Month
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
Liquid
Bulk
Temp
(deg F)
Vapor Pressure (psia)
Avg.
Min.
Max.
Vapor
Mol.
Weight.
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
Liquid
Mass
Fract.
Vapor
Mass
Fract.
Mol.
Weight
Basis for Vapor Pressure
Calculations
01/02/2015
TANKS 4.0 Report
Page 3 of 5
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
01/02/2015
TANKS 4.0 Report
Page 4 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFixed 2014 - Vertical Fixed Roof Tank
Haifa, Israel
Losses(lbs)
Components
Working Loss
Breathing Loss
Total Emissions
Jet kerosene
66.66
51.49
118.15
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
01/02/2015
TANKS 4.0 Report
Page 5 of 5
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
01/02/2015
TANKS 4.0 Report
Page 1 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFloating 2014
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.00
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Red/Primer
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock
Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
1
2
29
43
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
01/02/2015
TANKS 4.0 Report
Page 2 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFloating 2014 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Month
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
Liquid
Bulk
Temp
(deg F)
Vapor Pressure (psia)
Avg.
Min.
Max.
Vapor
Mol.
Weight.
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
Liquid
Mass
Fract.
Vapor
Mass
Fract.
Mol.
Weight
Basis for Vapor Pressure
Calculations
01/02/2015
TANKS 4.0 Report
Page 3 of 5
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
01/02/2015
TANKS 4.0 Report
Page 4 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFloating 2014 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
3.61
55.99
0.46
0.00
60.05
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
01/02/2015
TANKS 4.0 Report
Page 5 of 5
file:///C:/Program%20Files/Tanks409d/summarydisplay.htm
01/02/2015
T2 - kerosene
External Floating roof
1. Tank data
Diameter of the tank
D
Effective height of the stock liquid (while
roof landing episode)
hle
Shell Color and condition
α
Roof color and condition
α
Tank paint solar absorptance
α
Vapor space outage (while roof landing
episode)
HVO
m
feet
m
feet
color
condition
color
condition
dimensionless
m
Tank data
--Tank data
--חאקי
טובה
לבן
טוב
48.77
160.01
11.00
0.89
Table 7.1-6
Assumption - Green Dark
0.17
Table 7.1-6
0.53
Table 7.1-6
Possible to use also equation
1-15
assumption - equal to legs height
feet
11.00
Volume of the vapor space (while roof
landing episode)
Breather vent pressure setting
VV
ft
3
VV=PI()*D /4*Hvo
221,185
Equation 1-3
∆PBP
psi
Typical value
0.50
Equation 1-11
Breather vent vacuum setting
∆PBV
psi
Typical value
0.00
Equation 1-11
Breather vent pressure setting range
∆PB
psi
∆PB = PBP − PBV
0.50
Equation 1-11
2
2. Material data - קרוסין
Stock vapor molecular weight
MV
Density of the liquid inside the tank
Wl
Vapor density
WV
True vapor pressure of the stock liquid
P
Vapor pressure at daily average liquid
surface temperature
Vapor pressure at the daily maximum
liquid surface temperature, psia
Vapor pressure at the daily minimum
liquid surface temperature
Daily vapor pressure range
3013.12-013.xls - 2
gr/gr-mole
lb/lb-mole
g/ml
lb/gal
kg/m^3
lb/ft3
msds data
130
msds data
--msds data
---
0.80
6.68
4.5
0.28
mm Hg
PEI data
0.833
psia
--הנחה:
Pv=nRT -->
P2=P1*(T2/T1)
0.02
0.02
0.02
0.00
PVA
psia
PVX
psia
PVN
psia
T1(k)=20C+273
T2(k)=37.5C+273
∆PV
psia
∆PV = PVX − PVN
1/3
0
at 20°C
0.02
Equation 1-9
15/02/2017
3. Operation data
Number of days that the tank stands idle
(on roof landing episode)
Number of degassing and cleaning
episode
Number of roof landing episode
nd
days/landing episode
site data
4
landing episode/year
site data
0.07
landing episode/year
site data
0.07
Tanks Program
--Tanks Program
---
66
30
112
51
21
T2 - B&W 2015
Tanks Program
---
60.05
27
T2 - DFloating 2014
lb per emptying
Tanks Program
67
Kg per emptying
---
30
4. Normal operation (Tanks program)
lb per year
Kg per year
lb per year
Kg per year
Kg per year
Working (withdrawal) losses
Total emissions (Breathing & Working)
Breathing (standing) losses
5. Degassing and Cleaning (Tanks program)
Degassing: emission from one turnover of
lb per emptying
Edegass-floating
floating roof
Kg per emptying
Degassing: fixed roof with a height of roof
legs
Edegass-legs
Liquid fraction in sludge
Fliquid
Sludge volume
Sludge weight
Vs
Ws
Cleaning emissions
Ecleaning
Total Degassing and Cleaning emissions
Edegass-total
3013.12-013.xls - 2
0.8
m3 per emptying
Kg per emptying
lb per emptying
Kg per emptying
lb per emptying
Kg per emptying
Ecleaning = Ws * (1-Fliquid)
Edegass-total =
Edegass-floating + Edegass-legs + Ecleaning
2/3
T2 - B&W 2015
T2- DFixed 2014
(Only working losses)
Tanks FAQ - degassing and
cleaning
70
56,000
24,692
11,200
24,818
11,257
15/02/2017
6. Roof landing
Daily average liquid surface temperature
TLA
°R
T LA = 0 . 44 T AA + 0 . 56 T B + 0 . 0079 * α * I
534.97
Equation 1-26
Daily vapor temperature range
∆TV
°R
∆ TV = 0 .72 ∆ T A + 0.028 * α * I
41.01
Equation 1-8
Daily maximum liquid surface temperature
TLX
°R
TLX = TLA + 0.25*∆TV
545.22
Figure 7.1-17
Daily minimum liquid surface temperature
TLN
°R
TLN = TLA - 0.25*∆TV
524.71
Figure 7.1-17
Liquid bulk temperature
Max standing idle losses during roof
landing
TB
°R
TB = TAA + 6α - 1
528.15
Equation 1-28
LSL-max
lb per landing episode
Kg per landing episode
dimensionless
2
LSL-max = 5.9*D *hle*W l
--0.60 for a full liquid heel
0.50 for a partial
0.15 for drain-dry
11,093,038 Equation 2-13
5,031,769
0.50
Equation 2-26
(pages No 33,35)
1
KS =
1 + 0.053 * PVA * H VO
0.5
Equation 1-20
KS is assumed to be less than
or equal to the saturation factor
during filling (S) .
∆ TV ∆ PV − ∆ PB
+
T LA
PA − PVA
0.043
Liquid stock has a true vapor
pressure greater than 0.1psia Equation 1-7.
Filling saturation factor
S
saturation factor
KS
dimensionless
Vapor space expansion factor
KE
dimensionless
Standing idle losses during roof landing
LSL
lb per landing episode
PV
L SL = n d K E V M V K S
RT AA
7
Equation 2-16
Filling losses during roof landing
LFL
lb per landing episode
P * VV
M V * S
L FL =
R * T AA
41
Equation 2-26
Total losses during roof landing
LTL
lb per landing episode
Kg per landing episode
48
22
Equation 2-10
KE =
LTL=LSL+LFL
7. Summary
Working (withdrawal) losses
Breathing (standing) losses
Kg per year
Kg per year
30
21
Total Degassing and Cleaning emissions
Kg per year
750
Total losses during roof landing
Kg per year
1
803
3013.12-013.xls - 2
3/3
Kg per year
15/02/2017
ספח ד'
דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 2של קרוסין
3013.12-014
27/02/2017
19/31
3013.12-015
Transportation - Loading losses
Loading arm #1 - Kerosene
Density
Tank paint solar absorptance
Daily average ambient temperature
Wl
α
TAA
Yearly consumption
Myear
Cargo tank volume
V
Ntrucks
t
g/ml
dimensionless
°R
ton
m3
gal
m3
gal
1/year
min
Saturation factor
S
dimensionless
True vapor pressure of liquid
P
Molecular weight of vapors
M
Number of tank trucks
Duration of road truck filling
Table 5.2-1
mmHg
psia
0.833
0.02
@ 20°C
lb/lb-mole
130
Table 7.1-2
T=TB
°R
Controlled efficiency for the recovery
unit (vapor recovery efficiency)
eff1
%
vapor collection efficiency
eff2
%
overall reduction efficiency
eff
%
Loading losses of petroleum liquids
(uncontrolled emission rate)
LL
lb/103 gal
loaded
Flow rate of pollutant emission during
loading
Annual pollutant emission during
loading
T = TB = TAA + 6α - 1
527.40
0
LL total lb / loading
lb / min
Q
Kg / min
Kg / hr
Etotal
0.80
0.41
525.97
318
400
105,669
30.0
7,925
13
30
0.6
Temperature of bulk liquid loaded
Total loading losses of petroleum
msds data
site data
"Site" tab @ 3013-037
--data
--data
--Ntrucks = Myear / V
data
Submerge loading, dedicated
normal service
Kg / year
Truck passed the NSPS-level
annual test
70.0
eff=eff1*eff2/100
0
LL = 12.46
S *P*M
eff
1 −
T
100
0.030
LLtotal = LL*V
Q = Lltotal / t
-----
0.24
0.008
0.004
0.21
Etotal = LLtotal*Ntruks
1.39
Equation 1-28
page 5.2-6
can be 90% to over 99%
page 5.2-6
99.2- for tanker truck passed the
MACT-level annual leak test
98.7- for truck passed the NSPS-level
annual test
70 - for trucks not passing one of
these leak tests
Page 5.2-4 Equation 1
Assumption: the mass of the
Average pollutant emission
concentration during loading
3013.12-014.xls - 1
C
gr / m3
C = Q *t / V
3.6
1/1
pollutant is contained in the air
volume inside the tanker which is
replaced by the liquid loaded
15/02/2017
ספח ה'
חישוב פליטות ממיכל לאיסוף תשטיפים
27/02/2017
20/31
3013.12-015
תוכת :Tanksחישוב פליטה כתוצאה מאחסון ושיוי מפלס
27/02/2017
21/31
3013.12-015
3013.12-015
22/31
27/02/2017
3013.12-015
23/31
27/02/2017
3013.12-015
24/31
27/02/2017
תוכת :Tanksחישוב פליטה כתוצאה מיקוי וריקון מיכל )שלב א'(
27/02/2017
25/31
3013.12-015
3013.12-015
26/31
27/02/2017
3013.12-015
27/31
27/02/2017
תוכת :Tanksחישוב פליטה כתוצאה מיקוי וריקון מיכל )שלב ב'(
27/02/2017
28/31
3013.12-015
3013.12-015
29/31
27/02/2017
3013.12-015
30/31
27/02/2017
חישובי פליטה ממיכל תשטיפים
גיליון חישוב זה הוכן על ידי "פז" הדסה ויהול ) (1980בע"מ.
אין להעתיק ו\או לעשות שימוש כלשהו במידע ה"ל ללא הרשאה כתובה מ"פז" הדסה ויהול ) (1980בע"מ.
27/02/2017
31/31
3013.12-015
מסמך 6 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 2461 KB)
תשתיות פט וארגיה בע"מ
מסוף אלרואי
סיכום פליטות לאוויר
שת 2017
פרויקט3013.13 :
סימוכין3013.3-015 :
פברואר 2018
תוכן עייים
.1מבוא 4 ...............................................................................................................
.2תוי מסוף 5 ........................................................................................................
.2.1תוי מיכלים 5.........................................................................................................
.2.2תוים עבור מסוף מילוי מיכליות כביש 9.....................................................................
.3חישוב פליטות 10 .................................................................................................
.3.1כללי10 ...................................................................................................... ............
.3.2סוגי פליטות מחושבות 10 .........................................................................................
.3.3
בחירת חומרים בתוכת 11 ......................................................................... TANKS
.3.4תוים מטאורולוגיים 11 ..........................................................................................
.4סיכום פליטות לשת 12 .................................................................................. 2017
.4.1
מיכלים12 ...................................................................................................................... ...........
.4.2
מסוף מילוי מיכליות כביש 12 ...................................................................................................
.4.3
מיכל איסוף תשטיפים 13 ..........................................................................................................
.4.4
סיכום ממצאי יטור 13 ................................................................................................ LDAR
.4.5פליטה שתית מכלל המתקן 13 .................................................................................
.5פליטות לא שגרתיות במהלך שת 13 .................................................................. 2017
.6מקורות 14 ..........................................................................................................
26/02/2018
2/31
3013.13-015.doc
טבלאות
טבלה :1תוי מיכלים – מידע כללי ,מידות ותוי תפעול – שת 5........................................... 2017
טבלה :2תוי מעטפת וגגות – שת 6.................................................................................. 2017
טבלה :3תוי אביזרים – שת 7........................................................................................ 2017
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכת 8................................................... TANKS
טבלה :5תוים עבור מסוף מילוי מיכליות כביש – שת 9...................................................... 2017
טבלה :6חומרים מייצגים בתוכת 11 ............................................................................ TANKS
טבלה :7סיכום פליטות מכלים -שת 12 ............................................................................ 2017
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שת 12 ..................................................2017
טבלה :9סיכום פליטות חומרים אורגים דיפים עבור רכיבים בשת 13 .................................. 2017
טבלה :10סיכום פליטות שתי מכלל מסוף אלרואי – שת 13 .................................................2017
ספחים
ספח א'
טבלה (AP-42) 1-5.2
ספח ב'
תוי יטור LDARעבור מסוף אלרואי – סיכום שת 2017
ספח ג'
דוגמת חישוב עבור מיכל גג חיצוי צף מס' 2המאחסן קרוסין
ספח ד'
דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 1של קרוסין
ספח ה'
חישוב פליטות ממיכל לאיסוף תשטיפים
שירן שחר
שם עורך
26/02/2018
יואב פיסטיר
שם מאשר
להערות
תיאור
26.02.2018
תאריך
3/31
0
גרסה
3013.13-015.doc
.1מבוא
חברת תשתיות פט וארגיה בע"מ )להלן תש"ן( מפעילה את מסוף אלרואי לאחסון ושיוע
דלקים .
המסוף כולל:
•
מבי משרדים
•
חוות מכלים לאחסון דלקים מסוגים שוים
•
רציפי מילוי מכליות כביש )לשימוש בעת חירום בלבד(
המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכות
אלרואי ומדרום לו שכות קרית חרושת.
באתר 9מיכלים ,מתוכם 6מיכלים תפעוליים ו 3-מיכלי מלאי סגור )מיכלים מס' 6 ,1ו.(9-
מערכת השיוע היה באמצעות משאבות ובקרת מילוי ובוסף קיימות מערכות תומכות כגון
מערכות כיבוי אש ומערכות פיקוד ובקרה.
כחלק מהתאים ברישיון עסק מדצמבר ,2010בסוף כל שה קלדרית על תש"ן להגיש דו"ח
סיכום פליטות שתי לגבי השה שחלפה.
חישובי הפליטות בוצעו בעזרת תוכת Tanksומסמכי EPA-AP 42על פי תוי המתקים
הקיימים במסוף.
סיכום הפליטות הוכן על ידי חברת "פז" הדסה ויהול ) (1980בע"מ )להלן פז הדסה( ,והוא
מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות יטור LDARשהוגשו לרשויות.
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.2תוי מסוף
.2.1תוי מיכלים
בטבלאות הבאות מפורט מידע טכי של המיכלים בחוות המיכלים אלרואי.
טבלה :1תוי מיכלים – מידע כללי ,מידות ותוי תפעול – שת 2017
מספר
מיכל
סוג הדלק
המאוחסן
לחץ אדים
בטמפ' הוזל
הממוצעת
)(mmHg
405 @ 28°C
כמות
צריכה
שתית
)מ"ק(
0
גבעה חלקית
24,598
גבעה חלקית
48.77
גבעה חלקית
48.77
32,056
48.77
32,056
28,768
56,959
51,614
15.56
51,614
15.56
14.1
15.56
14.1
11.4
18.3
18.3
15.4
9.7
סוג יקוז
בתחתית
מיכל
קוטר
מיכל
)מטר(
פח מיכל
)מ"ק(
פח מיכל
פעיל
)מ"ק(
48.77
32,056
28,768
גובה /אורך
מעטפת
מיכל
)מטר(
17.16
15.4
32,056
28,768
17.16
15.4
10
28,768
17.16
15.4
9.5
17.16
15.4
10.3
14.1
14.1
14.1
)(1
בזין
2
קרוסין
0.833 @ 28°C
3
סולר
0.507 @ 28°C
49,118
4
סולר
0.507 @ 28°C
23,773
גבעה חלקית
5
סולר
0.507 @ 28°C
91,328
גבעה מלאה
68.27
)(2
סולר
0.507 @ 28°C
0
גבעה מלאה
68.27
56,959
7
סולר
0.507 @ 28°C
11,989
גבעה מלאה
68.27
56,959
51,614
8
קרוסין
0.833 @ 28°C
982
גבעה חלקית
48.8
36,547
34,228
19.54
)(3
קרוסין
0.833 @ 28°C
0
גבעה חלקית
48.77
32,056
28,768
17.16
367,704
332,913
1
6
9
201,787
סה"כ
) (1מיכל מס' 1שימש כמיכל מלאי ,וקה במערכת סגורה בחודש ספטמבר 2017וכס לשיפוץ לאחר ביצוע היקוי.
) (2מיכל מס' 6שימש כמיכל מלאי ,היה בשיפוץ ממרץ עד יוי .2017
) (3מיכל מס' 9שימש כמיכל מלאי ,לא היו תועות במיכל בשת .2017
הערה כללית :מיכלים 1,4,5,6,7,8וקו במהלך שת .2017
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גובה וזל
מירבי
)מטר(
גובה וזל
ממוצע
)מטר(
10.5
טבלה :2תוי מעטפת וגגות – שת 2017
מספר
מיכל
סוג גג
אטם ראשי
אטם משי
1
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
גג צף
חיצוי
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Liquid
mounted
Mechanical
Shoe
Rim
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Rim
mounted
Shoe
mounted
2
3
4
5
6
7
8
9
26/02/2018
צורת גג
סוג
חיבורי
גג
צבע
גג
מצב
צבע
גג
צבע
מעטפת
חיצוית
מצב צבע
מעטפת
חיצוית
סוג חיבורי
מעטפת
מצב
מעטפת
פימית
מיכל
מחומם
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חאקי
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חאקי
ישן
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
כחול בהיר
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
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טבלה :3תוי אביזרים – שת 2017
מספר
מיכל
1
2
3
4
5
6
7
8
9
סה"כ
שובר ואקום
כמות
2
2
2
2
2
2
2
6
2
26/02/2018
Vacuum
]set. [psi
0
0
0
0
0
0
0
0
0
Pressure
]set. [psi
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
רגליים מתכווות התומכות
בגג צף
גובה
כמות באזור
כמות
במרכז
)(ft
pontoon
29
43
11
29
43
11
29
43
11
29
43
11
72
107
11
72
107
11
72
107
11
36
54
9
29
43
11
7/31
כמות
מדי
מפלס
Rim
Vent
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
כמות בוצה
בקיון
)מ"ק(
"גרביים" לבאר
הדיגום המחורצת
ולרגלי הגג הצף
70
70
70
70
150
150
150
70
70
870
יש
יש
יש
יש
יש
יש
יש
יש
יש
3013.13-015.doc
החות שלקחו לצורך החישובים
.1עבור חישוב Degassingבמיכל עם גג צף – הוח:
•
גג צף ח על רגליים בגובה ) 9-11 ftבהתאם לטבלה לעיל( וזהו גם הגובה המרבי של הוזל
במיכל.
•
גובה ממוצע של הוזל במיכל היו 50%מגובה הוזל המרבי.
.2הוח כי יקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שים .היקיון יארך יום אחד.
.3הוח כי אירוע של חיתת גגות צפים מתבצע אחת ל 15-שים .זמן חיתת הגג במקרה זה לא
יעלה על 4ימים.
.4יחס הוזל בבוצה הוח כ[2] 0.8 -
.5בהתאם לטבלה 7.1-6על פי ] ,[1בחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,
לצורך חישובי פליטות לאוויר:
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכת Tanks
צבע מעטפת
מיכל
צבע לצורך חישובי אקסל
צבע לצורך חישובים בתוכת
בהתאם למסמך EPA AP-42
(*) Tanks
כחול בהיר
Gray Medium
Gray Medium
חאקי
Green Dark
Red/Primer
צהוב קרם
Beige/Cream
Aluminium/Specular
)*( בתוכת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך
.[1] EPA AP-42
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.2.2תוים עבור מסוף מילוי מיכליות כביש
טבלה :5תוים עבור מסוף מילוי מיכליות כביש – שת 2017
מס'
זרוע
1
2
3
4
5
6
7
8
מוצר
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
סה"כ
מילוי
עילי /תחתי
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
פח ממוצע של
מיכלית )מ"ק(
30
30
30
30
30
30
30
30
פח מילוי שתי
)מ"ק(
151
0
0
0
0
0
0
0
151
החות שלקחו צורך החישובים
.1
מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:
א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:
דוגמת חישוב עבור מיכל מס' :1
0.17 + 0.834
= 0.25
2
=
)α roof(1) + α Shell(1
2
= α tank2
ב .בשלב השי חושב מקדם αממוצע עבור הקרוסין:
0.26 + 0.43 + 0.26
= 0.31
3
=
)α tank(1) + α tank(8) + α tank(9
number of kerosene tanks
= α Kerosene
.2
זמן מילוי מיכלית חושב על פי פח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000
ליטר/דקה.
.3
Vapor collection efficiency - 70%
.4
Vapor recovery efficiency - 0%
.5
Saturation factorהוח כ (Submerged loading, dedicated normal service) 0.6-על פי
] .[1טבלה רלווטית מצורפת בספח א'.
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.3חישוב פליטות
.3.1כללי
חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכת Tanksובעזרת .[1] EPA-AP 42
הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ) (LDARמצורפת בספח ב'.
דוגמת חישוב עבור מיכל גג חיצוי צף )מיכל מס' (2המאחסן קרוסין ,מצורפת כספח ג' למסמך
זה.
דוגמת חישוב עבור זרוע מילוי עילי של קרוסין )זרוע מס' (1מצורפת כספח ד' למסמך זה.
בדוגמאות אלה יתן לראות את תוי הקלט )כולל החות( עליהם התבססו החישובים.
.3.2סוגי פליטות מחושבות
הערכת הפליטות ממיכלי אחסון כוללת ]:[3
• פליטות בזמן אחסון )(Breathing Losses
• פליטות משיויי מפלס )(Working Losses
• פליטות כתוצאה מיקוי וריקון מיכלים )(Degassing Losses
• פליטות כתוצאה מחיתת גגות צפים )(Roof Landing Losses
• פליטות כתוצאה מהפרשי לחץ )(Flash Losses
• פליטות בזמן מילוי מיכלים ומיכליות
בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ
).(Flash Losses
פליטות אלה רלווטיות לשיויי פתאומי\מיידי בלחץ הוזל ,תון הגורם להפרת שיווי המשקל
הקיים במיכל )בין גז לוזל( וכתוצאה מכך וצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הוזל
עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר וזל המאוחסן בלחץ שלח
לאחסון במיכל בעל לחץ מוך יותר ].[3
פליטות אלו הוזחו כיוון שכל החומרים מוחזקים בתאים אטמוספריים בכל אחד מהשלבים
הוגעים להובלתם ואחסום ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.
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.3.3בחירת חומרים בתוכת Tanks
על פי תוי MSDSשל הדלקים במסוף ,בחרו החומרים הבאים הקיימים בתוכת Tanks
כמייצגים של חומרים אלו:
טבלה :6חומרים מייצגים בתוכת Tanks
דלק קיים במסוף
חומר מייצג בתוכת Tanks
סולר )תחבורה והסקה(
Distillate fuel oil no 2
פט )קרוסין(
Jet kerosene
בזין
Gasoline RVP 10
.3.4תוים מטאורולוגיים
לצורך חישוב התוים בתוכת Tanksהוגדרו תוים מטאורולוגים המתאימים למפרץ חיפה על פי
מקורות ].[4
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.4סיכום פליטות לשת 2017
.4.1מיכלים
סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:
טבלה :7סיכום פליטות מכלים -שת 2017
מיכל
חומר
1
בזין
פליטות לאוויר
)ק"ג/שה(
1,168
2
קרוסין
795
3
סולר
57
4
סולר
822
5
סולר
1,754
6
סולר
1,129
7
סולר
1,703
8
קרוסין
758
9
קרוסין
767
סה"כ
9,518
.4.2מסוף מילוי מיכליות כביש
להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שת 2017
מס' זרוע
מוצר
מילוי עילי /תחתי
1
2
3
4
5
6
7
8
סה"כ
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
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פליטה שתית
)ק"ג/שה(
0.53
0
0
0
0
0
0
0
0.53
3013.13-015.doc
.4.3מיכל איסוף תשטיפים
סך הפליטה ממיכל לאיסוף תשטיפים היה כ 1 -ק"ג/שה.
חישוב מצורף בספח ה'.
יצוין כי החישוב מתבסס על החה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל
בעיקר יקוז מים מהמכלים.
.4.4סיכום ממצאי יטור LDAR
טבלה :9סיכום פליטות חומרים אורגים דיפים עבור רכיבים בשת 2017
סה"כ פליטות )ק"ג/שה(
סיכום פליטות LDAR
פליטה שתית )ק"ג/שה(
סה"כ
12
.4.5פליטה שתית מכלל המתקן
טבלה :10סיכום פליטות שתי מכלל מסוף אלרואי – שת 2017
סה"כ פליטות )ק"ג/שה(
חוות מיכלים
מסוף מילוי
מיכליות כביש
מיכל לאיסוף
תשטיפים
9,518
0.53
1
סיכום פליטות
רכיבים
סה"כ
)(LDAR
12
9,532
.5פליטות לא שגרתיות במהלך שת 2017
במהלך שת 2017לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמיל.
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.6מקורות
[1] EPA-AP42
[2] USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version
4.0 - APPENDIX D
] [3החיות הממוה לטיפול בבקשה להיתר פליטה לפי סעיף )9א( לתקות אוויר קי )היתרי פליטה(,
התש"ע – ,2010מהדורה ,4ספטמבר 2014
] [4האטלס האקלימי לתכון פיסי וסביבתי בישראל ,מהדורה שיה1994 ,
26/02/2018
14/31
3013.13-015.doc
ספח א'
טבלה 5.2-1
AP-42
26/02/2018
15/31
3013.13-015.doc
3013.13-015.doc
16/31
26/02/2018
ספח ב'
תוי יטור LDARעבור אלרואי – סיכום שת 2017
)מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך (05.02.2018
3013.13-004A
26/02/2018
17/31
3013.13-015.doc
LDAR
Fugitive Emission Monitoring
Report No.
RL-TS-R1-17
Plant:TASHAN
City:Haifa
District:Haifa
Production Unit:Alroy
Group:Group 1-2-3
Reporting period:Annual Summary
Report printing date: 05-Feb-2018
Technicians names:
Porcelan
Polik
Report editor:
Michael Ourievsky
Approved by:
Alexey Ratner, CEO
Table of Content
1. Project introduction
1.1 Scope of work
1.2 Project phases
2. Methodology
2.1 Definitions
2.2 Methodology
3. Summary of Monitoring Period
3.1 Cumulative Data of Monitoring Period
3.2 Summary of Monitoring Period
3.3 Form 07: component classification and emission estimations for production facilities
3.4 Chemical Summary
3.5 LDAR report for production facilities
4. First Measurement and Measurement After Repair Round 1
4.1 Form-07 by Round
4.2 Chemical Summary First Measurement
4.3 Chemical Summary After Repair
4.4 LDAR report for production facilities
5. Attachments
5.1 Calibration log list
5.2 Calibration gas certificates
5.3 Composition list & Response Factors
5.4 Quarterly equipment check Q1
5.5 Quarterly equipment check Q2
5.6 Quarterly equipment check Q3
5.7 Quarterly equipment check Q4
5.8 Quarterly production hours
3
3
4
4
6
7
9
10
12
14
15
17
19
21
22
24
25
26
27
28
29
1 Project introduction
1.1 Scope of work
1 rounds of measurements (from 01/01/2017 to 31/12/2017)
Measurements performed for following classes:
Group 1: PRD, Sampling Point
Group 2: Open End, Stem Valve
Group 3: Connection, Flange
The following equipment was out of service. Emission estimation was performed using the previous
measurements.
Round
Unit
2
Alroy
3
Alroy
Equipment
Round
Unit
Equipment
Remarks
T-01+pipe (from
19/09/17)
T-01+pipe (from
19/09/17)
1.2 Project phases
Monitoring: Group 1-2-3
Re-measurement after repair action
Revision of equipment and production processes
Inventorisation: adding or deleting components
Mapping of components on P&ID's
General
1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory
Accreditation Authority).
2. ISRAC is not responsible for the test results.
Project Introduction
page 3 of 29
2 Methodology
1.1 Definitions
Chemical State:
Gas/Vapor: stream which is in process conditions under gaseous or vapor form.
Light Liquid: a liquid having a VOC content greater than 10% (by volume) hat evaporates at 150°C
Heavy Liquid: a liquid having a VOC content of 10% or less (by volume) that evaporates at 150°C
Leak definition: 1,000 ppm (all sources)
Difficult to monitor components:
Any component situated at a level higher than five meters above ground level or any component situated at a distance further than two
meters from a platform and which cannot be accessed by employees in a safe way.
Any component which access requires the elevation of a person to a level higher than two meters above regular surfaces, and which
cannot be accessed in a safe.
Registered sources:
Sources with a leak value equal or greater than 9 ppm.
Default-zero:
This equation is valid for sources with a leak value of 0 ppm.A fixed EPA emission calculation rule is used for all these sources.
Total components:
All of the existing active components.
Total measured components:
All of the components, measured in specific monitoring round.
2.2 Methodology
Formulas:
Measured ppm values are converted to emission loss (kg/year) and these calculations are based on the E.P.A. “Correlation method SOCMI”
Modified Trapezoidal Emission Calculation Method:
The modified trapezoid method assumes that the mass leak rate changes linearly between any two monitoring points, except for
periods between leak detection and repair; the leak monitor reading is used from the time the leak is detected to the time it is repaired (i.e.,
re-screened).
Cumulative data:
In "Cumulative data" tables we provide the results of all of the measurements that performed from beginning of the year till the end of
current monitoring period (quarter). We also calculate the real sum of previous emissions based on the all rounds of the measurements
(before and after repairing attempts).(US EPA "Emission Estimation Protocol for Petroleum Refineries",Ver.2.1.1, 2011)
Methodology
page 4 of 29
Equation Set Details Report
Equation Set
Class
Chemical State
Default Zero
Pegged 100k
Multiplier
Exponent
Avg. Factor
Refinery
Connection
Light Liquid
7.5E-06
0.03
1.53E-06
0.735
0.00025
Refinery
Flange
Light Liquid
3.1E-07
0.084
4.61E-06
0.703
0.00025
Refinery
Open End
Light Liquid
2E-06
0.079
2.2E-06
0.704
0.0023
Refinery
PRD
Light Liquid
4E-06
0.11
1.36E-05
0.589
0.16
Refinery
Sampling Point
Light Liquid
4E-06
0.11
1.36E-05
0.589
0.015
Refinery
Stem Valve
Light Liquid
7.8E-06
0.14
2.29E-06
0.746
0.0109
Equations
page 5 of 29
Summary of Period: 01/01/2017-31/12/2017
The total emissions: 11.790kg
Component
Class
Total Components
count
PRD
Sampling
Point
Total Group 1:
Stem Valve
Open End
Total Group 2:
Flange
Connection
Total Group 3:
Total:
Overview by component class
Total Components above leak definition
(1,000 ppm)
count
R1
% of components above leak definition
(1,000 ppm)
%
R1
4
0
0.0%
0
0.1
4
0
0.0%
0
0.306
8
20
102
122
55
38
93
0
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
0
0.406
0.977
7.79
8.767
0.832
1.785
2.617
223
0
Unrepaired Components
Total Emissions
count
R1
kg
01/01/2017- 31/12/2017
0.0%
0
11.79
Overview by reading range
Reading Range
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000
ppm
Difficult to Monitor
Total:
Cumulative Data
Total Components
#
Round 1
%
220
3
0
0
98.7%
1.3%
0.0%
0.0%
0
0.0%
0
223
0.0%
100.0%
page 6 of 29
Summary of Monitoring Period Round 1
First measurement:
0 "difficult to monitor" sources.
220 default-zero sources with a calculated emission rate:
3 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
definition (1,000 ppm)
components above leak
definition
count
count
%
Total components
count
PRD
Sampling Point
Stem Valve
Open End
Flange
Connection
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
220
3
0
0
0
0
Total:
223
5.284 kg/year
2.125 kg/year
7.409 kg/year
Emission rate of
Total annual emission rate
components above leak
(all components)
definition
kg/year
kg/year
4
0
0
0.00%
0
0.123
4
0
0
0.00%
0
0.123
20
0
0
0.00%
0
1.198
102
3
0
0.00%
0
3.646
55
0
0
0.00%
0
0.131
38
0
0
0.00%
0
2.189
223
3
0
0.00%
0
7.41
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
98.65%
5.284
71.32%
1.35%
2.125
28.68%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
7.409
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
220 default-zero sources with a calculated emission rate:
3 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
5.284 kg/year
2.125 kg/year
7.409 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.123
Sampling Point
4
0
0
0.00%
0
0.123
Stem Valve
20
0
0
0.00%
0
1.198
Open End
102
3
0
0.00%
0
3.646
Flange
55
0
0
0.00%
0
0.131
Connection
38
0
0
0.00%
0
2.189
223
3
0
0.00%
0
7.41
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
220
3
0
0
0
0
Total:
223
Summary R1
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
98.65%
5.284
71.32%
1.35%
2.125
28.68%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
7.409
Comments
100%
page 7 of 29
Cumulative data for period
01/01/2017-31/12/2017
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Fugitive emission component classification and emission estimation for production facilities
01/01/2017-31/12/2017 Calculation period
Monitoring
Components Cumulative Components
Frequency above 1,000 ppm Emission above 100,000
ppm
cycles/year
6
6
6
6
6
6
2
2
2
2
2
2
1
1
1
1
1
1
Form-07 CU
%
R1
kg
Count
R1
Components in Components in Components in
reading range reading range reading range
1,000-100,000
9-999 ppm
0-8 ppm
ppm
Count
Count
Count
R1
R1
R1
TASHAN Company name
AlroyProduction Unit
Unrepaired
Total
Components
Components
above 1,000
ppm
Count
Count
R1
R1
Difficult
Major
Total
to
Components Components
Monitor
Count
Count
05-Feb-2018Date
Report Number
Chemical State Component Class Group
Count
0.00%
0.1
0
0
0
4
0
0
0
1
0.00%
0.306
0
0
0
4
0
0
0
0
0.00%
0.406
0
0
0
8
0
0
0
1
0.00%
0.977
0
0
0
20
0
0
0
16
0.00%
7.79
0
0
3
99
0
0
0
0
0.00%
8.767
0
0
3
119
0
0
0
16
0.00%
0.832
0
0
0
55
0
0
0
0
0.00%
1.785
0
0
0
38
0
0
0
0
0.00%
0.00%
2.617
11.79
0
0
0
0
0
3
93
220
0
0
0
0
0
0
0
17
GV
PRD
LL
HL
GV
Sampling Point
4
LL
HL
8
Subtotal G1
GV
Stem Valve
20
LL
HL
GV
Open End
102
LL
HL
122 Subtotal G2
GV
Flange
55
LL
HL
GV
Connection
38
LL
HL
93
Subtotal G3
223 Total Components
11.79 Total Cumulative Emission
G1
4
G2
G3
page 9 of 29
Chemical Summary by Component Class
Report Chemical Summary Cumulative
Calculation Period: 01/01/2017- 31/12/2017
Equation Set: Refinery
Units of Measurement: KG
Report Date: 05.02.2018
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
108883
Emissions
0.01
0.001
0.005
0.01
0.0401
0.0341
0.1002
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.0306
0.0031
0.0153
0.0306
0.1225
0.1041
0.3062
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.0977
0.0098
0.0489
0.0977
0.3909
0.3322
0.9772
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.779
0.0779
0.3895
0.779
3.1158
2.6485
7.7897
Chemical CU
page 10 of 29
Chemical Summary by Component Class
Report Chemical Summary Cumulative
Calculation Period: 01/01/2017- 31/12/2017
Equation Set: Refinery
Units of Measurement: KG
Report Date: 05.02.2018
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
108883
Emissions
0.0832
0.0083
0.0416
0.0832
0.3328
0.2829
0.832
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.1785
0.0179
0.0893
0.1785
0.7141
0.607
1.7853
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
1.179
0.118
0.5896
1.179
4.7162
4.0088
11.7906
Grand Total
Chemical CU
11.7906
page 11 of 29
LDAR report for production facilities
Plant
TASHAN
Unit
Drawing
LDAR 015
Component
Tag
Component
Type
Component
Class
Location Description
Unit
Monitoring Round
Alroy
Round 1
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 12 of 29
Round 1
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 1
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.123
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.123
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.246
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.198
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
0.0%
3.646
0
0
3
99
0
0
0
102
LL
2
HL
0.0%
4.844
0
0
3
119
0
0
16
122
Subtotal G2
1
GV
Flange
G3
1
0.0%
0.131
0
0
0
55
0
0
0
55
LL
1
HL
1
GV
Connection
1
0.0%
2.189
0
0
0
38
0
0
0
38
LL
1
HL
0.0%
2.32
0
0
0
93
0
0
0
93
Subtotal G3
0.0%
7.41
0
0
3
220
0
0
17
223 Total Components
7.41 Total Annual Emission Rate
TASHAN Company name
Round 1
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.123
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.123
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.246
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.198
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
0.0%
3.646
0
0
3
99
0
0
0
102
LL
2
HL
0.0%
4.844
0
0
3
119
0
0
16
122
Subtotal G2
1
GV
Flange
G3
1
0.0%
0.131
0
0
0
55
0
0
0
55
LL
1
HL
1
GV
Connection
1
0.0%
2.189
0
0
0
38
0
0
0
38
LL
1
HL
0.0%
2.32
0
0
0
93
0
0
0
93
Subtotal G3
0.0%
7.41
0
0
3
220
0
0
17
223 Total Components
7.41 Total Annual Emission Rate
Form-07 R1
page 14 of 29
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2017- 30/07/2017
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 05.02.2018
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
108883
Emissions
0.0123
0.0012
0.0061
0.0123
0.0492
0.0418
0.1229
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.0123
0.0012
0.0061
0.0123
0.0492
0.0418
0.1229
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.1198
0.012
0.0599
0.1198
0.4792
0.4073
1.198
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.3646
0.0365
0.1823
0.3646
1.4584
1.2397
3.6461
Chemical FM R1
page 15 of 29
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2017- 30/07/2017
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 05.02.2018
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
108883
Emissions
0.0131
0.0013
0.0065
0.0131
0.0524
0.0445
0.1309
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.2189
0.0219
0.1094
0.2189
0.8755
0.7442
2.1888
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.741
0.0741
0.3703
0.741
2.9639
2.5193
7.4096
Grand Total
Chemical FM R1
7.4096
page 16 of 29
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2017- 30/07/2017
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 05.02.2018
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
108883
Emissions
0.0123
0.0012
0.0061
0.0123
0.0492
0.0418
0.1229
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.0123
0.0012
0.0061
0.0123
0.0492
0.0418
0.1229
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.1198
0.012
0.0599
0.1198
0.4792
0.4073
1.198
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.3646
0.0365
0.1823
0.3646
1.4584
1.2397
3.6461
Chemical AR R1
page 17 of 29
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2017- 30/07/2017
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 05.02.2018
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
108883
Emissions
0.0131
0.0013
0.0065
0.0131
0.0524
0.0445
0.1309
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.2189
0.0219
0.1094
0.2189
0.8755
0.7442
2.1888
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TER-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
108883
0.741
0.0741
0.3703
0.741
2.9639
2.5193
7.4096
Grand Total
Chemical AR R1
7.4096
page 18 of 29
LDAR report for production facilities
Plant
TASHAN
Unit
Drawing
Component
Tag
LDAR 015 R1
Component
Type
Component
Class
Location Description
Unit
Monitoring Round
Alroy
Round 1
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 19 of 29
General
Calibration log list
Calibration gas certificates
Composition list & Response Factors
Quarterly production hours
Quarterly equipment check
Calibration log list
Plant
Round Equipment Analyzer
Type
Type
Ultra-Zero
Span Gas
Span gas Cylinder
Span
Check gas Check gas Cylinder
Check gas
No
concentration
No
concentration
Date
Equipment
No
Equipment
Serial
No
Check
Calibration Result
error
1-st 2-st 3-st
check check check
(A1) (A2) (A3)
(CP)
ppm ppm ppm
(A)
ppm
ppm
TASHAN
1
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
514
26-Jul-2017
1
0715622657
503
505
503
-0.07%
OK
TASHAN
1
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
514
26-Jul-2017
5
202016061436 506
500
500
-0.40%
OK
TASHAN
1
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
514
13-Aug-2017
1
0715622657
505
501
505
-0.07%
OK
TASHAN
1
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
514
13-Aug-2017
5
202016061436 503
504
506
0.07%
OK
TASHAN
1
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
514
31-Aug-2017
1
0715622657
499
505
505
-0.20%
OK
TASHAN
1
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
514
31-Aug-2017
5
202016061436 502
500
503
-0.46%
OK
TASHAN
1
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
514
05-Sep-2017
1
0715622657
501
502
501
-0.53%
OK
TASHAN
1
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
514
05-Sep-2017
5
202016061436 505
505
504
0.13%
OK
Cal-Log
page 21 of 29
Certificate
page 22 of 29
Certificate
page 23 of 29
Stream Composition Summary
Stream Name
Gasoline
Stream Content
TOLUENE-34 %, n-Octane-40 %, METHYL TER-BUTYL ETHER-10 %, CYCLOHEXANE-5
%, BENZENE-1 %, 1-Butene-10 %
Stream Summary
Stream Content
Dates
TVA
MiniRAE 10.6 MiniRAE 11.7
A=0.39, B=0.31
page 24 of 29
Quarterly Validation of LDAR Devices
Sampling Flow
Rate
Accuracy Check
Response Time
Comparison between two Devices
Date: 02-Jan-2017
1
Check
Quarter:
Span Gas Samplin
Check Gas
90%
Respons Respons Respons
Span gas
Check gas
1-st 2nd 3rd
Concentratio g Flow Resul
Concentratio
Equipmen
Equipment Anlyze
Calibratio Resul of
Resul Measure Differenc Differenc Resul
e Time 1 e Time 2 e Time 3
Equip.Ser. No
Span Gas Cylinder
Check Gas Cylinder
chec chec chec
n
Rate
n
t No
Type
r Type
t
n error
t Span
t
d ppm
e ppm
e%
t
No
No
k
k
k
ppm
l/min
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
EA000939
3
972
0.88
OK
Methane FF524456
514
509 510 511
1.19%
OK
875.
4
3
3
4
OK
2.18
0.05
-2.35%
OK
2
0115248185
TVA1000B
FID
Methane
EA000939
3
972
0.92
OK
Methane FF524456
514
510 510 513
1.39%
OK
875.
4
3
3
3
OK
2.14
-0.04
-1.87%
OK
3
0115248937
TVA1000B
FID
Methane
EA000939
3
972
1.01
OK
Methane FF524456
514
513 512 512
1.65%
OK
875.
4
4
4
3
OK
2.13
-0.16
6.99%
OK
4
0115248938
TVA1000B
FID
Methane
EA000939
3
972
1.24
OK
Methane FF524456
514
515 514 512
1.92%
OK
875.
4
4
3
4
OK
2.29
0.16
-7.51%
OK
5
20201606143
6
TVA2020
FID
Methane
EA000939
3
972
0.97
OK
Methane FF524456
514
510 513 514
1.65%
OK
875.
4
3
3
3
OK
2.74
-0.03
1.08%
OK
MiniRAE200
0
PID
Isobutylen EA000996
e
2
997
0.52
OK
Isobutylen EA000996
e
2
997
996 995 995
-0.25%
OK
898
3
3
2
OK
2.77
0.03
-1.09%
OK
6
Quarterly Validation
page 25 of 29
Quarterly Validation of LDAR Devices
Sampling Flow
Rate
Accuracy Check
Response Time
Comparison between two Devices
Date: 30-Mar-2017
2
Check
Quarter:
Span Gas Samplin
Check Gas
90%
Respons Respons Respons
Span gas
Check gas
1-st 2nd 3rd
Concentratio g Flow Resul
Concentratio
Equipmen
Equipment Anlyze
Calibratio Resul of
Resul Measure Differenc Differenc Resul
e Time 1 e Time 2 e Time 3
Equip.Ser. No
Span Gas Cylinder
Check Gas Cylinder
chec chec chec
n
Rate
n
t No
Type
r Type
t
n error
t Span
t
d ppm
e ppm
e%
t
No
No
k
k
k
ppm
l/min
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
EA000939
3
972
0.97
OK
Methane FF524456
514
512 513 511
1.59%
OK
875.
2
4
4
5
OK
1.24
0.02
-1.64%
OK
2
0115248185
TVA1000B
FID
Methane
EA000939
3
972
0.99
OK
Methane FF524456
514
503 507 506
0.26%
OK
875.
2
3
3
4
OK
1.22
-0.02
-1.64%
OK
3
0115248937
TVA1000B
FID
Methane
EA000939
3
972
1.02
OK
Methane FF524456
514
508 509 507
0.79%
OK
875.
2
4
4
4
OK
1.37
-0.02
1.44%
OK
4
0115248938
TVA1000B
FID
Methane
EA000939
3
972
1.14
OK
Methane FF524456
514
515 512 512
1.79%
OK
875.
2
3
3
4
OK
1.39
0.02
-1.46%
OK
5
20201606143
6
TVA2020
FID
Methane
EA000939
3
972
0.92
OK
Methane FF524456
514
510 513 512
1.52%
OK
875.
2
3
3
4
OK
1.22
0.22
-22%
OK
MiniRAE200
0
PID
Isobutylen EA000996
e
2
997
0.51
OK
Isobutylen EA000996
e
2
997
995 996 996
-0.21%
OK
898
3
3
3
OK
1
-0.22
18.03%
OK
6
Quarterly Validation
page 26 of 29
Quarterly Validation of LDAR Devices
Sampling Flow
Rate
Accuracy Check
Response Time
Comparison between two Devices
Date: 30-Jun-2017
3
Check
Quarter:
Span Gas Samplin
Check Gas
90%
Respons Respons Respons
Span gas
Check gas
1-st 2nd 3rd
Concentratio g Flow Resul
Concentratio
Equipmen
Equipment Anlyze
Calibratio Resul of
Resul Measure Differenc Differenc Resul
e Time 1 e Time 2 e Time 3
Equip.Ser. No
Span Gas Cylinder
Check Gas Cylinder
chec chec chec
n
Rate
n
t No
Type
r Type
t
n error
t Span
t
d ppm
e ppm
e%
t
No
No
k
k
k
ppm
l/min
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
EA000939
3
972
0.97
OK
Methane FF524456
514
500 503 506
-0.2%
OK
875.
2
4
4
4
OK
1.62
-0.09
5.26%
OK
2
0115248185
TVA1000B
FID
Methane
EA000939
3
972
0.99
OK
Methane FF524456
514
506 505 507
0.4%
OK
875.
2
4
3
4
OK
1.71
0.09
5.26%
OK
3
0115248937
TVA1000B
FID
Methane
EA000939
3
972
1.02
OK
Methane FF524456
514
500 504 500
-0.53%
OK
875.
2
4
4
4
OK
1.88
0.15
-8.67%
OK
4
0115248938
TVA1000B
FID
Methane
EA000939
3
972
1.14
OK
Methane FF524456
514
507 504 504
0.2%
OK
875.
2
4
3
4
OK
1.73
-0.15
7.98%
OK
5
20201606143
6
TVA2020
FID
Methane
EA000939
3
972
0.92
OK
Methane FF524456
514
501 501 507
-0.2%
OK
875.
2
3
4
4
OK
1.17
-0.05
4.1%
OK
MiniRAE200
0
PID
Isobutylen EA000996
e
2
997
0.51
OK
Isobutylen EA000996
e
2
997
997 998 998
-0.01%
OK
898
3
4
3
OK
1.22
0.05
-4.27%
OK
6
Quarterly Validation
page 27 of 29
Quarterly Validation of LDAR Devices
Sampling Flow
Rate
Accuracy Check
Response Time
Comparison between two Devices
Date: 03-Oct-2017
4
Check
Quarter:
Span Gas Samplin
Check Gas
90%
Respons Respons Respons
Span gas
Check gas
1-st 2nd 3rd
Concentratio g Flow Resul
Concentratio
Equipmen
Equipment Anlyze
Calibratio Resul of
Resul Measure Differenc Differenc Resul
e Time 1 e Time 2 e Time 3
Equip.Ser. No
Span Gas Cylinder
Check Gas Cylinder
chec chec chec
n
Rate
n
t No
Type
r Type
t
n error
t Span
t
d ppm
e ppm
e%
t
No
No
k
k
k
ppm
l/min
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
EA000943
1
971
0.82
OK
Methane FF524456
514
505 504 505
-1.82%
OK
874.
3
3
3
3
OK
1.41
-0.31
18.02%
OK
2
0115248185
TVA1000B
FID
Methane
EA000943
1
971
1
OK
Methane FF524456
514
500 501 501
-2.78%
OK
874.
3
3
3
3
OK
1.72
0.31
18.02%
OK
3
0115248937
TVA1000B
FID
Methane
EA000943
1
971
1.1
OK
Methane FF524456
514
476 476 473
-7.95%
OK
874.
3
4
4
4
OK
2.14
0.09
-4.39%
OK
4
0115248938
TVA1000B
FID
Methane
EA000943
1
971
1.16
OK
Methane FF524456
514
496 487 485
-5.35%
OK
874.
3
4
4
4
OK
2.05
-0.09
4.21%
OK
5
20201606143
6
TVA2020
FID
Methane
EA000943
1
971
0.96
OK
Methane FF524456
514
486 487 486
-6.11%
OK
874.
3
3
3
3
OK
1.73
0.23
-15.33%
OK
MiniRAE200
0
PID
Isobutylen EA000996
e
2
997
0.51
OK
Isobutylen EA000996
e
2
997
994 995 995
-0.31%
OK
898
4
4
3
OK
1.5
-0.23
13.29%
OK
6
Quarterly Validation
page 28 of 29
CUMULATIVE PRODUCTION HOURS TEMPLATE 2017
Plant
TASHAN
Unit
Drawing
Stream Name
Remark
Annual Production
Hours
Alroy
6006-100-006
Gasoline
6,264
Alroy
6006-100-007
Gasoline
6,264
Production Hours
Q1
01/01-31/03
Quarter =
Quarterly Production
hours
2,160
2,160
Q2
01/04-30/06
Quarter =
Quarterly Production
hours
2,184
2,184
Q3
01/07-30/09
Quarter =
Quarterly Production
hours
1,920
1,920
Q4
01/10-31/12
Quarter =
Quarterly Production
hours
0
0
page 29 of 29
ספח ג'
דוגמת חישוב עבור מיכל גג חיצוי צף מס' 2המאחסן קרוסין
3013.13-013-T2
3013.13-026
26/02/2018
18/31
3013.13-015.doc
T2 - kerosene
External Floating roof
1. Tank data
Diameter of the tank
D
Effective height of the stock liquid (while
roof landing episode)
hle
Shell Color and condition
α
Roof color and condition
α
Tank paint solar absorptance
α
Vapor space outage (while roof landing
episode)
HVO
m
feet
m
feet
color
condition
color
condition
dimensionless
m
Tank data
--Tank data
--חאקי
טובה
לבן
טוב
48.77
160.01
11.00
0.89
Table 7.1-6
Assumption - Green Dark
0.17
Table 7.1-6
0.53
Table 7.1-6
Possible to use also equation
1-15
assumption - equal to legs height
feet
11.00
Volume of the vapor space (while roof
landing episode)
Breather vent pressure setting
VV
ft
3
VV=PI()*D /4*Hvo
221,185
Equation 1-3
∆PBP
psi
Typical value
0.50
Equation 1-11
Breather vent vacuum setting
∆PBV
psi
Typical value
0.00
Equation 1-11
Breather vent pressure setting range
∆PB
psi
∆PB = PBP − PBV
0.50
Equation 1-11
2
2. Material data - קרוסין
Stock vapor molecular weight
MV
Density of the liquid inside the tank
Wl
Vapor density
WV
True vapor pressure of the stock liquid
P
Vapor pressure at daily average liquid
surface temperature
Vapor pressure at the daily maximum
liquid surface temperature, psia
Vapor pressure at the daily minimum
liquid surface temperature
Daily vapor pressure range
3013.13-013 - 2
gr/gr-mole
lb/lb-mole
g/ml
lb/gal
kg/m^3
lb/ft3
msds data
130
msds data
--msds data
---
0.80
6.68
4.5
0.28
mm Hg
PEI data
0.833
psia
--הנחה:
Pv=nRT -->
P2=P1*(T2/T1)
0.02
0.02
0.02
0.00
PVA
psia
PVX
psia
PVN
psia
T1(k)=20C+273
T2(k)=37.5C+273
∆PV
psia
∆PV = PVX − PVN
1/3
0
at 20°C
0.02
Equation 1-9
22/02/2018
3. Operation data
Number of days that the tank stands idle
(on roof landing episode)
Number of degassing and cleaning
episode
Number of roof landing episode
nd
days/landing episode
site data
4
landing episode/year
site data
0.07
landing episode/year
site data
0.07
Tanks Program
--Tanks Program
---
48
22
94
43
21
Tanks Program
---
60.05
27
lb per emptying
Tanks Program
67
Kg per emptying
---
30
4. Normal operation (Tanks program)
lb per year
Kg per year
lb per year
Kg per year
Kg per year
Working (withdrawal) losses
Total emissions (Breathing & Working)
Breathing (standing) losses
5. Degassing and Cleaning (Tanks program)
Degassing: emission from one turnover of
lb per emptying
Edegass-floating
floating roof
Kg per emptying
Degassing: fixed roof with a height of roof
legs
Edegass-legs
Liquid fraction in sludge
Fliquid
Sludge volume
Sludge weight
Vs
Ws
Cleaning emissions
Ecleaning
Total Degassing and Cleaning emissions
Edegass-total
3013.13-013 - 2
0.8
m3 per emptying
Kg per emptying
lb per emptying
Kg per emptying
lb per emptying
Kg per emptying
Ecleaning = Ws * (1-Fliquid)
Edegass-total =
Edegass-floating + Edegass-legs + Ecleaning
2/3
T2 - B&W 2017
T2 - B&W 2017
T2 - DFloating 2014
T2- DFixed 2014
(Only working losses)
Tanks FAQ - degassing and
cleaning
70
56,000
24,692
11,200
24,818
11,257
22/02/2018
6. Roof landing
Daily average liquid surface temperature
TLA
°R
T LA = 0 . 44 T AA + 0 . 56 T B + 0 . 0079 * α * I
534.97
Equation 1-26
Daily vapor temperature range
∆TV
°R
∆ TV = 0 .72 ∆ T A + 0.028 * α * I
41.01
Equation 1-8
Daily maximum liquid surface temperature
TLX
°R
TLX = TLA + 0.25*∆TV
545.22
Figure 7.1-17
Daily minimum liquid surface temperature
TLN
°R
TLN = TLA - 0.25*∆TV
524.71
Figure 7.1-17
Liquid bulk temperature
Max standing idle losses during roof
landing
TB
°R
TB = TAA + 6α - 1
528.15
Equation 1-28
LSL-max
lb per landing episode
Kg per landing episode
dimensionless
2
LSL-max = 5.9*D *hle*W l
--0.60 for a full liquid heel
0.50 for a partial
0.15 for drain-dry
11,093,038 Equation 2-13
5,031,769
0.50
Equation 2-26
(pages No 33,35)
1
KS =
1 + 0.053 * PVA * H VO
0.5
Equation 1-20
KS is assumed to be less than
or equal to the saturation factor
during filling (S) .
∆ TV ∆ PV − ∆ PB
+
T LA
PA − PVA
0.043
Liquid stock has a true vapor
pressure greater than 0.1psia Equation 1-7.
Filling saturation factor
S
saturation factor
KS
dimensionless
Vapor space expansion factor
KE
dimensionless
Standing idle losses during roof landing
LSL
lb per landing episode
PV
L SL = n d K E V M V K S
RT AA
7
Equation 2-16
Filling losses during roof landing
LFL
lb per landing episode
P * VV
M V * S
L FL =
R * T AA
41
Equation 2-26
Total losses during roof landing
LTL
lb per landing episode
Kg per landing episode
48
22
Equation 2-10
KE =
LTL=LSL+LFL
7. Summary
Working (withdrawal) losses
Breathing (standing) losses
Kg per year
Kg per year
22
21
Total Degassing and Cleaning emissions
Kg per year
750
Total losses during roof landing
Kg per year
1
795
3013.13-013 - 2
3/3
Kg per year
22/02/2018
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - B&W 2017
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
0.86
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Red/Primer
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock
Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
1
2
29
43
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
14/02/2018
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - B&W 2017 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
All
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
81.75
66.81
96.69
Liquid
Bulk
Temp
(deg F)
70.60
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0161
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
14/02/2018
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Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - B&W 2017 - External Floating Roof Tank
Haifa, Israel
Annual Emission Calcaulations
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
0.0161
160.0100
130.0000
1.0000
Withdrawal Losses (lb):
Annual Net Throughput (gal/yr.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
47.8696
6,498,077.0000
0.0075
7.0000
160.0100
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
5.3401
0.0003
130.0000
1.0000
150.3024
6.2000
Total Losses (lb):
93.9049
40.6952
1.6000
0.3000
6.2000
1.6000
0.0003
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock
Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
1
2
29
43
1
KFa(lb-mole/yr)
1.60
11.00
6.20
1.20
0.49
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
9.90
1.20
0.14
0.16
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.89
0.94
0.65
0.14
1.00
Losses(lb)
0.1705
1.6897
0.7794
1.6109
1.0488
0.0406
14/02/2018
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Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
14/02/2018
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - B&W 2017 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
40.70
47.87
5.34
0.00
93.90
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
14/02/2018
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
14/02/2018
TANKS 4.0 Report
Page 1 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFloating 2014
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.00
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Red/Primer
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock
Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
1
2
29
43
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
25/02/2018
TANKS 4.0 Report
Page 2 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFloating 2014 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Month
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
Liquid
Bulk
Temp
(deg F)
Vapor Pressure (psia)
Avg.
Min.
Max.
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
25/02/2018
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Page 3 of 5
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
25/02/2018
TANKS 4.0 Report
Page 4 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFloating 2014 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
3.61
55.99
0.46
0.00
60.05
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
25/02/2018
TANKS 4.0 Report
Page 5 of 5
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
25/02/2018
TANKS 4.0 Report
Page 1 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFixed 2014
Haifa
Israel
PEI
Vertical Fixed Roof Tank
kerosene
Tank Dimensions
Shell Height (ft):
Diameter (ft):
Liquid Height (ft) :
Avg. Liquid Height (ft):
Volume (gallons):
Turnovers:
Net Throughput(gal/yr):
Is Tank Heated (y/n):
N
Paint Characteristics
Shell Color/Shade:
Shell Condition
Roof Color/Shade:
Roof Condition:
Red/Primer
Good
White/White
Good
Roof Characteristics
Type:
Height (ft)
Slope (ft/ft) (Cone Roof)
Breather Vent Settings
Vacuum Settings (psig):
Pressure Settings (psig)
11.00
160.01
11.00
5.50
1,654,664.74
1.00
1,654,664.74
Cone
0.00
0.00
0.00
0.50
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
25/02/2018
TANKS 4.0 Report
Page 2 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFixed 2014 - Vertical Fixed Roof Tank
Haifa, Israel
Mixture/Component
Month
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
Liquid
Bulk
Temp
(deg F)
Vapor Pressure (psia)
Avg.
Min.
Max.
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
25/02/2018
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Page 3 of 5
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
25/02/2018
TANKS 4.0 Report
Page 4 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFixed 2014 - Vertical Fixed Roof Tank
Haifa, Israel
Losses(lbs)
Components
Working Loss
Breathing Loss
Total Emissions
Jet kerosene
66.66
51.49
118.15
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
25/02/2018
TANKS 4.0 Report
Page 5 of 5
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
25/02/2018
ספח ד'
דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 1של קרוסין
3013.13-014
26/02/2018
19/31
3013.13-015.doc
Transportation - Loading losses
Loading arm #1 - Kerosene
Density
Tank paint solar absorptance
Daily average ambient temperature
Wl
α
TAA
Yearly consumption
Myear
Cargo tank volume
V
Ntrucks
t
g/ml
dimensionless
°R
ton
m3
gal
m3
gal
1/year
min
Saturation factor
S
dimensionless
True vapor pressure of liquid
P
Molecular weight of vapors
M
Number of tank trucks
Duration of road truck filling
Table 5.2-1
mmHg
psia
0.833
0.02
@ 20°C
lb/lb-mole
130
Table 7.1-2
T=TB
°R
Controlled efficiency for the recovery
unit (vapor recovery efficiency)
eff1
%
vapor collection efficiency
eff2
%
overall reduction efficiency
eff
Flow rate of pollutant emission during
loading
Annual pollutant emission during
loading
T = TB = TAA + 6α - 1
LL
%
lb/10 gal
loaded
LL total lb / loading
lb / min
Q
Kg / min
Kg / hr
Etotal
527.40
0
Truck passed the NSPS-level
annual test
70.0
eff=eff1*eff2/100
0
3
Loading losses of petroleum liquids
(uncontrolled emission rate)
0.80
0.41
525.97
120
151
39,864
30.0
7,925
5
30
0.6
Temperature of bulk liquid loaded
Total loading losses of petroleum
msds data
site data
"Site" tab @ 3013-037
--data
--data
--Ntrucks = Myear / V
data
Submerge loading, dedicated
normal service
Kg / year
L L = 12.46
S *P*M
eff
1 −
T
100
0.030
LLtotal = LL*V
Q = Lltotal / t
-----
0.24
0.008
0.004
0.21
Etotal = LLtotal*Ntruks
0.53
Equation 1-28
page 5.2-6
can be 90% to over 99%
page 5.2-6
99.2- for tanker truck passed the
MACT-level annual leak test
98.7- for truck passed the NSPS-level
annual test
70 - for trucks not passing one of
these leak tests
Page 5.2-4 Equation 1
Assumption: the mass of the
Average pollutant emission
concentration during loading
3013.13-014.xls - 1
C
gr / m
3
C = Q *t / V
3.6
1/1
pollutant is contained in the air
volume inside the tanker which is
replaced by the liquid loaded
26/02/2018
ספח ה'
חישוב פליטות ממיכל לאיסוף תשטיפים
26/02/2018
20/31
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תוכת :Tanksחישוב פליטה כתוצאה מאחסון ושיוי מפלס
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24/31
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תוכת :Tanksחישוב פליטה כתוצאה מיקוי וריקון מיכל )שלב א'(
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26/31
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27/31
26/02/2018
תוכת :Tanksחישוב פליטה כתוצאה מיקוי וריקון מיכל )שלב ב'(
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חישובי פליטה ממיכל תשטיפים
גיליון חישוב זה הוכן על ידי "פז" הדסה ויהול ) (1980בע"מ.
אין להעתיק ו\או לעשות שימוש כלשהו במידע ה"ל ללא הרשאה כתובה מ"פז" הדסה ויהול ) (1980בע"מ.
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מסמך 7 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 3707 KB)
תשתיות נפט ואנרגיה בע"מ
מסוף אלרואי
סיכום פליטות לאוויר
שנת 2018
פרויקט3013.15 :
סימוכין3013.15-036 :
פברואר 2019
תוכן עניינים
.1מבוא 4.............................................................................................................................
.2נתוני מסוף 5.....................................................................................................................
.2.1נתוני מיכלים 5.........................................................................................................
.2.2נתונים עבור מסוף מילוי מיכליות כביש 9.....................................................................
.3חישוב פליטות 10 ..............................................................................................................
כללי10 ....................................................................................................... ...........
.3.1
סוגי פליטות מחושבות 10 .........................................................................................
.3.2
בחירת חומרים בתוכנת 11 ......................................................................... TANKS
.3.3
נתונים מטאורולוגיים 11 ..........................................................................................
.3.4
.4סיכום פליטות לשנת 12 ............................................................................................. 2018
מיכלים 12 ..................................................................................................
.4.1
מסוף מילוי מיכליות כביש 12 ..........................................................................
.4.2
מיכל איסוף תשטיפים 13 ...............................................................................
.4.3
סיכום ממצאי ניטור 13 ....................................................................... LDAR
.4.4
פליטה שנתית מכלל המתקן 13 ........................................................................
.4.5
.5פליטות לא שגרתיות במהלך שנת 13 ............................................................................2018
.6מקורות 14 .......................................................................................................................
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טבלאות
טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 5........................................... 2018
טבלה :2נתוני מעטפת וגגות – שנת 6.................................................................................. 2018
טבלה :3נתוני אביזרים – שנת 7......................................................................................... 2018
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת 8................................................... TANKS
טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 9...................................................... 2018
טבלה :6חומרים מייצגים בתוכנת 11 ............................................................................ TANKS
טבלה :7סיכום פליטות מכלים -שנת 12 ............................................................................ 2018
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שנת 12 ..................................................2018
טבלה :9סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 13 .................................. 2018
טבלה :10סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 13 .................................................2018
נספחים
נספח א'
טבלה )AP-42( 1-5.2
נספח ב'
נתוני ניטור LDARעבור מסוף אלרואי – סיכום שנת 2018
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין
נספח ד'
דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 1של קרוסין
נספח ה'
חישוב פליטות ממיכל לאיסוף תשטיפים
שניר דרור
שם עורך
25/02/2019
יואב פיסטינר
שם מאשר
להערות
תיאור
25.02.2019
תאריך
3/31
0
גרסה
3013.15-036.doc
.1מבוא
חברת תשתיות נפט ואנרגיה בע"מ (להלן תש"ן) מפעילה את מסוף אלרואי לאחסון ושינוע
דלקים .
המסוף כולל:
מבני משרדים
חוות מכלים לאחסון דלקים מסוגים שונים
רציפי מילוי מכליות כביש (לשימוש בעת חירום בלבד)
המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכונת
אלרואי ומדרום לו שכונת קרית חרושת.
באתר 9מיכלים ,מתוכם 5מיכלים תפעוליים ו 4-מיכלים אסטרטגים (מיכלים מס' 7,6,1ו.)9-
מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוסף קיימות מערכות תומכות כגון
מערכות כיבוי אש ומערכות פיקוד ובקרה.
כחלק מהתנאים ברישיון עסק מדצמבר ,2010בסוף כל שנה קלנדרית על תש"ן להגיש דו"ח
סיכום פליטות שנתי לגבי השנה שחלפה.
חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקנים
הקיימים במסוף.
סיכום הפליטות הוכן על ידי חברת "פז" הנדסה וניהול ( )1980בע"מ (להלן פז הנדסה) ,והוא
מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.
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.2נתוני מסוף
.2.1נתוני מיכלים
בטבלאות הבאות מפורט מידע טכני של המיכלים בחוות המיכלים אלרואי.
טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 2018
לחץ אדים
בטמפ' הנוזל
הממוצעת
)(mmHg
405 @ 28°C
כמות
צריכה
שנתית
(מ"ק)
28,206
גבעה חלקית
37,445
גבעה חלקית
48.77
גבעה חלקית
48.77
32,056
48.77
32,056
28,768
56,959
51,614
15.56
51,614
15.56
14.1
15.56
14.1
11.4
18.3
18.3
15.4
9.7
סוג ניקוז
בתחתית
מיכל
קוטר
מיכל
(מטר)
נפח מיכל
(מ"ק)
נפח מיכל
פעיל
(מ"ק)
48.77
32,056
28,768
גובה /אורך
מעטפת
מיכל
(מטר)
17.16
15.4
32,056
28,768
17.16
15.4
10
28,768
17.16
15.4
9.5
17.16
15.4
10.3
14.1
14.1
14.1
מספר
מיכל
סוג הדלק
המאוחסן
() 1
בנזין
2
קרוסין
0.833 @ 28°C
3
סולר
0.507 @ 28°C
37,035
4
סולר
0.507 @ 28°C
43,547
גבעה חלקית
5
סולר
0.507 @ 28°C
57,578
גבעה מלאה
68.27
6
() 3
סולר
0.507 @ 28°C
0
גבעה מלאה
68.27
56,959
7
()3
סולר
0.507 @ 28°C
0
גבעה מלאה
68.27
56,959
51,614
8
()4
קרוסין
0.833 @ 28°C
51,102
גבעה חלקית
48.8
36,547
34,228
19.54
9
() 2
קרוסין
0.833 @ 28°C
28,732
גבעה חלקית
48.77
32,056
28,768
17.16
367,704
332,913
1
289,645
סה"כ
( )1מכל מס' 1משמש כמכל מלאי ,בחודש פברואר עד אפריל המיכל עבר ריקון ומילוי חומר.
( )2מכל מס' 9משמש כמכל מלאי ,עבר שיפוץ ורק במהלך חודש אוקטובר נובמבר אוחסן חומר במיכל.
( )3מכלים מס' 6ו 7-משמשים כמכלי מלאי ,לא היו תנועות במכלים בשנת .2018
( )4מכל 8בשיפוץ מחודש נובמבר.
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גובה נוזל
מירבי
(מטר)
גובה נוזל
ממוצע
(מטר)
10.5
טבלה :2נתוני מעטפת וגגות – שנת 2018
מספר
מיכל
סוג גג
אטם ראשי
אטם משני
1
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Liquid
mounted
Mechanical
Shoe
Rim
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Rim
mounted
Rim
mounted
2
3
4
5
6
7
8
9
25/02/2019
צורת גג
סוג
חיבורי
גג
צבע
גג
מצב
צבע
גג
צבע
מעטפת
חיצונית
מצב צבע
מעטפת
חיצונית
סוג חיבורי
מעטפת
מצב
מעטפת
פנימית
מיכל
מחומם
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חאקי
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חאקי
ישן
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
כחול בהיר
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
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טבלה :3נתוני אביזרים – שנת 2018
מספר
מיכל
1
2
3
4
5
6
7
8
9
סה"כ
שובר ואקום
כמות
2
2
2
2
2
2
2
6
2
25/02/2019
Vacuum
]set. [psi
0
0
0
0
0
0
0
0
0
Pressure
]set. [psi
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
רגליים מתכווננות התומכות
בגג צף
גובה
כמות באזור
כמות
במרכז
()ft
pontoon
29
43
11
29
43
11
29
43
11
29
43
11
72
107
11
72
107
11
72
107
11
36
54
9
29
43
11
7/31
כמות
מדי
מפלס
Rim
Vent
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
כמות בוצה
בנקיון
(מ"ק)
"גרביים" לבאר
הדיגום המחורצת
ולרגלי הגג הצף
70
70
70
70
150
150
150
70
70
870
יש
יש
יש
יש
יש
יש
יש
יש
יש
3013.15-036.doc
הנחות שנלקחו לצורך החישובים
.1עבור חישוב Degassingבמיכל עם גג צף – הונח:
גג צף נח על רגליים בגובה ( 9-11 ftבהתאם לטבלה לעיל) וזהו גם הגובה המרבי של הנוזל
במיכל.
גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.
.2הונח כי ניקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שנים .הניקיון יארך יום אחד.
.3הונח כי אירוע של נחיתת גגות צפים מתבצע אחת ל 15-שנים .זמן נחיתת הגג במקרה זה לא
יעלה על 4ימים.
.4יחס הנוזל בבוצה הונח כ]2[ 0.8 -
.5בהתאם לטבלה 7.1-6על פי [ ,]1נבחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,
לצורך חישובי פליטות לאוויר:
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת Tanks
צבע מעטפת
מיכל
צבע לצורך חישובי אקסל
צבע לצורך חישובים בתוכנת
בהתאם למסמך EPA AP-42
)*( Tanks
כחול בהיר
Gray Medium
Gray Medium
חאקי
Green Dark
Red/Primer
צהוב קרם
Beige/Cream
Aluminium/Specular
(*) בתוכנת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך
.]1[ EPA AP-42
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.2.2נתונים עבור מסוף מילוי מיכליות כביש
טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 2018
מס'
זרוע
1
2
3
4
5
6
7
8
מוצר
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
סה"כ
מילוי
עילי /תחתי
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
נפח ממוצע של
מיכלית (מ"ק)
30
30
30
30
30
30
30
30
נפח מילוי שנתי
(מ"ק)
2,066
0
0
0
0
0
0
0
2,066
הנחות שנלקחו צורך החישובים
.1
מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:
א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:
דוגמת חישוב עבור מיכל מס' :2
0.17 0.834
0.25
2
) roof(2) Shell(2
2
tank2
ב .בשלב השני חושב מקדם αממוצע עבור הקרוסין:
0.25 0.43 0.26
0.31
3
) tank(2) tank(8) tank(9
number of kerosene tanks
Kerosene
.2
זמן מילוי מיכלית חושב על פי נפח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000
ליטר/דקה.
.3
Vapor collection efficiency - 70%
.4
Vapor recovery efficiency - 0%
.5
Saturation factorהונח כ (Submerged loading, dedicated normal service) 0.6-על פי
[ .]1טבלה רלוונטית מצורפת בנספח א'.
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.3חישוב פליטות
.3.1כללי
חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכנת Tanksובעזרת .]1[ EPA-AP 42
הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ( )LDARמצורפת בנספח ב'.
דוגמת חישוב עבור מיכל גג חיצוני צף (מיכל מס' )2המאחסן קרוסין ,מצורפת כנספח ג' למסמך
זה.
דוגמת חישוב עבור זרוע מילוי עילי של קרוסין (זרוע מס' )1מצורפת כנספח ד' למסמך זה.
בדוגמאות אלה ניתן לראות את נתוני הקלט (כולל הנחות) עליהם התבססו החישובים.
.3.2סוגי פליטות מחושבות
הערכת הפליטות ממיכלי אחסון כוללת [:]3
פליטות בזמן אחסון )(Breathing Losses
פליטות משינויי מפלס )(Working Losses
פליטות כתוצאה מניקוי וריקון מיכלים )(Degassing Losses
פליטות כתוצאה מנחיתת גגות צפים )(Roof Landing Losses
פליטות כתוצאה מהפרשי לחץ )(Flash Losses
פליטות בזמן מילוי מיכלים ומיכליות
בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ
).(Flash Losses
פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלחץ הנוזל ,נתון הגורם להפרת שיווי המשקל
הקיים במיכל (בין גז לנוזל) וכתוצאה מכך נוצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הנוזל
עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר נוזל המאוחסן בלחץ נשלח
לאחסון במיכל בעל לחץ נמוך יותר [.]3
פליטות אלו הוזנחו כיוון שכל החומרים מוחזקים בתנאים אטמוספריים בכל אחד מהשלבים
הנוגעים להובלתם ואחסונם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.
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.3.3בחירת חומרים בתוכנת Tanks
על פי נתוני MSDSשל הדלקים במסוף ,נבחרו החומרים הבאים הקיימים בתוכנת Tanks
כמייצגים של חומרים אלו:
טבלה :6חומרים מייצגים בתוכנת Tanks
דלק קיים במסוף
חומר מייצג בתוכנת Tanks
סולר (תחבורה והסקה)
Distillate fuel oil no 2
נפט (קרוסין)
Jet kerosene
בנזין
Gasoline RVP 10
.3.4נתונים מטאורולוגיים
לצורך חישוב הנתונים בתוכנת Tanksהוגדרו נתונים מטאורולוגים המתאימים למפרץ חיפה על פי
מקורות [.]4
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.4סיכום פליטות לשנת 2018
.4.1מיכלים
סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:
טבלה :7סיכום פליטות מכלים -שנת 2018
מיכל
חומר
פליטות לאוויר
(ק"ג/שנה)
1
בנזין (*)
3,092
2
קרוסין
806
3
סולר
46
4
סולר
839
5
סולר
1,732
6
סולר
1,695
7
סולר
1,695
8
קרוסין (ינואר – אוקטובר)
682
9
קרוסין (אוקטובר-נובמבר)
152
10,740
סה"כ
(*) מכל מס' – 1לא אוחסן חומר בחודש פברואר – אפריל במהלך השנה.
.4.2מסוף מילוי מיכליות כביש
להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שנת 2018
מס' זרוע
מוצר
מילוי עילי /תחתי
1
2
3
4
5
6
7
8
סה"כ
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
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פליטה שנתית
(ק"ג/שנה)
7.36
0
0
0
0
0
0
0
7.36
3013.15-036.doc
.4.3מיכל איסוף תשטיפים
סך הפליטה ממיכל לאיסוף תשטיפים הינה כ 1 -ק"ג/שנה.
חישוב מצורף בנספח ה'.
יצוין כי החישוב מתבסס על הנחה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל
בעיקר ניקוז מים מהמכלים.
.4.4סיכום ממצאי ניטור LDAR
טבלה :9סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 2018
סה"כ פליטות (ק"ג/שנה)
סיכום פליטות LDAR
פליטה שנתית (ק"ג/שנה)
סה"כ
22
.4.5פליטה שנתית מכלל המתקן
טבלה :10סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 2018
סה"כ פליטות (ק"ג/שנה)
חוות מיכלים
מסוף מילוי
מיכליות כביש
מיכל לאיסוף
תשטיפים
10,740
7.36
1
סיכום פליטות
רכיבים
סה"כ
()LDAR
22
10,770
.5פליטות לא שגרתיות במהלך שנת 2018
במהלך שנת 2018לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.
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.6מקורות
]1[ EPA-AP42
]2[ USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version
4.0 - APPENDIX D
[ ]3הנחיות הממונה לטיפול בבקשה להיתר פליטה לפי סעיף (9א) לתקנות אוויר נקי (היתרי פליטה),
התש"ע – ,2010מהדורה ,4ספטמבר 2014
[ ]4האטלס האקלימי לתכנון פיסי וסביבתי בישראל ,מהדורה שנייה1994 ,
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נספח א'
טבלה 5.2-1
AP-42
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נספח ב'
נתוני ניטור LDARעבור אלרואי – סיכום שנת 2018
(מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך )03.02.2019
3013.15-004A
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LDAR
Fugitive Emission Monitoring
Report No.
RL-TS-R-A-18
Plant:TASHAN
City:Haifa
District:Haifa
Production Unit:Alroy
Group:Group 1-2-3
Reporting period:Annual Summary
Report printing date:03-Feb-2019
Technicians names:Polik
Portselan
Tomarov
Report editor:
Michael Ourievsky
Approved by:
Alexey Ratner, CEO
1
Table of Content
1. Project introduction
1.1 Scope of work
1.2 Project phases
2. Methodology
2.1 Definitions
2.2 Methodology
3. Summary of Monitoring Period
3.1 Cumulative Data of Monitoring Period
3.2 Summary of Monitoring Period
3.3 Form 07: component classification and emission estimations for production facilities
3.4 Chemical Summary
3.5 LDAR report for production facilities
4. First Measurement and Measurement After Repair Round 1
4.1 Form-07 by Round
4.2 Chemical Summary First Measurement
4.3 Chemical Summary After Repair
4.4 LDAR report for production facilities
5. First Measurement and Measurement After Repair Round 2
5.1 Form-07 by Round
5.2 Chemical Summary First Measurement
5.3 Chemical Summary After Repair
5.4 LDAR report for production facilities
6. First Measurement and Measurement After Repair Round 3
6.1 Form-07 by Round
6.2 Chemical Summary First Measurement
6.3 Chemical Summary After Repair
6.4 LDAR report for production facilities
7. First Measurement and Measurement After Repair Round 4
7.1 Form-07 by Round
7.2 Chemical Summary First Measurement
7.3 Chemical Summary After Repair
7.4 LDAR report for production facilities
8. First Measurement and Measurement After Repair Round 5
8.1 Form-07 by Round
8.2 Chemical Summary First Measurement
8.3 Chemical Summary After Repair
8.4 LDAR report for production facilities
9. First Measurement and Measurement After Repair Round 6
9.1 Form-07 by Round
9.2 Chemical Summary First Measurement
9.3 Chemical Summary After Repair
9.4 LDAR report for production facilities
Table Of Content
5
5
6
6
8
9
16
17
19
21
22
23
24
26
27
28
29
31
32
34
36
38
39
40
41
43
44
46
48
50
51
52
53
page 2 of 116
10. Graphs First Measurement Round 1
10.1 Overview by Reading Range
10.2 Comparison between count of sources & kg/year, by sources
10.3 Total overview by chemicals
11. Graphs Measurement After Repair Round 1
11.1 Overview by Reading Range
11.2 Comparison between count of sources & kg/year, by sources
11.3 Total overview by chemicals
12. Graphs First Measurement Round 2
12.1 Overview by Reading Range
12.2 Comparison between count of sources & kg/year, by sources
12.3 Total overview by chemicals
13. Graphs Measurement After Repair Round 2
13.1 Overview by Reading Range
13.2 Comparison between count of sources & kg/year, by sources
13.3 Total overview by chemicals
14. Graphs First Measurement Round 3
14.1 Overview by Reading Range
14.2 Comparison between count of sources & kg/year, by sources
14.3 Total overview by chemicals
15. Graphs Measurement After Repair Round 3
15.1 Overview by Reading Range
15.2 Comparison between count of sources & kg/year, by sources
15.3 Total overview by chemicals
16. Graphs First Measurement Round 4
16.1 Overview by Reading Range
16.2 Comparison between count of sources & kg/year, by sources
16.3 Total overview by chemicals
17. Graphs Measurement After Repair Round 4
17.1 Overview by Reading Range
17.2 Comparison between count of sources & kg/year, by sources
17.3 Total overview by chemicals
18. Graphs First Measurement Round 5
18.1 Overview by Reading Range
18.2 Comparison between count of sources & kg/year, by sources
18.3 Total overview by chemicals
19. Graphs Measurement After Repair Round 5
19.1 Overview by Reading Range
19.2 Comparison between count of sources & kg/year, by sources
19.3 Total overview by chemicals
20. Graphs First Measurement Round 6
20.1 Overview by Reading Range
20.2 Comparison between count of sources & kg/year, by sources
20.3 Total overview by chemicals
Table Of Content
55
57
56
59
61
60
63
65
64
67
69
68
71
73
72
75
77
76
79
81
80
83
85
84
87
89
88
91
93
92
95
97
96
page 3 of 116
21. Graphs Measurement After Repair Round 6
21.1 Overview by Reading Range
21.2 Comparison between count of sources & kg/year, by sources
21.3 Total overview by chemicals
22. Graphs Cumulative
22.1 Comparison between count of sources above leak definition, by quarter
22.2 Comparison between % of components above leak definition by quarter
22.3 Comparison between count of sources & kg/year, by sources Cumulative
22.4 Total overview by chemicals
23. Attachments
23.1 Calibration loglist
23.2 Calibration gas certificates
23.3 Composition list & Response Factors
23.4 Quarterly equipment check Q1
23.5 Quarterly equipment check Q2
23.6 Quarterly equipment check Q3
23.7 Quarterly equipment check Q4
23.8 Quarterly production hours
Table Of Content
99
101
100
103
104
105
106
108
109
111
112
113
114
115
116
page 4 of 116
1 Project introduction
1.1 Scope of work
6 rounds of measurements (from 01/01/2018 to 31/12/2018)
Measurements performed for following classes:
Group 1: PRD, Sampling Point
Group 2: Open End, Stem Valve
Group 3: Connection, Flange
1.2 Project phases
Monitoring: Group 1-2-3
Re-measurement after repair action
Revision of equipment and production processes
Inventorisation: adding or deleting components
Mapping of components on P&ID's
General
1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory
Accreditation Authority).
2. ISRAC is not responsible for the test results.
Project Introduction
page 5 of 116
2 Methodology
1.1 Definitions
Chemical State:
Gas/Vapor: stream which is in process conditions under gaseous or vapor form.
Light Liquid: a liquid having a VOC content greater than 10% (by volume) hat evaporates at 150°C
Heavy Liquid: a liquid having a VOC content of 10% or less (by volume) that evaporates at 150°C
Leak definition: 1,000 ppm (all sources)
Difficult to monitor components:
Any component situated at a level higher than five meters above ground level or any component situated at a distance further than
two meters from a platform and which cannot be accessed by employees in a safe way.
Any component which access requires the elevation of a person to a level higher than two meters above regular surfaces, and which
cannot be accessed in a safe.
Registered sources:
Sources with a leak value equal or greater than 9 ppm.
Default-zero:
This equation is valid for sources with a leak value of 0 ppm.A fixed EPA emission calculation rule is used for all these sources.
Total components:
All of the existing active components.
Total measured components:
All of the components, measured in specific monitoring round.
2.2 Methodology
Formulas:
Measured ppm values are converted to emission loss (kg/year) and these calculations are based on the E.P.A. “Correlation method
Refinery”
Modified Trapezoidal Emission Calculation Method:
The modified trapezoid method assumes that the mass leak rate changes linearly between any two monitoring points, except for
periods between leak detection and repair; the leak monitor reading is used from the time the leak is detected to the time it is repaired (i.e.,
re-screened).
Cumulative data:
In "Cumulative data" tables we provide the results of all of the measurements that performed from beginning of the year till the end of
current monitoring period (quarter). We also calculate the real sum of previous emissions based on the all rounds of the measurements
(before and after repairing attempts).(US EPA "Emission Estimation Protocol for Petroleum Refineries")
Methodology
page 6 of 116
Equation Set Details Report
Equation Set
Class
Chemical State
Default Zero
Pegged 100k
Multiplier
Exponent
Avg. Factor
Refinery
Connection
Light Liquid
7.5E-06
0.03
1.53E-06
0.735
0.00025
Refinery
Flange
Light Liquid
3.1E-07
0.084
4.61E-06
0.703
0.00025
Refinery
Open End
Light Liquid
2E-06
0.079
2.2E-06
0.704
0.0023
Refinery
PRD
Light Liquid
4E-06
0.11
1.36E-05
0.589
0.16
Refinery
Sampling Point
Light Liquid
4E-06
0.11
1.36E-05
0.589
0.015
Refinery
Stem Valve
Light Liquid
7.8E-06
0.14
2.29E-06
0.746
0.0109
Equations
page 7 of 116
Summary of Period: 01/01/2018-31/12/2018
The total emissions: 22.275kg
Component
Class
Total Components
count
PRD
Sampling Point
Total Group 1:
Stem Valve
Open End
Total Group 2:
Flange
Connection
Total Group 3:
4
4
8
20
102
122
55
38
93
Total:
Overview by component class
Total Components above leak definition
% of components above leak definition
Unrepaired Components
(1,000 ppm)
(1,000 ppm)
count
%
count
Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round
1
2
3
4
5
6
1
2
3
4
5
6
1
2
3
4
5
6
223
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
1
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
1.0%
0.8%
0.0%
0.0%
0.0%
0.4%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Total Emissions
kg
01/01/2018- 31/12/2018
0
0
0
0
0
0
0
0
0
0.548
0.14
0.688
1.367
17.574
18.941
0.149
2.497
2.646
0
22.275
Overview by reading range
Reading Range
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
Total:
Cumulative Data
#
Round 1
6
2
0
0
0
0
8
%
#
75.0%
25.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 2
8
0
0
0
0
0
8
%
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 3
183
40
0
0
0
0
223
Total Components
%
#
82.1%
17.9%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 4
8
0
0
0
0
0
8
%
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 5
126
3
1
0
1
0
130
%
#
96.9%
2.3%
0.8%
0.0%
0.8%
0.0%
100.0%
Round 6
8
0
0
0
0
0
8
%
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
page 8 of 116
Summary of Monitoring Period Round 1
First measurement:
0 "difficult to monitor" sources.
6 default-zero sources with a calculated emission rate:
2 registered sources with a calculated emission rate:
0.21 kg/year
2.886 kg/year
3.096 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
6
2
0
0
0
0
Total:
8
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
2
0
0.00%
0
2.956
4
0
0
0.00%
0
0.14
8
2
0
0.00%
0
3.096
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
75.00%
0.21
6.78%
25.00%
2.886
93.22%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
3.096
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
6 default-zero sources with a calculated emission rate:
2 registered sources with a calculated emission rate:
0.21 kg/year
2.886 kg/year
3.096 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
2
0
0.00%
0
2.956
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
2
0
0.00%
0
3.096
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
6
2
0
0
0
0
Total:
8
Summary R1
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
75.00%
0.21
6.78%
25.00%
2.886
93.22%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
3.096
Comments
100%
page 9 of 116
Summary of Monitoring Period Round 2
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
0
0
0.00%
0
0.14
8
0
0
0.00%
0
0.28
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Summary R2
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
page 10 of 116
Summary of Monitoring Period Round 3
First measurement:
0 "difficult to monitor" sources.
183 default-zero sources with a calculated emission rate:
40 registered sources with a calculated emission rate:
5.379 kg/year
25.571 kg/year
30.95 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Stem Valve
Open End
Flange
Connection
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
183
40
0
0
0
0
Total:
223
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
0
0
0.00%
0
0.14
20
0
0
0.00%
0
1.367
102
40
0
0.00%
0
26.658
55
0
0
0.00%
0
0.149
38
0
0
0.00%
0
2.497
223
40
0
0.00%
0
30.951
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
82.06%
5.379
17.38%
17.94%
25.571
82.62%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
30.95
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
183 default-zero sources with a calculated emission rate:
40 registered sources with a calculated emission rate:
5.379 kg/year
25.571 kg/year
30.95 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Stem Valve
20
0
0
0.00%
0
1.367
Open End
102
40
0
0.00%
0
26.658
Flange
55
0
0
0.00%
0
0.149
Connection
38
0
0
0.00%
0
2.497
223
40
0
0.00%
0
30.951
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
183
40
0
0
0
0
Total:
223
Summary R3
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
82.06%
5.379
17.38%
17.94%
25.571
82.62%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
30.95
Comments
100%
page 11 of 116
Summary of Monitoring Period Round 4
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
0
0
0.00%
0
0.14
8
0
0
0.00%
0
0.28
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Summary R4
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
page 12 of 116
Summary of Monitoring Period Round 5
First measurement:
0 "difficult to monitor" sources.
126 default-zero sources with a calculated emission rate:
4 registered sources with a calculated emission rate:
3.364 kg/year
5.694 kg/year
9.058 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Stem Valve
Open End
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
126
3
1
0
1
0
Total:
130
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
0
0
0.00%
0
0.14
20
0
0
0.00%
0
1.367
102
3
1
33.21%
3.008
7.411
130
3
1
33.21%
3.008
9.058
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
96.92%
3.364
37.14%
2.31%
2.686
29.65%
0.77%
3.008
33.21%
0.00%
0
0.00%
0.77%
3.008
33.21%
0.00%
0
0.00%
100%
9.058
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
126 default-zero sources with a calculated emission rate:
4 registered sources with a calculated emission rate:
3.364 kg/year
3.257 kg/year
6.621 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Stem Valve
20
0
0
0.00%
0
1.367
Open End
102
4
0
0.00%
0
4.974
Total:
130
4
0
0.00%
0
6.621
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
126
4
0
0
0
0
Total:
130
Summary R5
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
96.92%
3.364
50.81%
3.08%
3.257
49.19%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
6.621
Comments
100%
page 13 of 116
Summary of Monitoring Period Round 6
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
0
0
0.00%
0
0.14
8
0
0
0.00%
0
0.28
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Summary R6
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
page 14 of 116
Cumulative data for period
01/01/2018-31/12/2018
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph Cumulative
page 15 of 116
Fugitive emission component classification and emission estimation for production facilities
01/01/2018-31/12/2018
Monitoring
Frequency
Components above 1,000 ppm
cycles/year
Cumulative Components above
Emission
100,000 ppm
%
R6
6
6 0.00%
6
6
6 0.00%
6
0.00%
2
2 0.00%
2
2
2 0.00%
2
0.00%
1
1 0.00%
1
1
1 0.00%
1
0.00%
0.00%
R5
R4
kg
R3
R2
Count
R1
Calculation period TASHAN
Alroy
Components in
Components in
Components in
reading range
reading range 9-999 reading range 0-8 ppm
1,000-100,000 ppm
ppm
Count
Count
Count
Unrepaired
Components
Count
Company name 22-Jan-2019
Date
Production Unit
Report Number
Total Components Difficult
Major
Total
Chemical State Component Class Group
above 1,000 ppm
to
Components Components
Monitor
Count
R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1
Count
Count
Count
0.00% 0.00% 0.00% 0.00% 0.00%
0.548
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
2
4
4
4
4
4
2 0
0
0
0
0
0 0
0
0
0
0
0
0
1
4
0.00% 0.00% 0.00% 0.00% 0.00%
0.14
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
4
4
4
4
4
4 0
0
0
0
0
0 0
0
0
0
0
0
0
0
4
0.00% 0.00% 0.00% 0.00% 0.00%
0.688
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
2
8
8
8
8
8
6 0
0
0
0
0
0 0
0
0
0
0
0
0
1
8
0.00% 0.00% 0.00% 0.00% 0.00%
1.367
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
20
0
20
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
16
20
0.98% 0.00% 0.00% 0.00% 0.00%
17.574
0 0
0
0
0
0 0
1
0
0
0
0 0
3
0 40
0
0
0
98
0
62
0
0 0
0
0
0
0
0 0
1
0
0
0
0
0
0
102
0.82% 0.00% 0.00% 0.00% 0.00%
18.941
0 0
0
0
0
0 0
1
0
0
0
0 0
3
0 40
0
0
0 118
0
82
0
0 0
0
0
0
0
0 0
1
0
0
0
0
0
16
122
0.00% 0.00% 0.00% 0.00% 0.00%
0.149
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0
55
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
55
0.00% 0.00% 0.00% 0.00% 0.00%
2.497
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0
38
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
38
0.00% 0.00% 0.00% 0.00% 0.00%
0.45% 0.00% 0.00% 0.00% 0.00%
2.646
22.275
0 0
0 0
0
0
0
0
0
0
0 0
0 0
0
1
0
0
0
0
0
0
0 0
0 0
0
3
0 0
0 40
0
0
0
2
0
0
8 126
0 93
8 183
0
8
0 0
6 0
0
0
0
0
0
0
0
0
0 0
0 0
0
1
0
0
0
0
0
0
0
0
0
0
0
17
93
223
22.275
GV
LL
HL
GV
LL
HL
Subtotal G1
GV
LL
HL
GV
LL
HL
Subtotal G2
GV
LL
HL
GV
LL
HL
Subtotal G3
PRD
G1
Sampling Point
Stem Valve
G2
Open End
Flange
G3
Connection
Total Components
Total Cumulative Emission
Chemical Summary by Component Class
Report Chemical Summary Cumulative
Calculation Period: 01/01/2018- 31/12/2018
Equation Set: Refinery
Units of Measurement: KG
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.0548
0.0055
0.0274
0.0548
0.2192
0.1863
0.548
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.1367
0.0137
0.0683
0.1367
0.5466
0.4646
1.3666
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
1.7574
0.1757
0.8787
1.7574
7.0294
5.975
17.5736
Chemical CU
page 17 of 116
Chemical Summary by Component Class
Report Chemical Summary Cumulative
Calculation Period: 01/01/2018- 31/12/2018
Equation Set: Refinery
Units of Measurement: KG
Report Date: 03.02.2019
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.0149
0.0015
0.0075
0.0149
0.0597
0.0508
0.1493
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.2497
0.025
0.1248
0.2497
0.9986
0.8488
2.4966
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
2.2275
0.2228
1.1137
2.2275
8.9096
7.5732
22.2743
Grand Total
Chemical CU
22.2743
page 18 of 116
LDAR report for production facilities
Plant
TASHAN
Unit
Alroy
Drawing
Component
Tag
6006-100-007 75
LDAR 015
Component
Type
Component
Class
Blind Flange
Open End
Location Description
Top of T-1
Unit
Monitoring Round
Alroy
Round 1-2-3-4-5-6
ppm value, First
Measurement
Date of First
Measurement
1,305 29-Nov-2018
Repair Due Date of repair
Repair type
08-Dec-2018 29-Nov-2018 Tightening
date of
remeasurement
after repair
attempt
29-Nov-2018
Technicians
ppm value of
remeasurement
after repair
attempt
Date of
repair
Remarks
Repair type
date of
remeasurement
after repair
attempt
ppm value of
remeasurement
after repair attempt
123
page 19 of 116
Round 1
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R1
page 20 of 116
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 1
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
2.956
0
0
2
2
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
3.096
0
0
2
6
0
0
1
8
Subtotal G1
0.0%
3.096
0
0
2
6
0
0
1
8 Total Components
3.096 Total Annual Emission Rate
TASHAN Company name
Round 1
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
2.956
0
0
2
2
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
3.096
0
0
2
6
0
0
1
8
Subtotal G1
0.0%
3.096
0
0
2
6
0
0
1
8 Total Components
3.096 Total Annual Emission Rate
Form-07 R1
page 21 of 116
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2018- 01/03/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.2956
0.0296
0.1478
0.2956
1.1824
1.005
2.956
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.3096
0.031
0.1548
0.3096
1.2385
1.0527
3.0962
Grand Total
Chemical FM R1
3.0962
page 22 of 116
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2018- 01/03/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.2956
0.0296
0.1478
0.2956
1.1824
1.005
2.956
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.3096
0.031
0.1548
0.3096
1.2385
1.0527
3.0962
Grand Total
Chemical AR R1
3.0962
page 23 of 116
LDAR report for production facilities
Plant
TASHAN
Unit
Drawing
Component
Tag
LDAR 015 R1
Component
Type
Component
Class
Location Description
Unit
Monitoring Round
Alroy
Round 1
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 24 of 116
Round 2
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R2
page 25 of 116
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 2
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
TASHAN Company name
Round 2
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
Form-07 R2
page 26 of 116
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2018- 05/03/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1122
0.0954
0.2804
Grand Total
Chemical FM R2
0.2804
page 27 of 116
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2018- 05/03/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1122
0.0954
0.2804
Grand Total
Chemical AR R2
0.2804
page 28 of 116
LDAR report for production facilities
Plant
TASHAN
Unit
Drawing
Component
Tag
LDAR 015 R2
Component
Type
Component
Class
Location Description
Unit
Monitoring Round
Alroy
Round 2
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 29 of 116
Round 3
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R3
page 30 of 116
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 3
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.367
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
0.0%
26.658
0
0
40
62
0
0
0
102
LL
2
HL
0.0%
28.025
0
0
40
82
0
0
16
122
Subtotal G2
1
GV
Flange
G3
1
0.0%
0.149
0
0
0
55
0
0
0
55
LL
1
HL
1
GV
Connection
1
0.0%
2.497
0
0
0
38
0
0
0
38
LL
1
HL
0.0%
2.646
0
0
0
93
0
0
0
93
Subtotal G3
0.0%
30.951
0
0
40
183
0
0
17
223 Total Components
30.951 Total Annual Emission Rate
TASHAN Company name
Round 3
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.367
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
0.0%
26.658
0
0
40
62
0
0
0
102
LL
2
HL
0.0%
28.025
0
0
40
82
0
0
16
122
Subtotal G2
1
GV
Flange
G3
1
0.0%
0.149
0
0
0
55
0
0
0
55
LL
1
HL
1
GV
Connection
1
0.0%
2.497
0
0
0
38
0
0
0
38
LL
1
HL
0.0%
2.646
0
0
0
93
0
0
0
93
Subtotal G3
0.0%
30.951
0
0
40
183
0
0
17
223 Total Components
30.951 Total Annual Emission Rate
Form-07 R3
page 31 of 116
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2018- 17/05/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.1367
0.0137
0.0683
0.1367
0.5466
0.4646
1.3666
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
2.6658
0.2666
1.3329
2.6658
10.6631
9.0636
26.6578
Chemical FM R3
page 32 of 116
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2018- 17/05/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.0149
0.0015
0.0075
0.0149
0.0597
0.0508
0.1493
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.2497
0.025
0.1248
0.2497
0.9986
0.8488
2.4966
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
3.0951
0.3096
1.5475
3.0951
12.3802
10.5232
30.9507
Grand Total
Chemical FM R3
30.9507
page 33 of 116
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2018- 17/05/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.1367
0.0137
0.0683
0.1367
0.5466
0.4646
1.3666
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
2.6658
0.2666
1.3329
2.6658
10.6631
9.0636
26.6578
Chemical AR R3
page 34 of 116
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2018- 17/05/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.0149
0.0015
0.0075
0.0149
0.0597
0.0508
0.1493
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.2497
0.025
0.1248
0.2497
0.9986
0.8488
2.4966
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
3.0951
0.3096
1.5475
3.0951
12.3802
10.5232
30.9507
Grand Total
Chemical AR R3
30.9507
page 35 of 116
LDAR report for production facilities
Plant
TASHAN
Unit
Drawing
Component
Tag
LDAR 015 R3
Component
Type
Component
Class
Location Description
Unit
Monitoring Round
Alroy
Round 3
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 36 of 116
Round 4
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R4
page 37 of 116
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 4
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
TASHAN Company name
Round 4
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
Form-07 R4
page 38 of 116
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2018- 20/08/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1122
0.0954
0.2804
Grand Total
Chemical FM R4
0.2804
page 39 of 116
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2018- 20/08/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1122
0.0954
0.2804
Grand Total
Chemical AR R4
0.2804
page 40 of 116
LDAR report for production facilities
Plant
TASHAN
Unit
Drawing
Component
Tag
LDAR 015 R4
Component
Type
Component
Class
Location Description
Unit
Monitoring Round
Alroy
Round 4
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 41 of 116
Round 5
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R5
page 42 of 116
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 5
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.367
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
1.0%
7.411
0
1
3
98
1
0
0
102
LL
2
HL
0.8%
8.778
0
1
3
118
1
0
16
122
Subtotal G2
0.8%
9.058
0
1
3
126
1
0
17
130 Total Components
9.058 Total Annual Emission Rate
TASHAN Company name
Round 5
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.367
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
0.0%
4.974
0
0
4
98
0
0
0
102
LL
2
HL
0.0%
6.341
0
0
4
118
0
0
16
122
Subtotal G2
0.0%
6.621
0
0
4
126
0
0
17
130 Total Components
6.621 Total Annual Emission Rate
Form-07 R5
page 43 of 116
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2018- 29/11/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.1367
0.0137
0.0683
0.1367
0.5466
0.4646
1.3666
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.7411
0.0741
0.3706
0.7411
2.9645
2.5199
7.4113
Chemical FM R5
page 44 of 116
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2018- 29/11/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
All
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.9058
0.0906
0.4529
0.9058
3.6233
3.0799
9.0583
Grand Total
Chemical FM R5
9.0583
page 45 of 116
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2018- 29/11/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.1367
0.0137
0.0683
0.1367
0.5466
0.4646
1.3666
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.4974
0.0497
0.2487
0.4974
1.9894
1.691
4.9736
Chemical AR R5
page 46 of 116
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2018- 29/11/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
All
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.6621
0.0662
0.331
0.6621
2.6482
2.251
6.6206
Grand Total
Chemical AR R5
6.6206
page 47 of 116
LDAR report for production facilities
Plant
TASHAN
Unit
Alroy
Drawing
Component
Tag
6006-100-007 75
LDAR 015 R5
Component
Type
Component
Class
Blind Flange
Open End
Location Description
Top of T-1
Unit
Monitoring Round
Alroy
Round 5
ppm value, First
Measurement
Date of First
Measurement
1,305 29-Nov-2018
Repair Due Date of repair
Repair type
08-Dec-2018 29-Nov-2018 Tightening
date of
remeasurement
after repair
attempt
29-Nov-2018
Technicians
ppm value of
remeasurement
after repair
attempt
Date of
repair
Remarks
Repair type
date of
remeasurement
after repair
attempt
ppm value of
remeasurement
after repair attempt
123
page 48 of 116
Round 6
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R6
page 49 of 116
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 6
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
TASHAN Company name
Round 6
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
Form-07 R6
page 50 of 116
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2018- 16/12/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1122
0.0954
0.2804
Grand Total
Chemical FM R6
0.2804
page 51 of 116
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2018- 16/12/2018
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 03.02.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1122
0.0954
0.2804
Grand Total
Chemical AR R6
0.2804
page 52 of 116
LDAR report for production facilities
Plant
TASHAN
Unit
Drawing
Component
Tag
LDAR 015 R6
Component
Type
Component
Class
Location Description
Unit
Monitoring Round
Alroy
Round 6
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 53 of 116
Graphs
Round 1
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R1
page 54 of 116
Graph6.1.1 R1
page 55 of 116
Graph6.1.3 R1
page 56 of 116
Graph6.1.2 R1
page 57 of 116
Graphs
Round 1
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R1
page 58 of 116
Graph6.2.1 R1
page 59 of 116
Graph6.2.3 R1
page 60 of 116
Graph6.2.2 R1
page 61 of 116
Graphs
Round 2
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R2
page 62 of 116
Graph6.1.1 R2
page 63 of 116
Graph6.1.3 R2
page 64 of 116
Graph6.1.2 R2
page 65 of 116
Graphs
Round 2
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R2
page 66 of 116
Graph6.2.1 R2
page 67 of 116
Graph6.2.3 R2
page 68 of 116
Graph6.2.2 R2
page 69 of 116
Graphs
Round 3
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R3
page 70 of 116
Graph6.1.1 R3
page 71 of 116
Graph6.1.3 R3
page 72 of 116
Graph6.1.2 R3
page 73 of 116
Graphs
Round 3
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R3
page 74 of 116
Graph6.2.1 R3
page 75 of 116
Graph6.2.3 R3
page 76 of 116
Graph6.2.2 R3
page 77 of 116
Graphs
Round 4
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R4
page 78 of 116
Graph6.1.1 R4
page 79 of 116
Graph6.1.3 R4
page 80 of 116
Graph6.1.2 R4
page 81 of 116
Graphs
Round 4
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R4
page 82 of 116
Graph6.2.1 R4
page 83 of 116
Graph6.2.3 R4
page 84 of 116
Graph6.2.2 R4
page 85 of 116
Graphs
Round 5
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R5
page 86 of 116
Graph6.1.1 R5
page 87 of 116
Graph6.1.3 R5
page 88 of 116
Graph6.1.2 R5
page 89 of 116
Graphs
Round 5
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R5
page 90 of 116
Graph6.2.1 R5
page 91 of 116
Graph6.2.3 R5
page 92 of 116
Graph6.2.2 R5
page 93 of 116
Graphs
Round 6
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R6
page 94 of 116
Graph6.1.1 R6
page 95 of 116
Graph6.1.3 R6
page 96 of 116
Graph6.1.2 R6
page 97 of 116
Graphs
Round 6
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R6
page 98 of 116
Graph6.2.1 R6
page 99 of 116
Graph6.2.3 R6
page 100 of 116
Graph6.2.2 R6
page 101 of 116
Graphs
Cumulative data for period
01/01/2018-31/12/2018
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph Graphs Cumul
page 102 of 116
Graph6.3.1
page 103 of 116
Graph6.3.2
page 104 of 116
Graph6.3.3
page 105 of 116
Graph6.3.4
page 106 of 116
General
Calibration loglist
Calibration gas certificates
Composition list & Response Factors
Quarterly production hours
Quarterly equipment check
Paragraph General
page 107 of 116
Calibration log list
Plant
Round Equipment Analyzer
Type
Type
Ultra-Zero
Span Gas
Span gas Cylinder
Span
Check gas Check gas Cylinder
Check gas
No
concentration
No
concentration
Date
Equipment
No
Equipment
Serial
No
(A)
ppm
ppm
Check
Calibration Result
error
1-st 2-st 3-st
check check check
(A1) (A2) (A3)
(CP)
ppm ppm ppm
TASHAN
1
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF51428
1,000
01-Mar-2018
5
202016061436 504
505
504
0.07%
OK
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
05-Mar-2018
2
0115248185
511
513
513
1.65%
OK
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
05-Mar-2018
3
0115248937
501
501
502
-0.53%
OK
TASHAN
2
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
19-Mar-2018
5
202016061436 511
510
510
1.26%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
16-May-2018
2
0115248185
500
493
499
-1.32%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
16-May-2018
5
202016061436 504
502
501
-0.33%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
17-May-2018
2
0115248185
503
504
504
-0.07%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
17-May-2018
5
202016061436 507
507
507
0.60%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
24-May-2018
5
202016061436 504
505
505
0.13%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
30-May-2018
5
202016061436 508
504
506
0.40%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
30-May-2018
2
0115248185
512
511
511
1.46%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
04-Jun-2018
3
0115248937
508
508
506
0.66%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
04-Jun-2018
5
202016061436 504
504
505
0.07%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
12-Jun-2018
1
0715622657
502
500
497
-0.86%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
12-Jun-2018
3
0115248937
505
502
500
-0.33%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
13-Jun-2018
3
0115248937
507
509
509
0.86%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
20-Aug-2018
1
0715622657
496
498
500
-1.19%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
21-Aug-2018
1
0715622657
499
501
500
-0.79%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
06-Sep-2018
3
0115248937
489
502
503
-1.19%
OK
TASHAN
5
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
29-Nov-2018
2
0115248185
502
501
501
-0.53%
OK
TASHAN
5
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
29-Nov-2018
3
0115248937
500
499
500
-0.86%
OK
TASHAN
5
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
02-Dec-2018
2
0115248185
503
502
502
-0.33%
OK
TASHAN
5
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
02-Dec-2018
3
0115248937
499
500
501
-0.79%
OK
TASHAN
5
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
03-Dec-2018
3
0115248937
487
498
497
-1.98%
OK
TASHAN
5
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
03-Dec-2018
2
0115248185
500
499
502
-0.73%
OK
TASHAN
6
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
16-Dec-2018
5
202016061436 504
505
505
0.13%
OK
TASHAN
5
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
25-Dec-2018
3
0115248937
498
499
498
-1.12%
OK
TASHAN
5
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
13-Jan-2019
5
202016061436 505
505
505
0.20%
OK
Cal-Log
page 108 of 116
Certificate
page 109 of 116
Certificate
page 110 of 116
Stream Composition Summary
Stream Name
Stream Content
Stream Content
Dates
TVA
Gasoline
TOLUENE-34 %, n-Octane-40 %, METHYL TERT-BUTYL ETHER-10 %,
CYCLOHEXANE-5 %, BENZENE-1 %, 1-Butene-10 %
A=0.42, B=0.29
Petroleum
TOLUENE-7.5 %, n-Octane-55.3 %, CYCLOHEXANE-35.2 %, BENZENE-2 %
A=0.39, B=0.31
Stream Summary
MiniRAE 10.6 MiniRAE 11.7
page 111 of 116
Quarterly Validation of LDAR Devices
Date: 28-Dec-2017
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Anlyzer Type
Span Gas
Sampling Flow
Rate
1
Check
Sampling
Span Gas
Flow
Span gas
Concentration
Result Check Gas
Rate
Cylinder No
ppm
l/min
Accuracy Check
Response Time
Comparison between two Devices
90%
Check Gas
Response Response Response
Second
of
Check gas
1-st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Time 1 Time 2 Time 3 Result
Result
Device
Result
Span
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
FF51428
1,000
1.1
OK
Methane
FF524456
504
492 490 486
-2.91%
OK
900
3
3
3
OK
1.94
1.8
0.14
-7.78%
OK
2
0115248185
TVA1000B
FID
Methane
FF51428
1,000
0.99
OK
Methane
FF524456
504
501 501 502
-0.53%
OK
900
4
4
4
OK
1.62
1.74
-0.12
6.9%
OK
3
0115248937
TVA1000B
FID
Methane
FF51428
1,000
1.25
OK
Methane
FF524456
504
489 486 486
-3.37%
OK
900
3
3
3
OK
1.8
1.94
-0.14
7.22%
OK
5
202016061436
TVA2020
FID
Methane
FF51428
1,000
0.96
OK
Methane
FF524456
504
481 479 479
-4.83%
OK
900
3
3
3
OK
1.74
1.8
-0.06
3.33%
OK
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.51
OK
Isobutylene EA0009962
997
996 996 997
-0.15%
OK
898
4
4
4
OK
1.88
1.68
0.2
-11.9%
OK
6
Quarterly Validation
page 112 of 116
Quarterly Validation of LDAR Devices
Date: 04-Apr-2018
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Anlyzer Type
Span Gas
Sampling Flow
Rate
2
Check
Sampling
Span Gas
Flow
Span gas
Concentration
Result Check Gas
Rate
Cylinder No
ppm
l/min
Accuracy Check
Response Time
Comparison between two Devices
90%
Check Gas
Response Response Response
Second
of
Check gas
1-st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Time 1 Time 2 Time 3 Result
Result
Device
Result
Span
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
FF51430
1,000
1.01
OK
Methane
FF524456
504
508 508 507
0.73%
OK
900
3
3
3
OK
1.12
1.22
-0.1
8.2%
OK
2
0115248185
TVA1000B
FID
Methane
FF51430
1,000
1.09
OK
Methane
FF524456
504
511 512 512
1.52%
OK
900
3
3
3
OK
1.18
1.3
-0.12
9.23%
OK
3
0115248937
TVA1000B
FID
Methane
FF51430
1,000
0.96
OK
Methane
FF524456
504
506 504 504
0.13%
OK
900
3
3
3
OK
1.22
1.12
0.1
-8.93%
OK
5
202016061436
TVA2020
FID
Methane
FF51430
1,000
1.01
OK
Methane
FF524456
504
513 512 512
1.65%
OK
900
3
3
3
OK
1.3
1.22
0.08
-6.56%
OK
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.5
OK
Isobutylene EA0009962
997
995 995 995
-0.28%
OK
898
4
4
4
OK
1.15
1.3
-0.15
11.54%
OK
6
Quarterly Validation
page 113 of 116
Quarterly Validation of LDAR Devices
Date: 04-Jul-2018
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Anlyzer Type
Span Gas
Sampling Flow
Rate
3
Check
Sampling
Span Gas
Flow
Span gas
Concentration
Result Check Gas
Rate
Cylinder No
ppm
l/min
Accuracy Check
Response Time
Comparison between two Devices
90%
Check Gas
Response Response Response
Second
of
Check gas
1-st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Time 1 Time 2 Time 3 Result
Result
Device
Result
Span
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
FF51430
1,000
1.06
OK
Methane
FF524456
504
503 504 503
-0.13%
OK
900
3
3
3
OK
2.85
2.44
0.41
-16.8%
OK
2
0115248185
TVA1000B
FID
Methane
FF51430
1,000
0.97
OK
Methane
FF524456
504
504 505 503
0%
OK
900
3
3
3
OK
1.18
1.22
-0.04
3.28%
OK
3
0115248937
TVA1000B
FID
Methane
FF51430
1,000
1.23
OK
Methane
FF524456
504
502 503 503
-0.26%
OK
900
3
3
3
OK
2.15
2.61
-0.46
17.62%
OK
5
202016061436
TVA2020
FID
Methane
FF51430
1,000
0.95
OK
Methane
FF524456
504
506 503 505
0.13%
OK
900
3
3
3
OK
3.41
3.05
0.36
-11.8%
OK
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.5
OK
Isobutylene EA0009962
997
997 996 996
-0.15%
OK
898
4
4
3
OK
2.5
2.1
0.4
-19.05%
OK
6
Quarterly Validation
page 114 of 116
Quarterly Validation of LDAR Devices
Date: 02-Oct-2018
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Anlyzer Type
Span Gas
Sampling Flow
Rate
4
Check
Sampling
Span Gas
Flow
Span gas
Concentration
Result Check Gas
Rate
Cylinder No
ppm
l/min
Accuracy Check
Response Time
Comparison between two Devices
90%
Check Gas
Response Response Response
Second
of
Check gas
1-st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Time 1 Time 2 Time 3 Result
Result
Device
Result
Span
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
FF51430
1,000
0.96
OK
Methane
FF524456
504
495 494 494
-1.92%
OK
900
4
4
4
OK
1.55
1.48
0.07
-4.73%
OK
2
0115248185
TVA1000B
FID
Methane
FF51430
1,000
1.31
OK
Methane
FF524456
504
491 492 492
-2.45%
OK
900
4
4
4
OK
1.79
1.82
-0.03
1.65%
OK
3
0115248937
TVA1000B
FID
Methane
FF51430
1,000
1.4
OK
Methane
FF524456
504
506 507 506
0.46%
OK
900
3
4
4
OK
1.99
1.95
0.04
-2.05%
OK
5
202016061436
TVA2020
FID
Methane
FF51430
1,000
1.02
OK
Methane
FF524456
504
518 518 518
2.78%
OK
900
3
3
3
OK
1.52
1.59
-0.07
4.4%
OK
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.51
OK
Isobutylene EA0009962
997
996 995 995
-0.25%
OK
898
4
4
4
OK
2.5
2.1
0.4
-19.05%
OK
6
Quarterly Validation
page 115 of 116
CUMULATIVE PRODUCTION HOURS TEMPLATE 2018
Plant
TASHAN
Unit
Drawing
Stream Name
Remark
Annual Production
Hours
Alroy
6006-100-006
Gasoline
8,760
Alroy
6006-100-007
Gasoline
8,760
Production Hours
Q1
01/01-31/03
Quarter =
Quarterly Production
hours
2,190
2,190
Q2
01/04-30/06
Quarter =
Quarterly Production
hours
2,190
2,190
Q3
01/07-30/09
Quarter =
Quarterly Production
hours
2,190
2,190
Q4
01/10-31/12
Quarter =
Quarterly Production
hours
2,190
2,190
page 116 of 116
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין
3013.15-034-T2
3013.15-025
25/02/2019
18/31
3013.15-036.doc
T2 - kerosene
External Floating roof
1. Tank data
Diameter of the tank
D
Effective height of the stock liquid (while
roof landing episode)
hle
Shell Color and condition
α
Roof color and condition
α
Tank paint solar absorptance
α
Vapor space outage (while roof landing
episode)
HVO
m
feet
m
feet
color
condition
color
condition
dimensionless
m
Tank data
--Tank data
--חאקי
טובה
לבן
טוב
48.77
160.01
11.00
0.89
Table 7.1-6
Assumption - Green Dark
0.17
Table 7.1-6
0.53
Table 7.1-6
Possible to use also equation
1-15
assumption - equal to legs height
feet
11.00
Volume of the vapor space (while roof
landing episode)
Breather vent pressure setting
VV
ft
3
VV=PI()*D /4*Hvo
221,185
Equation 1-3
ΔPBP
psi
Typical value
0.50
Equation 1-11
Breather vent vacuum setting
ΔPBV
psi
Typical value
0.00
Equation 1-11
Breather vent pressure setting range
ΔPB
psi
∆PB = PBP − PBV
0.50
Equation 1-11
2
2. Material data - קרוסין
Stock vapor molecular weight
MV
Density of the liquid inside the tank
Wl
Vapor density
WV
True vapor pressure of the stock liquid
P
Vapor pressure at daily average liquid
surface temperature
Vapor pressure at the daily maximum
liquid surface temperature, psia
Vapor pressure at the daily minimum
liquid surface temperature
Daily vapor pressure range
3013.15-034.xls - 2
gr/gr-mole
lb/lb-mole
g/ml
lb/gal
kg/m^3
lb/ft3
msds data
130
msds data
--msds data
---
0.80
6.68
4.5
0.28
mm Hg
PEI data
0.833
psia
--הנחה:
Pv=nRT -->
P2=P1*(T2/T1)
0.02
0.02
0.02
0.00
PVA
psia
PVX
psia
PVN
psia
T1(k)=20C+273
T2(k)=37.5C+273
ΔPV
psia
∆PV = PVX − PVN
1/3
0
at 20°C
0.02
Equation 1-9
20/02/2019
3. Operation data
Number of days that the tank stands idle
(on roof landing episode)
Number of degassing and cleaning
episode
Number of roof landing episode
nd
days/landing episode
site data
4
landing episode/year
site data
0.07
landing episode/year
site data
0.07
Tanks Program
--Tanks Program
---
73
33
119
54
21
T2 - B&W 2018
Tanks Program
---
60.05
27
T2 - DFloating 2018
lb per emptying
Tanks Program
67
Kg per emptying
---
30
4. Normal operation (Tanks program)
lb per year
Kg per year
lb per year
Kg per year
Kg per year
Working (withdrawal) losses
Total emissions (Breathing & Working)
Breathing (standing) losses
5. Degassing and Cleaning (Tanks program)
Degassing: emission from one turnover of
lb per emptying
Edegass-floating
floating roof
Kg per emptying
Degassing: fixed roof with a height of roof
legs
Edegass-legs
Liquid fraction in sludge
Fliquid
Sludge volume
Sludge weight
Vs
Ws
Cleaning emissions
Ecleaning
Total Degassing and Cleaning emissions
Edegass-total
3013.15-034.xls - 2
0.8
m3 per emptying
Kg per emptying
lb per emptying
Kg per emptying
lb per emptying
Kg per emptying
Ecleaning = Ws * (1-Fliquid)
Edegass-total =
Edegass-floating + Edegass-legs + Ecleaning
2/3
T2 - B&W 2018
T2- DFixed 2018
(Only working losses)
Tanks FAQ - degassing and
cleaning
70
56,000
24,692
11,200
24,818
11,257
20/02/2019
6. Roof landing
Daily average liquid surface temperature
TLA
°R
T LA = 0 . 44 T AA + 0 . 56 T B + 0 . 0079 * α * I
541.74
Equation 1-26
Daily vapor temperature range
ΔTV
°R
∆ TV = 0 .72 ∆ T A + 0.028 * α * I
56.73
Equation 1-8
Daily maximum liquid surface temperature
TLX
°R
TLX = TLA + 0.25*ΔTV
555.92
Figure 7.1-17
Daily minimum liquid surface temperature
TLN
°R
TLN = TLA - 0.25*ΔTV
527.56
Figure 7.1-17
Liquid bulk temperature
Max standing idle losses during roof
landing
TB
°R
TB = TAA + 6α - 1
530.06
Equation 1-28
LSL-max
lb per landing episode
Kg per landing episode
dimensionless
2
LSL-max = 5.9*D *hle*W l
--0.60 for a full liquid heel
0.50 for a partial
0.15 for drain-dry
11,093,038 Equation 2-13
5,031,769
0.50
Equation 2-26
(pages No 33,35)
1
KS =
1 + 0.053 * PVA * H VO
0.5
Equation 1-20
KS is assumed to be less than
or equal to the saturation factor
during filling (S) .
∆ TV ∆ PV − ∆ PB
+
T LA
PA − PVA
0.071
Liquid stock has a true vapor
pressure greater than 0.1psia Equation 1-7.
Filling saturation factor
S
saturation factor
KS
dimensionless
Vapor space expansion factor
KE
dimensionless
Standing idle losses during roof landing
LSL
lb per landing episode
PV
L SL = n d K E V M V K S
RT AA
12
Equation 2-16
Filling losses during roof landing
LFL
lb per landing episode
P * VV
M V * S
L FL =
R * T AA
41
Equation 2-26
Total losses during roof landing
LTL
lb per landing episode
Kg per landing episode
52
24
Equation 2-10
KE =
LTL=LSL+LFL
7. Summary
Working (withdrawal) losses
Breathing (standing) losses
Kg per year
Kg per year
33
21
Total Degassing and Cleaning emissions
Kg per year
750
Total losses during roof landing
Kg per year
2
806
3013.15-034.xls - 2
3/3
Kg per year
20/02/2019
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - B&W 2018
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.30
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Red/Primer
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock
Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
1
2
29
43
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.7 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - B&W 2018 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
All
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
81.75
66.81
96.69
Liquid
Bulk
Temp
(deg F)
70.60
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0161
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
20/02/2019
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - B&W 2018 - External Floating Roof Tank
Haifa, Israel
Annual Emission Calcaulations
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
0.0161
160.0100
130.0000
1.0000
Withdrawal Losses (lb):
Annual Net Throughput (gal/yr.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
72.8711
9,891,924.0000
0.0075
7.0000
160.0100
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
5.3380
0.0003
130.0000
1.0000
150.3024
6.2000
Total Losses (lb):
118.8887
40.6796
1.6000
0.3000
6.2000
1.6000
0.0003
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock
Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
1
2
29
43
1
KFa(lb-mole/yr)
1.60
11.00
6.20
1.20
0.49
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
9.90
1.20
0.14
0.16
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.89
0.94
0.65
0.14
1.00
Losses(lb)
0.1705
1.6891
0.7791
1.6103
1.0484
0.0406
20/02/2019
TANKS 4.0 Report
Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - B&W 2018 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
40.68
72.87
5.34
0.00
118.89
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
TANKS 4.0 Report
Page 1 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFixed 2018
Haifa
Israel
PEI
Vertical Fixed Roof Tank
kerosene
Tank Dimensions
Shell Height (ft):
Diameter (ft):
Liquid Height (ft) :
Avg. Liquid Height (ft):
Volume (gallons):
Turnovers:
Net Throughput(gal/yr):
Is Tank Heated (y/n):
N
Paint Characteristics
Shell Color/Shade:
Shell Condition
Roof Color/Shade:
Roof Condition:
Red/Primer
Good
White/White
Good
Roof Characteristics
Type:
Height (ft)
Slope (ft/ft) (Cone Roof)
Breather Vent Settings
Vacuum Settings (psig):
Pressure Settings (psig)
11.00
160.01
11.00
5.50
1,654,664.74
1.00
1,654,664.74
Cone
0.00
0.00
0.00
0.50
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.7 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
TANKS 4.0 Report
Page 2 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFixed 2018 - Vertical Fixed Roof Tank
Haifa, Israel
Mixture/Component
Month
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
Liquid
Bulk
Temp
(deg F)
Vapor Pressure (psia)
Avg.
Min.
Max.
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
20/02/2019
TANKS 4.0 Report
Page 3 of 5
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
TANKS 4.0 Report
Page 4 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFixed 2018 - Vertical Fixed Roof Tank
Haifa, Israel
Losses(lbs)
Components
Working Loss
Breathing Loss
Total Emissions
Jet kerosene
66.66
51.50
118.16
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
TANKS 4.0 Report
Page 5 of 5
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
TANKS 4.0 Report
Page 1 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFloating 2018
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.00
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Red/Primer
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock
Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
1
2
29
43
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.7 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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TANKS 4.0 Report
Page 2 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFloating 2018 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Month
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
Liquid
Bulk
Temp
(deg F)
Vapor Pressure (psia)
Avg.
Min.
Max.
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
20/02/2019
TANKS 4.0 Report
Page 3 of 5
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
TANKS 4.0 Report
Page 4 of 5
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFloating 2018 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
3.60
55.99
0.46
0.00
60.05
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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TANKS 4.0 Report
Page 5 of 5
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2019
נספח ד'
דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 1של קרוסין
3013.15-035
25/02/2019
19/31
3013.15-036.doc
Transportation - Loading losses
Loading arm #1 - Kerosene
Density
Tank paint solar absorptance
Daily average ambient temperature
Wl
α
TAA
Yearly consumption
Myear
Cargo tank volume
V
Ntrucks
t
g/ml
dimensionless
°R
ton
m3
gal
m3
gal
1/year
min
Saturation factor
S
dimensionless
True vapor pressure of liquid
P
Molecular weight of vapors
M
Number of tank trucks
Duration of road truck filling
Table 5.2-1
mmHg
psia
0.833
0.02
@ 20°C
lb/lb-mole
130
Table 7.1-2
T=TB
°R
Controlled efficiency for the recovery
unit (vapor recovery efficiency)
eff1
%
vapor collection efficiency
eff2
%
overall reduction efficiency
eff
%
Loading losses of petroleum liquids
(uncontrolled emission rate)
LL
lb/103 gal
loaded
Flow rate of pollutant emission during
loading
Annual pollutant emission during
loading
T = TB = TAA + 6α - 1
527.40
0
LL total lb / loading
lb / min
Q
Kg / min
Kg / hr
Etotal
0.80
0.41
525.97
1,642
2,066
545,780
30.0
7,925
69
30
0.6
Temperature of bulk liquid loaded
Total loading losses of petroleum
msds data
site data
"Site" tab @ 3013-037
--data
--data
--Ntrucks = Myear / V
data
Submerge loading, dedicated
normal service
Kg / year
Truck passed the NSPS-level
annual test
70.0
eff=eff1*eff2/100
0
LL = 12.46
S *P*M
eff
1 −
T
100
0.030
LLtotal = LL*V
Q = Lltotal / t
-----
0.24
0.008
0.004
0.21
Etotal = LLtotal*Ntruks
7.36
Equation 1-28
page 5.2-6
can be 90% to over 99%
page 5.2-6
99.2- for tanker truck passed the
MACT-level annual leak test
98.7- for truck passed the NSPS-level
annual test
70 - for trucks not passing one of
these leak tests
Page 5.2-4 Equation 1
Assumption: the mass of the
Average pollutant emission
concentration during loading
3013.15-035.xls - 1
C
gr / m3
C = Q *t / V
3.6
1/1
pollutant is contained in the air
volume inside the tanker which is
replaced by the liquid loaded
17/02/2019
נספח ה'
חישוב פליטות ממיכל לאיסוף תשטיפים
25/02/2019
20/31
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תוכנת :Tanksחישוב פליטה כתוצאה מאחסון ושינוי מפלס
25/02/2019
21/31
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3013.15-036.doc
22/31
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24/31
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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב א')
25/02/2019
25/31
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3013.15-036.doc
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27/31
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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב ב')
25/02/2019
28/31
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30/31
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חישובי פליטה ממיכל תשטיפים
גיליון חישוב זה הוכן על ידי "פז" הנדסה וניהול ( )1980בע"מ.
אין להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ( )1980בע"מ.
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מסמך 8 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 5957 KB)
תשתיות נפט ואנרגיה בע"מ
מסוף אלרואי
סיכום פליטות לאוויר
שנת 2019
פרויקט3013.16 :
סימוכין3013.16-036 :
פברואר 2020
תוכן עניינים
.1מבוא 4 ...............................................................................................................
.2נתוני מסוף 5 ........................................................................................................
.2.1נתוני מיכלים 5.........................................................................................................
.2.2נתונים עבור מסוף מילוי מיכליות כביש 9.....................................................................
.3חישוב פליטות 10 .................................................................................................
.3.1כללי 10 ............................................................................................................
.3.2סוגי פליטות מחושבות 10 .......................................................................................
.3.3בחירת חומרים בתוכנת 11 ......................................................................... TANKS
.3.4נתונים מטאורולוגיים 11 ........................................................................................
.4סיכום פליטות לשנת 12 .................................................................................. 2019
.4.1מיכלים 12 ..........................................................................................................
.4.2מסוף מילוי מיכליות כביש 12 ..................................................................................
.4.3מיכל איסוף תשטיפים 13 .......................................................................................
.4.4סיכום ממצאי ניטור 13 ............................................................................... LDAR
.4.5פליטה שנתית מכלל המתקן 13 ................................................................................
.5פליטות לא שגרתיות במהלך שנת 13 .................................................................. 2019
.6מקורות 14 ..........................................................................................................
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טבלאות
טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 5........................................... 2019
טבלה :2נתוני מעטפת וגגות – שנת 6.................................................................................. 2019
טבלה :3נתוני אביזרים – שנת 7......................................................................................... 2019
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת 8................................................... TANKS
טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 9...................................................... 2019
טבלה :6חומרים מייצגים בתוכנת 11 ............................................................................ TANKS
טבלה :7סיכום פליטות מכלים -שנת 12 ............................................................................ 2019
טבלה :9סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 13 .................................. 2019
טבלה :10סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 13 .................................................2019
נספחים
נספח א'
טבלה )AP-42( 1-5.2
נספח ב'
נתוני ניטור LDARעבור מסוף אלרואי – סיכום שנת 2019
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין
נספח ד'
חישוב פליטות ממיכל לאיסוף תשטיפים
אביטל בלניק
שם עורך
17/02/2020
יואב פיסטינר
שם מאשר
להערות
תיאור
17.02.2020
תאריך
3/30
0
גרסה
3013.16-036
.1מבוא
חברת תשתיות נפט ואנרגיה בע"מ (להלן תש"ן) מפעילה את מסוף אלרואי לאחסון ושינוע
דלקים .
המסוף כולל:
•
מבני משרדים
•
חוות מכלים לאחסון דלקים מסוגים שונים
•
רציפי מילוי מכליות כביש (לשימוש בעת חירום בלבד)
המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכונת
אלרואי ומדרום לו שכונת קרית חרושת.
באתר 9מיכלים ,מתוכם 6מיכלים תפעוליים ו 3-מיכלים אסטרטגים (מיכלים מס' 6,1ו.)9-
מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוסף קיימות מערכות תומכות כגון
מערכות כיבוי אש ומערכות פיקוד ובקרה.
כחלק מהתנאים ברישיון עסק מדצמבר ,2010בסוף כל שנה קלנדרית על תש"ן להגיש דו"ח
סיכום פליטות שנתי לגבי השנה שחלפה.
חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקנים
הקיימים במסוף.
סיכום הפליטות הוכן על ידי חברת "פז" הנדסה וניהול ( )1980בע"מ (להלן פז הנדסה) ,והוא
מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.
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.2נתוני מסוף
.2.1נתוני מיכלים
בטבלאות הבאות מפורט מידע טכני של המיכלים בחוות המיכלים אלרואי.
טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 2019
לחץ אדים
בטמפ' הנוזל
הממוצעת
)(mmHg
405 @ 28°C
כמות
צריכה
שנתית
(מ"ק)
0
גבעה חלקית
22,511
גבעה חלקית
48.77
גבעה חלקית
48.77
32,056
48.77
32,056
28,768
56,959
51,614
15.56
51,614
15.56
14.1
15.56
14.1
11.4
18.3
18.3
15.4
9.7
סוג ניקוז
בתחתית
מיכל
קוטר
מיכל
(מטר)
נפח מיכל
(מ"ק)
נפח מיכל
פעיל
(מ"ק)
48.77
32,056
28,768
גובה /אורך
מעטפת
מיכל
(מטר)
17.16
15.4
32,056
28,768
17.16
15.4
10
28,768
17.16
15.4
9.5
17.16
15.4
10.3
14.1
14.1
14.1
מספר
מיכל
סוג הדלק
המאוחסן
) 1( 1
בנזין
2
קרוסין
0.833 @ 28°C
3
סולר
0.507 @ 28°C
30,507
4
סולר
0.507 @ 28°C
32,549
גבעה חלקית
5
סולר
0.507 @ 28°C
12,286
גבעה מלאה
68.27
) 1( 6
סולר
0.507 @ 28°C
0
גבעה מלאה
68.27
56,959
7
סולר
0.507 @ 28°C
46,565
גבעה מלאה
68.27
56,959
51,614
)2( 8
קרוסין
0.833 @ 28°C
41,306
גבעה חלקית
48.8
36,547
34,228
19.54
) 1( 9
קרוסין
0.833 @ 28°C
0
גבעה חלקית
48.77
32,056
28,768
17.16
367,704
332,913
סה"כ
185,724
( )1מכלים מס' 6 ,1ו 9-משמשים כמכלי מלאי ,לא היו תנועות במכלים בשנת .2019
( )2מכל 8עבר חידוש צביעת גג בפברואר ,2019והחלפת אטם ראשוני מסוג Liquid mountedבמרץ .2019
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גובה נוזל
מירבי
(מטר)
גובה נוזל
ממוצע
(מטר)
10.5
טבלה :2נתוני מעטפת וגגות – שנת 2019
מספר
מיכל
סוג גג
אטם ראשי
אטם משני
1
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Liquid
mounted
Mechanical
Shoe
Rim
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Rim
mounted
Rim
mounted
2
3
4
5
6
7
8
9
17/02/2020
צורת גג
סוג
חיבורי
גג
צבע
גג
מצב
צבע
גג
צבע
מעטפת
חיצונית
מצב צבע
מעטפת
חיצונית
סוג חיבורי
מעטפת
מצב
מעטפת
פנימית
מיכל
מחומם
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חום
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חום
ישן
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
כחול בהיר
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
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טבלה :3נתוני אביזרים – שנת 2019
מספר
מיכל
1
2
3
4
5
6
7
8
9
סה"כ
שובר ואקום
כמות
2
2
2
2
2
2
2
6
2
Vacuum
]set. [psi
0
0
0
0
0
0
0
0
0
Pressure
]set. [psi
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
רגליים מתכווננות התומכות
בגג צף()1
גובה כמות באזור
כמות
במרכז
()ft
pontoon
29
43
11
29
43
11
29
43
11
29
43
11
72
107
11
72
107
11
72
107
11
36
54
9
29
43
11
כמות
מדי
מפלס
Rim
Vent
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
כמות בוצה
בנקיון
(מ"ק)
"גרביים" לבאר
הדיגום המחורצת
ולרגלי הגג הצף()1
70
70
70
70
150
150
150
70
70
870
יש
יש
יש
יש
יש
יש
יש
יש
יש
( )1הנ"ל לא נלקחו בחשבון בחישוב הפליטות מתוכנת ה TANKS-מפני שנדגמו במסגרת ניטורי ה.LDAR-
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הנחות שנלקחו לצורך החישובים
.1עבור חישוב Degassingבמיכל עם גג צף – הונח:
•
גג צף נח על רגליים בגובה ( 9-11 ftבהתאם לטבלה לעיל) וזהו גם הגובה המרבי של הנוזל
במיכל.
•
גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.
.2הונח כי ניקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שנים .הניקיון יארך יום אחד.
.3הונח כי אירוע של נחיתת גגות צפים מתבצע אחת ל 15-שנים .זמן נחיתת הגג במקרה זה לא
יעלה על 4ימים.
.4יחס הנוזל בבוצה הונח כ]2[ 0.8 -
.5בהתאם לטבלה 7.1-6על פי [ ,]1נבחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,
לצורך חישובי פליטות לאוויר:
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת Tanks
צבע מעטפת
מיכל
צבע לצורך חישובי אקסל
צבע לצורך חישובים בתוכנת
בהתאם למסמך EPA AP-42
)*( Tanks
כחול בהיר
Gray Medium
Gray Medium
Brown
Aluminium/Diffuse
Beige/Cream
Aluminium/Specular
White
White
חום
צהוב קרם
לבן
(*) בתוכנת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך
.]1[ EPA AP-42
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.2.2נתונים עבור מסוף מילוי מיכליות כביש
טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 2019
מס'
זרוע
1
2
3
4
5
6
7
8
מוצר
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
סה"כ
מילוי
עילי /תחתי
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
נפח מילוי שנתי
(מ"ק)
0
0
0
0
0
0
0
0
0
נפח ממוצע של
מיכלית (מ"ק)
30
30
30
30
30
30
30
30
הנחות שנלקחו צורך החישובים
.1
מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:
א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:
דוגמת חישוב עבור מיכל מס' :2
ב .בשלב השני חושב מקדם αממוצע עבור הקרוסין:
.2
זמן מילוי מיכלית חושב על פי נפח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000
ליטר/דקה.
.3
Vapor collection efficiency - 70%
.4
Vapor recovery efficiency - 0%
.5
Saturation factorהונח כ (Submerged loading, dedicated normal service) 0.6-על פי
[ .]1טבלה רלוונטית מצורפת בנספח א'.
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.3חישוב פליטות
.3.1כללי
חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכנת Tanksובעזרת .]1[ EPA-AP 42
הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ( )LDARמצורפת בנספח ב'.
דוגמת חישוב עבור מיכל גג חיצוני צף (מיכל מס' )2המאחסן קרוסין ,מצורפת כנספח ג' למסמך
זה.
בדוגמאות אלה ניתן לראות את נתוני הקלט (כולל הנחות) עליהם התבססו החישובים.
.3.2סוגי פליטות מחושבות
הערכת הפליטות ממיכלי אחסון כוללת [:]3
• פליטות בזמן אחסון )(Breathing Losses
• פליטות משינויי מפלס )(Working Losses
• פליטות כתוצאה מניקוי וריקון מיכלים )(Degassing Losses
• פליטות כתוצאה מנחיתת גגות צפים )(Roof Landing Losses
• פליטות כתוצאה מהפרשי לחץ )(Flash Losses
• פליטות בזמן מילוי מיכלים ומיכליות
בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ
).(Flash Losses
פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלחץ הנוזל ,נתון הגורם להפרת שיווי המשקל
הקיים במיכל (בין גז לנוזל) וכתוצאה מכך נוצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הנוזל
עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר נוזל המאוחסן בלחץ נשלח
לאחסון במיכל בעל לחץ נמוך יותר [.]3
פליטות אלו הוזנחו כיוון שכל החומרים מוחזקים בתנאים אטמוספריים בכל אחד מהשלבים
הנוגעים להובלתם ואחסונם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.
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.3.3בחירת חומרים בתוכנת Tanks
על פי נתוני MSDSשל הדלקים במסוף ,נבחרו החומרים הבאים הקיימים בתוכנת Tanks
כמייצגים של חומרים אלו:
טבלה :6חומרים מייצגים בתוכנת Tanks
דלק קיים במסוף
חומר מייצג בתוכנת Tanks
סולר (תחבורה והסקה)
Distillate fuel oil no 2
נפט (קרוסין)
Jet kerosene
בנזין
Gasoline RVP 10
.3.4נתונים מטאורולוגיים
לצורך חישוב הנתונים בתוכנת Tanksהוגדרו נתונים מטאורולוגים המתאימים למפרץ חיפה על פי
מקורות [.]4
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.4סיכום פליטות לשנת 2019
.4.1מיכלים
סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:
טבלה :7סיכום פליטות מכלים -שנת 2019
מיכל
חומר
פליטות לאוויר
(ק"ג/שנה)
1
בנזין
3,603
2
קרוסין
788
3
סולר
38
4
סולר
826
5
סולר
1,701
6
סולר
1,693
7
סולר
1,723
8
קרוסין
792
9
קרוסין
758
11,921
סה"כ
.4.2מסוף מילוי מיכליות כביש
עבור זרועות המילוי לא חושבו פליטות לשנת ,2019מאחר וזרועות המילוי לא פעלו במהלך השנה.
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.4.3מיכל איסוף תשטיפים
סך הפליטה ממיכל לאיסוף תשטיפים הינה כ 1 -ק"ג/שנה.
חישוב מצורף בנספח ד'.
יצוין כי החישוב מתבסס על הנחה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל
בעיקר ניקוז מים מהמכלים.
.4.4סיכום ממצאי ניטור LDAR
טבלה :8סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 2019
סה"כ פליטות (ק"ג/שנה)
סיכום פליטות LDAR
פליטה שנתית (ק"ג/שנה)
סה"כ
8
.4.5פליטה שנתית מכלל המתקן
טבלה :9סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 2019
סה"כ פליטות (ק"ג/שנה)
חוות מיכלים
מסוף מילוי
מיכליות כביש
מיכל לאיסוף
תשטיפים
11,921
0
1
סיכום פליטות
רכיבים
סה"כ
()LDAR
8
11,930
.5פליטות לא שגרתיות במהלך שנת 2019
במהלך שנת 2019לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.
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.6מקורות
]1[ EPA-AP42
]2[ USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version
4.0 - APPENDIX D
[ ]3הנחיות הממונה לטיפול בבקשה להיתר פליטה לפי סעיף (9א) לתקנות אוויר נקי (היתרי פליטה),
התש"ע – ,2010מהדורה ,4ספטמבר 2014
[ ]4האטלס האקלימי לתכנון פיסי וסביבתי בישראל ,מהדורה שנייה1994 ,
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נספח א'
טבלה 5.2-1
AP-42
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נספח ב'
נתוני ניטור LDARעבור אלרואי – סיכום שנת 2019
(מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך )26.12.2019
3013.16-006A
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LDAR
Fugitive Emission Monitoring
Report No.
RL-TS-R-A-19
Plant:TASHAN
City:Haifa
District:Haifa
Production Unit:Alroy
Group:Group 1-2-3
Reporting period:Annual Summary
Report printing date:26-Dec-2019
Technicians names:Polik
Portselan
Tomarov
Report editor:
Michael Ourievsky
Approved by:
Alexey Ratner, CEO
1
Table of Content
1. Project introduction
1.1 Scope of work
1.2 Project phases
2. Methodology
2.1 Definitions
2.2 Methodology
3. Summary of Monitoring Period
3.1 Cumulative Data of Monitoring Period
3.2 Summary of Monitoring Period
3.3 Form 07: component classification and emission estimations for production facilities
3.4 Chemical Summary
3.5 LDAR report for production facilities
4. First Measurement and Measurement After Repair Round 1
4.1 Form-07 by Round
4.2 Chemical Summary First Measurement
4.3 Chemical Summary After Repair
4.4 LDAR report for production facilities
5. First Measurement and Measurement After Repair Round 2
5.1 Form-07 by Round
5.2 Chemical Summary First Measurement
5.3 Chemical Summary After Repair
5.4 LDAR report for production facilities
6. First Measurement and Measurement After Repair Round 3
6.1 Form-07 by Round
6.2 Chemical Summary First Measurement
6.3 Chemical Summary After Repair
6.4 LDAR report for production facilities
7. First Measurement and Measurement After Repair Round 4
7.1 Form-07 by Round
7.2 Chemical Summary First Measurement
7.3 Chemical Summary After Repair
7.4 LDAR report for production facilities
8. First Measurement and Measurement After Repair Round 5
8.1 Form-07 by Round
8.2 Chemical Summary First Measurement
8.3 Chemical Summary After Repair
8.4 LDAR report for production facilities
9. First Measurement and Measurement After Repair Round 6
9.1 Form-07 by Round
9.2 Chemical Summary First Measurement
9.3 Chemical Summary After Repair
9.4 LDAR report for production facilities
Table Of Content
5
5
6
6
8
9
16
17
19
21
22
23
24
26
27
28
29
31
32
34
36
38
39
40
41
43
44
46
48
50
51
52
53
page 2 of 120
10. Graphs First Measurement Round 1
10.1 Overview by Reading Range
10.2 Comparison between count of sources & kg/year, by sources
10.3 Total overview by chemicals
11. Graphs Measurement After Repair Round 1
11.1 Overview by Reading Range
11.2 Comparison between count of sources & kg/year, by sources
11.3 Total overview by chemicals
12. Graphs First Measurement Round 2
12.1 Overview by Reading Range
12.2 Comparison between count of sources & kg/year, by sources
12.3 Total overview by chemicals
13. Graphs Measurement After Repair Round 2
13.1 Overview by Reading Range
13.2 Comparison between count of sources & kg/year, by sources
13.3 Total overview by chemicals
14. Graphs First Measurement Round 3
14.1 Overview by Reading Range
14.2 Comparison between count of sources & kg/year, by sources
14.3 Total overview by chemicals
15. Graphs Measurement After Repair Round 3
15.1 Overview by Reading Range
15.2 Comparison between count of sources & kg/year, by sources
15.3 Total overview by chemicals
16. Graphs First Measurement Round 4
16.1 Overview by Reading Range
16.2 Comparison between count of sources & kg/year, by sources
16.3 Total overview by chemicals
17. Graphs Measurement After Repair Round 4
17.1 Overview by Reading Range
17.2 Comparison between count of sources & kg/year, by sources
17.3 Total overview by chemicals
18. Graphs First Measurement Round 5
18.1 Overview by Reading Range
18.2 Comparison between count of sources & kg/year, by sources
18.3 Total overview by chemicals
19. Graphs Measurement After Repair Round 5
19.1 Overview by Reading Range
19.2 Comparison between count of sources & kg/year, by sources
19.3 Total overview by chemicals
20. Graphs First Measurement Round 6
20.1 Overview by Reading Range
20.2 Comparison between count of sources & kg/year, by sources
20.3 Total overview by chemicals
Table Of Content
55
57
56
59
61
60
63
65
64
67
69
68
71
73
72
75
77
76
79
81
80
83
85
84
87
89
88
91
93
92
95
97
96
page 3 of 120
21. Graphs Measurement After Repair Round 6
21.1 Overview by Reading Range
21.2 Comparison between count of sources & kg/year, by sources
21.3 Total overview by chemicals
22. Graphs Cumulative
22.1 Comparison between count of sources above leak definition, by quarter
22.2 Comparison between % of components above leak definition by quarter
22.3 Comparison between count of sources & kg/year, by sources Cumulative
22.4 Total overview by chemicals
23. Attachments
23.1 Calibration loglist
23.2 Calibration gas certificates
23.3 Composition list & Response Factors
23.4 Quarterly equipment check Q1
23.5 Quarterly equipment check Q2
23.6 Quarterly equipment check Q3
23.7 Quarterly equipment check Q4
23.8 Quarterly production hours
Table Of Content
99
101
100
103
104
105
106
108
109
115
116
117
118
119
120
page 4 of 120
1 Project introduction
1.1 Scope of work
6 rounds of measurements (from 01/01/2019 to 31/12/2019)
Measurements performed for following classes:
Group 1: PRD, Sampling Point
Group 2: Open End, Stem Valve
Group 3: Connection, Flange
1.2 Project phases
Monitoring: Group 1-2-3
Re-measurement after repair action
Revision of equipment and production processes
Inventorisation: adding or deleting components
Mapping of components on P&ID's
General
1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory
Accreditation Authority).
2. ISRAC is not responsible for the test results.
Project Introduction
page 5 of 120
2 Methodology
1.1 Definitions
Chemical State:
Gas/Vapor: stream which is in process conditions under gaseous or vapor form.
Light Liquid: a liquid having a VOC content greater than 10% (by volume) hat evaporates at 150°C
Heavy Liquid: a liquid having a VOC content of 10% or less (by volume) that evaporates at 150°C
Leak definition: 1,000 ppm (all sources)
Difficult to monitor components:
Any component situated at a level higher than five meters above ground level or any component situated at a distance further than
two meters from a platform and which cannot be accessed by employees in a safe way.
Any component which access requires the elevation of a person to a level higher than two meters above regular surfaces, and which
cannot be accessed in a safe.
Registered sources:
Sources with a leak value equal or greater than 9 ppm.
Default-zero:
This equation is valid for sources with a leak value of 0 ppm.A fixed EPA emission calculation rule is used for all these sources.
Total components:
All of the existing active components.
Total measured components:
All of the components, measured in specific monitoring round.
2.2 Methodology
Formulas:
Measured ppm values are converted to emission loss (kg/year) and these calculations are based on the E.P.A. “Correlation method
Refinery”
Modified Trapezoidal Emission Calculation Method:
The modified trapezoid method assumes that the mass leak rate changes linearly between any two monitoring points, except for
periods between leak detection and repair; the leak monitor reading is used from the time the leak is detected to the time it is repaired (i.e.,
re-screened).
Cumulative data:
In "Cumulative data" tables we provide the results of all of the measurements that performed from beginning of the year till the end of
current monitoring period (quarter). We also calculate the real sum of previous emissions based on the all rounds of the measurements
(before and after repairing attempts).(US EPA "Emission Estimation Protocol for Petroleum Refineries")
Methodology
page 6 of 120
Equation Set Details Report
Equation Set
Class
Chemical State
Default Zero
Pegged 100k
Multiplier
Exponent
Avg. Factor
Refinery
Connection
Light Liquid
7.5E-06
0.03
1.53E-06
0.735
0.00025
Refinery
Flange
Light Liquid
3.1E-07
0.084
4.61E-06
0.703
0.00025
Refinery
Open End
Light Liquid
2E-06
0.079
2.2E-06
0.704
0.0023
Refinery
PRD
Light Liquid
4E-06
0.11
1.36E-05
0.589
0.16
Refinery
Sampling Point
Light Liquid
4E-06
0.11
1.36E-05
0.589
0.015
Refinery
Stem Valve
Light Liquid
7.8E-06
0.14
2.29E-06
0.746
0.0109
Equations
page 7 of 120
Summary of Period: 01/01/2019-31/12/2019
The total emissions: 7.755kg
Overview by component class
Component
Class
Total Components
count
Total Components above leak definition
% of components above leak definition
Unrepaired Components
(1,000 ppm)
(1,000 ppm)
count
%
count
Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round
1
2
3
4
5
6
1
2
3
4
5
6
1
2
3
4
5
6
Total Emissions
kg
01/01/2019- 31/12/2019
PRD
Sampling Point
Total Group 1:
Stem Valve
Open End
Total Group 2:
Flange
Connection
Total Group 3:
4
4
8
20
102
122
55
38
93
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.14
1.354
1.494
1.367
2.248
3.615
0.149
2.497
2.646
Total:
223
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
7.755
Overview by reading range
Total Components
Round 1
Reading Range
#
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
Total:
Cumulative Data
Round 2
%
6
2
0
0
0
0
8
#
75.0%
25.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 3
%
7
1
0
0
0
0
8
#
87.5%
12.5%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 4
%
223
0
0
0
0
0
223
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 5
%
8
0
0
0
0
0
8
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 6
%
130
0
0
0
0
0
130
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
%
8
0
0
0
0
0
8
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
page 8 of 120
Summary of Monitoring Period Round 1
First measurement:
0 "difficult to monitor" sources.
6 default-zero sources with a calculated emission rate:
2 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
6
2
0
0
0
0
Total:
8
0.21 kg/year
6.524 kg/year
6.734 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
2
0
0.00%
0
6.594
8
2
0
0.00%
0
6.734
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
75.00%
0.21
3.12%
25.00%
6.524
96.88%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
6.734
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
6 default-zero sources with a calculated emission rate:
2 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
0.21 kg/year
6.524 kg/year
6.734 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
2
0
0.00%
0
6.594
Total:
8
2
0
0.00%
0
6.734
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
6
2
0
0
0
0
Total:
8
Summary R1
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
75.00%
0.21
3.12%
25.00%
6.524
96.88%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
6.734
Comments
100%
page 9 of 120
Summary of Monitoring Period Round 2
First measurement:
0 "difficult to monitor" sources.
7 default-zero sources with a calculated emission rate:
1 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
7
1
0
0
0
0
Total:
8
0.245 kg/year
3.515 kg/year
3.76 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
1
0
0.00%
0
3.62
8
1
0
0.00%
0
3.76
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
87.50%
0.245
6.52%
12.50%
3.515
93.48%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
3.76
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
7 default-zero sources with a calculated emission rate:
1 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
0.245 kg/year
3.515 kg/year
3.76 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
1
0
0.00%
0
3.62
Total:
8
1
0
0.00%
0
3.76
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
7
1
0
0
0
0
Total:
8
Summary R2
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
87.50%
0.245
6.52%
12.50%
3.515
93.48%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
3.76
Comments
100%
page 10 of 120
Summary of Monitoring Period Round 3
First measurement:
0 "difficult to monitor" sources.
223 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Stem Valve
Open End
Flange
Connection
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
223
0
0
0
0
0
Total:
223
6.063 kg/year
0 kg/year
6.063 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
0
0
0.00%
0
0.14
20
0
0
0.00%
0
1.363
102
0
0
0.00%
0
1.782
55
0
0
0.00%
0
0.149
38
0
0
0.00%
0
2.49
223
0
0
0.00%
0
6.064
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
6.063
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
6.063
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
223 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
6.063 kg/year
0 kg/year
6.063 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Stem Valve
20
0
0
0.00%
0
1.363
Open End
102
0
0
0.00%
0
1.782
Flange
55
0
0
0.00%
0
0.149
Connection
38
0
0
0.00%
0
2.49
223
0
0
0.00%
0
6.064
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
223
0
0
0
0
0
Total:
223
Summary R3
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
6.063
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
6.063
Comments
100%
page 11 of 120
Summary of Monitoring Period Round 4
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
0.283 kg/year
0 kg/year
0.283 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
4
0
0
0.00%
0
0.141
8
0
0
0.00%
0
0.282
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.283
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.283
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
0.283 kg/year
0 kg/year
0.283 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
Sampling Point
4
0
0
0.00%
0
0.141
Total:
8
0
0
0.00%
0
0.282
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Summary R4
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.283
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.283
Comments
100%
page 12 of 120
Summary of Monitoring Period Round 5
First measurement:
0 "difficult to monitor" sources.
130 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Stem Valve
Open End
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
130
0
0
0
0
0
Total:
130
3.462 kg/year
0 kg/year
3.462 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
4
0
0
0.00%
0
0.141
20
0
0
0.00%
0
1.378
102
0
0
0.00%
0
1.802
130
0
0
0.00%
0
3.462
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
3.462
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
3.462
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
130 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
3.462 kg/year
0 kg/year
3.462 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
Sampling Point
4
0
0
0.00%
0
0.141
Stem Valve
20
0
0
0.00%
0
1.378
Open End
102
0
0
0.00%
0
1.802
Total:
130
0
0
0.00%
0
3.462
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
130
0
0
0
0
0
Total:
130
Summary R5
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
3.462
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
3.462
Comments
100%
page 13 of 120
Summary of Monitoring Period Round 6
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
0.283 kg/year
0 kg/year
0.283 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
4
0
0
0.00%
0
0.141
8
0
0
0.00%
0
0.282
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.283
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.283
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
0.283 kg/year
0 kg/year
0.283 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
Sampling Point
4
0
0
0.00%
0
0.141
Total:
8
0
0
0.00%
0
0.282
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Summary R6
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.283
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.283
Comments
100%
page 14 of 120
Cumulative data for period
01-01-2019-31-12-2019
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph Cumulative
page 15 of 120
Fugitive emission component classification and emission estimation for production facilities
01/01/2018-31/12/2018 Calculation period
Monitoring
Frequency
Components above 1,000 ppm
cycles/year
Cumulative Components above
Emission
100,000 ppm
%
R6
6
6 0.00%
6
6
6 0.00%
6
0.00%
2
2 0.00%
2
2
2 0.00%
2
0.00%
1
1 0.00%
1
1
1 0.00%
1
0.00%
0.00%
R5
R4
kg
R3
R2
Count
R1
Components in
Components in
Components in
reading range
reading range 9-999 reading range 0-8 ppm
1,000-100,000 ppm
ppm
Count
Count
Count
Unrepaired
Components
Count
TASHAN Company name
22-Jan-2019 Date
Alroy Production Unit
Report Number
Total Components Difficult
Major
Total
Chemical State Component Class Group
above 1,000 ppm
to
Components Components
Monitor
Count
R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1
Count
Count
Count
0.00% 0.00% 0.00% 0.00% 0.00%
0.14
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
4
4
4
4
4
4 0
0
0
0
0
0 0
0
0
0
0
0
0
1
0.00% 0.00% 0.00% 0.00% 0.00%
1.354
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
1
2
4
4
4
4
3
2 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0.00% 0.00% 0.00% 0.00% 0.00%
1.494
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
1
2
8
8
8
8
7
6 0
0
0
0
0
0 0
0
0
0
0
0
0
1
0.00% 0.00% 0.00% 0.00% 0.00%
1.367
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
20
0
20
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
16
0.00% 0.00% 0.00% 0.00% 0.00%
2.248
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0 102
0 102
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0.00% 0.00% 0.00% 0.00% 0.00%
3.615
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0 122
0 122
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
16
0.00% 0.00% 0.00% 0.00% 0.00%
0.149
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0
55
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0.00% 0.00% 0.00% 0.00% 0.00%
2.497
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0
38
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0.00% 0.00% 0.00% 0.00% 0.00%
0.00% 0.00% 0.00% 0.00% 0.00%
2.646
7.755
0 0
0 0
0
0
0
0
0
0
0 0
0 0
0
0
0
0
0
0
0
0
0 0
0 0
0
0
0
0
0
0
0
1
0
2
0
0
8 130
0 93
8 223
0
7
0 0
6 0
0
0
0
0
0
0
0
0
0 0
0 0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
GV
PRD
LL
HL
GV
Sampling Point
4
LL
HL
8 Subtotal G1
GV
Stem Valve
20
LL
HL
GV
Open End
102
LL
HL
122 Subtotal G2
GV
Flange
55
LL
HL
GV
Connection
38
LL
HL
93 Subtotal G3
223 Total Components
G1
4
7.755 Total Cumulative Emission
G2
G3
Chemical Summary by Component Class
Report Chemical Summary Cumulative
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: Refinery
Units of Measurement: KG
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1354
0.0135
0.0677
0.1354
0.5416
0.4604
1.354
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1367
0.0137
0.0683
0.1367
0.5466
0.4646
1.3666
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.2248
0.0225
0.1124
0.2248
0.8993
0.7644
2.2482
Chemical CU
page 17 of 120
Chemical Summary by Component Class
Report Chemical Summary Cumulative
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: Refinery
Units of Measurement: KG
Report Date: 26.12.2019
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0149
0.0015
0.0075
0.0149
0.0597
0.0508
0.1493
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.2497
0.025
0.1248
0.2497
0.9986
0.8488
2.4966
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.7755
0.0776
0.3877
0.7755
3.1019
2.6367
7.7549
Grand Total
Chemical CU
7.7549
page 18 of 120
LDAR report for production facilities
Unit
Drawing
LDAR 015
Component
Tag
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 1-2-3-4-5-6
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 19 of 120
Round 1
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R1
page 20 of 120
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 1
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.14
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
6.594
0
0
2
2
0
0
0
4
HL
6
0.0%
6.734
0
0
2
6
0
0
1
8
Subtotal G1
0.0%
6.734
0
0
2
6
0
0
1
8 Total Components
6.734 Total Annual Emission Rate
TASHAN Company name
Round 1
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.14
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
6.594
0
0
2
2
0
0
0
4
HL
6
0.0%
6.734
0
0
2
6
0
0
1
8
Subtotal G1
0.0%
6.734
0
0
2
6
0
0
1
8 Total Components
6.734 Total Annual Emission Rate
Form-07 R1
page 21 of 120
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.6594
0.0659
0.3297
0.6594
2.6377
2.2421
6.5942
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.6734
0.0673
0.3367
0.6734
2.6938
2.2898
6.7344
Grand Total
Chemical FM R1
6.7344
page 22 of 120
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.6594
0.0659
0.3297
0.6594
2.6377
2.2421
6.5942
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.6734
0.0673
0.3367
0.6734
2.6938
2.2898
6.7344
Grand Total
Chemical AR R1
6.7344
page 23 of 120
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R1
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 1
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 24 of 120
Round 2
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R2
page 25 of 120
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 2
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.14
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
3.62
0
0
1
3
0
0
0
4
HL
6
0.0%
3.76
0
0
1
7
0
0
1
8
Subtotal G1
0.0%
3.76
0
0
1
7
0
0
1
8 Total Components
3.76 Total Annual Emission Rate
TASHAN Company name
Round 2
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.14
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
3.62
0
0
1
3
0
0
0
4
HL
6
0.0%
3.76
0
0
1
7
0
0
1
8
Subtotal G1
0.0%
3.76
0
0
1
7
0
0
1
8 Total Components
3.76 Total Annual Emission Rate
Form-07 R2
page 26 of 120
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.362
0.0362
0.181
0.362
1.448
1.2308
3.62
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.376
0.0376
0.188
0.376
1.5041
1.2785
3.7602
Grand Total
Chemical FM R2
3.7602
page 27 of 120
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.362
0.0362
0.181
0.362
1.448
1.2308
3.62
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.376
0.0376
0.188
0.376
1.5041
1.2785
3.7602
Grand Total
Chemical AR R2
3.7602
page 28 of 120
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R2
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 2
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 29 of 120
Round 3
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R3
page 30 of 120
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 3
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.14
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
0.14
0
0
0
4
0
0
0
4
HL
6
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
GV
Stem Valve
G2
2
LL
2
0.0%
1.363
0
0
0
20
0
0
16
20
HL
2
GV
Open End
2
LL
2
0.0%
1.782
0
0
0
102
0
0
0
102
HL
2
0.0%
3.145
0
0
0
122
0
0
16
122
Subtotal G2
GV
Flange
G3
1
LL
1
0.0%
0.149
0
0
0
55
0
0
0
55
HL
1
GV
Connection
1
LL
1
0.0%
2.49
0
0
0
38
0
0
0
38
HL
1
0.0%
2.639
0
0
0
93
0
0
0
93
Subtotal G3
0.0%
6.064
0
0
0
223
0
0
17
223 Total Components
6.064 Total Annual Emission Rate
TASHAN Company name
Round 3
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.14
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
0.14
0
0
0
4
0
0
0
4
HL
6
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
GV
Stem Valve
G2
2
LL
2
0.0%
1.363
0
0
0
20
0
0
16
20
HL
2
GV
Open End
2
LL
2
0.0%
1.782
0
0
0
102
0
0
0
102
HL
2
0.0%
3.145
0
0
0
122
0
0
16
122
Subtotal G2
GV
Flange
G3
1
LL
1
0.0%
0.149
0
0
0
55
0
0
0
55
HL
1
GV
Connection
1
LL
1
0.0%
2.49
0
0
0
38
0
0
0
38
HL
1
0.0%
2.639
0
0
0
93
0
0
0
93
Subtotal G3
0.0%
6.064
0
0
0
223
0
0
17
223 Total Components
6.064 Total Annual Emission Rate
Form-07 R3
page 31 of 120
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1782
0.0178
0.0891
0.1782
0.7129
0.6059
1.7821
Chemical FM R3
page 32 of 120
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0149
0.0015
0.0074
0.0149
0.0596
0.0506
0.1489
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.249
0.0249
0.1245
0.249
0.9959
0.8465
2.4898
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.6064
0.0606
0.3031
0.6064
2.4253
2.0614
6.0632
Grand Total
Chemical FM R3
6.0632
page 33 of 120
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1782
0.0178
0.0891
0.1782
0.7129
0.6059
1.7821
Chemical AR R3
page 34 of 120
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0149
0.0015
0.0074
0.0149
0.0596
0.0506
0.1489
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.249
0.0249
0.1245
0.249
0.9959
0.8465
2.4898
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.6064
0.0606
0.3031
0.6064
2.4253
2.0614
6.0632
Grand Total
Chemical AR R3
6.0632
page 35 of 120
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R3
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 3
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 36 of 120
Round 4
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R4
page 37 of 120
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 4
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.141
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
0.141
0
0
0
4
0
0
0
4
HL
6
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.282
0
0
0
8
0
0
1
8 Total Components
0.282 Total Annual Emission Rate
TASHAN Company name
Round 4
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.141
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
0.141
0
0
0
4
0
0
0
4
HL
6
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.282
0
0
0
8
0
0
1
8 Total Components
0.282 Total Annual Emission Rate
Form-07 R4
page 38 of 120
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0282
0.0028
0.0142
0.0282
0.113
0.096
0.2824
Grand Total
Chemical FM R4
0.2824
page 39 of 120
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0282
0.0028
0.0142
0.0282
0.113
0.096
0.2824
Grand Total
Chemical AR R4
0.2824
page 40 of 120
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R4
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 4
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 41 of 120
Round 5
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R5
page 42 of 120
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 5
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.141
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
0.141
0
0
0
4
0
0
0
4
HL
6
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
GV
Stem Valve
G2
2
LL
2
0.0%
1.378
0
0
0
20
0
0
16
20
HL
2
GV
Open End
2
LL
2
0.0%
1.802
0
0
0
102
0
0
0
102
HL
2
0.0%
3.18
0
0
0
122
0
0
16
122
Subtotal G2
0.0%
3.462
0
0
0
130
0
0
17
130 Total Components
3.462 Total Annual Emission Rate
TASHAN Company name
Round 5
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.141
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
0.141
0
0
0
4
0
0
0
4
HL
6
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
GV
Stem Valve
G2
2
LL
2
0.0%
1.378
0
0
0
20
0
0
16
20
HL
2
GV
Open End
2
LL
2
0.0%
1.802
0
0
0
102
0
0
0
102
HL
2
0.0%
3.18
0
0
0
122
0
0
16
122
Subtotal G2
0.0%
3.462
0
0
0
130
0
0
17
130 Total Components
3.462 Total Annual Emission Rate
Form-07 R5
page 43 of 120
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1378
0.0138
0.0689
0.1378
0.5511
0.4684
1.3778
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1802
0.018
0.0901
0.1802
0.7207
0.6126
1.8018
Chemical FM R5
page 44 of 120
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
All
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.3462
0.0346
0.1732
0.3462
1.3848
1.177
3.462
Grand Total
Chemical FM R5
3.462
page 45 of 120
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1378
0.0138
0.0689
0.1378
0.5511
0.4684
1.3778
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1802
0.018
0.0901
0.1802
0.7207
0.6126
1.8018
Chemical AR R5
page 46 of 120
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
All
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.3462
0.0346
0.1732
0.3462
1.3848
1.177
3.462
Grand Total
Chemical AR R5
3.462
page 47 of 120
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R5
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 5
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 48 of 120
Round 6
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R6
page 49 of 120
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 6
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.141
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
0.141
0
0
0
4
0
0
0
4
HL
6
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.282
0
0
0
8
0
0
1
8 Total Components
0.282 Total Annual Emission Rate
TASHAN Company name
Round 6
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999 range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
GV
PRD
G1
6
LL
6
0.0%
0.141
0
0
0
4
0
0
1
4
HL
6
GV
Sampling Point
6
LL
6
0.0%
0.141
0
0
0
4
0
0
0
4
HL
6
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.282
0
0
0
8
0
0
1
8 Total Components
0.282 Total Annual Emission Rate
Form-07 R6
page 50 of 120
Chemical Summary by Component Class
Report Chemical Summary First Measurement
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0282
0.0028
0.0142
0.0282
0.113
0.096
0.2824
Grand Total
Chemical FM R6
0.2824
page 51 of 120
Chemical Summary by Component Class
Report Chemical Summary After Repair
Calculation Period: 01/01/2019- 31/12/2019
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 26.12.2019
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0282
0.0028
0.0142
0.0282
0.113
0.096
0.2824
Grand Total
Chemical AR R6
0.2824
page 52 of 120
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R6
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 6
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 53 of 120
Graphs
Round 1
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R1
page 54 of 120
Graph6.1.1 R1
page 55 of 120
Graph6.1.3 R1
page 56 of 120
Graph6.1.2 R1
page 57 of 120
Graphs
Round 1
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R1
page 58 of 120
Graph6.2.1 R1
page 59 of 120
Graph6.2.3 R1
page 60 of 120
Graph6.2.2 R1
page 61 of 120
Graphs
Round 2
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R2
page 62 of 120
Graph6.1.1 R2
page 63 of 120
Graph6.1.3 R2
page 64 of 120
Graph6.1.2 R2
page 65 of 120
Graphs
Round 2
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R2
page 66 of 120
Graph6.2.1 R2
page 67 of 120
Graph6.2.3 R2
page 68 of 120
Graph6.2.2 R2
page 69 of 120
Graphs
Round 3
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R3
page 70 of 120
Graph6.1.1 R3
page 71 of 120
Graph6.1.3 R3
page 72 of 120
Graph6.1.2 R3
page 73 of 120
Graphs
Round 3
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R3
page 74 of 120
Graph6.2.1 R3
page 75 of 120
Graph6.2.3 R3
page 76 of 120
Graph6.2.2 R3
page 77 of 120
Graphs
Round 4
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R4
page 78 of 120
Graph6.1.1 R4
page 79 of 120
Graph6.1.3 R4
page 80 of 120
Graph6.1.2 R4
page 81 of 120
Graphs
Round 4
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R4
page 82 of 120
Graph6.2.1 R4
page 83 of 120
Graph6.2.3 R4
page 84 of 120
Graph6.2.2 R4
page 85 of 120
Graphs
Round 5
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R5
page 86 of 120
Graph6.1.1 R5
page 87 of 120
Graph6.1.3 R5
page 88 of 120
Graph6.1.2 R5
page 89 of 120
Graphs
Round 5
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R5
page 90 of 120
Graph6.2.1 R5
page 91 of 120
Graph6.2.3 R5
page 92 of 120
Graph6.2.2 R5
page 93 of 120
Graphs
Round 6
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R6
page 94 of 120
Graph6.1.1 R6
page 95 of 120
Graph6.1.3 R6
page 96 of 120
Graph6.1.2 R6
page 97 of 120
Graphs
Round 6
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R6
page 98 of 120
Graph6.2.1 R6
page 99 of 120
Graph6.2.3 R6
page 100 of 120
Graph6.2.2 R6
page 101 of 120
Graphs
Cumulative data for period
01-01-2019-31-12-2019
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph Graphs Cumul
page 102 of 120
Graph6.3.1
page 103 of 120
Graph6.3.2
page 104 of 120
Graph6.3.3
page 105 of 120
Graph6.3.4
page 106 of 120
General
Calibration loglist
Calibration gas certificates
Composition list & Response Factors
Quarterly production hours
Quarterly equipment check
Paragraph General
page 107 of 120
Calibration log list
Plant
Round Equipment Analyzer
Type
Type
Ultra-Zero
Span Gas
Span gas Cylinder
Span
Check gas Check gas Cylinder
Check gas
No
concentration
No
concentration
Date
Equipment
No
Equipment
Serial
No
(A)
ppm
ppm
Check
Calibration Result
error
1-st 2-st 3-st
check check check
(A1) (A2) (A3)
(CP)
ppm ppm ppm
TASHAN
1
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
07-Jan-2019
5
202016061436 505
507
507
0.46%
OK
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
10-Jan-2019
1
0715622657
501
501
501
-0.60%
OK
TASHAN
2
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
10-Jan-2019
5
202016061436 506
505
505
0.26%
OK
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
25-Jan-2019
1
0715622657
491
491
491
-2.58%
OK
TASHAN
2
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
25-Jan-2019
5
202016061436 503
502
503
-0.26%
OK
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
07-Mar-2019
1
0715622657
496
496
495
-1.65%
OK
TASHAN
2
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
07-Mar-2019
5
202016061436 503
503
503
-0.20%
OK
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
03-Apr-2019
1
0715622657
500
500
500
-0.79%
OK
TASHAN
2
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
03-Apr-2019
5
202016061436 504
504
504
0.00%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
02-May-2019
3
0115248937
502
503
504
-0.20%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
02-May-2019
5
202016061436 502
504
504
-0.13%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
05-May-2019
3
0115248937
511
510
510
1.26%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
05-May-2019
5
202016061436 503
503
504
-0.13%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
12-May-2019
1
0715622657
502
502
503
-0.33%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
12-May-2019
2
0115248185
505
505
507
0.33%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF16599
501
13-May-2019
5
202016061436 504
505
504
0.46%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF16599
501
12-Jun-2019
2
0115248185
510
510
511
1.66%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF16599
501
12-Jun-2019
3
0115248937
503
503
503
0.20%
OK
TASHAN
4
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51430
1,000
Methane
FF524456
504
02-Sep-2019
5
202016061436 503
502
502
-0.33%
OK
TASHAN
4
TVA2020
FID
Air, THC < 0.5ppm
Methane
FF51430
1,000
Methane
FF524456
504
15-Sep-2019
5
202016061436 509
508
508
0.86%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51430
1,000
Methane
FF524456
504
15-Sep-2019
3
0115248937
488
487
487
-3.31%
OK
TASHAN
5
TVA2020
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF524456
504
21-Nov-2019
5
202016061436 503
502
503
-0.26%
OK
TASHAN
6
TVA2020
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF524456
504
04-Dec-2019
5
202016061436 499
500
497
-1.06%
OK
TASHAN
5
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF524456
504
04-Dec-2019
2
0115248185
502
501
503
-0.40%
OK
TASHAN
5
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF524456
504
04-Dec-2019
3
0115248937
500
501
502
-0.60%
OK
Cal-Log
page 108 of 120
Certificate
page 109 of 120
Certificate
page 110 of 120
Certificate
page 111 of 120
Certificate
page 112 of 120
Certificate
page 113 of 120
Certificate
page 114 of 120
Stream Composition Summary
Stream Name
Stream Content
Stream Content
Dates
TVA
Gasoline
TOLUENE-34 %, n-Octane-40 %, METHYL TERT-BUTYL ETHER-10 %,
CYCLOHEXANE-5 %, BENZENE-1 %, 1-Butene-10 %
A=0.42, B=0.29
Petroleum
TOLUENE-7.5 %, n-Octane-55.3 %, CYCLOHEXANE-35.2 %, BENZENE-2 %
A=0.39, B=0.31
Stream Summary
MiniRAE 10.6 MiniRAE 11.7
page 115 of 120
Quarterly Validation of LDAR Devices
Date: 26-Dec-2018
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Analyzer
Span Gas
Sampling Flow
Rate
1
Check
Sampling
Span Gas
Flow
Span gas
Concentration
Result Check Gas
Rate
Cylinder No
ppm
l/min
Accuracy Check
Response Time
Comparison between two Devices
90%
Check Gas
Response Response Response
Second
of
Check gas
1-st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Time 1 Time 2 Time 3 Result
Result
Device
Result
Span
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
FF51430
1,000
1.01
OK
Methane
FF524456
504
507 513 507
0.99%
OK
900
4
4
4
OK
1.45
1.74
-0.29
16.67%
OK
2
0115248185
TVA1000B
FID
Methane
FF51430
1,000
1.13
OK
Methane
FF524456
504
495 497 497
-1.52%
OK
900
4
4
4
OK
2.11
1.98
0.13
-6.57%
OK
3
0115248937
TVA1000B
FID
Methane
FF51430
1,000
1.13
OK
Methane
FF524456
504
515 510 512
1.65%
OK
900
4
4
4
OK
1.22
1.15
0.07
-6.09%
OK
5
202016061436
TVA2020
FID
Methane
FF51430
1,000
1.09
OK
Methane
FF524456
504
501 500 501
-0.66%
OK
900
3
3
3
OK
2.24
2.11
0.13
-6.16%
OK
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.5
OK
Isobutylene EA0009962
997
995 994 994
-0.35%
OK
898
4
4
4
OK
2.5
2.1
0.4
-19.05%
OK
6
Quarterly Validation
page 116 of 120
Quarterly Validation of LDAR Devices
Date: 31-Mar-2019
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Analyzer
Span Gas
Sampling Flow
Rate
2
Check
Sampling
Span Gas
Flow
Span gas
Concentration
Result Check Gas
Rate
Cylinder No
ppm
l/min
Accuracy Check
Response Time
Comparison between two Devices
90%
Check Gas
Response Response Response
Second
of
Check gas
1-st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Time 1 Time 2 Time 3 Result
Result
Device
Result
Span
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
FF51430
1,000
1
OK
Methane
FF524456
504
495 502 501
-0.93%
OK
900
3
3
3
OK
2.2
2.14
0.06
-2.8%
OK
2
0115248185
TVA1000B
FID
Methane
FF51430
1,000
1.36
OK
Methane
FF524456
504
497 500 502
-0.86%
OK
900
3
3
3
OK
2.14
2.2
-0.06
2.73%
OK
3
0115248937
TVA1000B
FID
Methane
FF51430
1,000
1.26
OK
Methane
FF524456
504
495 501 502
-0.93%
OK
900
3
3
3
OK
2.18
2.35
-0.17
7.23%
OK
5
202016061436
TVA2020
FID
Methane
FF51430
1,000
0.99
OK
Methane
FF524456
504
504 505 505
0.13%
OK
900
3
3
3
OK
2.35
2.18
0.17
-7.8%
OK
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.5
OK
Isobutylene EA0009962
997
988 987 987
-1.05%
OK
898
3
3
3
OK
2.04
2.11
-0.07
3.32%
OK
6
Quarterly Validation
page 117 of 120
Quarterly Validation of LDAR Devices
Date: 02-Jul-2019
Quarter:
Equipment No Equip.Ser. No Equipment Type
3
Analyzer
Span Gas
Span gas
Cylinder No
Sampling Flow
Rate
Check
Sampling
Span Gas
Flow
Concentration
Result
Rate
Accuracy Check
Response Time
Comparison between two Devices
Check Gas
90%
Check Gas
Response Response Response
Second
of
Check gas
1-st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Time 1 Time 2 Time 3 Result
Result
Device
Result
Span
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
ppm
sec
sec
sec
ppm
l/min
1
0715622657
TVA1000B
FID
Methane
ET0022842
995
0.98
OK
Methane
FF524456
504
496 498 498
-1.32%
OK 895.5
4
4
4
OK
2.51
2.53
-0.02
0.79%
OK
2
0115248185
TVA1000B
FID
Methane
ET0022842
995
1.12
OK
Methane
FF524456
504
501 500 500
-0.73%
OK 895.5
4
4
4
OK
1.72
1.69
0.03
-1.78%
OK
3
0115248937
TVA1000B
FID
Methane
ET0022842
995
1.09
OK
Methane
FF524456
504
502 502 502
-0.4%
OK 895.5
4
4
4
OK
1.44
1.5
-0.06
4%
OK
5
202016061436
TVA2020
FID
Methane
ET0022842
995
1.05
OK
Methane
FF524456
504
504 504 504
0%
OK 895.5
4
4
4
OK
2.1
2.08
0.02
-0.96%
OK
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.51
OK
Isobutylene
EA0009962
997
995 995 995
-0.28%
OK
4
4
4
OK
3
3
0
0%
OK
6
Quarterly Validation
898
page 118 of 120
Quarterly Validation of LDAR Devices
Date: 01-Oct-2019
Quarter:
Equipment No Equip.Ser. No Equipment Type
4
Analyzer
Span Gas
Span gas
Cylinder No
Sampling Flow
Rate
Check
Sampling
Span Gas
Flow
Concentration
Result
Rate
Accuracy Check
Response Time
Comparison between two Devices
Check Gas
90%
Check Gas
Response Response Response
Second
of
Check gas
1-st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Time 1 Time 2 Time 3 Result
Result
Device
Result
Span
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
ppm
sec
sec
sec
ppm
l/min
1
0715622657
TVA1000B
FID
Methane
ET0022842
995
0.98
OK
Methane
FF524456
504
507 506 507
0.53%
OK 895.5
3
4
3
OK
2.17
2.22
-0.05
2.25%
OK
2
0115248185
TVA1000B
FID
Methane
ET0022842
995
1.12
OK
Methane
FF524456
504
500 500 501
-0.73%
OK 895.5
4
4
3
OK
1.47
1.8
-0.33
18.33%
OK
3
0115248937
TVA1000B
FID
Methane
ET0022842
995
1.09
OK
Methane
FF524456
504
503 506 505
0.13%
OK 895.5
3
4
4
OK
2.85
2.71
0.14
-5.17%
OK
5
202016061436
TVA2020
FID
Methane
ET0022842
995
1.05
OK
Methane
FF524456
504
500 502 499
-0.73%
OK 895.5
3
3
4
OK
2.03
1.88
0.15
-7.98%
OK
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.51
OK
Isobutylene
EA0009962
997
995 995 995
-0.28%
OK
4
4
4
OK
3
3
0
0%
OK
6
Quarterly Validation
898
page 119 of 120
CUMULATIVE PRODUCTION HOURS TEMPLATE 2019
Plant
TASHAN
Unit
Drawing
Stream Name
Remark
Annual Production
Hours
Alroy
6006-100-006
Gasoline
8,760
Alroy
6006-100-007
Gasoline
8,760
Production Hours
Q1
01/01-31/03
Quarter =
Quarterly Production
hours
2,160
2,160
Q2
01/04-30/06
Quarter =
Quarterly Production
hours
2,184
2,184
Q3
01/07-30/09
Quarter =
Quarterly Production
hours
2,208
2,208
Q4
01/10-31/12
Quarter =
Quarterly Production
hours
2,208
2,208
page 120 of 120
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין
3013.16-034-T2
3013.16-025
17/02/2020
18/30
3013.16-036
T2 - kerosene
External Floating roof
1. Tank data
Diameter of the tank
D
Effective height of the stock liquid (while
roof landing episode)
hle
Shell Color and condition
α
Roof color and condition
α
Tank paint solar absorptance
α
Vapor space outage (while roof landing
episode)
HVO
m
feet
m
feet
color
condition
color
condition
dimensionless
m
Tank data
--Tank data
--חום
טובה
לבן
טוב
48.77
160.01
11.00
0.58
Table 7.1-6
Brown
0.17
Table 7.1-6
0.38
Table 7.1-6
Possible to use also equation
1-15
assumption - equal to legs height
feet
11.00
Volume of the vapor space (while roof
landing episode)
Breather vent pressure setting
VV
ft
3
VV=PI()*D /4*Hvo
221,185
Equation 1-3
ΔPBP
psi
Typical value
0.50
Equation 1-11
Breather vent vacuum setting
ΔPBV
psi
Typical value
0.00
Equation 1-11
Breather vent pressure setting range
ΔPB
psi
PB PBP PBV
0.50
Equation 1-11
2
2. Material data - קרוסין
Stock vapor molecular weight
MV
Density of the liquid inside the tank
Wl
Vapor density
WV
True vapor pressure of the stock liquid
P
Vapor pressure at daily average liquid
surface temperature
Vapor pressure at the daily maximum
liquid surface temperature, psia
Vapor pressure at the daily minimum
liquid surface temperature
Daily vapor pressure range
3013.16-034 - 2
gr/gr-mole
lb/lb-mole
g/ml
lb/gal
kg/m^3
lb/ft3
msds data
130
msds data
--msds data
---
0.80
6.68
4.5
0.28
mm Hg
PEI data
0.833
psia
--הנחה:
Pv=nRT -->
P2=P1*(T2/T1)
0.02
0.02
0.02
0.00
PVA
psia
PVX
psia
PVN
psia
T1(k)=20C+273
T2(k)=37.5C+273
ΔPV
psia
PV PVX PVN
1/3
0
at 20°C
0.02
Equation 1-9
13/02/2020
3. Operation data
Number of days that the tank stands idle
(on roof landing episode)
Number of degassing and cleaning
episode
Number of roof landing episode
nd
days/landing episode
site data
4
landing episode/year
site data
0.07
landing episode/year
site data
0.07
Tanks Program
--Tanks Program
---
44
20
79
36
16
Tanks Program
---
59.04
27
lb per emptying
Tanks Program
61
Kg per emptying
---
28
4. Normal operation (Tanks program)
lb per year
Kg per year
lb per year
Kg per year
Kg per year
Working (withdrawal) losses
Total emissions (Breathing & Working)
Breathing (standing) losses
5. Degassing and Cleaning (Tanks program)
Degassing: emission from one turnover
Edegass-floating lb per emptying
of floating roof
Kg per emptying
Degassing: fixed roof with a height of
roof legs
Edegass-legs
Liquid fraction in sludge
Fliquid
Sludge volume
Sludge weight
Vs
Ws
Cleaning emissions
Ecleaning
Total Degassing and Cleaning emissions
Edegass-total
3013.16-034 - 2
0.8
m3 per emptying
Kg per emptying
lb per emptying
Kg per emptying
lb per emptying
Kg per emptying
Ecleaning = Ws * (1-Fliquid)
Edegass-total =
Edegass-floating + Edegass-legs + Ecleaning
2/3
T2 - B&W 2019
T2 - B&W 2019
T2 - DFloating 2019
T2- DFixed 2019
(Only working losses)
Tanks FAQ - degassing and
cleaning
70
56,000
24,692
11,200
24,811
11,254
13/02/2020
6. Roof landing
Daily average liquid surface temperature
TLA
°R
Daily vapor temperature range
Daily maximum liquid surface
temperature
ΔTV
°R
TLX
Daily minimum liquid surface temperature
Liquid bulk temperature
Max standing idle losses during roof
landing
T LA 0 .44 T AA 0 .56 T B 0 .0079 * * I
532.17
Equation 1-26
TV 0.72 T A 0.028 * * I
32.95
Equation 1-8
°R
TLX = TLA + 0.25*ΔTV
540.41
Figure 7.1-17
TLN
°R
TLN = TLA - 0.25*ΔTV
523.93
Figure 7.1-17
TB
°R
527.22
Equation 1-28
LSL-max
lb per landing episode
Kg per landing episode
TB = TAA + 6α - 1
LSL-max = 5.9*D2*hle*W l
--0.60 for a full liquid heel
0.50 for a partial
0.15 for drain-dry
11,093,038 Equation 2-13
5,031,769
0.50
Equation 2-26
(pages No 33,35)
1
KS
1 0.053 * PVA * H VO
0.5
Equation 1-20
KS is assumed to be less than
or equal to the saturation
factor during filling (S) .
TV PV PB
T LA
PA PVA
0.028
Liquid stock has a true vapor
pressure greater than 0.1psia Equation 1-7.
Filling saturation factor
S
dimensionless
saturation factor
KS
dimensionless
Vapor space expansion factor
KE
dimensionless
Standing idle losses during roof landing
LSL
lb per landing episode
PV
L SL n d K E V M V K S
RT AA
5
Equation 2-16
Filling losses during roof landing
LFL
lb per landing episode
P * VV
M V * S
L FL
R * T AA
41
Equation 2-26
Total losses during roof landing
LTL
lb per landing episode
Kg per landing episode
46
21
Equation 2-10
KE
LTL=LSL+LFL
7. Summary
Working (withdrawal) losses
Breathing (standing) losses
Kg per year
Kg per year
20
16
Total Degassing and Cleaning emissions
Kg per year
750
Total losses during roof landing
Kg per year
1
788
3013.16-034 - 2
3/3
Kg per year
13/02/2020
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - B&W 2019
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
0.78
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Aluminum/Diffuse
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - B&W 2019 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
All
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
76.52
65.35
87.69
Liquid
Bulk
Temp
(deg F)
68.86
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0136
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
02/02/2020
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - B&W 2019 - External Floating Roof Tank
Haifa, Israel
Annual Emission Calcaulations
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
0.0136
160.0100
130.0000
1.0000
Withdrawal Losses (lb):
Annual Net Throughput (gal/yr.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
43.8093
5,946,910.0000
0.0075
7.0000
160.0100
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
0.8398
0.0002
130.0000
1.0000
27.8819
6.2000
Total Losses (lb):
79.1496
34.5005
1.6000
0.3000
6.2000
1.6000
0.0002
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
KFa(lb-mole/yr)
1.60
6.20
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
1.20
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.94
1.00
Losses(lb)
0.1446
0.6608
0.0345
02/02/2020
TANKS 4.0 Report
Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - B&W 2019 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
34.50
43.81
0.84
0.00
79.15
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFixed 2019
Haifa
Israel
PEI
Vertical Fixed Roof Tank
kerosene
Tank Dimensions
Shell Height (ft):
Diameter (ft):
Liquid Height (ft) :
Avg. Liquid Height (ft):
Volume (gallons):
Turnovers:
Net Throughput(gal/yr):
Is Tank Heated (y/n):
N
Paint Characteristics
Shell Color/Shade:
Shell Condition
Roof Color/Shade:
Roof Condition:
Aluminum/Diffuse
Good
White/White
Good
Roof Characteristics
Type:
Height (ft)
Slope (ft/ft) (Cone Roof)
Breather Vent Settings
Vacuum Settings (psig):
Pressure Settings (psig)
11.00
160.01
11.00
5.50
1,654,664.74
1.00
1,654,664.74
Cone
0.00
0.00
0.00
0.50
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
Apr
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
72.10
62.74
81.45
Liquid
Bulk
Temp
(deg F)
67.57
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0118
0.0092
0.0159
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
02/02/2020
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Month:
Standing Losses (lb):
Vapor Space Volume (cu ft):
Vapor Density (lb/cu ft):
Vapor Space Expansion Factor:
Vented Vapor Saturation Factor:
January
February
March
April
May
June
July
August
September
October
November
December
Tank Vapor Space Volume:
Vapor Space Volume (cu ft):
Tank Diameter (ft):
Vapor Space Outage (ft):
Tank Shell Height (ft):
Average Liquid Height (ft):
Roof Outage (ft):
Roof Outage (Cone Roof)
Roof Outage (ft):
Roof Height (ft):
Roof Slope (ft/ft):
Shell Radius (ft):
Vapor Density
Vapor Density (lb/cu ft):
Vapor Molecular Weight (lb/lb-mole):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Daily Avg. Liquid Surface Temp. (deg. R):
Daily Average Ambient Temp. (deg. F):
Ideal Gas Constant R
(psia cuft / (lb-mol-deg R)):
Liquid Bulk Temperature (deg. R):
Tank Paint Solar Absorptance (Shell):
Tank Paint Solar Absorptance (Roof):
Daily Total Solar Insulation
Factor (Btu/sqft day):
Vapor Space Expansion Factor
Vapor Space Expansion Factor:
Daily Vapor Temperature Range (deg. R):
Daily Vapor Pressure Range (psia):
Breather Vent Press. Setting Range(psia):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Vapor Pressure at Daily Minimum Liquid
Surface Temperature (psia):
Vapor Pressure at Daily Maximum Liquid
Surface Temperature (psia):
Daily Avg. Liquid Surface Temp. (deg R):
Daily Min. Liquid Surface Temp. (deg R):
Daily Max. Liquid Surface Temp. (deg R):
Daily Ambient Temp. Range (deg. R):
Vented Vapor Saturation Factor
Vented Vapor Saturation Factor:
Vapor Pressure at Daily Average Liquid:
Surface Temperature (psia):
Vapor Space Outage (ft):
Working Losses (lb):
Vapor Molecular Weight (lb/lb-mole):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Net Throughput (gal/mo.):
Annual Turnovers:
Turnover Factor:
Maximum Liquid Volume (gal):
Maximum Liquid Height (ft):
Tank Diameter (ft):
Working Loss Product Factor:
Total Losses (lb):
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Losses(lbs)
Components
Working Loss
Breathing Loss
Total Emissions
Jet kerosene
60.63
32.78
93.41
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFloating 2019
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.00
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Aluminum/Diffuse
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
Apr
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
76.46
63.88
89.04
Liquid
Bulk
Temp
(deg F)
68.86
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0136
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
02/02/2020
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Month:
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
January
February
March
April
May
June
July
August
September
October
November
December
Withdrawal Losses (lb):
Net Throughput (gal/mo.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
Total Losses (lb):
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
KFa(lb-mole/yr)
1.60
6.20
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
1.20
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.94
1.00
Losses(lb)
0.0000
0.0000
0.0000
02/02/2020
TANKS 4.0 Report
Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
2.99
55.99
0.07
0.00
59.04
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
נספח ד'
חישוב פליטות ממיכל לאיסוף תשטיפים
17/02/2020
19/30
3013.16-036
תוכנת :Tanksחישוב פליטה כתוצאה מאחסון ושינוי מפלס
17/02/2020
20/30
3013.16-036
3013.16-036
21/30
17/02/2020
3013.16-036
22/30
17/02/2020
3013.16-036
23/30
17/02/2020
תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב א')
17/02/2020
24/30
3013.16-036
3013.16-036
25/30
17/02/2020
3013.16-036
26/30
17/02/2020
תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב ב')
17/02/2020
27/30
3013.16-036
3013.16-036
28/30
17/02/2020
3013.16-036
29/30
17/02/2020
חישובי פליטה ממיכל תשטיפים
גיליון חישוב זה הוכן על ידי "פז" הנדסה וניהול ( )1980בע"מ.
אין להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ( )1980בע"מ.
17/02/2020
30/30
3013.16-036
מסמך 9 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 3655 KB)
תשתיות נפט ואנרגיה בע"מ
מסוף אלרואי
סיכום פליטות לאוויר
שנת 2020
פרויקט3013.17 :
סימוכין3013.17-036 :
פברואר 2021
תוכן עניינים
.1מבוא 4 ...............................................................................................................
.2נתוני מסוף 5 ........................................................................................................
.2.1נתוני מיכלים 5.........................................................................................................
.2.2נתונים עבור מסוף מילוי מיכליות כביש 9.....................................................................
.3חישוב פליטות 10 .................................................................................................
.3.1כללי 10 ............................................................................................................
.3.2סוגי פליטות מחושבות 10 .......................................................................................
.3.3בחירת חומרים בתוכנת 11 ......................................................................... TANKS
.3.4נתונים מטאורולוגיים 11 ........................................................................................
.4סיכום פליטות לשנת 12 .................................................................................. 2020
.4.1מיכלים 12 ..........................................................................................................
.4.2מסוף מילוי מיכליות כביש 12 ..................................................................................
.4.3מיכל איסוף תשטיפים 13 .......................................................................................
.4.4סיכום ממצאי ניטור 13 ............................................................................... LDAR
.4.5פליטה שנתית מכלל המתקן 13 ................................................................................
.5פליטות לא שגרתיות במהלך שנת 13 .................................................................. 2020
.6מקורות 14 ..........................................................................................................
28/02/2021
2/30
3013.17-036.doc
טבלאות
טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 5........................................... 2020
טבלה :2נתוני מעטפת וגגות – שנת 6.................................................................................. 2020
טבלה :3נתוני אביזרים – שנת 7......................................................................................... 2020
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת 8................................................... TANKS
טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 9...................................................... 2020
טבלה :6חומרים מייצגים בתוכנת 11 ............................................................................ TANKS
טבלה :7סיכום פליטות מכלים -שנת 12 ............................................................................ 2020
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שנת 12 ..................................................2020
נספחים
נספח א'
טבלה )AP-42( 1-5.2
נספח ב'
נתוני ניטור LDARעבור מסוף אלרואי – סיכום שנת 2020
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין
נספח ד'
חישוב פליטות ממיכל לאיסוף תשטיפים
אביטל בלניק
שם עורך
28/02/2021
יואב פיסטינר
שם מאשר
להערות
תיאור
28.02.2021
תאריך
3/30
0
גרסה
3013.17-036.doc
.1מבוא
חברת תשתיות נפט ואנרגיה בע"מ (להלן תש"ן) מפעילה את מסוף אלרואי לאחסון ושינוע
דלקים .
המסוף כולל:
•
מבני משרדים
•
חוות מכלים לאחסון דלקים מסוגים שונים
•
רציפי מילוי מכליות כביש (לשימוש בעת חירום בלבד)
המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכונת
אלרואי ומדרום לו שכונת קרית חרושת.
באתר 9מיכלים ,מתוכם 7מכלים תפעוליים ו 2-מכלים המשמשים כמכלים אסטרטגיים
(מכלים מס' 1ו.)9-
מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוסף קיימות מערכות תומכות כגון
מערכות כיבוי אש ומערכות פיקוד ובקרה.
כחלק מהתנאים ברישיון עסק מדצמבר ,2010בסוף כל שנה קלנדרית על תש"ן להגיש דו"ח
סיכום פליטות שנתי לגבי השנה שחלפה.
חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקנים
הקיימים במסוף.
סיכום הפליטות הוכן על ידי חברת "פז" הנדסה וניהול ( )1980בע"מ (להלן פז הנדסה) ,והוא
מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.
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.2נתוני מסוף
.2.1נתוני מיכלים
בטבלאות הבאות מפורט מידע טכני של המיכלים בחוות המיכלים אלרואי.
טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 2020
לחץ אדים
בטמפ' הנוזל
הממוצעת
)(mmHg
405 @ 28°C
כמות
צריכה
שנתית
(מ"ק)
0
גבעה חלקית
38,648
גבעה חלקית
48.77
גבעה חלקית
48.77
32,056
48.77
32,056
28,768
56,959
51,614
15.56
51,614
15.56
14.1
15.56
14.1
11.4
18.3
18.3
15.4
9.7
סוג ניקוז
בתחתית
מיכל
קוטר
מיכל
(מטר)
נפח מיכל
(מ"ק)
נפח מיכל
פעיל
(מ"ק)
48.77
32,056
28,768
גובה /אורך
מעטפת
מיכל
(מטר)
17.16
15.4
32,056
28,768
17.16
15.4
10
28,768
17.16
15.4
9.5
17.16
15.4
10.3
14.1
14.1
14.1
מספר
מיכל
סוג הדלק
המאוחסן
)1( 1
בנזין
2
קרוסין
0.833 @ 28°C
3
סולר
0.507 @ 28°C
15,794
4
סולר
0.507 @ 28°C
38,116
גבעה חלקית
5
סולר
0.507 @ 28°C
6,852
גבעה מלאה
68.27
6
סולר
0.507 @ 28°C
20,092
גבעה מלאה
68.27
56,959
7
סולר
0.507 @ 28°C
3,078
גבעה מלאה
68.27
56,959
51,614
8
קרוסין
0.833 @ 28°C
118
גבעה חלקית
48.8
36,547
34,228
19.54
)1( 9
קרוסין
0.833 @ 28°C
0
גבעה חלקית
48.77
32,056
28,768
17.16
367,704
332,913
122,698
סה"כ
( )1מכלים מס' 1ו 9-משמשים כמכלי מלאי ,לא היו תנועות במכלים בשנת .2020
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גובה נוזל
מירבי
(מטר)
גובה נוזל
ממוצע
(מטר)
10.5
טבלה :2נתוני מעטפת וגגות – שנת 2020
מספר
מיכל
סוג גג
אטם ראשי
אטם משני
1
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Liquid
mounted
Mechanical
Shoe
Rim
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Rim
mounted
Rim
mounted
2
3
4
5
6
7
8
9
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צורת גג
סוג
חיבורי
גג
צבע
גג
מצב
צבע
גג
צבע
מעטפת
חיצונית
מצב צבע
מעטפת
חיצונית
סוג חיבורי
מעטפת
מצב
מעטפת
פנימית
מיכל
מחומם
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חום
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חום
ישן
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
כחול בהיר
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
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טבלה :3נתוני אביזרים – שנת 2020
מספר
מיכל
1
2
3
4
5
6
7
8
9
סה"כ
שובר ואקום
כמות
2
2
2
2
2
2
2
6
2
Vacuum
]set. [psi
0
0
0
0
0
0
0
0
0
Pressure
]set. [psi
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
רגליים מתכווננות התומכות
בגג צף()1
גובה כמות באזור
כמות
במרכז
()ft
pontoon
29
43
11
29
43
11
29
43
11
29
43
11
72
107
11
72
107
11
72
107
11
36
54
9
29
43
11
כמות
מדי
מפלס
Rim
Vent
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
כמות בוצה
בנקיון
(מ"ק)
"גרביים" לבאר
הדיגום המחורצת
ולרגלי הגג הצף()1
70
70
70
70
150
150
150
70
70
870
יש
יש
יש
יש
יש
יש
יש
יש
יש
( )1הנ"ל לא נלקחו בחשבון בחישוב הפליטות מתוכנת ה TANKS-מפני שנדגמו במסגרת ניטורי ה.LDAR-
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הנחות שנלקחו לצורך החישובים
.1עבור חישוב Degassingבמיכל עם גג צף – הונח:
•
גג צף נח על רגליים בגובה ( 9-11 ftבהתאם לטבלה לעיל) וזהו גם הגובה המרבי של הנוזל
במיכל.
•
גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.
.2הונח כי ניקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שנים .הניקיון יארך יום אחד.
.3הונח כי אירוע של נחיתת גגות צפים מתבצע אחת ל 15-שנים .זמן נחיתת הגג במקרה זה לא
יעלה על 4ימים.
.4יחס הנוזל בבוצה הונח כ]2[ 0.8 -
.5בהתאם לטבלה 7.1-6על פי [ ,]1נבחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,
לצורך חישובי פליטות לאוויר:
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת Tanks
צבע מעטפת
מיכל
צבע לצורך חישובי אקסל
צבע לצורך חישובים בתוכנת
בהתאם למסמך EPA AP-42
)*( Tanks
כחול בהיר
Gray Medium
Gray Medium
Brown
Aluminium/Diffuse
Beige/Cream
Aluminium/Specular
White
White
חום
צהוב קרם
לבן
(*) בתוכנת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך
.]1[ EPA AP-42
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.2.2נתונים עבור מסוף מילוי מיכליות כביש
טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 2020
מס'
זרוע
1
2
3
4
5
6
7
8
מוצר
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
סה"כ
מילוי
עילי /תחתי
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
נפח מילוי שנתי
(מ"ק)
12
0
0
0
0
0
0
0
12
נפח ממוצע של
מיכלית (מ"ק)
30
30
30
30
30
30
30
30
הנחות שנלקחו צורך החישובים
.1
מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:
א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:
דוגמת חישוב עבור מיכל מס' :2
ב .בשלב השני חושב מקדם αממוצע עבור הקרוסין:
.2
זמן מילוי מיכלית חושב על פי נפח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000
ליטר/דקה.
.3
Vapor collection efficiency - 70%
.4
Vapor recovery efficiency - 0%
.5
Saturation factorהונח כ (Submerged loading, dedicated normal service) 0.6-על פי
[ .]1טבלה רלוונטית מצורפת בנספח א'.
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.3חישוב פליטות
.3.1כללי
חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכנת Tanksובעזרת .]1[ EPA-AP 42
הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ( )LDARמצורפת בנספח ב'.
דוגמת חישוב עבור מיכל גג חיצוני צף (מיכל מס' )2המאחסן קרוסין ,מצורפת כנספח ג' למסמך
זה.
בדוגמאות אלה ניתן לראות את נתוני הקלט (כולל הנחות) עליהם התבססו החישובים.
.3.2סוגי פליטות מחושבות
הערכת הפליטות ממיכלי אחסון כוללת [:]3
• פליטות בזמן אחסון )(Breathing Losses
• פליטות משינויי מפלס )(Working Losses
• פליטות כתוצאה מניקוי וריקון מיכלים )(Degassing Losses
• פליטות כתוצאה מנחיתת גגות צפים )(Roof Landing Losses
• פליטות כתוצאה מהפרשי לחץ )(Flash Losses
• פליטות בזמן מילוי מיכלים ומיכליות
בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ
).(Flash Losses
פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלחץ הנוזל ,נתון הגורם להפרת שיווי המשקל
הקיים במיכל (בין גז לנוזל) וכתוצאה מכך נוצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הנוזל
עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר נוזל המאוחסן בלחץ נשלח
לאחסון במיכל בעל לחץ נמוך יותר [.]3
פליטות אלו הוזנחו כיוון שכל החומרים מוחזקים בתנאים אטמוספריים בכל אחד מהשלבים
הנוגעים להובלתם ואחסונם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.
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.3.3בחירת חומרים בתוכנת Tanks
על פי נתוני MSDSשל הדלקים במסוף ,נבחרו החומרים הבאים הקיימים בתוכנת Tanks
כמייצגים של חומרים אלו:
טבלה :6חומרים מייצגים בתוכנת Tanks
דלק קיים במסוף
חומר מייצג בתוכנת Tanks
סולר (תחבורה והסקה)
Distillate fuel oil no 2
נפט (קרוסין)
Jet kerosene
בנזין
Gasoline RVP 10
.3.4נתונים מטאורולוגיים
לצורך חישוב הנתונים בתוכנת Tanksהוגדרו נתונים מטאורולוגים המתאימים למפרץ חיפה על פי
מקורות [.]4
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.4סיכום פליטות לשנת 2020
.4.1מיכלים
סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:
טבלה :7סיכום פליטות מכלים -שנת 2020
מיכל
חומר
פליטות לאוויר
(ק"ג/שנה)
1
בנזין
3,603
2
קרוסין
802
3
סולר
25
4
סולר
831
5
סולר
1,697
6
סולר
1,706
7
סולר
1,695
8
קרוסין
756
9
קרוסין
758
11,873
סה"כ
.4.2מסוף מילוי מיכליות כביש
להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שנת 2020
מס' זרוע
מוצר
מילוי עילי /תחתי
1
2
3
4
5
6
7
8
סה"כ
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
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פליטה שנתית
(ק"ג/שנה)
0.04
0
0
0
0
0
0
0
0.04
3013.17-036.doc
.4.3מיכל איסוף תשטיפים
סך הפליטה ממיכל לאיסוף תשטיפים הינה כ 1 -ק"ג/שנה.
חישוב מצורף בנספח ד'.
יצוין כי החישוב מתבסס על הנחה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל
בעיקר ניקוז מים מהמכלים.
.4.4סיכום ממצאי ניטור LDAR
טבלה :9סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 2020
סה"כ פליטות (ק"ג/שנה)
סיכום פליטות LDAR
פליטה שנתית (ק"ג/שנה)
סה"כ
6.26
.4.5פליטה שנתית מכלל המתקן
טבלה :10סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 2020
סה"כ פליטות (ק"ג/שנה)
חוות מיכלים
מסוף מילוי
מיכליות כביש
מיכל לאיסוף
תשטיפים
11,873
0.04
1
סיכום פליטות
רכיבים
סה"כ
()LDAR
6.26
11,880
.5פליטות לא שגרתיות במהלך שנת 2020
במהלך שנת 2020לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.
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.6מקורות
]1[ EPA-AP42
]2[ USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version
4.0 - APPENDIX D
[ ]3הנחיות הממונה לטיפול בבקשה להיתר פליטה לפי סעיף (9א) לתקנות אוויר נקי (היתרי פליטה),
התש"ע – ,2010מהדורה ,4ספטמבר 2014
[ ]4האטלס האקלימי לתכנון פיסי וסביבתי בישראל ,מהדורה שנייה1994 ,
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נספח א'
טבלה 5.2-1
AP-42
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28/02/2021
נספח ב'
נתוני ניטור LDARעבור אלרואי – סיכום שנת 2020
(מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך )25.02.2021
3013.17-008A
28/02/2021
17/30
3013.17-036.doc
LDAR
Fugitive Emission Monitoring
Report No.
RL-TS-R-A-20
Plant:TASHAN
City:Haifa
District:Haifa
Production Unit:Alroy
Group:Group 1-2-3
Reporting period:Annual Summary
Report printing date:25-Feb-2021
Technicians names:Mancarj
Polik
Portselan
Report editor:
Michael Ourievsky
Approved by:
Alexey Ratner, CEO
1
Table of Content
1. Project introduction
1.1 Scope of work
1.2 Project phases
2. Methodology
2.1 Definitions
2.2 Methodology
3. Summary of Monitoring Period
3.1 Cumulative Data of Monitoring Period
3.2 Summary of Monitoring Period
3.3 Form 07: component classification and emission estimations for production facilities
3.4 Chemical Summary
3.5 LDAR report for production facilities
4. First Measurement and Measurement After Repair Round 1
4.1 Form-07 by Round
4.2 Chemical Summary First Measurement
4.3 Chemical Summary After Repair
4.4 LDAR report for production facilities
5. First Measurement and Measurement After Repair Round 2
5.1 Form-07 by Round
5.2 Chemical Summary First Measurement
5.3 Chemical Summary After Repair
5.4 LDAR report for production facilities
6. First Measurement and Measurement After Repair Round 3
6.1 Form-07 by Round
6.2 Chemical Summary First Measurement
6.3 Chemical Summary After Repair
6.4 LDAR report for production facilities
7. First Measurement and Measurement After Repair Round 4
7.1 Form-07 by Round
7.2 Chemical Summary First Measurement
7.3 Chemical Summary After Repair
7.4 LDAR report for production facilities
8. First Measurement and Measurement After Repair Round 5
8.1 Form-07 by Round
8.2 Chemical Summary First Measurement
8.3 Chemical Summary After Repair
8.4 LDAR report for production facilities
9. First Measurement and Measurement After Repair Round 6
9.1 Form-07 by Round
9.2 Chemical Summary First Measurement
9.3 Chemical Summary After Repair
9.4 LDAR report for production facilities
Table Of Content
5
5
6
6
9
10
17
18
20
22
23
24
25
27
28
29
30
32
33
35
37
39
40
41
42
44
45
47
49
51
52
53
54
page 2 of 121
10. Graphs First Measurement Round 1
10.1 Overview by Reading Range
10.2 Comparison between count of sources & kg/year, by sources
10.3 Total overview by chemicals
11. Graphs Measurement After Repair Round 1
11.1 Overview by Reading Range
11.2 Comparison between count of sources & kg/year, by sources
11.3 Total overview by chemicals
12. Graphs First Measurement Round 2
12.1 Overview by Reading Range
12.2 Comparison between count of sources & kg/year, by sources
12.3 Total overview by chemicals
13. Graphs Measurement After Repair Round 2
13.1 Overview by Reading Range
13.2 Comparison between count of sources & kg/year, by sources
13.3 Total overview by chemicals
14. Graphs First Measurement Round 3
14.1 Overview by Reading Range
14.2 Comparison between count of sources & kg/year, by sources
14.3 Total overview by chemicals
15. Graphs Measurement After Repair Round 3
15.1 Overview by Reading Range
15.2 Comparison between count of sources & kg/year, by sources
15.3 Total overview by chemicals
16. Graphs First Measurement Round 4
16.1 Overview by Reading Range
16.2 Comparison between count of sources & kg/year, by sources
16.3 Total overview by chemicals
17. Graphs Measurement After Repair Round 4
17.1 Overview by Reading Range
17.2 Comparison between count of sources & kg/year, by sources
17.3 Total overview by chemicals
18. Graphs First Measurement Round 5
18.1 Overview by Reading Range
18.2 Comparison between count of sources & kg/year, by sources
18.3 Total overview by chemicals
19. Graphs Measurement After Repair Round 5
19.1 Overview by Reading Range
19.2 Comparison between count of sources & kg/year, by sources
19.3 Total overview by chemicals
20. Graphs First Measurement Round 6
20.1 Overview by Reading Range
20.2 Comparison between count of sources & kg/year, by sources
20.3 Total overview by chemicals
Table Of Content
56
58
57
60
62
61
64
66
65
68
70
69
72
74
73
76
78
77
80
82
81
84
86
85
88
90
89
92
94
93
96
98
97
page 3 of 121
21. Graphs Measurement After Repair Round 6
21.1 Overview by Reading Range
21.2 Comparison between count of sources & kg/year, by sources
21.3 Total overview by chemicals
22. Graphs Cumulative
22.1 Comparison between count of sources above leak definition, by quarter
22.2 Comparison between % of components above leak definition by quarter
22.3 Comparison between count of sources & kg/year, by sources Cumulative
22.4 Total overview by chemicals
23. Attachments
23.1 Calibration loglist
23.2 Calibration gas certificates
23.3 Composition list & Response Factors
23.4 Quarterly equipment check Q1
23.5 Quarterly equipment check Q2
23.6 Quarterly equipment check Q3
23.7 Quarterly equipment check Q4
23.8 Quarterly production hours
Table Of Content
100
102
101
104
105
106
107
109
110
116
117
118
119
120
121
page 4 of 121
1 Project introduction
1.1 Scope of work
6 rounds of measurements (from 01/01/2020 to 31/12/2020)
Measurements performed for following classes:
Group 1: PRD, Sampling Point
Group 2: Open End, Stem Valve
Group 3: Connection, Flange
1.2 Project phases
Monitoring: Group 1-2-3
Re-measurement after repair action
Revision of equipment and production processes
Inventorisation: adding or deleting components
Mapping of components on P&ID's
General
1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory
Accreditation Authority).
2. ISRAC is not responsible for the test results.
Project Introduction
page 5 of 121
2 Methodology
1.1 Definitions
Chemical State:
Gas/Vapor: stream which is in process conditions under gaseous or vapor form.
Light Liquid: a liquid having a VOC content greater than 10% (by volume) hat evaporates at 150°C
Heavy Liquid: a liquid having a VOC content of 10% or less (by volume) that evaporates at 150°C
Leak definition: 1,000 ppm (all sources)
Difficult to monitor components:
Any component situated at a level higher than five meters above ground level or any component situated at a distance further than
two meters from a platform and which cannot be accessed by employees in a safe way.
Any component which access requires the elevation of a person to a level higher than two meters above regular surfaces, and which
cannot be accessed in a safe.
Registered sources:
Sources with a leak value equal or greater than 9 ppm.
Default-zero:
This equation is valid for sources with a leak value of 0 ppm.A fixed EPA emission calculation rule is used for all these sources.
Total components:
All of the existing active components.
Total measured components:
All of the components, measured in specific monitoring round.
2.2 Methodology
Formulas:
Measured ppm values are converted to emission loss (kg/year) and these calculations are based on the E.P.A. “Correlation method
Refinery”
Modified Trapezoidal Emission Calculation Method:
The modified trapezoid method assumes that the mass leak rate changes linearly between any two monitoring points, except for
periods between leak detection and repair; the leak monitor reading is used from the time the leak is detected to the time it is repaired (i.e.,
re-screened).
Cumulative data:
In "Cumulative data" tables we provide the results of all of the measurements that performed from beginning of the year till the end of
current monitoring period (quarter). We also calculate the real sum of previous emissions based on the all rounds of the measurements
(before and after repairing attempts).(US EPA "Emission Estimation Protocol for Petroleum Refineries")
Methodology
page 6 of 121
Equation Set Details Report
Equation Set
Class
Chemical State
Default Zero
Pegged 100k
Multiplier
Exponent
Avg. Factor
Refinery
Connection
Light Liquid
7.5E-06
0.03
1.53E-06
0.735
0.00025
Refinery
Flange
Light Liquid
3.1E-07
0.084
4.61E-06
0.703
0.00025
Refinery
Open End
Light Liquid
2E-06
0.079
2.2E-06
0.704
0.0023
Refinery
PRD
Light Liquid
4E-06
0.11
1.36E-05
0.589
0.16
Refinery
Sampling Point
Light Liquid
4E-06
0.11
1.36E-05
0.589
0.015
Refinery
Stem Valve
Light Liquid
7.8E-06
0.14
2.29E-06
0.746
0.0109
Equations
page 7 of 121
Project summary
The situation of TASHAN indicates there are no leaks.
0 "difficult to monitor" sources.
223 default-zero sources (0-8ppm).
0 registered sources (9-999ppm).
0 components above leak definition (1,000ppm)
The total calculated emission rate:
6.257 kg
Overview by component class
Component Class
Total components
Components 9-999ppm
count
count
Components above
leak definition (1,000
ppm)
count
% of components
9-999ppm
% of components
above leak definition
Total emission
kg
%
%
PRD
Sampling Point
Stem Valve
Open End
Flange
Connection
4
4
20
102
55
38
0
0
0
0
0
0
0
0
0
0
0
0
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
01/01/2020-31/12/2020
0.141
0.301
1.37
1.792
0.15
2.503
Total:
223
0
0
0.00%
0.00%
6.257
Overview per Unit
Unit
Total components
Total emission
kg
01/01/2020-31/12/2020
count
Alroy
223
6.257
Total:
223
6.257
Summary of Period
page 8 of 121
Summary of Period: 01/01/2020-31/12/2020
The total emissions: 6.257kg
Overview by component class
Component
Class
Total Components
count
Total Components above leak definition
% of components above leak definition
Unrepaired Components
(1,000 ppm)
(1,000 ppm)
count
%
count
Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round
1
2
3
4
5
6
1
2
3
4
5
6
1
2
3
4
5
6
Total Emissions
kg
01/01/2020- 31/12/2020
PRD
Sampling Point
Total Group 1:
Stem Valve
Open End
Total Group 2:
Flange
Connection
Total Group 3:
4
4
8
20
102
122
55
38
93
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.141
0.301
0.442
1.37
1.792
3.162
0.15
2.503
2.653
Total:
223
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
6.257
Overview by reading range
Total Components
Round 1
Reading Range
#
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
Total:
Cumulative Data
Round 2
%
8
0
0
0
0
0
8
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 3
%
8
0
0
0
0
0
8
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 4
%
223
0
0
0
0
0
223
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 5
%
8
0
0
0
0
0
8
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
Round 6
%
130
0
0
0
0
0
130
#
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
%
7
1
0
0
0
0
8
87.5%
12.5%
0.0%
0.0%
0.0%
0.0%
100.0%
page 9 of 121
Summary of Monitoring Period Round 1
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
0
0
0.00%
0
0.14
8
0
0
0.00%
0
0.28
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
0.28 kg/year
0 kg/year
0.28 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Summary R1
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
page 10 of 121
Summary of Monitoring Period Round 2
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
0
0
0.00%
0
0.14
8
0
0
0.00%
0
0.28
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
0.28 kg/year
0 kg/year
0.28 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Summary R2
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.28
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.28
Comments
100%
page 11 of 121
Summary of Monitoring Period Round 3
First measurement:
0 "difficult to monitor" sources.
223 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
6.063 kg/year
0 kg/year
6.063 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Stem Valve
Open End
Flange
Connection
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
223
0
0
0
0
0
Total:
223
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
4
0
0
0.00%
0
0.14
20
0
0
0.00%
0
1.363
102
0
0
0.00%
0
1.782
55
0
0
0.00%
0
0.149
38
0
0
0.00%
0
2.49
223
0
0
0.00%
0
6.064
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
6.063
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
6.063
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
223 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
6.063 kg/year
0 kg/year
6.063 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Stem Valve
20
0
0
0.00%
0
1.363
Open End
102
0
0
0.00%
0
1.782
Flange
55
0
0
0.00%
0
0.149
Connection
38
0
0
0.00%
0
2.49
223
0
0
0.00%
0
6.064
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
223
0
0
0
0
0
Total:
223
Summary R3
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
6.063
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
6.063
Comments
100%
page 12 of 121
Summary of Monitoring Period Round 4
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
0.283 kg/year
0 kg/year
0.283 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
4
0
0
0.00%
0
0.141
8
0
0
0.00%
0
0.282
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.283
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.283
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
0.283 kg/year
0 kg/year
0.283 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
Sampling Point
4
0
0
0.00%
0
0.141
Total:
8
0
0
0.00%
0
0.282
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Summary R4
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.283
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.283
Comments
100%
page 13 of 121
Summary of Monitoring Period Round 5
First measurement:
0 "difficult to monitor" sources.
130 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
3.462 kg/year
0 kg/year
3.462 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Stem Valve
Open End
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
130
0
0
0
0
0
Total:
130
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
4
0
0
0.00%
0
0.141
20
0
0
0.00%
0
1.378
102
0
0
0.00%
0
1.802
130
0
0
0.00%
0
3.462
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
3.462
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
3.462
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
130 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
3.462 kg/year
0 kg/year
3.462 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
Sampling Point
4
0
0
0.00%
0
Stem Valve
20
0
0
0.00%
0
1.378
Open End
102
0
0
0.00%
0
1.802
Total:
130
0
0
0.00%
0
3.462
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
130
0
0
0
0
0
Total:
130
Summary R5
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
3.462
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
3.462
0.141
Comments
100%
page 14 of 121
Summary of Monitoring Period Round 6
First measurement:
0 "difficult to monitor" sources.
7 default-zero sources with a calculated emission rate:
1 registered sources with a calculated emission rate:
0.247 kg/year
2.141 kg/year
2.388 kg/year
The total calculated emission rate:
Component Class
Total components
count
PRD
Sampling Point
Total:
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
7
1
0
0
0
0
Total:
8
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
4
1
0
0.00%
0
2.247
8
1
0
0.00%
0
2.388
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
87.50%
0.247
10.34%
12.50%
2.141
89.66%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
2.388
Comments
100%
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
Component Class
Total components
count
PRD
0.283 kg/year
0 kg/year
0.283 kg/year
Overview by component class
Components 9-999ppm
Components above leak
% emission rate of
Emission rate of
Total annual emission rate
definition (1,000 ppm)
components above leak
components above leak
(all components)
definition
definition
count
count
%
kg/year
kg/year
4
0
0
0.00%
0
0.141
Sampling Point
4
0
0
0.00%
0
0.141
Total:
8
0
0
0.00%
0
0.282
Reading Range
Total components
count
0-8 ppm
9-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
Total:
8
Summary R6
Overview by reading range
Percentage of Total
Annual Emission Rate
Percentage of Total
Components
Annual Emission Rate
%
kg/year
%
100.00%
0.283
100.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
0.00%
0
0.00%
100%
0.283
Comments
100%
page 15 of 121
Cumulative data for period
01-01-2020-31-12-2020
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph Cumulative
page 16 of 121
Fugitive emission component classification and emission estimation for production facilities
01/01/2018-31/12/2018 Calculation period
Monitoring
Frequency
Components above 1,000 ppm
cycles/year
Cumulative Components above
Emission
100,000 ppm
%
R6
6
6 0.00%
6
6
6 0.00%
6
0.00%
2
2 0.00%
2
2
2 0.00%
2
0.00%
1
1 0.00%
1
1
1 0.00%
1
0.00%
0.00%
R5
R4
kg
R3
R2
Count
R1
Components in
Components in
Components in
reading range
reading range 9-999 reading range 0-8 ppm
1,000-100,000 ppm
ppm
Count
Count
Count
Unrepaired
Components
Count
TASHAN Company name
22-Jan-2019 Date
Alroy Production Unit
Report Number
Total Components Difficult
Major
Total
Chemical State Component Class Group
above 1,000 ppm
to
Components Components
Monitor
Count
R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1
0
0
Count
Count
0
Count
0.00% 0.00% 0.00% 0.00% 0.00%
0.141
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
4
4
4
4
4
4 0
0
0
0
0
0 0
0
0
0
1
0.00% 0.00% 0.00% 0.00% 0.00%
0.301
0 0
0
0
0
0 0
0
0
0
0
0 1
0
0
0
0
0
3
4
4
4
4
4 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0.00% 0.00% 0.00% 0.00% 0.00%
0.442
0 0
0
0
0
0 0
0
0
0
0
0 1
0
0
0
0
0
7
8
8
8
8
8 0
0
0
0
0
0 0
0
0
0
0
0
0
1
0.00% 0.00% 0.00% 0.00% 0.00%
1.37
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
20
0
20
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
16
0.00% 0.00% 0.00% 0.00% 0.00%
1.792
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0 102
0 102
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0.00% 0.00% 0.00% 0.00% 0.00%
3.162
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0 122
0 122
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
16
0.00% 0.00% 0.00% 0.00% 0.00%
0.15
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0
55
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0.00% 0.00% 0.00% 0.00% 0.00%
2.503
0 0
0
0
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0
38
0
0 0
0
0
0
0
0 0
0
0
0
0
0
0
0
0.00% 0.00% 0.00% 0.00% 0.00%
0.00% 0.00% 0.00% 0.00% 0.00%
2.653
6.257
0 0
0 0
0
0
0
0
0
0
0 0
0 0
0
0
0
0
0
0
0
0
0 0
0 1
0
0
0
0
0
0
0
0
0
0
0
0
7 130
0 93
8 223
0
8
0 0
8 0
0
0
0
0
0
0
0
0
0 0
0 0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
GV
PRD
LL
HL
GV
Sampling Point
4
LL
HL
8 Subtotal G1
GV
Stem Valve
20
LL
HL
GV
Open End
102
LL
HL
122 Subtotal G2
GV
Flange
55
LL
HL
GV
Connection
38
LL
HL
93 Subtotal G3
223 Total Components
G1
4
6.257 Total Cumulative Emission
G2
G3
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary Cumulative
Equation Set: Refinery
Units of Measurement: KG
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.007
0.0141
0.0562
0.0478
0.1406
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0301
0.003
0.015
0.0301
0.1203
0.1022
0.3007
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.137
0.0137
0.0685
0.137
0.5481
0.4659
1.3702
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1792
0.0179
0.0896
0.1792
0.7168
0.6093
1.792
Chemical CU
page 18 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary Cumulative
Equation Set: Refinery
Units of Measurement: KG
Report Date: 25.02.2021
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.015
0.0015
0.0075
0.015
0.0599
0.0509
0.1498
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.2503
0.025
0.1252
0.2503
1.0014
0.8512
2.5034
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.6257
0.0625
0.3128
0.6257
2.5027
2.1273
6.2567
Grand Total
Chemical CU
6.2567
page 19 of 121
LDAR report for production facilities
Unit
Drawing
LDAR 015
Component
Tag
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 1‐2‐3‐4‐5‐6
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 20 of 121
Round 1
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R1
page 21 of 121
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 1
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
TASHAN Company name
Round 1
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
Form-07 R1
page 22 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary First Measurement
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1118
0.095
0.2796
Grand Total
Chemical FM R1
0.2796
page 23 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary After Repair
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1118
0.095
0.2796
Grand Total
Chemical AR R1
0.2796
page 24 of 121
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R1
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 1
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 25 of 121
Round 2
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R2
page 26 of 121
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 2
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
TASHAN Company name
Round 2
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.28
0
0
0
8
0
0
1
8 Total Components
0.28 Total Annual Emission Rate
Form-07 R2
page 27 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary First Measurement
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1118
0.095
0.2796
Grand Total
Chemical FM R2
0.2796
page 28 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary After Repair
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.028
0.0028
0.014
0.028
0.1118
0.095
0.2796
Grand Total
Chemical AR R2
0.2796
page 29 of 121
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R2
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 2
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 30 of 121
Round 3
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R3
page 31 of 121
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 3
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.363
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
0.0%
1.782
0
0
0
102
0
0
0
102
LL
2
HL
0.0%
3.145
0
0
0
122
0
0
16
122
Subtotal G2
1
GV
Flange
G3
1
0.0%
0.149
0
0
0
55
0
0
0
55
LL
1
HL
1
GV
Connection
1
0.0%
2.49
0
0
0
38
0
0
0
38
LL
1
HL
0.0%
2.639
0
0
0
93
0
0
0
93
Subtotal G3
0.0%
6.064
0
0
0
223
0
0
17
223 Total Components
6.064 Total Annual Emission Rate
TASHAN Company name
Round 3
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.14
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.14
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.28
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.363
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
0.0%
1.782
0
0
0
102
0
0
0
102
LL
2
HL
0.0%
3.145
0
0
0
122
0
0
16
122
Subtotal G2
1
GV
Flange
G3
1
0.0%
0.149
0
0
0
55
0
0
0
55
LL
1
HL
1
GV
Connection
1
0.0%
2.49
0
0
0
38
0
0
0
38
LL
1
HL
0.0%
2.639
0
0
0
93
0
0
0
93
Subtotal G3
0.0%
6.064
0
0
0
223
0
0
17
223 Total Components
6.064 Total Annual Emission Rate
Form-07 R3
page 32 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary First Measurement
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1782
0.0178
0.0891
0.1782
0.7129
0.6059
1.7821
Chemical FM R3
page 33 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary First Measurement
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0149
0.0015
0.0074
0.0149
0.0596
0.0506
0.1489
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.249
0.0249
0.1245
0.249
0.9959
0.8465
2.4898
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.6064
0.0606
0.3031
0.6064
2.4253
2.0614
6.0632
Grand Total
Chemical FM R3
6.0632
page 34 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary After Repair
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.014
0.0014
0.007
0.014
0.0559
0.0475
0.1398
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1363
0.0136
0.0681
0.1363
0.5451
0.4634
1.3628
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1782
0.0178
0.0891
0.1782
0.7129
0.6059
1.7821
Chemical AR R3
page 35 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary After Repair
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
Flange
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0149
0.0015
0.0074
0.0149
0.0596
0.0506
0.1489
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.249
0.0249
0.1245
0.249
0.9959
0.8465
2.4898
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.6064
0.0606
0.3031
0.6064
2.4253
2.0614
6.0632
Grand Total
Chemical AR R3
6.0632
page 36 of 121
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R3
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 3
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 37 of 121
Round 4
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R4
page 38 of 121
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 4
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.141
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.141
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.282
0
0
0
8
0
0
1
8 Total Components
0.282 Total Annual Emission Rate
TASHAN Company name
Round 4
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.141
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.141
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.282
0
0
0
8
0
0
1
8 Total Components
0.282 Total Annual Emission Rate
Form-07 R4
page 39 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary First Measurement
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0282
0.0028
0.0142
0.0282
0.113
0.096
0.2824
Grand Total
Chemical FM R4
0.2824
page 40 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary After Repair
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0282
0.0028
0.0142
0.0282
0.113
0.096
0.2824
Grand Total
Chemical AR R4
0.2824
page 41 of 121
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R4
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 4
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 42 of 121
Round 5
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R5
page 43 of 121
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 5
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.141
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.141
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.378
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
0.0%
1.802
0
0
0
102
0
0
0
102
LL
2
HL
0.0%
3.18
0
0
0
122
0
0
16
122
Subtotal G2
0.0%
3.462
0
0
0
130
0
0
17
130 Total Components
3.462 Total Annual Emission Rate
TASHAN Company name
Round 5
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.141
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.141
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
2
GV
Stem Valve
G2
2
0.0%
1.378
0
0
0
20
0
0
16
20
LL
2
HL
2
GV
Open End
2
0.0%
1.802
0
0
0
102
0
0
0
102
LL
2
HL
0.0%
3.18
0
0
0
122
0
0
16
122
Subtotal G2
0.0%
3.462
0
0
0
130
0
0
17
130 Total Components
3.462 Total Annual Emission Rate
Form-07 R5
page 44 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary First Measurement
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1378
0.0138
0.0689
0.1378
0.5511
0.4684
1.3778
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1802
0.018
0.0901
0.1802
0.7207
0.6126
1.8018
Chemical FM R5
page 45 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary First Measurement
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
All
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.3462
0.0346
0.1732
0.3462
1.3848
1.177
3.462
Grand Total
Chemical FM R5
3.462
page 46 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary After Repair
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Stem Valve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1378
0.0138
0.0689
0.1378
0.5511
0.4684
1.3778
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.1802
0.018
0.0901
0.1802
0.7207
0.6126
1.8018
Chemical AR R5
page 47 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary After Repair
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
All
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.3462
0.0346
0.1732
0.3462
1.3848
1.177
3.462
Grand Total
Chemical AR R5
3.462
page 48 of 121
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R5
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 5
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 49 of 121
Round 6
First measurement.
Measurement after repair attempt.
Form 07: component classification and emission estimations
Correlation Equation Chemical Summary by Component Class
Form 15: LDAR report for production facilities
Paragraph By Round R6
page 50 of 121
Fugitive emission component classification and emission estimation for production facilities
TASHAN Company name
Round 6
Monitoring round
Alroy Production Unit
First measurement
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.141
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
2.247
0
0
1
3
0
0
0
4
LL
6
HL
0.0%
2.388
0
0
1
7
0
0
1
8
Subtotal G1
0.0%
2.388
0
0
1
7
0
0
1
8 Total Components
2.388 Total Annual Emission Rate
TASHAN Company name
Round 6
Monitoring round
Alroy Production Unit
Measurement after repair attempt
Monitoring Components Annual Components Components Components Components
Total
Difficult to
Major
Total
Chemical State Component Class Group
Frequency
above Leak Emission
above
in reading
in reading
in reading Components
Monitor
Components Components
Definition
Rate
100,000 ppm range 1,000- range 9-999
range 0-8
above Leak
100,000 ppm
ppm
ppm
Definition
cycles/year
%
kg/year
Count
Count
Count
Count
Count
Count
Count
Count
6
GV
PRD
G1
6
0.0%
0.141
0
0
0
4
0
0
1
4
LL
6
HL
6
GV
Sampling Point
6
0.0%
0.141
0
0
0
4
0
0
0
4
LL
6
HL
0.0%
0.282
0
0
0
8
0
0
1
8
Subtotal G1
0.0%
0.282
0
0
0
8
0
0
1
8 Total Components
0.282 Total Annual Emission Rate
Form-07 R6
page 51 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary First Measurement
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.2247
0.0225
0.1123
0.2247
0.8987
0.7639
2.2468
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.2388
0.0239
0.1194
0.2388
0.9552
0.8119
2.388
Grand Total
Chemical FM R6
2.388
page 52 of 121
Chemical Summary by Component Class
Calculation Period: 01/01/2020- 31/12/2020
Report Chemical Summary After Repair
Equation Set: SOCMI
Units of Measurement: KG/year
Report Date: 25.02.2021
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
CAS Number
106-98-9
71432
110827
1634044
111-65-9
108883
Emissions
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
Sampling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0141
0.0014
0.0071
0.0141
0.0565
0.048
0.1412
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octane
TOLUENE
106-98-9
71432
110827
1634044
111-65-9
108883
0.0282
0.0028
0.0142
0.0282
0.113
0.096
0.2824
Grand Total
Chemical AR R6
0.2824
page 53 of 121
LDAR report for production facilities
Unit
Drawing
Component
Tag
LDAR 015 R6
Plant
Unit
Monitoring Round
TASHAN
Alroy
Round 6
Component
Type
Component
Class
Location Description
ppm value, First
Measurement
Date of First
Measurement
Repair Due
Date of
repair
Repair type
Technicians
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
Date of
repair
Remarks
Repair type
date of
ppm value of
remeasurement
remeasurement
after repair attempt after repair attempt
page 54 of 121
Graphs
Round 1
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R1
page 55 of 121
Graph6.1.1 R1
page 56 of 121
Graph6.1.3 R1
page 57 of 121
Graph6.1.2 R1
page 58 of 121
Graphs
Round 1
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R1
page 59 of 121
Graph6.2.1 R1
page 60 of 121
Graph6.2.3 R1
page 61 of 121
Graph6.2.2 R1
page 62 of 121
Graphs
Round 2
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R2
page 63 of 121
Graph6.1.1 R2
page 64 of 121
Graph6.1.3 R2
page 65 of 121
Graph6.1.2 R2
page 66 of 121
Graphs
Round 2
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R2
page 67 of 121
Graph6.2.1 R2
page 68 of 121
Graph6.2.3 R2
page 69 of 121
Graph6.2.2 R2
page 70 of 121
Graphs
Round 3
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R3
page 71 of 121
Graph6.1.1 R3
page 72 of 121
Graph6.1.3 R3
page 73 of 121
Graph6.1.2 R3
page 74 of 121
Graphs
Round 3
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R3
page 75 of 121
Graph6.2.1 R3
page 76 of 121
Graph6.2.3 R3
page 77 of 121
Graph6.2.2 R3
page 78 of 121
Graphs
Round 4
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R4
page 79 of 121
Graph6.1.1 R4
page 80 of 121
Graph6.1.3 R4
page 81 of 121
Graph6.1.2 R4
page 82 of 121
Graphs
Round 4
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R4
page 83 of 121
Graph6.2.1 R4
page 84 of 121
Graph6.2.3 R4
page 85 of 121
Graph6.2.2 R4
page 86 of 121
Graphs
Round 5
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R5
page 87 of 121
Graph6.1.1 R5
page 88 of 121
Graph6.1.3 R5
page 89 of 121
Graph6.1.2 R5
page 90 of 121
Graphs
Round 5
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R5
page 91 of 121
Graph6.2.1 R5
page 92 of 121
Graph6.2.3 R5
page 93 of 121
Graph6.2.2 R5
page 94 of 121
Graphs
Round 6
First measurement.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph First R6
page 95 of 121
Graph6.1.1 R6
page 96 of 121
Graph6.1.3 R6
page 97 of 121
Graph6.1.2 R6
page 98 of 121
Graphs
Round 6
Measurement after repair attempt.
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph After R6
page 99 of 121
Graph6.2.1 R6
page 100 of 121
Graph6.2.3 R6
page 101 of 121
Graph6.2.2 R6
page 102 of 121
Graphs
Cumulative data for period
01-01-2020-31-12-2020
Comparison between count of sources & kg/year, by reading range
Comparison between count of sources & kg/year, by sources
Total overview by chemicals
Paragraph Graphs Cumul
page 103 of 121
Graph6.3.1
page 104 of 121
Graph6.3.2
page 105 of 121
Graph6.3.3
page 106 of 121
Graph6.3.4
page 107 of 121
General
Calibration loglist
Calibration gas certificates
Composition list & Response Factors
Quarterly production hours
Quarterly equipment check
Paragraph General
page 108 of 121
Calibration log list
Plant
Round Equipment Analyzer
Type
Type
Ultra-Zero
Span Gas
Span gas Cylinder
Span
Check gas Check gas Cylinder
Check gas
No
concentration
No
concentration
Date
Equipment
No
Equipment
Serial
No
Check
Calibration Result
error
1-st 2-st 3-st
check check check
(A1) (A2) (A3)
(CP)
ppm ppm ppm
(A)
ppm
ppm
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
01-Mar-2020
2
0115248185
513
513
512
1.72%
OK
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF524456
504
08-Mar-2020
2
0115248185
510
509
510
1.12%
OK
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
FF51428
1,000
Methane
FF16599
501
08-Mar-2020
3
0115248937
501
501
500
-0.27%
OK
TASHAN
2
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
31-Mar-2020
3
0115248937
507
503
501
-0.07%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
21-May-2020
5
202016061436 503
503
502
-0.26%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
21-May-2020
1
0715622657
514
514
513
1.92%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
27-May-2020
5
202016061436 504
506
506
0.26%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
27-May-2020
1
0715622657
509
509
509
0.99%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF32161
510
18-Jun-2020
2
0115248185
507
506
506
-0.72%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF32161
510
18-Jun-2020
1
0715622657
509
507
506
-0.52%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF524456
504
28-Jun-2020
5
202016061436 501
503
502
-0.40%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF524456
504
28-Jun-2020
3
0115248937
512
512
510
1.46%
OK
TASHAN
3
TVA2020
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF524456
504
05-Jul-2020
5
202016061436 502
504
501
-0.33%
OK
TASHAN
3
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF524456
504
05-Jul-2020
1
0715622657
507
508
504
0.46%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
21-Jul-2020
2
0115248185
499
510
506
0.20%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
21-Jul-2020
3
0115248937
492
497
488
-2.31%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
30-Aug-2020
8
05355151349
509
511
508
1.06%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
31-Aug-2020
3
0115248937
502
504
501
-0.33%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
31-Aug-2020
8
05355151349
509
507
507
0.73%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
01-Sep-2020
3
0115248937
487
488
487
-3.31%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
01-Sep-2020
8
05355151349
505
504
504
0.07%
OK
TASHAN
4
TVA1000B
FID
Air, THC < 0.5ppm
Methane
ET0022865
995
Methane
FF524456
504
08-Sep-2020
1
0715622657
479
480
480
-4.83%
OK
TASHAN
1
TVA2020
FID
Air, THC < 0.5ppm
Methane
ET0022842
995
Methane
FF524456
504
02-Dec-2020
5
202016061436 506
508
502
0.26%
OK
Cal-Log
page 109 of 121
Certificate
page 110 of 121
Certificate
page 111 of 121
Certificate
page 112 of 121
Certificate
page 113 of 121
Certificate
page 114 of 121
Certificate
page 115 of 121
Stream Composition Summary
Stream Name
Stream Content
Stream Content
Dates
TVA
Gasoline
TOLUENE-34 %, n-Octane-40 %, METHYL TERT-BUTYL ETHER-10 %,
CYCLOHEXANE-5 %, BENZENE-1 %, 1-Butene-10 %
A=0.42, B=0.29
Petroleum
TOLUENE-7.5 %, n-Octane-55.3 %, CYCLOHEXANE-35.2 %, BENZENE-2 %
A=0.39, B=0.31
Stream Summary
MiniRAE 10.6 MiniRAE 11.7
page 116 of 121
Quarterly Validation of LDAR Devices
Date: 29‐Dec‐2019
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Analyzer
Span Gas
Sampling Flow
Rate
1
Check
Sampling
Span Gas
Flow
Span gas
Concentration
Result Check Gas
Rate
Cylinder No
ppm
l/min
Accuracy Check
Response Time
Comparison between two Devices
90%
Check Gas
Response Response Response
Second
of
Check gas
1‐st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Time 1 Time 2 Time 3 Result
Result
Device
Result
Span
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
ET0022842
995
1.14
OK
Methane
FF524456
504
503 506 507
0.26%
OK 895.5
4
3
4
OK
2.71
2.85
‐0.14
4.91%
OK
2
0115248185
TVA1000B
FID
Methane
ET0022842
995
0.98
OK
Methane
FF524456
504
498 497 496
‐1.39%
OK 895.5
4
3
4
OK
2.01
2.15
‐0.14
6.51%
OK
3
0115248937
TVA1000B
FID
Methane
ET0022842
995
1.1
OK
Methane
FF524456
504
503 504 502
‐0.2%
OK 895.5
3
4
4
OK
1.12
1.4
‐0.28
20%
OK
5
202016061436
TVA2020
FID
Methane
ET0022842
995
1.17
OK
Methane
FF524456
504
494 497 495
‐1.72%
OK 895.5
4
3
4
OK
2.8
2.44
0.36
‐14.75%
OK
6
7
110219070002
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.51
OK
Isobutylene 995‐286088
500
505 505 504
0.79%
OK 898.2
4
4
4
OK
3
3.1
‐0.1
3.23%
OK
NEO
PID
Isobutylene
EA0009962
997
0.45
OK
Isobutylene 995‐286088
500
511 510 510
1.92%
OK 898.2
3
3
3
OK
3.1
3
0.1
‐3.33%
OK
Quarterly Validation
page 117 of 121
Quarterly Validation of LDAR Devices
Date: 02‐Apr‐2020
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Analyzer
Span Gas
Sampling Flow
Rate
Accuracy Check
Response Time
Comparison between two Devices
2
Check
Sampling
90%
Span Gas
Check Gas
Response Response Response
Second
Flow
of
Span gas
Check gas
1‐st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Concentration
Time 1 Time 2 Time 3 Result
Result Check Gas
Result
Device
Result
Rate
Span
Cylinder No
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
l/min
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
ET0022842
995
0.94
OK
Methane
FF16599
501
506 502 503
0.33%
OK 895.5
4
3
4
OK
2.35
2.01
0.34
‐16.92%
OK
2
0115248185
TVA1000B
FID
Methane
ET0022842
995
0.89
OK
Methane
FF16599
501
504 501 498
‐0.2%
OK 895.5
3
4
3
OK
1.22
1.4
‐0.18
12.86%
OK
3
0115248937
TVA1000B
FID
Methane
ET0022842
995
0.94
OK
Methane
FF16599
501
497 499 502
‐0.53%
OK 895.5
4
4
3
OK
2.15
1.9
0.25
‐13.16%
OK
5
202016061436
TVA2020
FID
Methane
ET0022842
995
1.11
OK
Methane
FF16599
501
508 501 509
0.8%
OK 895.5
4
4
4
OK
2.5
2.31
0.19
‐8.23%
OK
6
7
110219070002
MiniRAE2000
PID
Isobutylene
EA0009962
997
0.5
OK
Isobutylene 995‐286088
500
505 505 504
0.79%
OK 898.2
4
4
4
OK
2.1
2.3
‐0.2
8.7%
OK
NEO
PID
Isobutylene
EA0009962
997
0.47
OK
Isobutylene 995‐286088
500
511 510 510
1.92%
OK 898.2
3
3
3
OK
1.9
1.7
0.2
‐11.76%
OK
Quarterly Validation
page 118 of 121
Quarterly Validation of LDAR Devices
Date: 06‐Jul‐2020
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Analyzer
Span Gas
Sampling Flow
Rate
Accuracy Check
Response Time
Comparison between two Devices
3
Check
Sampling
90%
Span Gas
Check Gas
Response Response Response
Second
Flow
of
Span gas
Check gas
1‐st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Concentration
Time 1 Time 2 Time 3 Result
Result Check Gas
Result
Device
Result
Rate
Span
Cylinder No
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
l/min
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
ET0022842
995
0.93
OK
Methane
FF32161
510
504 506 507
‐0.85%
OK 895.5
4
4
3
OK
2.12
2.18
‐0.06
2.75%
OK
2
0115248185
TVA1000B
FID
Methane
ET0022842
995
0.92
OK
Methane
FF32161
510
510 512 511
0.2%
OK 895.5
3
4
4
OK
2.55
2.31
0.24
‐10.39%
OK
3
0115248937
TVA1000B
FID
Methane
ET0022842
995
1.13
OK
Methane
FF32161
510
499 501 503
‐1.76%
OK 895.5
4
4
4
OK
1.79
1.55
0.24
‐15.48%
OK
5
202016061436
TVA2020
FID
Methane
ET0022842
995
0.97
OK
Methane
FF32161
510
507 508 508
‐0.46%
OK 895.5
3
4
4
OK
2.33
2.84
‐0.51
17.96%
OK
MiniRAE2000
PID
Isobutylene
EA0010369
996
0.5
OK
Isobutylene 995‐286088
500
514 513 513
2.52%
OK 896.9
4
3
3
OK
1.5
1.4
0.1
‐7.14%
OK
6
7
110219070002
NEO
PID
Isobutylene
EA0010369
996
0.49
OK
Isobutylene 995‐286088
500
511 511 510
1.99%
OK 896.9
5
5
5
OK
1.4
1.5
‐0.1
6.67%
OK
8
05355151349
TVA1000B
FID
Methane
ET0022842
995
0.91
OK
Methane
510
511 510 510
0.07%
OK 895.5
4
4
4
OK
3.18
3.22
‐0.04
1.24%
OK
Quarterly Validation
FF32161
page 119 of 121
Quarterly Validation of LDAR Devices
Date: 23‐Sep‐2020
Equipment No Equip.Ser. No
Quarter:
Equipment
Type
Analyzer
Span Gas
Sampling Flow
Rate
Accuracy Check
Response Time
Comparison between two Devices
4
Check
Sampling
90%
Span Gas
Check Gas
Response Response Response
Second
Flow
of
Span gas
Check gas
1‐st 2nd 3rd Calibration
Instrument
Difference Difference
Concentration
Concentration
Time 1 Time 2 Time 3 Result
Result Check Gas
Result
Device
Result
Rate
Span
Cylinder No
Cylinder No
check check check error
Reading
ppm
%
Reading
ppm
l/min
ppm
ppm
sec
sec
sec
1
0715622657
TVA1000B
FID
Methane
ET0022842
995
0.92
OK
Methane
FF32161
510
507 509 511
‐0.2%
OK 895.5
4
4
4
OK
2.1
2.24
‐0.14
6.25%
OK
2
0115248185
TVA1000B
FID
Methane
ET0022842
995
0.9
OK
Methane
FF32161
510
517 515 516
1.18%
OK 895.5
4
4
4
OK
1.47
1.3
0.17
‐13.08%
OK
3
0115248937
TVA1000B
FID
Methane
ET0022842
995
1.19
OK
Methane
FF32161
510
506 506 505
‐0.85%
OK 895.5
4
4
4
OK
1.81
1.99
‐0.18
9.05%
OK
5
202016061436
TVA2020
FID
Methane
ET0022842
995
0.99
OK
Methane
FF32161
510
501 501 502
‐1.7%
OK 895.5
4
4
4
OK
2.45
2.1
0.35
‐16.67%
OK
MiniRAE2000
PID
Isobutylene
EA0010369
996
0.49
OK
Isobutylene 995‐286088
500
502 502 503
0.33%
OK 896.9
6
6
5
OK
1.3
1.44
‐0.14
9.72%
OK
6
7
110219070002
NEO
PID
Isobutylene
EA0010369
996
0.47
OK
Isobutylene 995‐286088
500
499 499 499
‐0.34%
OK 896.9
3
3
3
OK
1.44
1.3
0.14
‐10.77%
OK
8
05355151349
TVA1000B
FID
Methane
ET0022842
995
0.95
OK
Methane
FF32161
510
509 508 508
‐0.33%
OK 895.5
4
3
4
OK
2.55
2.16
0.39
‐18.06%
OK
9
33461300
TVA1000B
FID
Methane
FF51428
1,000
1.26
OK
Methane
FF32161
510
497 501 500
‐2.09%
OK
3
3
3
OK
1.58
1.68
‐0.1
5.95%
OK
Quarterly Validation
900
page 120 of 121
CUMULATIVE PRODUCTION HOURS TEMPLATE 2020
Plant
TASHAN
Unit
Drawing
Stream Name
Remark
Annual Production
Hours
Alroy
6006-100-006
Gasoline
8,784
Alroy
6006-100-007
Gasoline
8,784
Production Hours
Q1
01/01-31/03
Quarter =
Quarterly Production
hours
2,184
2,184
Q2
01/04-30/06
Quarter =
Quarterly Production
hours
2,184
2,184
Q3
01/07-30/09
Quarter =
Quarterly Production
hours
2,208
2,208
Q4
01/10-31/12
Quarter =
Quarterly Production
hours
2,208
2,208
page 121 of 121
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין
3013.17-034-T2
3013.17-025
28/02/2021
18/30
3013.17-036.doc
T2 - kerosene
External Floating roof
1. Tank data
Diameter of the tank
D
Effective height of the stock liquid (while
roof landing episode)
hle
Shell Color and condition
α
Roof color and condition
α
Tank paint solar absorptance
α
Vapor space outage (while roof landing
episode)
HVO
m
feet
m
feet
color
condition
color
condition
dimensionless
m
Tank data
--Tank data
--חום
טובה
לבן
טוב
48.77
160.01
11.00
0.58
Table 7.1-6
Brown
0.17
Table 7.1-6
0.38
Table 7.1-6
Possible to use also equation
1-15
assumption - equal to legs height
feet
11.00
Volume of the vapor space (while roof
landing episode)
Breather vent pressure setting
VV
ft
3
VV=PI()*D /4*Hvo
221,185
Equation 1-3
ΔPBP
psi
Typical value
0.50
Equation 1-11
Breather vent vacuum setting
ΔPBV
psi
Typical value
0.00
Equation 1-11
Breather vent pressure setting range
ΔPB
psi
PB PBP PBV
0.50
Equation 1-11
2
2. Material data - קרוסין
Stock vapor molecular weight
MV
Density of the liquid inside the tank
Wl
Vapor density
WV
True vapor pressure of the stock liquid
P
Vapor pressure at daily average liquid
surface temperature
Vapor pressure at the daily maximum
liquid surface temperature, psia
Vapor pressure at the daily minimum
liquid surface temperature
Daily vapor pressure range
3013.17-034.xls - 2
gr/gr-mole
lb/lb-mole
g/ml
lb/gal
kg/m^3
lb/ft3
msds data
130
msds data
--msds data
---
0.80
6.68
4.5
0.28
mm Hg
PEI data
0.833
psia
--הנחה:
Pv=nRT -->
P2=P1*(T2/T1)
0.02
0.02
0.02
0.00
PVA
psia
PVX
psia
PVN
psia
T1(k)=20C+273
T2(k)=37.5C+273
ΔPV
psia
PV PVX PVN
1/3
0
at 20°C
0.02
Equation 1-9
28/02/2021
3. Operation data
Number of days that the tank stands idle
(on roof landing episode)
Number of degassing and cleaning
episode
Number of roof landing episode
nd
days/landing episode
site data
4
landing episode/year
site data
0.07
landing episode/year
site data
0.07
Tanks Program
--Tanks Program
---
75
34
111
50
16
T2 - B&W 2020
Tanks Program
---
59.04
27
T2 - DFloating 2019
lb per emptying
Tanks Program
61
Kg per emptying
---
28
4. Normal operation (Tanks program)
lb per year
Kg per year
lb per year
Kg per year
Kg per year
Working (withdrawal) losses
Total emissions (Breathing & Working)
Breathing (standing) losses
5. Degassing and Cleaning (Tanks program)
Degassing: emission from one turnover
Edegass-floating lb per emptying
of floating roof
Kg per emptying
Degassing: fixed roof with a height of
roof legs
Edegass-legs
Liquid fraction in sludge
Fliquid
Sludge volume
Sludge weight
Vs
Ws
Cleaning emissions
Ecleaning
Total Degassing and Cleaning emissions
Edegass-total
3013.17-034.xls - 2
0.8
m3 per emptying
Kg per emptying
lb per emptying
Kg per emptying
lb per emptying
Kg per emptying
Ecleaning = Ws * (1-Fliquid)
Edegass-total =
Edegass-floating + Edegass-legs + Ecleaning
2/3
T2 - B&W 2020
T2- DFixed 2019
(Only working losses)
Tanks FAQ - degassing and
cleaning
70
56,000
24,692
11,200
24,811
11,254
28/02/2021
6. Roof landing
Daily average liquid surface temperature
TLA
°R
Daily vapor temperature range
Daily maximum liquid surface
temperature
ΔTV
°R
TLX
Daily minimum liquid surface temperature
Liquid bulk temperature
Max standing idle losses during roof
landing
T LA 0 .44 T AA 0 .56 T B 0 .0079 * * I
532.17
Equation 1-26
TV 0.72 T A 0.028 * * I
32.95
Equation 1-8
°R
TLX = TLA + 0.25*ΔTV
540.41
Figure 7.1-17
TLN
°R
TLN = TLA - 0.25*ΔTV
523.93
Figure 7.1-17
TB
°R
527.22
Equation 1-28
LSL-max
lb per landing episode
Kg per landing episode
TB = TAA + 6α - 1
LSL-max = 5.9*D2*hle*W l
--0.60 for a full liquid heel
0.50 for a partial
0.15 for drain-dry
11,093,038 Equation 2-13
5,031,769
0.50
Equation 2-26
(pages No 33,35)
1
KS
1 0.053 * PVA * H VO
0.5
Equation 1-20
KS is assumed to be less than
or equal to the saturation
factor during filling (S) .
TV PV PB
T LA
PA PVA
0.028
Liquid stock has a true vapor
pressure greater than 0.1psia Equation 1-7.
Filling saturation factor
S
dimensionless
saturation factor
KS
dimensionless
Vapor space expansion factor
KE
dimensionless
Standing idle losses during roof landing
LSL
lb per landing episode
PV
L SL n d K E V M V K S
RT AA
5
Equation 2-16
Filling losses during roof landing
LFL
lb per landing episode
P * VV
M V * S
L FL
R * T AA
41
Equation 2-26
Total losses during roof landing
LTL
lb per landing episode
Kg per landing episode
46
21
Equation 2-10
KE
LTL=LSL+LFL
7. Summary
Working (withdrawal) losses
Breathing (standing) losses
Kg per year
Kg per year
34
16
Total Degassing and Cleaning emissions
Kg per year
750
Total losses during roof landing
Kg per year
1
802
3013.17-034.xls - 2
3/3
Kg per year
28/02/2021
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - B&W 2020
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.34
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Aluminum/Diffuse
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
28/02/2021
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - B&W 2020 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
All
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
76.52
65.35
87.69
Liquid
Bulk
Temp
(deg F)
68.86
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0136
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
28/02/2021
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - B&W 2020 - External Floating Roof Tank
Haifa, Israel
Annual Emission Calcaulations
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
0.0136
160.0100
130.0000
1.0000
Withdrawal Losses (lb):
Annual Net Throughput (gal/yr.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
75.2122
10,209,723.0000
0.0075
7.0000
160.0100
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
0.8398
0.0002
130.0000
1.0000
27.8819
6.2000
Total Losses (lb):
110.5526
34.5005
1.6000
0.3000
6.2000
1.6000
0.0002
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
KFa(lb-mole/yr)
1.60
6.20
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
1.20
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.94
1.00
Losses(lb)
0.1446
0.6608
0.0345
28/02/2021
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Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - B&W 2020 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
34.50
75.21
0.84
0.00
110.55
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFixed 2019
Haifa
Israel
PEI
Vertical Fixed Roof Tank
kerosene
Tank Dimensions
Shell Height (ft):
Diameter (ft):
Liquid Height (ft) :
Avg. Liquid Height (ft):
Volume (gallons):
Turnovers:
Net Throughput(gal/yr):
Is Tank Heated (y/n):
N
Paint Characteristics
Shell Color/Shade:
Shell Condition
Roof Color/Shade:
Roof Condition:
Aluminum/Diffuse
Good
White/White
Good
Roof Characteristics
Type:
Height (ft)
Slope (ft/ft) (Cone Roof)
Breather Vent Settings
Vacuum Settings (psig):
Pressure Settings (psig)
11.00
160.01
11.00
5.50
1,654,664.74
1.00
1,654,664.74
Cone
0.00
0.00
0.00
0.50
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
Apr
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
72.10
62.74
81.45
Liquid
Bulk
Temp
(deg F)
67.57
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0118
0.0092
0.0159
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
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Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Month:
Standing Losses (lb):
Vapor Space Volume (cu ft):
Vapor Density (lb/cu ft):
Vapor Space Expansion Factor:
Vented Vapor Saturation Factor:
January
February
March
April
May
June
July
August
September
October
November
December
Tank Vapor Space Volume:
Vapor Space Volume (cu ft):
Tank Diameter (ft):
Vapor Space Outage (ft):
Tank Shell Height (ft):
Average Liquid Height (ft):
Roof Outage (ft):
Roof Outage (Cone Roof)
Roof Outage (ft):
Roof Height (ft):
Roof Slope (ft/ft):
Shell Radius (ft):
Vapor Density
Vapor Density (lb/cu ft):
Vapor Molecular Weight (lb/lb-mole):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Daily Avg. Liquid Surface Temp. (deg. R):
Daily Average Ambient Temp. (deg. F):
Ideal Gas Constant R
(psia cuft / (lb-mol-deg R)):
Liquid Bulk Temperature (deg. R):
Tank Paint Solar Absorptance (Shell):
Tank Paint Solar Absorptance (Roof):
Daily Total Solar Insulation
Factor (Btu/sqft day):
Vapor Space Expansion Factor
Vapor Space Expansion Factor:
Daily Vapor Temperature Range (deg. R):
Daily Vapor Pressure Range (psia):
Breather Vent Press. Setting Range(psia):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Vapor Pressure at Daily Minimum Liquid
Surface Temperature (psia):
Vapor Pressure at Daily Maximum Liquid
Surface Temperature (psia):
Daily Avg. Liquid Surface Temp. (deg R):
Daily Min. Liquid Surface Temp. (deg R):
Daily Max. Liquid Surface Temp. (deg R):
Daily Ambient Temp. Range (deg. R):
Vented Vapor Saturation Factor
Vented Vapor Saturation Factor:
Vapor Pressure at Daily Average Liquid:
Surface Temperature (psia):
Vapor Space Outage (ft):
Working Losses (lb):
Vapor Molecular Weight (lb/lb-mole):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Net Throughput (gal/mo.):
Annual Turnovers:
Turnover Factor:
Maximum Liquid Volume (gal):
Maximum Liquid Height (ft):
Tank Diameter (ft):
Working Loss Product Factor:
Total Losses (lb):
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TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Losses(lbs)
Components
Working Loss
Breathing Loss
Total Emissions
Jet kerosene
60.63
32.78
93.41
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
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Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFloating 2019
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.00
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Aluminum/Diffuse
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
Apr
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
76.46
63.88
89.04
Liquid
Bulk
Temp
(deg F)
68.86
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0136
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
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Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Month:
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
January
February
March
April
May
June
July
August
September
October
November
December
Withdrawal Losses (lb):
Net Throughput (gal/mo.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
Total Losses (lb):
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
KFa(lb-mole/yr)
1.60
6.20
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
1.20
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.94
1.00
Losses(lb)
0.0000
0.0000
0.0000
02/02/2020
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Page 4 of 6
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Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
2.99
55.99
0.07
0.00
59.04
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
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Page 6 of 6
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02/02/2020
נספח ד'
חישוב פליטות ממיכל לאיסוף תשטיפים
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תוכנת :Tanksחישוב פליטה כתוצאה מאחסון ושינוי מפלס
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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב א')
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3013.17-036.doc
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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב ב')
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חישובי פליטה ממיכל תשטיפים
גיליון חישוב זה הוכן על ידי "פז" הנדסה וניהול ( )1980בע"מ.
אין להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ( )1980בע"מ.
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מסמך 10 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 6058 KB)
תשתיות פט וא רגיה בע"מ
מסוף אלרואי
סיכום פליטות לאוויר
ש ת 2021
פרויקט3013.18 :
סימוכין3013.18-036 :
פברואר 2022
תוכן ע יי ים
.1מבוא 4.............................................................................................................................
.2תו י מסוף 5.....................................................................................................................
.2.1תו י מיכלים 5.........................................................................................................
.2.2תו ים עבור מסוף מילוי מיכליות כביש 9.....................................................................
.3חישוב פליטות 10 ..............................................................................................................
.3.1כללי10 ......................................................................................................................... ...
.3.2סוגי פליטות מחושבות 10 ..................................................................................................
.3.3בחירת חומרים בתוכ ת 11 ................................................................................... TANKS
.3.4תו ים מטאורולוגיים11 ....................................................................................................
.4סיכום פליטות לש ת 12 ............................................................................................. 2021
.4.1מיכלים 12 ........................................................................................................................
.4.2מסוף מילוי מיכליות כביש 12 .............................................................................................
.4.3מיכל איסוף תשטיפים 13 ...................................................................................................
.4.4סיכום ממצאי יטור 13 .......................................................................................... LDAR
.4.5פליטה ש תית מכלל המתקן 13 ...........................................................................................
.5פליטות לא שגרתיות במהלך ש ת 13 ............................................................................2021
.6מקורות 14 .......................................................................................................................
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טבלאות
טבלה :1תו י מיכלים – מידע כללי ,מידות ו תו י תפעול – ש ת 5........................................... 2021
טבלה :2תו י מעטפת וגגות – ש ת 6.................................................................................. 2021
טבלה :3תו י אביזרים – ש ת 7......................................................................................... 2021
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכ ת 8................................................... TANKS
טבלה :5תו ים עבור מסוף מילוי מיכליות כביש – ש ת 9...................................................... 2021
טבלה :6חומרים מייצגים בתוכ ת 11 ............................................................................ TANKS
טבלה :7סיכום פליטות מכלים -ש ת 12 ............................................................................ 2021
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -ש ת 12 ..................................................2021
ספחים
ספח א'
טבלה (AP-42) 1-5.2
ספח ב'
תו י יטור LDARעבור מסוף אלרואי – סיכום ש ת 2021
ספח ג'
דוגמת חישוב עבור מיכל גג חיצו י צף מס' 2המאחסן קרוסין
ספח ד'
חישוב פליטות ממיכל לאיסוף תשטיפים
מירה ליה-זיו איסקוב
שם עורך
28/02/2022
יואב פיסטי ר
שם מאשר
28.02.2022
תאריך
3/30
להערות
תיאור
0
גרסה
3013.18-036.doc
.1מבוא
חברת תשתיות פט וא רגיה בע"מ )להלן תש"ן( מפעילה את מסוף אלרואי לאחסון ושי וע
דלקים .
המסוף כולל:
מב י משרדים
חוות מכלים לאחסון דלקים מסוגים שו ים
רציפי מילוי מכליות כביש )לשימוש בעת חירום בלבד(
המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכו ת
אלרואי ומדרום לו שכו ת קרית חרושת.
באתר 9מיכלים ,מתוכם 7מכלים תפעוליים ו 2-מכלים המשמשים כמכלים אסטרטגיים
)מכלים מס' 1ו.(9-
מערכת השי וע הי ה באמצעות משאבות ובקרת מילוי וב וסף קיימות מערכות תומכות כגון
מערכות כיבוי אש ומערכות פיקוד ובקרה.
כחלק מהת אים ברישיון עסק מדצמבר ,2010בסוף כל ש ה קל דרית על תש"ן להגיש דו"ח
סיכום פליטות ש תי לגבי הש ה שחלפה.
חישובי הפליטות בוצעו בעזרת תוכ ת Tanksומסמכי EPA-AP 42על פי תו י המתק ים
הקיימים במסוף.
סיכום הפליטות הוכן על ידי חברת "פז" ה דסה ו יהול ) (1980בע"מ )להלן פז ה דסה( ,והוא
מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות יטור LDARשהוגשו לרשויות.
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.2תו י מסוף
.2.1תו י מיכלים
בטבלאות הבאות מפורט מידע טכ י של המיכלים בחוות המיכלים אלרואי.
טבלה :1תו י מיכלים – מידע כללי ,מידות ו תו י תפעול – ש ת 2021
לחץ אדים
בטמפ' ה וזל
הממוצעת
)(mmHg
405 @ 28°C
כמות
צריכה
ש תית
)מ"ק(
0
גבעה חלקית
19,692
גבעה חלקית
48.77
גבעה חלקית
48.77
32,056
48.77
32,056
28,768
56,959
51,614
15.56
51,614
15.56
14.1
15.56
14.1
11.4
18.3
18.3
15.4
9.7
סוג יקוז
בתחתית
מיכל
קוטר
מיכל
)מטר(
פח מיכל
)מ"ק(
פח מיכל
פעיל
)מ"ק(
48.77
32,056
28,768
גובה /אורך
מעטפת
מיכל
)מטר(
17.16
15.4
32,056
28,768
17.16
15.4
10
28,768
17.16
15.4
9.5
17.16
15.4
10.3
14.1
14.1
14.1
מספר
מיכל
סוג הדלק
המאוחסן
(1) 1
ב זין
2
קרוסין
0.833 @ 28°C
3
סולר
0.507 @ 28°C
23,194
4
סולר
0.507 @ 28°C
56,674
גבעה חלקית
5
סולר
0.507 @ 28°C
11,986
גבעה מלאה
68.27
(1) 6
סולר
0.507 @ 28°C
0
גבעה מלאה
68.27
56,959
(1) 7
סולר
0.507 @ 28°C
0
גבעה מלאה
68.27
56,959
51,614
(1) 8
קרוסין
0.833 @ 28°C
0
גבעה חלקית
48.8
36,547
34,228
19.54
(1) 9
קרוסין
0.833 @ 28°C
0
גבעה חלקית
48.77
32,056
28,768
17.16
367,704
332,913
111,547
סה"כ
) (1מכלים מס' 8 ,7 ,6 ,1ו 9-משמשים כמכלי מלאי ,לא היו ת ועות במכלים בש ת .2021
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גובה וזל
מירבי
)מטר(
גובה וזל
ממוצע
)מטר(
10.5
טבלה :2תו י מעטפת וגגות – ש ת 2021
מספר
מיכל
סוג גג
אטם ראשי
אטם מש י
1
גג צף
חיצו י
גג צף
חיצו י
גג צף
חיצו י
גג צף
חיצו י
גג צף
חיצו י
גג צף
חיצו י
גג צף
חיצו י
גג צף
חיצו י
גג צף
חיצו י
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Liquid
mounted
Mechanical
Shoe
Rim
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Rim
mounted
Rim
mounted
2
3
4
5
6
7
8
9
28/02/2022
צורת גג
סוג
חיבורי
גג
צבע
גג
מצב
צבע
גג
צבע
מעטפת
חיצו ית
מצב צבע
מעטפת
חיצו ית
סוג חיבורי
מעטפת
מצב
מעטפת
פ ימית
מיכל
מחומם
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חום
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חום
ישן
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
כחול בהיר
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
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טבלה :3תו י אביזרים – ש ת 2021
מספר
מיכל
1
2
3
4
5
6
7
8
9
סה"כ
שובר ואקום
כמות
2
2
2
2
2
2
2
6
2
Vacuum
]set. [psi
0
0
0
0
0
0
0
0
0
Pressure
]set. [psi
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
רגליים מתכוו ות התומכות
בגג צף)(1
גובה כמות באזור
כמות
במרכז
)(ft
pontoon
29
43
11
29
43
11
29
43
11
29
43
11
72
107
11
72
107
11
72
107
11
36
54
9
29
43
11
כמות
מדי
מפלס
Rim
Vent
כמות בוצה
ב קיון
)מ"ק(
"גרביים" לבאר
הדיגום המחורצת
ולרגלי הגג הצף)(1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
70
70
70
70
150
150
150
70
70
870
יש
יש
יש
יש
יש
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יש
) (1ה "ל לא לקחו בחשבון בחישוב הפליטות מתוכ ת ה TANKS-מפ י ש דגמו במסגרת יטורי ה.LDAR-
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ה חות ש לקחו לצורך החישובים
.1עבור חישוב Degassingבמיכל עם גג צף – הו ח:
גג צף ח על רגליים בגובה ) 9-11 ftבהתאם לטבלה לעיל( וזהו גם הגובה המרבי של ה וזל
במיכל.
גובה ממוצע של ה וזל במיכל הי ו 50%מגובה ה וזל המרבי.
.2הו ח כי יקיון כללי וריקון של המיכלים מתבצע אחת ל 15-ש ים .ה יקיון יארך יום אחד.
.3הו ח כי אירוע של חיתת גגות צפים מתבצע אחת ל 15-ש ים .זמן חיתת הגג במקרה זה לא
יעלה על 4ימים.
.4יחס ה וזל בבוצה הו ח כ[2] 0.8 -
.5בהתאם לטבלה 7.1-6על פי ] ,[1בחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,
לצורך חישובי פליטות לאוויר:
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכ ת Tanks
צבע מעטפת
מיכל
צבע לצורך חישובי אקסל
צבע לצורך חישובים בתוכ ת
בהתאם למסמך EPA AP-42
(*) Tanks
כחול בהיר
Gray Medium
Gray Medium
Brown
Aluminium/Diffuse
Beige/Cream
Aluminium/Specular
White
White
חום
צהוב קרם
לבן
)*( בתוכ ת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך
.[1] EPA AP-42
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.2.2תו ים עבור מסוף מילוי מיכליות כביש
טבלה :5תו ים עבור מסוף מילוי מיכליות כביש – ש ת 2021
מס'
זרוע
1
2
3
4
5
6
7
8
מוצר
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
סה"כ
מילוי
עילי /תחתי
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
פח מילוי ש תי
)מ"ק(
12
0
0
0
0
0
0
0
12
פח ממוצע של
מיכלית )מ"ק(
30
30
30
30
30
30
30
30
ה חות ש לקחו צורך החישובים
.1
מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:
א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:
דוגמת חישוב עבור מיכל מס' :2
ב .בשלב הש י חושב מקדם αממוצע עבור הקרוסין:
.2
זמן מילוי מיכלית חושב על פי פח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000
ליטר/דקה.
.3
Vapor collection efficiency - 70%
.4
Vapor recovery efficiency - 0%
.5
Saturation factorהו ח כ (Submerged loading, dedicated normal service) 0.6-על פי
] .[1טבלה רלוו טית מצורפת ב ספח א'.
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.3חישוב פליטות
.3.1כללי
חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכ ת Tanksובעזרת .[1] EPA-AP 42
הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ) (LDARמצורפת ב ספח ב'.
דוגמת חישוב עבור מיכל גג חיצו י צף )מיכל מס' (2המאחסן קרוסין ,מצורפת כ ספח ג' למסמך
זה.
בדוגמאות אלה יתן לראות את תו י הקלט )כולל ה חות( עליהם התבססו החישובים.
.3.2סוגי פליטות מחושבות
הערכת הפליטות ממיכלי אחסון כוללת ]:[3
פליטות בזמן אחסון )(Breathing Losses
פליטות משי ויי מפלס )(Working Losses
פליטות כתוצאה מ יקוי וריקון מיכלים )(Degassing Losses
פליטות כתוצאה מ חיתת גגות צפים )(Roof Landing Losses
פליטות כתוצאה מהפרשי לחץ )(Flash Losses
פליטות בזמן מילוי מיכלים ומיכליות
בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ
).(Flash Losses
פליטות אלה רלוו טיות לשי ויי פתאומי\מיידי בלחץ ה וזל ,תון הגורם להפרת שיווי המשקל
הקיים במיכל )בין גז ל וזל( וכתוצאה מכך וצר תהליך הבזקה ,בו מרכיבים קלים מפאזה ה וזל
עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר וזל המאוחסן בלחץ שלח
לאחסון במיכל בעל לחץ מוך יותר ].[3
פליטות אלו הוז חו כיוון שכל החומרים מוחזקים בת אים אטמוספריים בכל אחד מהשלבים
ה וגעים להובלתם ואחסו ם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.
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.3.3בחירת חומרים בתוכ ת Tanks
על פי תו י MSDSשל הדלקים במסוף ,בחרו החומרים הבאים הקיימים בתוכ ת Tanks
כמייצגים של חומרים אלו:
טבלה :6חומרים מייצגים בתוכ ת Tanks
דלק קיים במסוף
חומר מייצג בתוכ ת Tanks
סולר )תחבורה והסקה(
Distillate fuel oil no 2
פט )קרוסין(
Jet kerosene
ב זין
Gasoline RVP 10
.3.4תו ים מטאורולוגיים
לצורך חישוב ה תו ים בתוכ ת Tanksהוגדרו תו ים מטאורולוגים המתאימים למפרץ חיפה על פי
מקורות ].[4
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.4סיכום פליטות לש ת 2021
.4.1מיכלים
סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:
טבלה :7סיכום פליטות מכלים -ש ת 2021
מיכל
חומר
פליטות לאוויר
)ק"ג/ש ה(
1
ב זין
3,603
2
קרוסין
785
3
סולר
31
4
סולר
848
5
סולר
1,701
6
סולר
1,693
7
סולר
1,693
8
קרוסין
756
9
קרוסין
758
11,867
סה"כ
.4.2מסוף מילוי מיכליות כביש
להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.
טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -ש ת 2021
פליטה ש תית
)ק"ג/ש ה(
מס' זרוע
מוצר
מילוי עילי /תחתי
1
2
3
4
5
6
7
8
סה"כ
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
0.04
0
0
0
0
0
0
0
0.04
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.4.3מיכל איסוף תשטיפים
סך הפליטה ממיכל לאיסוף תשטיפים הי ה כ 1 -ק"ג/ש ה.
חישוב מצורף ב ספח ד'.
יצוין כי החישוב מתבסס על ה חה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל
בעיקר יקוז מים מהמכלים.
.4.4סיכום ממצאי יטור LDAR
טבלה :9סיכום פליטות חומרים אורג ים דיפים עבור רכיבים בש ת 2021
סה"כ פליטות )ק"ג/ש ה(
סיכום פליטות LDAR
פליטה ש תית )ק"ג/ש ה(
סה"כ
6
.4.5פליטה ש תית מכלל המתקן
טבלה :10סיכום פליטות ש תי מכלל מסוף אלרואי – ש ת 2021
סה"כ פליטות )ק"ג/ש ה(
חוות מיכלים
מסוף מילוי
מיכליות כביש
מיכל לאיסוף
תשטיפים
11,867
0.04
1
סיכום פליטות
רכיבים
סה"כ
)(LDAR
6
11,874
.5פליטות לא שגרתיות במהלך ש ת 2021
במהלך ש ת 2021לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמי ל.
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.6מקורות
[1] EPA-AP42
[2] USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version
4.0 - APPENDIX D
] [3ה חיות להגשת בקשה להיתר פליטה ושי וי הפעלה משמעותי ה חיות הממו ה לטיפול בבקשה
להיתר פליטה לפי סעיף )9א( לתק ות אוויר קי )היתרי פליטה( ,התש"ע – ,2010מהדורה ,5
ובמבר 2020
] [4האטלס האקלימי לתכ ון פיסי וסביבתי בישראל ,מהדורה ש ייה1994 ,
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ספח א'
טבלה 5.2-1
AP-42
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ספח ב'
תו י יטור LDARעבור אלרואי – סיכום ש ת 2021
)מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך (17.02.2022
3013.18-004A
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LDAR
Fugi ve Emission Monitoring
Report No.
RL-E I-R1-6-21
Plant: Energy Infrastructures LTD
City: Haifa
District: Haifa
Production Unit: Alroy
Report printing date:
17-Feb-2022
Report editor:
Michael Ourievsky
Approved by:
Alexey Ratner
Table of Content
1. Executive Summary
2. Project introduction
2.1 Scope of work
2.2 Project phases
3. Monitoring Results
Table 3.1 – Overview by component class
Table 3.2 – Overview by reading range
Table 3.3 – Overview per Unit
Table 3.4 – Monitoring results, last known situation
Graph 3.5 – Total overview by chemicals
4. Historical overview
Table 4.1 – Historical overview by component class
Table 4.2 – Historical Overview by Unit
5. Detailed monitoring summary
Table 5.1 - Cumulative summary, Fugitive emission component classification and emission estimation for
production facilities
Table 5.2 – Chemical Summary by Component Class
Table 5.3 - LDAR report for production facilities
Table 5.4 - Components with more than 5 significant leaks detected during last 12 months
Graph 5.6 - Comparison between count of components & kg/year, by components
Graph 5.7 - Comparison between total annual emissions (kg/year), by class & year
6. Summary by monitoring period, Round 1
Table 6.1 - First measurements, overview by component class
Table 6.2 - First measurement, overview by reading range
Table 6.3 - Measurement after repair attempt, overview by component class
Table 6.4 - Measurement after repair attempt, Overview by reading range
Table 6.5 - Form 07: First measurement and measurement after repair
Table 6.6 - Chemical Summary by Component Class, First Measurement
Table 6.7 - Chemical Summary by Component Class, After Repair
Table 6.8 - LDAR report for production facilities
Graph 6.10 - Count of components & kg/year
Graph 6.11 - Overview by reading range
Graph 6.12 - Overview by chemicals
6. Summary by monitoring period, Round 2
Table 6.1 - First measurements, overview by component class
Table 6.2 - First measurement, overview by reading range
Table 6.3 - Measurement after repair attempt, overview by component class
Table 6.4 - Measurement after repair attempt, Overview by reading range
Table 6.5 - Form 07: First measurement and measurement after repair
Table 6.6 - Chemical Summary by Component Class, First Measurement
Table 6.7 - Chemical Summary by Component Class, After Repair
Table 6.8 - LDAR report for production facilities
Graph 6.10 - Count of components & kg/year
Graph 6.11 - Overview by reading range
Graph 6.12 - Overview by chemicals
6. Summary by monitoring period, Round 3
Table 6.1 - First measurements, overview by component class
Table 6.2 - First measurement, overview by reading range
Table 6.3 - Measurement after repair attempt, overview by component class
Table 6.4 - Measurement after repair attempt, Overview by reading range
Table 6.5 - Form 07: First measurement and measurement after repair
Table 6.6 - Chemical Summary by Component Class, First Measurement
Table 6.7 - Chemical Summary by Component Class, After Repair
Table 6.8 - LDAR report for production facilities
Graph 6.10 - Count of components & kg/year
Graph 6.11 - Overview by reading range
Graph 6.12 - Overview by chemicals
6. Summary by monitoring period, Round 4
Table 6.1 - First measurements, overview by component class
Table 6.2 - First measurement, overview by reading range
Table 6.3 - Measurement after repair attempt, overview by component class
Table 6.4 - Measurement after repair attempt, Overview by reading range
Table 6.5 - Form 07: First measurement and measurement after repair
Table 6.6 - Chemical Summary by Component Class, First Measurement
5
6
6
6
7
7
7
8
8
10
10
10
10
11
12
13
15
16
17
18
19
20
21
21
21
21
22
23
24
25
26
27
28
29
30
30
30
30
31
32
33
34
35
36
37
38
39
39
39
39
40
42
44
45
46
47
48
49
50
50
50
50
51
Table 6.7 - Chemical Summary by Component Class, After Repair
Table 6.8 - LDAR report for production facilities
Graph 6.10 - Count of components & kg/year
Graph 6.11 - Overview by reading range
Graph 6.12 - Overview by chemicals
6. Summary by monitoring period, Round 5
Table 6.1 - First measurements, overview by component class
Table 6.2 - First measurement, overview by reading range
Table 6.3 - Measurement after repair attempt, overview by component class
Table 6.4 - Measurement after repair attempt, Overview by reading range
Table 6.5 - Form 07: First measurement and measurement after repair
Table 6.6 - Chemical Summary by Component Class, First Measurement
Table 6.7 - Chemical Summary by Component Class, After Repair
Table 6.8 - LDAR report for production facilities
Graph 6.10 - Count of components & kg/year
Graph 6.11 - Overview by reading range
Graph 6.12 - Overview by chemicals
6. Summary by monitoring period, Round 6
Table 6.1 - First measurements, overview by component class
Table 6.2 - First measurement, overview by reading range
Table 6.3 - Measurement after repair attempt, overview by component class
Table 6.4 - Measurement after repair attempt, Overview by reading range
Table 6.5 - Form 07: First measurement and measurement after repair
Table 6.6 - Chemical Summary by Component Class, First Measurement
Table 6.7 - Chemical Summary by Component Class, After Repair
Table 6.8 - LDAR report for production facilities
Graph 6.10 - Count of components & kg/year
Graph 6.11 - Overview by reading range
Graph 6.12 - Overview by chemicals
7. Attachments
7.1 General Remarks
Table 7.1.1 Monitored components
Table 7.1.2 Unmonitored P&IDs
Table 7.2 Project schedule
7.3 Methodology
7.4 Calibration loglist
7.5 Calibration gas certificates
7.6 Stream Composition Summary
7.7 Quarterly Validation of LDAR Devices, Quater 1
7.8 Quarterly Validation of LDAR Devices, Quater 2
7.9 Quarterly Validation of LDAR Devices, Quater 3
7.10 Quarterly Validation of LDAR Devices, Quater 4
7.11 Cumulative production hours template
52
53
54
55
56
57
58
59
59
59
59
60
62
64
65
66
67
68
69
70
70
70
70
71
72
73
74
75
76
78
78
78
78
78
79
80
81
87
88
89
90
91
92
1. Executive Summary
The total number of active components at Energy Infrastructures LTD is 223.
Six rounds of measurements have been performed in 2021.
The total calculated emission from 01/01/2021 to 31/12/2021 is 6.08 kg.
The number of components above leak definition found from the beginning of the year – 0
The number of pegged readings (above 100,000 ppm) found from the beginning of the year - 0
The last known situation of Energy Infrastructures LTD indicates there are no leaks
5/92
2 Project introduction
2.1 Scope of work
Following measurements been performed in 2021:
Round
Round 1
Round 2
Round 3
Round 4
Round 5
Round 6
Unit
G1
Monitored group
G2
G3
Alroy
Alroy
Alroy
Alroy
Alroy
Alroy
2.2 Project phases
Monitoring
Re-measurement after repair
Revision of equipment and production processes
Inventorisation: adding or deleting components
General
1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory Accreditation Authority).
2. ISRAC is not responsible for the test results.
3. The following data is provided by the customer: production hours, P&IDs, and stream information.
6/92
3. Monitoring results
The table “Overview by component class” below shows the number of active components, number of leaks above leak definitions and number of components that are still leaking in each class
(according to the monitoring round), and total calculated emissions in the specified period.
Table 3.1 Overview by component class,
Component Class
01/01/2021-31/12/2021
Total
Components
count
Total Components above
leak definition
count
% of components above
leak definition
%
Unrepaired Components
Total Emissions
count
kg
Round 1
Round 2
Round 3
Round 4
Round 5
Round 6
Round 1
Round 2
Round 3
Round 4
Round 5
Round 6
Average
Round 1
Round 2
Round 3
Round 4
Round 5
Round 6
01/01/202131/12/2021
PRD
Sampling Point
Total Group 1:
Stem Valve
Open End
Total Group 2:
Flange
Connection
Total Group 3:
4
4
8
20
102
122
55
38
93
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.14
0.14
0.28
1.367
1.787
3.154
0.149
2.497
2.646
Total:
223
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
6.08
In table “Overview by reading range” all the components divided by their reading range at first measurement according to the monitoring round.
Table 3.2 Overview by reading range
Total Components
Reading Range
Round 1
#
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above leak definition
Difficult to Monitor
Total:
Round 2
%
8
0
0
0
0
0
0
0
8
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
Round 3
%
8
0
0
0
0
0
0
0
8
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
Round 4
%
223
0
0
0
0
0
0
0
223
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
Round 5
%
8
0
0
0
0
0
0
0
8
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
Round 6
%
130
0
0
0
0
0
0
0
130
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
%
8
0
0
0
0
0
0
0
8
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
7/92
Table 3.3 Overview per Unit, 01/01/2021-31/12/2021
Unit
Total
components
Components above leak definition
count
Alroy
Total:
R1
223
223
R2
0
0
R3
R4
0
0
R5
0
0
0
0
R6
0
0
Total emission
kg
01/01/202131/12/2021
0
6.08
0
6.08
Table 3.4 – Monitoring results, 01/01/2021-31/12/2021, last known situation.
The last known situation of Energy Infrastructures LTD indicates there are no leaks.
0 "difficult to monitor" sources.
223 default-zero sources (0ppm).
0 registered sources (1-999ppm).
0 components above leak definition
Component Class
Total
components
count
PRD
Sampling Point
Stem Valve
Open End
Flange
Connection
Total:
Components 1- Components 500- Components 750499ppm
749ppm
999ppm
count
4
4
20
102
55
38
223
count
0
0
0
0
0
0
0
count
0
0
0
0
0
0
0
Components % of components
% of
above leak
1-999ppm
components
definition (1,000
above leak
ppm)
definition
count
%
%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
8/92
Graph 3-5 - Total overview by chemicals, 01/01/2021-31/12/2021.
9/92
4 . Historical overview
Table 4.1 – Historical overview by component class, 2019-2021 .
Component Class
Total Components above leak definition count, summary of all rounds
2019
2020
2021
% of components above leak definition, average of all rounds) %
2019
2020
2021
Total Emissions kg
2019
2020
2021
PRD
0
0
0
0.00%
0.00%
0.00%
0.14
0.14
0.14
Sampling Point
0
0
0
0.00%
0.00%
0.00%
1.35
0.3
0.14
Total Group 1
0
0
0
0.00%
0.00%
0.00%
1.49
0.44
0.28
Stem Valve
0
0
0
0.00%
0.00%
0.00%
1.37
1.37
1.37
Open End
0
0
0
0.00%
0.00%
0.00%
2.25
1.79
1.79
Total Group 2
0
0
0
0.00%
0.00%
0.00%
3.61
3.16
3.15
Flange
0
0
0
0.00%
0.00%
0.00%
0.15
0.15
0.15
Connection
0
0
0
0.00%
0.00%
0.00%
2.5
2.5
2.5
Total Group 3
0
0
0
0.00%
0.00%
0.00%
2.65
2.65
2.65
0
0
0
0.00%
0.00%
0.00%
7.75
6.26
6.08
Total:
Table 4.1 – Historical Overview by Unit, 2019-2021
Unit
Total emission
kg
Total Components above leak definition, summary of all rounds
2019
2020
2021
2019
2020
2021
Alroy
0
0
0
7.75
6.26
6.08
Total:
0
0
0
7.75
6.26
6.08
10/92
5. Detailed monitoring summary
01/01/2021-31/12/2021
11/92
Fugitive emission component classification and emission estimation for production facilities
01/01/2021-31/12/2021 Calculation period
Monitoring
Frequency
cycles/year
Components above 1,000 ppm
%
R6
R5
R4
R3 R2 R1
6
6 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
6
6
6 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
6
0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
2
2 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
2
2
2 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
2
0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
1
1 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
1
1
1 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
1
0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
Cumulative Components above
Components in reading
Components in reading
Emission
100,000 ppm
range 1,000-100,000 ppm
range 750-999 ppm
kg
Count
Count
Count
R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1
0.14 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
0.14 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
0.28 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
1.367 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
1.787 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
3.154 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
0.149 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
2.497 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
2.646 0 0 0 0 0 0
6.08 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Energy Infrastructures LTD Company name
17-Feb-2022 Date
Alroy Production
Report Number
Unit
Components in reading
Components in reading Components in reading
Unrepaired
Total Components Difficult to
Total
Chemical Component Class Group
range 500-749 ppm
range 1-499 ppm
range 0 ppm
Components
above 1,000 ppm
Monitor Components
State
Count
Count
Count
Count
Count
Count
R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 Count
GV
PRD
G1
0 0 0 0 0 0 0 0 0 0 0 0 4 4 4 4 4 4 0 0 0 0 0 0 0 0 0 0 0 0
0
4
LL
HL
GV
Sampling Point
0 0 0 0 0 0 0 0 0 0 0 0 4 4 4 4 4 4 0 0 0 0 0 0 0 0 0 0 0 0
0
4
LL
HL
0 0 0 0 0 0 0 0 0 0 0 0 8 8 8 8 8 8 0 0 0 0 0 0 0 0 0 0 0 0
0
8 Subtotal G1
GV
Stem Valve
G2
0 0 0 0 0 0 0 0 0 0 0 0 0 20 0 20 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
20
LL
HL
GV
Open End
0 0 0 0 0 0 0 0 0 0 0 0 0 102 0 102 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
102
LL
HL
0 0 0 0 0 0 0 0 0 0 0 0 0 122 0 122 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
122 Subtotal G2
GV
Flange
G3
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 55 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
55
LL
HL
GV
Connection
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 38 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
38
LL
HL
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 93 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
93 Subtotal G3
0 0 0 0 0 0 0 0 0 0 0 0 8 130 8 223 8 8 0 0 0 0 0 0 0 0 0 0 0 0
0
223 Total Components
6.08 Total Cumulative Emission
12/92
Table 5.2 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Cumula tive
Equa tion Set:
Refinery
Units of Mea s urement:
KG
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
Emissions
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Stem Va lve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.1367
0.0137
0.0683
0.1367
0.5466
0.4646
1.3666
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.1787
0.0179
0.0894
0.1787
0.7148
0.6076
1.7871
13/92
Table 5.2 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Cumula tive
Equa tion Set:
Refinery
Units of Mea s urement:
KG
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
Fla nge
Chemical Name (Stream Name if Not Speciated)
CAS Number
Emissions
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.0149
0.0015
0.0075
0.0149
0.0597
0.0508
0.1493
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.2497
0.025
0.1248
0.2497
0.9986
0.8488
2.4966
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.608
0.0609
0.304
0.608
2.4319
2.0672
6.08
Grand Total
6.08
14/92
re p a i r
t yp e
D a te o f
Re pa i r
t
t yp e
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
Re pa i r
Plant
En e rg y I n f ra s tru ctu re s LT D
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
D a te o f
re p a i r
Due
Re pa i r
u re m e n
ement
s t Me a s
on
Mo re
3 d ro p s th a n
per min
u te
D a te o f
F i rs t Me
asur
l u e , Fi r
D e s cri p
Lo ca o n
p p m va
e n t Cl a
Co m p o n
ss
e n t T yp
Co m p o n
e
e n t Ta g
a l Sta te
Ch e m i c
Co m p o n
g
D ra w i n
Un i t
Round
Table 5.3-LDAR report for production facilities
Unit
Al ro y
15/92
on
Due
re p a i r
t yp e
Re pa i r
D a te o f
Re pa i r
a s u re m
ent
u re m e n
t
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
t yp e
Unit
Al ro y
Re pa i r
Plant
En e rg y I n f ra s tru ctu re s LT D
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
D a te o f
re p a i r
F i rs t Me
s t Me a s
D a te o f
Mo re
3 d ro p s th a n
per min
u te
l u e , Fi r
D e s cri p
Lo ca o n
p p m va
e n t Cl a
Co m p o n
ss
e n t T yp
Co m p o n
e
e n t Ta g
a l Sta te
Ch e m i c
Co m p o n
g
D ra w i n
Un i t
Table 5.4-LDAR report for production facilities
In the table below we provided a list of components with more than 5 Leaks during the last 12 months as follows:≥ 10,000 ppm, or more than 3 drops per minute or ≥ 1,000 ppm for PRDs
Monitoring Round
R o u n d 1- 2- 3- 4- 5- 6
16/92
Graph 5-6 – Comparison between count of components & emissions, 01/01/2021-31/12/2021.
17/92
Graph 5-7 – Comparison between total annual emissions (kg/year) , by class & year.
18/92
6. Summary by monitoring period, Round 1
19/92
In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :
1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .
2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).
This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.
Round 1
Summary of Monitoring Period
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
Table 6.1 - First measurements, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
count
Components above leak
definition
count
count
Table 6.2 – First measurement, overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.28
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%
kg/year
Total:
8
100%
0.28
100%
count
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate: 0.28 kg/year
0 registered sources with a calculated emission rate: 0 kg/year
The total calculated emission rate:
0.28 kg/year
Table 6.3 -Measurement after repair attempt, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
count
Components above leak
definition
count
count
Table 6.4 -Measurement after repair attempt, Overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
count
%
kg/year
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.28
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Total:
8
100%
0.28
100%
20/92
Table 6.5 - Form 07: First Measurement and Measurement after repair
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Components above
Annual
Components
Leak Definition
Emission Rate above
100,000 ppm
%
kg/year
Count
Components in
reading range
1,000- 100,000
ppm
Count
Components in
reading range
750-999 ppm
Components in
reading range
500-749 ppm
Count
Count
Energy Infrastructures LTD Company name
Alroy Production Unit
Components in
Components in Total Components above
reading range
reading range
Leak Definition
1-499 ppm
0 ppm
Count
Count
Round 1 Monitoring round
First measurement
Difficult to
Total
Chemical Component Class Group
Monitor Components State
Count
Count
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.0%
0.28
0.28
0
0
0
0
0
0
0
0
8
8
8
8
0
0
0
0
Energy Infrastructures LTD Company name
Alroy Production Unit
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Count
Components
above Leak
Definition
%
Annual
Emission
Rate
kg/year
Components
above 100,000
ppm
Count
Components in reading
range 1,000- 100,000
ppm
Count
Components in
reading range 750999 ppm
Count
Components in
reading range 500749 ppm
Count
Components in
reading range 1-499
ppm
Count
Components in
reading range 0
ppm
Count
Total Components
above Leak
Definition
Count
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.0%
0.28
0.28
0
0
0
0
0
0
0
0
0
0
8
8
0
0
GV
PRD
LL
HL
GV
Sampling Point
4
LL
HL
8 Subtotal G1
8 Total Components
0.28 Total Annual Emission Rate
G1
4
Round 1 Monitoring round
Measurement after
repair attempt
Difficult
Total
Chemical Component Class Group
to
Components State
Monitor
Count
Count
GV
PRD
G1
0
4
LL
HL
GV
Sampling Point
0
4
LL
HL
0
8 Subtotal G1
0
8 Total Components
0.28 Total Annual Emission Rate
21/92
Table 6.6 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Firs t Mea s urement
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.02
0
0.02
0.02
0.12
0.1
0.28
Grand Total
0.28
22/92
Table 6.7 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry After Repa ir
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.02
0
0.02
0.02
0.12
0.1
0.28
Grand Total
0.28
23/92
on
Due
re p a i r
t yp e
Re pa i r
D a te o f
Re pa i r
a s u re m
ent
u re m e n
t
t yp e
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
Re pa i r
Plant
En e rg y I n f ra s tru ctu re s LT D
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
D a te o f
re p a i r
F i rs t Me
s t Me a s
D a te o f
Mo re
3 d ro p s th a n
per min
u te
l u e , Fi r
D e s cri p
Lo ca o n
p p m va
e n t Cl a
Co m p o n
ss
e n t T yp
Co m p o n
e
e n t Ta g
a l Sta te
Ch e m i c
Co m p o n
g
D ra w i n
Un i t
Table 6.8-LDAR report for production facilities
Unit
Al ro y
24/92
Graph 6.10 – Round 1, overview by component class, kg/year.
25/92
Graph 6-11 – Round 1, overview by reading range.
26/92
Graph 6-12 – Round 1, overview by chemicals.
27/92
6. Summary by monitoring period, Round 2
28/92
In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :
1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .
2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).
This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.
Round 2
Summary of Monitoring Period
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
Table 6.1 - First measurements, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
count
Components above leak
definition
count
count
Table 6.2 – First measurement, overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.28
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%
kg/year
Total:
8
100%
0.28
100%
count
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate: 0.28 kg/year
0 registered sources with a calculated emission rate: 0 kg/year
The total calculated emission rate:
0.28 kg/year
Table 6.3 -Measurement after repair attempt, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
count
Components above leak
definition
count
count
Table 6.4 -Measurement after repair attempt, Overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
count
%
kg/year
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.28
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Total:
8
100%
0.28
100%
29/92
Table 6.5 - Form 07: First Measurement and Measurement after repair
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Components above
Annual
Components
Leak Definition
Emission Rate above
100,000 ppm
%
kg/year
Count
Components in
reading range
1,000- 100,000
ppm
Count
Components in
reading range
750-999 ppm
Components in
reading range
500-749 ppm
Count
Count
Energy Infrastructures LTD Company name
Alroy Production Unit
Components in
Components in Total Components above
reading range
reading range
Leak Definition
1-499 ppm
0 ppm
Count
Count
Round 2 Monitoring round
First measurement
Difficult to
Total
Chemical Component Class Group
Monitor Components State
Count
Count
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.0%
0.28
0.28
0
0
0
0
0
0
0
0
8
8
8
8
0
0
0
0
Energy Infrastructures LTD Company name
Alroy Production Unit
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Count
Components
above Leak
Definition
%
Annual
Emission
Rate
kg/year
Components
above 100,000
ppm
Count
Components in reading
range 1,000- 100,000
ppm
Count
Components in
reading range 750999 ppm
Count
Components in
reading range 500749 ppm
Count
Components in
reading range 1-499
ppm
Count
Components in
reading range 0
ppm
Count
Total Components
above Leak
Definition
Count
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.0%
0.28
0.28
0
0
0
0
0
0
0
0
0
0
8
8
0
0
GV
PRD
LL
HL
GV
Sampling Point
4
LL
HL
8 Subtotal G1
8 Total Components
0.28 Total Annual Emission Rate
G1
4
Round 2 Monitoring round
Measurement after
repair attempt
Difficult
Total
Chemical Component Class Group
to
Components State
Monitor
Count
Count
GV
PRD
G1
0
4
LL
HL
GV
Sampling Point
0
4
LL
HL
0
8 Subtotal G1
0
8 Total Components
0.28 Total Annual Emission Rate
30/92
Table 6.6 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Firs t Mea s urement
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.02
0
0.02
0.02
0.12
0.1
0.28
Grand Total
0.28
31/92
Table 6.7 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry After Repa ir
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.02
0
0.02
0.02
0.12
0.1
0.28
Grand Total
0.28
32/92
on
Due
re p a i r
t yp e
Re pa i r
D a te o f
Re pa i r
a s u re m
ent
u re m e n
t
t yp e
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
Re pa i r
Plant
En e rg y I n f ra s tru ctu re s LT D
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
D a te o f
re p a i r
F i rs t Me
s t Me a s
D a te o f
Mo re
3 d ro p s th a n
per min
u te
l u e , Fi r
D e s cri p
Lo ca o n
p p m va
e n t Cl a
Co m p o n
ss
e n t T yp
Co m p o n
e
e n t Ta g
a l Sta te
Ch e m i c
Co m p o n
g
D ra w i n
Un i t
Table 6.8-LDAR report for production facilities
Unit
Al ro y
33/92
Graph 6.10 – Round 2, overview by component class, kg/year.
34/92
Graph 6-11 – Round 2, overview by reading range.
35/92
Graph 6-12 – Round 2, overview by chemicals.
36/92
6. Summary by monitoring period, Round 3
37/92
In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :
1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .
2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).
This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.
Round 3
Summary of Monitoring Period
First measurement:
0 "difficult to monitor" sources.
223 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
6.06 kg/year
0 kg/year
6.06 kg/year
Table 6.1 - First measurements, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Stem Valve
20
0
0
0.00%
0
1.36
Open End
102
0
0
0.00%
0
1.78
Flange
55
0
0
0.00%
0
0.15
Connection
38
0
0
0.00%
0
2.49
Total:
223
0
0
0.00%
0
6.06
count
Components above leak
definition
count
count
Table 6.2 – First measurement, overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
223
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
6.06
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%
kg/year
Total:
223
100%
6.06
100%
count
Measurement after repair attempt:
0 "difficult to monitor" sources.
223 default-zero sources with a calculated emission rate: 6.06 kg/year
0 registered sources with a calculated emission rate: 0 kg/year
The total calculated emission rate:
6.06 kg/year
Table 6.3 -Measurement after repair attempt, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Stem Valve
20
0
0
0.00%
0
1.36
Open End
102
0
0
0.00%
0
1.78
Flange
55
0
0
0.00%
0
0.15
Connection
38
0
0
0.00%
0
2.49
Total:
223
0
0
0.00%
0
6.06
count
Components above leak
definition
count
count
Table 6.4 -Measurement after repair attempt, Overview by reading range
Reading Range
Total components
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
223
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
6.06
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Total:
223
100%
6.06
100%
count
Percentage of Total Components
Annual Emission Rate
%
kg/year
38/92
Table 6.5 - Form 07: First Measurement and Measurement after repair
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Components above
Annual
Components
Leak Definition
Emission Rate above
100,000 ppm
%
2
2
2
2
2
2
1
1
1
1
1
1
kg/year
Count
Components in
reading range
1,000- 100,000
ppm
Count
Components in
reading range
750-999 ppm
Components in
reading range
500-749 ppm
Count
Count
Energy Infrastructures LTD Company name
Alroy Production Unit
Components in
Components in Total Components above
reading range
reading range
Leak Definition
1-499 ppm
0 ppm
Count
Count
Round 3 Monitoring round
First measurement
Difficult to
Total
Chemical Component Class Group
Monitor Components State
Count
Count
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.28
0
0
0
0
8
8
0
0
0.0%
1.36
0
0
0
0
20
20
0
0
0.0%
1.78
0
0
0
0
102
102
0
0
0.0%
3.14
0
0
0
0
122
122
0
0
0.0%
0.15
0
0
0
0
55
55
0
0
0.0%
2.49
0
0
0
0
38
38
0
0
0.0%
0.0%
2.64
6.06
0
0
0
0
0
0
0
0
93
223
93
223
0
0
0
0
Energy Infrastructures LTD Company name
Alroy Production Unit
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
2
2
2
2
2
2
1
1
1
1
1
1
Count
Components
above Leak
Definition
%
Annual
Emission
Rate
kg/year
Components
above 100,000
ppm
Count
Components in reading
range 1,000- 100,000
ppm
Count
Components in
reading range 750999 ppm
Count
Components in
reading range 500749 ppm
Count
Components in
reading range 1-499
ppm
Count
Components in
reading range 0
ppm
Count
Total Components
above Leak
Definition
Count
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.28
0
0
0
0
0
8
0
0.0%
1.36
0
0
0
0
0
20
0
0.0%
1.78
0
0
0
0
0
102
0
0.0%
3.14
0
0
0
0
0
122
0
0.0%
0.15
0
0
0
0
0
55
0
0.0%
2.49
0
0
0
0
0
38
0
0.0%
0.0%
2.64
6.06
0
0
0
0
0
0
0
0
0
0
93
223
0
0
GV
PRD
LL
HL
GV
Sampling Point
4
LL
HL
8 Subtotal G1
GV
Stem Valve
20
LL
HL
GV
Open End
102
LL
HL
122 Subtotal G2
GV
Flange
55
LL
HL
GV
Connection
38
LL
HL
93 Subtotal G3
223 Total Components
6.06 Total Annual Emission Rate
G1
4
G2
G3
Round 3 Monitoring round
Measurement after
repair attempt
Difficult
Total
Chemical Component Class Group
to
Components State
Monitor
Count
Count
GV
PRD
G1
0
4
LL
HL
GV
Sampling Point
0
4
LL
HL
0
8 Subtotal G1
GV
Stem Valve
G2
0
20
LL
HL
GV
Open End
0
102
LL
HL
0
122 Subtotal G2
GV
Flange
G3
0
55
LL
HL
GV
Connection
0
38
LL
HL
0
93 Subtotal G3
0
223 Total Components
6.06 Total Annual Emission Rate
39/92
Table 6.6 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Firs t Mea s urement
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Stem Va lve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.14
0.01
0.07
0.14
0.55
0.46
1.37
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.18
0.02
0.09
0.18
0.71
0.61
1.79
40/92
Table 6.6 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Firs t Mea s urement
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
Fla nge
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.25
0.02
0.12
0.25
1
0.85
2.49
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.6
0.05
0.31
0.6
2.44
2.07
6.07
Grand Total
6.07
41/92
Table 6.7 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry After Repa ir
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Stem Va lve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.14
0.01
0.07
0.14
0.55
0.46
1.37
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.18
0.02
0.09
0.18
0.71
0.61
1.79
42/92
Table 6.7 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry After Repa ir
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
Fla nge
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.25
0.02
0.12
0.25
1
0.85
2.49
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.6
0.05
0.31
0.6
2.44
2.07
6.07
Grand Total
6.07
43/92
on
Due
re p a i r
t yp e
Re pa i r
D a te o f
Re pa i r
a s u re m
ent
u re m e n
t
t yp e
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
Re pa i r
Plant
En e rg y I n f ra s tru ctu re s LT D
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
D a te o f
re p a i r
F i rs t Me
s t Me a s
D a te o f
Mo re
3 d ro p s th a n
per min
u te
l u e , Fi r
D e s cri p
Lo ca o n
p p m va
e n t Cl a
Co m p o n
ss
e n t T yp
Co m p o n
e
e n t Ta g
a l Sta te
Ch e m i c
Co m p o n
g
D ra w i n
Un i t
Table 6.8-LDAR report for production facilities
Unit
Al ro y
44/92
Graph 6.10 – Round 3, overview by component class, kg/year.
45/92
Graph 6-11 – Round 3, overview by reading range.
46/92
Graph 6-12 – Round 3, overview by chemicals.
47/92
6. Summary by monitoring period, Round 4
48/92
In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :
1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .
2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).
This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.
Round 4
Summary of Monitoring Period
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
Table 6.1 - First measurements, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
count
Components above leak
definition
count
count
Table 6.2 – First measurement, overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.28
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%
kg/year
Total:
8
100%
0.28
100%
count
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate: 0.28 kg/year
0 registered sources with a calculated emission rate: 0 kg/year
The total calculated emission rate:
0.28 kg/year
Table 6.3 -Measurement after repair attempt, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
count
Components above leak
definition
count
count
Table 6.4 -Measurement after repair attempt, Overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
count
%
kg/year
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.28
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Total:
8
100%
0.28
100%
49/92
Table 6.5 - Form 07: First Measurement and Measurement after repair
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Components above
Annual
Components
Leak Definition
Emission Rate above
100,000 ppm
%
kg/year
Count
Components in
reading range
1,000- 100,000
ppm
Count
Components in
reading range
750-999 ppm
Components in
reading range
500-749 ppm
Count
Count
Energy Infrastructures LTD Company name
Alroy Production Unit
Components in
Components in Total Components above
reading range
reading range
Leak Definition
1-499 ppm
0 ppm
Count
Count
Round 4 Monitoring round
First measurement
Difficult to
Total
Chemical Component Class Group
Monitor Components State
Count
Count
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.0%
0.28
0.28
0
0
0
0
0
0
0
0
8
8
8
8
0
0
0
0
Energy Infrastructures LTD Company name
Alroy Production Unit
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Count
Components
above Leak
Definition
%
Annual
Emission
Rate
kg/year
Components
above 100,000
ppm
Count
Components in reading
range 1,000- 100,000
ppm
Count
Components in
reading range 750999 ppm
Count
Components in
reading range 500749 ppm
Count
Components in
reading range 1-499
ppm
Count
Components in
reading range 0
ppm
Count
Total Components
above Leak
Definition
Count
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.0%
0.28
0.28
0
0
0
0
0
0
0
0
0
0
8
8
0
0
GV
PRD
LL
HL
GV
Sampling Point
4
LL
HL
8 Subtotal G1
8 Total Components
0.28 Total Annual Emission Rate
G1
4
Round 4 Monitoring round
Measurement after
repair attempt
Difficult
Total
Chemical Component Class Group
to
Components State
Monitor
Count
Count
GV
PRD
G1
0
4
LL
HL
GV
Sampling Point
0
4
LL
HL
0
8 Subtotal G1
0
8 Total Components
0.28 Total Annual Emission Rate
50/92
Table 6.6 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Firs t Mea s urement
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.02
0
0.02
0.02
0.12
0.1
0.28
Grand Total
0.28
51/92
Table 6.7 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry After Repa ir
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.02
0
0.02
0.02
0.12
0.1
0.28
Grand Total
0.28
52/92
on
Due
re p a i r
t yp e
Re pa i r
D a te o f
Re pa i r
a s u re m
ent
u re m e n
t
t yp e
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
Re pa i r
Plant
En e rg y I n f ra s tru ctu re s LT D
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
D a te o f
re p a i r
F i rs t Me
s t Me a s
D a te o f
Mo re
3 d ro p s th a n
per min
u te
l u e , Fi r
D e s cri p
Lo ca o n
p p m va
e n t Cl a
Co m p o n
ss
e n t T yp
Co m p o n
e
e n t Ta g
a l Sta te
Ch e m i c
Co m p o n
g
D ra w i n
Un i t
Table 6.8-LDAR report for production facilities
Unit
Al ro y
53/92
Graph 6.10 – Round 4, overview by component class, kg/year.
54/92
Graph 6-11 – Round 4, overview by reading range.
55/92
Graph 6-12 – Round 4, overview by chemicals.
56/92
6. Summary by monitoring period, Round 5
57/92
In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :
1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .
2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).
This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.
Round 5
Summary of Monitoring Period
First measurement:
0 "difficult to monitor" sources.
130 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
3.46 kg/year
0 kg/year
3.46 kg/year
Table 6.1 - First measurements, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Stem Valve
20
0
0
0.00%
0
1.38
Open End
102
0
0
0.00%
0
1.8
Total:
130
0
0
0.00%
0
3.46
count
Components above leak
definition
count
count
Table 6.2 – First measurement, overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
130
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
3.46
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%
kg/year
Total:
130
100%
3.46
100%
count
Measurement after repair attempt:
0 "difficult to monitor" sources.
130 default-zero sources with a calculated emission rate: 3.46 kg/year
0 registered sources with a calculated emission rate: 0 kg/year
The total calculated emission rate:
3.46 kg/year
Table 6.3 -Measurement after repair attempt, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Stem Valve
20
0
0
0.00%
0
1.38
Open End
102
0
0
0.00%
0
1.8
Total:
130
0
0
0.00%
0
3.46
count
Components above leak
definition
count
count
Table 6.4 -Measurement after repair attempt, Overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
count
%
kg/year
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
130
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
3.46
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Total:
130
100%
3.46
100%
58/92
Table 6.5 - Form 07: First Measurement and Measurement after repair
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Components above
Annual
Components
Leak Definition
Emission Rate above
100,000 ppm
%
2
2
2
2
2
2
kg/year
Count
Components in
reading range
1,000- 100,000
ppm
Count
Components in
reading range
750-999 ppm
Components in
reading range
500-749 ppm
Count
Count
Energy Infrastructures LTD Company name
Alroy Production Unit
Components in
Components in Total Components above
reading range
reading range
Leak Definition
1-499 ppm
0 ppm
Count
Count
Round 5 Monitoring round
First measurement
Difficult to
Total
Chemical Component Class Group
Monitor Components State
Count
Count
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.28
0
0
0
0
8
8
0
0
0.0%
1.38
0
0
0
0
20
20
0
0
0.0%
1.8
0
0
0
0
102
102
0
0
0.0%
0.0%
3.18
3.46
0
0
0
0
0
0
0
0
122
130
122
130
0
0
0
0
Energy Infrastructures LTD Company name
Alroy Production Unit
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
2
2
2
2
2
2
Count
Components
above Leak
Definition
%
Annual
Emission
Rate
kg/year
Components
above 100,000
ppm
Count
Components in reading
range 1,000- 100,000
ppm
Count
Components in
reading range 750999 ppm
Count
Components in
reading range 500749 ppm
Count
Components in
reading range 1-499
ppm
Count
Components in
reading range 0
ppm
Count
Total Components
above Leak
Definition
Count
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.28
0
0
0
0
0
8
0
0.0%
1.38
0
0
0
0
0
20
0
0.0%
1.8
0
0
0
0
0
102
0
0.0%
0.0%
3.18
3.46
0
0
0
0
0
0
0
0
0
0
122
130
0
0
GV
PRD
LL
HL
GV
Sampling Point
4
LL
HL
8 Subtotal G1
GV
Stem Valve
20
LL
HL
GV
Open End
102
LL
HL
122 Subtotal G2
130 Total Components
3.46 Total Annual Emission Rate
G1
4
G2
Round 5 Monitoring round
Measurement after
repair attempt
Difficult
Total
Chemical Component Class Group
to
Components State
Monitor
Count
Count
GV
PRD
G1
0
4
LL
HL
GV
Sampling Point
0
4
LL
HL
0
8 Subtotal G1
GV
Stem Valve
G2
0
20
LL
HL
GV
Open End
0
102
LL
HL
0
122 Subtotal G2
0
130 Total Components
3.46 Total Annual Emission Rate
59/92
Table 6.6 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Firs t Mea s urement
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Stem Va lve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.14
0.01
0.07
0.14
0.55
0.47
1.38
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.18
0.02
0.09
0.18
0.72
0.61
1.8
60/92
Table 6.6 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Firs t Mea s urement
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
All
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.34
0.03
0.18
0.34
1.39
1.18
3.46
Grand Total
3.46
61/92
Table 6.7 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry After Repa ir
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Stem Va lve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.14
0.01
0.07
0.14
0.55
0.47
1.38
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.18
0.02
0.09
0.18
0.72
0.61
1.8
62/92
Table 6.7 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry After Repa ir
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
All
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.34
0.03
0.18
0.34
1.39
1.18
3.46
Grand Total
3.46
63/92
on
Due
re p a i r
t yp e
Re pa i r
D a te o f
Re pa i r
a s u re m
ent
u re m e n
t
t yp e
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
Re pa i r
Plant
En e rg y I n f ra s tru ctu re s LT D
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
D a te o f
re p a i r
F i rs t Me
s t Me a s
D a te o f
Mo re
3 d ro p s th a n
per min
u te
l u e , Fi r
D e s cri p
Lo ca o n
p p m va
e n t Cl a
Co m p o n
ss
e n t T yp
Co m p o n
e
e n t Ta g
a l Sta te
Ch e m i c
Co m p o n
g
D ra w i n
Un i t
Table 6.8-LDAR report for production facilities
Unit
Al ro y
64/92
Graph 6.10 – Round 5, overview by component class, kg/year.
65/92
Graph 6-11 – Round 5, overview by reading range.
66/92
Graph 6-12 – Round 5, overview by chemicals.
67/92
6. Summary by monitoring period, Round 6
68/92
In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :
1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .
2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).
This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.
Round 6
Summary of Monitoring Period
First measurement:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate:
0 registered sources with a calculated emission rate:
The total calculated emission rate:
0.28 kg/year
0 kg/year
0.28 kg/year
Table 6.1 - First measurements, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
count
Components above leak
definition
count
count
Table 6.2 – First measurement, overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.28
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
%
kg/year
Total:
8
100%
0.28
100%
count
Measurement after repair attempt:
0 "difficult to monitor" sources.
8 default-zero sources with a calculated emission rate: 0.28 kg/year
0 registered sources with a calculated emission rate: 0 kg/year
The total calculated emission rate:
0.28 kg/year
Table 6.3 -Measurement after repair attempt, overview by component class
Component Class
Total components
Components 1-999ppm
PRD
4
0
% emission rate of components Emission rate of components Total annual emission rate (all
above leak definition
above leak definition
components)
%
kg/year
kg/year
0
0.00%
0
0.14
Sampling Point
4
0
0
0.00%
0
0.14
Total:
8
0
0
0.00%
0
0.28
count
Components above leak
definition
count
count
Table 6.4 -Measurement after repair attempt, Overview by reading range
Reading Range
Total components
Percentage of Total Components
Annual Emission Rate
count
%
kg/year
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above 1,000 ppm
Difficult to Monitor
8
0
0
0
0
0
0
0
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.28
0
0
0
0
0
0
0
Percentage of
Total Annual Emission Rate
%
100.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
0.00%
Total:
8
100%
0.28
100%
69/92
Table 6.5 - Form 07: First Measurement and Measurement after repair
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Components above
Annual
Components
Leak Definition
Emission Rate above
100,000 ppm
%
kg/year
Count
Components in
reading range
1,000- 100,000
ppm
Count
Components in
reading range
750-999 ppm
Components in
reading range
500-749 ppm
Count
Count
Energy Infrastructures LTD Company name
Alroy Production Unit
Components in
Components in Total Components above
reading range
reading range
Leak Definition
1-499 ppm
0 ppm
Count
Count
Round 6 Monitoring round
First measurement
Difficult to
Total
Chemical Component Class Group
Monitor Components State
Count
Count
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.14
0
0
0
0
4
4
0
0
0.0%
0.0%
0.28
0.28
0
0
0
0
0
0
0
0
8
8
8
8
0
0
0
0
Energy Infrastructures LTD Company name
Alroy Production Unit
Monitoring
Frequency
cycles/year
6
6
6
6
6
6
Count
Components
above Leak
Definition
%
Annual
Emission
Rate
kg/year
Components
above 100,000
ppm
Count
Components in reading
range 1,000- 100,000
ppm
Count
Components in
reading range 750999 ppm
Count
Components in
reading range 500749 ppm
Count
Components in
reading range 1-499
ppm
Count
Components in
reading range 0
ppm
Count
Total Components
above Leak
Definition
Count
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.14
0
0
0
0
0
4
0
0.0%
0.0%
0.28
0.28
0
0
0
0
0
0
0
0
0
0
8
8
0
0
GV
PRD
LL
HL
GV
Sampling Point
4
LL
HL
8 Subtotal G1
8 Total Components
0.28 Total Annual Emission Rate
G1
4
Round 6 Monitoring round
Measurement after
repair attempt
Difficult
Total
Chemical Component Class Group
to
Components State
Monitor
Count
Count
GV
PRD
G1
0
4
LL
HL
GV
Sampling Point
0
4
LL
HL
0
8 Subtotal G1
0
8 Total Components
0.28 Total Annual Emission Rate
70/92
Table 6.6 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry Firs t Mea s urement
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.02
0
0.02
0.02
0.12
0.1
0.28
Grand Total
0.28
71/92
Table 6.7 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2021- 31/12/2021
Report Chemica l Summa ry After Repa ir
Equa tion Set:
SOCMI
Units of Mea s urement:
KG/yea r
Report Da te: 17.02.2022
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
Emissions
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.01
0
0.01
0.01
0.06
0.05
0.14
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.02
0
0.02
0.02
0.12
0.1
0.28
Grand Total
0.28
72/92
on
Due
re p a i r
t yp e
Re pa i r
D a te o f
Re pa i r
a s u re m
ent
u re m e n
t
t yp e
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
Re pa i r
Plant
En e rg y I n f ra s tru ctu re s LT D
d a te
a e r r eo f r e m e a s u r e
pair a
m
empt ent
ppm
a e r r ev a l u e o f r e m e
pair a
a
e m p t s u re m e n t
D a te o f
re p a i r
F i rs t Me
s t Me a s
D a te o f
Mo re
3 d ro p s th a n
per min
u te
l u e , Fi r
D e s cri p
Lo ca o n
p p m va
e n t Cl a
Co m p o n
ss
e n t T yp
Co m p o n
e
e n t Ta g
a l Sta te
Ch e m i c
Co m p o n
g
D ra w i n
Un i t
Table 6.8-LDAR report for production facilities
Unit
Al ro y
73/92
Graph 6.10 – Round 6, overview by component class, kg/year.
74/92
Graph 6-11 – Round 6, overview by reading range.
75/92
Graph 6-12 – Round 6, overview by chemicals.
76/92
Attachments
77/92
7.1 General remarks
Table 7-1-1 - Monitored components
Unit
Round 1
In scope
Alroy
Total
Round 2
Measured
In scope
Round 3
Measured
In scope
Round 4
Measured
In scope
Round 5
Measured
In scope
Round 6
Measured
In scope
Measured
8
8
8
8
223
223
8
8
130
130
8
8
8
8
8
8
223
223
8
8
130
130
8
8
7.2 Project schedule (excluding measurements after repair)
Unit
Alroy
Start date
Round 1
End date
06/01/2021
06/01/2021
Start date
Round 2
End date
21/02/2021
21/02/2021
Start date
Round 3
End date
07/06/2021
07/06/2021
Start date
Round 4
End date
23/08/2021
23/08/2021
Start date
Round 5
End date
20/10/2021
20/10/2021
Start date
Round 6
End date
12/12/2021
12/12/2021
78/92
7.3 Methodology
Definitions
Chemical State:
Gas/Vapor:
Light Liquid:
stream which is in process conditions under gaseous or vapor form.
a liquid having a VOC content greater than 10% (by volume)
that evaporates at 150°C
Heavy Liquid:
a liquid having a VOC content of 10% or less (by volume)
that evaporates at 150°C
Leak definition:
1,000 ppm (all sources)
Difficult to monitor components:
Any component positioned at a level higher than five meters above ground level or any
component situated at a distance further than two meters from a platform and which
cannot be accessed by employees in a safe way.
Any component which access requires the elevation of a person to a level higher
than two meters above regular surfaces, and which cannot be accessed safetly.
Registered components:
Components with a leak value greater than 0 ppm.
Default-zero:
This equation is valid for sources with a leak value of 0 ppm.
A fixed EPA emission calculation rule is used for all these components.
Total components:
All of the existing active components.
Total measured components:
All of the components, measured in specific monitoring round.
Methodology
Formulas:
Measured ppm values are converted to emission loss (kg/year) and these
calculations are based on the E.P.A. “Correlation method”
Modified Trapezoidal Emission Calculation Method:
The modified trapezoid method assumes that the mass leak rate changes
linearly between any two monitoring points, except for periods between leak
leak detection and repair; the leak monitor reading is used from the time the
leak is detected to the time it is repaired (i.e., re-screened).
Cumulative data:
In "Cumulative data" tables we provide the results of all of the measurements
that performed from the beginning of the year till the end of current monitoring
period (quarter). We also calculate the real sum of previous emissions based on
the all rounds of the measurements (before and after repairing attempts).
(US EPA "Emission Estimation Protocol for Petroleum Refineries")
79/92
Table 7.4 - Calibration log list
Plant
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Round
1
2
2
2
3
3
3
3
3
3
3
3
3
4
4
5
5
5
5
5
5
5
5
Equipment Type
TVA2020
TVA2020
TVA1000B
TVA1000B
TVA1000B
TVA2020
TVA1000B
TVA2020
TVA2020
TVA1000B
TVA1000B
TVA2020
TVA2020
TVA2020
TVA1000B
TVA1000B
TVA2020
TVA1000B
TVA1000B
TVA2020
TVA2020
TVA2020
TVA2020
Analyzer Type
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
Ultra-Zero
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Span Gas
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Span gas Cylinder No
ET0022865
ET0022865
ET0022842
ET0022842
ET0022865
ET0022865
ET0022865
ET0022865
ET0022842
ET0022842
ET0022842
ET0022842
ET0022842
ET0022842
ET0022842
ET0022842
ET0022842
ET0022842
12663
12663
12663
12663
12663
Span concentration
ppm
995
995
995
995
995
995
995
995
995
995
995
995
995
995
995
995
995
995
1,000
1,000
1,000
1,000
1,000
Check gas
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Check gas Cylinder No
FF524456
FF524456
FF524456
FF524456
FF524456
FF524456
FF524456
FF524456
FF32161
FF32161
FF32161
FF32161
FF32161
FF32161
FF32161
FF32161
FF32161
FF32161
93531
93531
93531
93531
93531
Check gas
concentration
(A)
ppm
504
504
504
504
504
504
504
504
510
510
510
510
510
510
510
510
510
510
500
500
500
500
500
Date
06-Jan-2021
21-Feb-2021
02-Mar-2021
02-Mar-2021
06-Jun-2021
06-Jun-2021
07-Jun-2021
07-Jun-2021
08-Jun-2021
08-Jun-2021
15-Jun-2021
15-Jun-2021
20-Jun-2021
23-Aug-2021
19-Sep-2021
20-Oct-2021
20-Oct-2021
07-Nov-2021
12-Dec-2021
30-Dec-2021
20-Jan-2022
03-Feb-2022
06-Feb-2022
Equipment No
5
5
3
1
9
5
9
5
5
3
3
5
5
5
2
9
5
9
9
5
5
5
5
Equipment Serial
No
202016061436
202016061436
0115248937
0715622657
33461300
202016061436
33461300
202016061436
202016061436
0115248937
0115248937
202016061436
202016061436
202016061436
0115248185
33461300
202016061436
33461300
33461300
202016061436
202016061436
202016061436
202016061436
Check
1-st check 2-st check
(A1)
(A2)
ppm
ppm
512
513
501
507
503
505
549
496
507
509
512
510
494
491
503
496
507
506
508
507
481
481
495
491
512
510
490
488
510
514
509
507
496
504
510
512
490
488
509
512
513
509
509
504
514
514
Calibration error
3-st check
(A3)
ppm
511
496
505
495
504
507
498
507
506
508
480
503
511
495
508
503
508
506
499
506
506
506
515
Result
(CP)
1.59%
-0.53%
0.07%
1.85%
0.53%
1.12%
-1.92%
-0.40%
-0.72%
-0.46%
-5.75%
-2.68%
0.20%
-3.73%
0.13%
-0.72%
-1.44%
-0.13%
-1.53%
1.80%
1.87%
1.27%
2.87%
80/92
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
81/92
82/92
83/92
84/92
85/92
86/92
Table 7.6 - Stream Composition Summary
Stream Name
Gasoline
Petroleum
Stream Content
TOLUENE-34 %, n-Octane-40 %, METHYL TERT-BUTYL ETHER-10 %, CYCLOHEXANE-5 %, BENZENE-1 %, 1-Butene-10 %
TOLUENE-7.5 %, n-Octane-55.3 %, CYCLOHEXANE-35.2 %, BENZENE-2 %
Stream Content Dates
TVA
A=0.42, B=0.29
A=0.39, B=0.31
MiniRAE 10.6
MiniRAE 11.7
87/92
Table 7.7 - Quarterly Validation of LDAR Devices
Date: 30-Dec-2020
Equipment
Equip.Ser. No
No
1
2
3
5
6
7
8
9
Quarter:
Equipment
Analyzer Span Gas
Type
0715622657 TVA1000B
0115248185 TVA1000B
0115248937 TVA1000B
202016061436 TVA2020
MiniRAE2000
110219070002
NEO
05355151349 TVA1000B
33461300
TVA1000B
Qua rterly Va lida tion Qua ter 1
FID
FID
FID
FID
PID
PID
FID
FID
Sampling Flow Rate
Check
1
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Span gas
Cylinder No
ET0022842
ET0022842
ET0022842
ET0022842
EA0010369
EA0010369
ET0022842
ET0022842
Span Gas
Concentration
Sampling
Flow Rate
ppm
l/min
995
995
995
995
996
996
995
995
0.94
0.9
0.91
1.13
0.51
0.52
0.98
1.11
Accuracy Check
Result Check Gas
Check gas
Cylinder No
OK Methane
OK Methane
OK Methane
OK Methane
OK Isobutylene
OK Isobutylene
OK Methane
OK Methane
FF16599
FF16599
FF16599
FF16599
995-286088
995-286088
FF16599
FF16599
Check Gas
Concentration
Response Time
90% of Response
1-st
2nd
3rd Calibration
Time 1
Result Span
check check check
error
ppm
501
501
501
501
500
500
501
501
504
502
498
501
510
519
499
501
503
505
501
502
510
517
501
502
506
505
502
503
511
520
502
502
0.46%
0.4%
-0.33%
0%
1.92%
3.59%
-0.27%
-0.07%
OK
OK
OK
OK
OK
OK
OK
OK
Response
Time 2
Response
Time 3 Result
ppm
sec
sec
sec
895.5
895.5
895.5
895.5
896.9
896.9
895.5
895.5
4
4
4
4
6
6
4
4
4
4
4
4
5
6
4
4
4
4
4
4
5
6
4
4
88/92
OK
OK
OK
OK
OK
OK
OK
OK
Table 7.8 - Quarterly Validation of LDAR Devices
Date: 30-Mar-2021
Equipment
Equip.Ser. No
No
1
2
3
5
6
7
8
9
Quarter:
Equipment
Analyzer Span Gas
Type
0715622657 TVA1000B
0115248185 TVA1000B
0115248937 TVA1000B
202016061436 TVA2020
MiniRAE2000
110219070002
NEO
05355151349 TVA1000B
33461300
TVA1000B
Qua rterly Va lida tion Qua ter 2
FID
FID
FID
FID
PID
PID
FID
FID
Sampling Flow Rate
Check
2
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Span gas
Cylinder No
ET0022842
ET0022842
ET0022842
ET0022842
EA0010369
EA0010369
ET0022842
ET0022842
Span Gas
Concentration
Sampling
Flow Rate
ppm
l/min
995
995
995
995
996
996
995
995
1.1
0.92
1.36
1.2
0.49
0.44
1.24
1.36
Accuracy Check
Result Check Gas
Check gas
Cylinder No
OK Methane
OK Methane
OK Methane
OK Methane
OK Isobutylene
OK Isobutylene
OK Methane
OK Methane
FF16599
FF16599
FF16599
FF16599
995-286088
995-286088
FF16599
FF16599
Check Gas
Concentration
Response Time
90% of Response
1-st
2nd
3rd Calibration
Time 1
Result Span
check check check
error
ppm
501
501
501
501
500
500
501
501
507
505
506
499
504
491
504
501
509
503
504
502
504
492
509
502
506
504
504
501
504
492
508
501
1.06%
0.4%
0.53%
-0.27%
0.66%
-1.8%
1%
-0.13%
OK
OK
OK
OK
OK
OK
OK
OK
Response
Time 2
Response
Time 3 Result
ppm
sec
sec
sec
895.5
895.5
895.5
895.5
896.9
896.9
895.5
895.5
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
89/92
OK
OK
OK
OK
OK
OK
OK
OK
Table 7.9 - Quarterly Validation of LDAR Devices
Date: 30-Jun-2021
Equipment
Equip.Ser. No
No
1
2
3
5
6
7
8
9
Quarter:
Equipment
Analyzer Span Gas
Type
0715622657 TVA1000B
0115248185 TVA1000B
0115248937 TVA1000B
202016061436 TVA2020
MiniRAE2000
110219070002
NEO
05355151349 TVA1000B
33461300
TVA1000B
Qua rterly Va lida tion Qua ter 3
FID
FID
FID
FID
PID
PID
FID
FID
Sampling Flow Rate
Check
3
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Span gas
Cylinder No
ET0022842
ET0022842
ET0022842
ET0022842
EA0010369
EA0010369
ET0022842
ET0022842
Span Gas
Concentration
Sampling
Flow Rate
ppm
l/min
995
995
995
995
996
996
995
995
1.07
0.92
1.13
1.08
0.49
0.53
1.12
1.21
Accuracy Check
Result Check Gas
Check gas
Cylinder No
OK Methane
OK Methane
OK Methane
OK Methane
OK Isobutylene
OK Isobutylene
OK Methane
OK Methane
FF16599
FF16599
FF16599
FF16599
995-286088
995-286088
FF16599
FF16599
Check Gas
Concentration
Response Time
90% of Response
1-st
2nd
3rd Calibration
Time 1
Result Span
check check check
error
ppm
501
501
501
501
500
500
501
501
511
501
501
507
510
511
508
501
510
502
499
506
509
512
508
503
510
498
498
504
509
512
507
501
1.66%
-0.33%
-0.53%
0.73%
1.72%
2.19%
1.13%
-0.07%
OK
OK
OK
OK
OK
OK
OK
OK
Response
Time 2
Response
Time 3 Result
ppm
sec
sec
sec
895.5
895.5
895.5
895.5
896.9
896.9
895.5
895.5
4
4
4
4
5
5
4
4
4
4
4
4
5
4
4
4
4
4
4
4
5
5
4
4
90/92
OK
OK
OK
OK
OK
OK
OK
OK
Table 7.10 - Quarterly Validation of LDAR Devices
Date: 30-Sep-2021
Equipment
Equip.Ser. No
No
1
2
3
5
6
7
8
9
Quarter:
Equipment
Analyzer Span Gas
Type
0715622657 TVA1000B
0115248185 TVA1000B
0115248937 TVA1000B
202016061436 TVA2020
MiniRAE2000
110219070002
NEO
05355151349 TVA1000B
33461300
TVA1000B
Qua rterly Va lida tion Qua ter 4
FID
FID
FID
FID
PID
PID
FID
FID
Sampling Flow Rate
Check
4
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Span gas
Cylinder No
ET0022865
ET0022865
ET0022865
ET0022865
EA0010369
EA0010369
ET0022865
ET0022865
Span Gas
Concentration
Sampling
Flow Rate
ppm
l/min
995
995
995
995
996
996
995
995
0.91
1
1.22
1.15
0.51
0.54
0.96
1.26
Accuracy Check
Result Check Gas
Check gas
Cylinder No
OK Methane
OK Methane
OK Methane
OK Methane
OK Isobutylene
OK Isobutylene
OK Methane
OK Methane
FF16599
FF16599
FF16599
FF16599
995-286088
995-286088
FF16599
FF16599
Check Gas
Concentration
Response Time
90% of Response
1-st
2nd
3rd Calibration
Time 1
Result Span
check check check
error
ppm
501
501
501
501
500
500
501
501
506
502
504
503
500
501
498
507
505
503
501
501
599
500
497
504
503
501
499
504
500
501
501
505
0.53%
0%
-0.13%
0.13%
6.45%
-0.01%
-0.66%
0.66%
OK
OK
OK
OK
OK
OK
OK
OK
Response
Time 2
Response
Time 3 Result
ppm
sec
sec
sec
895.5
895.5
895.5
895.5
896.9
896.9
895.5
895.5
4
4
4
3
4
5
5
4
3
4
3
4
4
5
5
4
4
4
4
4
4
4
5
4
91/92
OK
OK
OK
OK
OK
OK
OK
OK
Table 7.11 - PRODUCTION HOURS TEMPLATE
Plant
Energy Infrastructures LTD
Unit
Alroy
Alroy
Drawing
6006-100-006
6006-100-007
Stream Name
Gasoline
Gasoline
Remark
Annual Production Hours
8,760
8,760
Q1
01/01-31/03
Quarter =
Quarterly Production hours
2,160
2,160
Q2
01/04-30/06
Quarter =
Quarterly Production hours
2,184
2,184
Q3
01/07-30/09
Quarter =
Quarterly Production hours
2,208
2,208
Q4
01/10-31/12
Quarter =
Quarterly Production hours
2,208
2,208
92/92
ספח ג'
דוגמת חישוב עבור מיכל גג חיצו י צף מס' 2המאחסן קרוסין
3013.18-034-T2
3013.18-025
28/02/2022
18/30
3013.18-036.doc
T2 - kerosene
External Floating roof
1. Tank data
Diameter of the tank
D
Effective height of the stock liquid (while
roof landing episode)
hle
Shell Color and condition
α
Roof color and condition
α
Tank paint solar absorptance
α
Vapor space outage (while roof landing
episode)
HVO
m
feet
m
feet
color
condition
color
condition
dimensionless
m
Tank data
--Tank data
--חום
טובה
לבן
טוב
48.77
160.01
11.00
0.58
Table 7.1-6
Brown
0.17
Table 7.1-6
0.38
Table 7.1-6
Possible to use also equation
1-15
assumption - equal to legs height
feet
11.00
Volume of the vapor space (while roof
landing episode)
Breather vent pressure setting
VV
ft
3
VV=PI()*D /4*Hvo
221,185
Equation 1-3
ΔPBP
psi
Typical value
0.50
Equation 1-11
Breather vent vacuum setting
ΔPBV
psi
Typical value
0.00
Equation 1-11
Breather vent pressure setting range
ΔPB
psi
PB PBP PBV
0.50
Equation 1-11
2
2. Material data - קרוסין
Stock vapor molecular weight
MV
Density of the liquid inside the tank
Wl
Vapor density
WV
True vapor pressure of the stock liquid
P
Vapor pressure at daily average liquid
surface temperature
Vapor pressure at the daily maximum
liquid surface temperature, psia
Vapor pressure at the daily minimum
liquid surface temperature
Daily vapor pressure range
3013.18-034.xls - 2
gr/gr-mole
lb/lb-mole
g/ml
lb/gal
kg/m^3
lb/ft3
msds data
130
msds data
--msds data
---
0.80
6.68
4.5
0.28
mm Hg
PEI data
0.833
psia
--הנחה:
Pv=nRT -->
P2=P1*(T2/T1)
0.02
0.02
0.02
0.00
PVA
psia
PVX
psia
PVN
psia
T1(k)=20C+273
T2(k)=37.5C+273
ΔPV
psia
PV PVX PVN
1/3
0
at 20°C
0.02
Equation 1-9
28/02/2022
3. Operation data
Number of days that the tank stands idle
(on roof landing episode)
Number of degassing and cleaning
episode
Number of roof landing episode
nd
days/landing episode
site data
4
landing episode/year
site data
0.07
landing episode/year
site data
0.07
Tanks Program
--Tanks Program
---
38
17
74
33
16
T2 - B&W 2021
Tanks Program
---
59
27
T2 - DFloating 2019
lb per emptying
Tanks Program
61
Kg per emptying
---
28
4. Normal operation (Tanks program)
lb per year
Kg per year
lb per year
Kg per year
Kg per year
Working (withdrawal) losses
Total emissions (Breathing & Working)
Breathing (standing) losses
5. Degassing and Cleaning (Tanks program)
Degassing: emission from one turnover
Edegass-floating lb per emptying
of floating roof
Kg per emptying
Degassing: fixed roof with a height of
roof legs
Edegass-legs
Liquid fraction in sludge
Fliquid
Sludge volume
Sludge weight
Vs
Ws
Cleaning emissions
Ecleaning
Total Degassing and Cleaning emissions
Edegass-total
3013.18-034.xls - 2
0.8
m3 per emptying
Kg per emptying
lb per emptying
Kg per emptying
lb per emptying
Kg per emptying
Ecleaning = Ws * (1-Fliquid)
Edegass-total =
Edegass-floating + Edegass-legs + Ecleaning
2/3
T2 - B&W 2021
T2- DFixed 2019
(Only working losses)
Tanks FAQ - degassing and
cleaning
70
56,000
24,692
11,200
24,811
11,254
28/02/2022
6. Roof landing
Daily average liquid surface temperature
TLA
°R
Daily vapor temperature range
Daily maximum liquid surface
temperature
ΔTV
°R
TLX
Daily minimum liquid surface temperature
Liquid bulk temperature
Max standing idle losses during roof
landing
T LA 0 .44 T AA 0 .56 T B 0 .0079 * * I
532.17
Equation 1-26
TV 0.72 T A 0.028 * * I
32.95
Equation 1-8
°R
TLX = TLA + 0.25*ΔTV
540.41
Figure 7.1-17
TLN
°R
TLN = TLA - 0.25*ΔTV
523.93
Figure 7.1-17
TB
°R
527.22
Equation 1-28
LSL-max
lb per landing episode
Kg per landing episode
TB = TAA + 6α - 1
LSL-max = 5.9*D2*hle*W l
--0.60 for a full liquid heel
0.50 for a partial
0.15 for drain-dry
11,093,038 Equation 2-13
5,031,769
0.50
Equation 2-26
(pages No 33,35)
1
KS
1 0.053 * PVA * H VO
0.5
Equation 1-20
KS is assumed to be less than
or equal to the saturation
factor during filling (S) .
TV PV PB
T LA
PA PVA
0.028
Liquid stock has a true vapor
pressure greater than 0.1psia Equation 1-7.
Filling saturation factor
S
dimensionless
saturation factor
KS
dimensionless
Vapor space expansion factor
KE
dimensionless
Standing idle losses during roof landing
LSL
lb per landing episode
PV
L SL n d K E V M V K S
RT AA
5
Equation 2-16
Filling losses during roof landing
LFL
lb per landing episode
P * VV
M V * S
L FL
R * T AA
41
Equation 2-26
Total losses during roof landing
LTL
lb per landing episode
Kg per landing episode
46
21
Equation 2-10
KE
LTL=LSL+LFL
7. Summary
Working (withdrawal) losses
Breathing (standing) losses
Kg per year
Kg per year
17
16
Total Degassing and Cleaning emissions
Kg per year
750
Total losses during roof landing
Kg per year
1
785
3013.18-034.xls - 2
3/3
Kg per year
28/02/2022
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - B&W 2021
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
0.68
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Aluminum/Diffuse
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2022
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - B&W 2021 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
All
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
76.52
65.35
87.69
Liquid
Bulk
Temp
(deg F)
68.86
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0136
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
20/02/2022
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - B&W 2021 - External Floating Roof Tank
Haifa, Israel
Annual Emission Calcaulations
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
0.0136
160.0100
130.0000
1.0000
Withdrawal Losses (lb):
Annual Net Throughput (gal/yr.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
38.3228
5,202,143.0000
0.0075
7.0000
160.0100
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
0.8398
0.0002
130.0000
1.0000
27.8819
6.2000
Total Losses (lb):
73.6631
34.5005
1.6000
0.3000
6.2000
1.6000
0.0002
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
KFa(lb-mole/yr)
1.60
6.20
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
1.20
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.94
1.00
Losses(lb)
0.1446
0.6608
0.0345
20/02/2022
TANKS 4.0 Report
Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2022
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - B&W 2021 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
34.50
38.32
0.84
0.00
73.66
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2022
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
20/02/2022
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFixed 2019
Haifa
Israel
PEI
Vertical Fixed Roof Tank
kerosene
Tank Dimensions
Shell Height (ft):
Diameter (ft):
Liquid Height (ft) :
Avg. Liquid Height (ft):
Volume (gallons):
Turnovers:
Net Throughput(gal/yr):
Is Tank Heated (y/n):
N
Paint Characteristics
Shell Color/Shade:
Shell Condition
Roof Color/Shade:
Roof Condition:
Aluminum/Diffuse
Good
White/White
Good
Roof Characteristics
Type:
Height (ft)
Slope (ft/ft) (Cone Roof)
Breather Vent Settings
Vacuum Settings (psig):
Pressure Settings (psig)
11.00
160.01
11.00
5.50
1,654,664.74
1.00
1,654,664.74
Cone
0.00
0.00
0.00
0.50
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
Apr
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
72.10
62.74
81.45
Liquid
Bulk
Temp
(deg F)
67.57
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0118
0.0092
0.0159
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
02/02/2020
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Month:
Standing Losses (lb):
Vapor Space Volume (cu ft):
Vapor Density (lb/cu ft):
Vapor Space Expansion Factor:
Vented Vapor Saturation Factor:
January
February
March
April
May
June
July
August
September
October
November
December
Tank Vapor Space Volume:
Vapor Space Volume (cu ft):
Tank Diameter (ft):
Vapor Space Outage (ft):
Tank Shell Height (ft):
Average Liquid Height (ft):
Roof Outage (ft):
Roof Outage (Cone Roof)
Roof Outage (ft):
Roof Height (ft):
Roof Slope (ft/ft):
Shell Radius (ft):
Vapor Density
Vapor Density (lb/cu ft):
Vapor Molecular Weight (lb/lb-mole):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Daily Avg. Liquid Surface Temp. (deg. R):
Daily Average Ambient Temp. (deg. F):
Ideal Gas Constant R
(psia cuft / (lb-mol-deg R)):
Liquid Bulk Temperature (deg. R):
Tank Paint Solar Absorptance (Shell):
Tank Paint Solar Absorptance (Roof):
Daily Total Solar Insulation
Factor (Btu/sqft day):
Vapor Space Expansion Factor
Vapor Space Expansion Factor:
Daily Vapor Temperature Range (deg. R):
Daily Vapor Pressure Range (psia):
Breather Vent Press. Setting Range(psia):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Vapor Pressure at Daily Minimum Liquid
Surface Temperature (psia):
Vapor Pressure at Daily Maximum Liquid
Surface Temperature (psia):
Daily Avg. Liquid Surface Temp. (deg R):
Daily Min. Liquid Surface Temp. (deg R):
Daily Max. Liquid Surface Temp. (deg R):
Daily Ambient Temp. Range (deg. R):
Vented Vapor Saturation Factor
Vented Vapor Saturation Factor:
Vapor Pressure at Daily Average Liquid:
Surface Temperature (psia):
Vapor Space Outage (ft):
Working Losses (lb):
Vapor Molecular Weight (lb/lb-mole):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Net Throughput (gal/mo.):
Annual Turnovers:
Turnover Factor:
Maximum Liquid Volume (gal):
Maximum Liquid Height (ft):
Tank Diameter (ft):
Working Loss Product Factor:
Total Losses (lb):
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Losses(lbs)
Components
Working Loss
Breathing Loss
Total Emissions
Jet kerosene
60.63
32.78
93.41
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFloating 2019
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.00
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Aluminum/Diffuse
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
Apr
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
76.46
63.88
89.04
Liquid
Bulk
Temp
(deg F)
68.86
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0136
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
02/02/2020
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Month:
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
January
February
March
April
May
June
July
August
September
October
November
December
Withdrawal Losses (lb):
Net Throughput (gal/mo.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
Total Losses (lb):
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
KFa(lb-mole/yr)
1.60
6.20
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
1.20
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.94
1.00
Losses(lb)
0.0000
0.0000
0.0000
02/02/2020
TANKS 4.0 Report
Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
2.99
55.99
0.07
0.00
59.04
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
ספח ד'
חישוב פליטות ממיכל לאיסוף תשטיפים
28/02/2022
19/30
3013.18-036.doc
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תוכ ת :Tanksחישוב פליטה כתוצאה מ יקוי וריקון מיכל )שלב א'(
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26/30
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תוכ ת :Tanksחישוב פליטה כתוצאה מ יקוי וריקון מיכל )שלב ב'(
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חישובי פליטה ממיכל תשטיפים
גיליון חישוב זה הוכן על ידי "פז" ה דסה ו יהול ) (1980בע"מ.
אין להעתיק ו\או לעשות שימוש כלשהו במידע ה "ל ללא הרשאה כתובה מ"פז" ה דסה ו יהול ) (1980בע"מ.
28/02/2022
30/30
3013.18-036.doc
מסמך 11 מתוך 11
פתיחת הקובץ באתר הממשלה (pdf, 2696 KB)
תשתיות אנרגיה בע"מ
מסוף אלרואי
סיכום פליטות לאוויר
שנת 2022
פרויקט3013.19 :
סימוכין3013.19-036 :
פברואר 2023
תוכן עניינים
.1מבוא 4.............................................................................................................................
.2נתוני מסוף 5.....................................................................................................................
.2.1נתוני מיכלים 5.........................................................................................................
.2.2נתונים עבור מסוף מילוי מיכליות כביש 9.....................................................................
.3חישוב פליטות 10 ..............................................................................................................
.3.1כללי10 ........................................................................................................................ ....
.3.2סוגי פליטות מחושבות 10 ..................................................................................................
.3.3בחירת חומרים בתוכנת 11 ................................................................................... TANKS
.3.4נתונים מטאורולוגיים11 ....................................................................................................
.4סיכום פליטות לשנת 12 ............................................................................................. 2022
.4.1מיכלים 12 ........................................................................................................................
.4.2מסוף מילוי מיכליות כביש 12 .............................................................................................
.4.3מיכל איסוף תשטיפים 12 ...................................................................................................
.4.4סיכום ממצאי ניטור 12 .......................................................................................... LDAR
.4.5פליטה שנתית מכלל המתקן 13 ...........................................................................................
.5פליטות לא שגרתיות במהלך שנת 13 ............................................................................2022
.6מקורות 14 .......................................................................................................................
26/02/2023
2/30
3013.19-036.doc
טבלאות
טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 5........................................... 2022
טבלה :2נתוני מעטפת וגגות – שנת 6.................................................................................. 2022
טבלה :3נתוני אביזרים – שנת 7......................................................................................... 2022
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת 8................................................... TANKS
טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 9...................................................... 2022
טבלה :6חומרים מייצגים בתוכנת 11 ............................................................................ TANKS
טבלה :7סיכום פליטות מכלים -שנת 12 ............................................................................ 2022
טבלה :8סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 12 .................................. 2022
טבלה :9סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 13 .................................................. 2022
נספחים
נספח א'
טבלה )AP-42( 1-5.2
נספח ב'
נתוני ניטור LDARעבור מסוף אלרואי – סיכום שנת 2022
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין
נספח ד'
חישוב פליטות ממיכל לאיסוף תשטיפים
מירה ליה-זיו איסקוב
שם עורך
26/02/2023
יואב פיסטינר
שם מאשר
26.02.2023
תאריך
3/30
להערות
תיאור
0
גרסה
3013.19-036.doc
.1מבוא
חברת תשתיות נפט ואנרגיה בע"מ (להלן תש"א) מפעילה את מסוף אלרואי לאחסון ושינוע
דלקים .
המסוף כולל:
•
מבני משרדים
•
חוות מכלים לאחסון דלקים מסוגים שונים
•
רציפי מילוי מכליות כביש (לשימוש בעת חירום בלבד)
המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכונת
אלרואי ומדרום לו שכונת קרית חרושת.
באתר 9מיכלים ,מתוכם 7מכלים תפעוליים ו 2-מכלים המשמשים כמכלים אסטרטגיים
(מכלים מס' 1ו.)9-
מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוסף קיימות מערכות תומכות כגון
מערכות כיבוי אש ומערכות פיקוד ובקרה.
כחלק מהתנאים ברישיון עסק מדצמבר ,2010בסוף כל שנה קלנדרית על תש"א להגיש דו"ח
סיכום פליטות שנתי לגבי השנה שחלפה.
חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקנים
הקיימים במסוף.
סיכום הפליטות הוכן על ידי חברת "פז" הנדסה וניהול ( )1980בע"מ (להלן פז הנדסה) ,והוא
מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.
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.2נתוני מסוף
.2.1נתוני מיכלים
בטבלאות הבאות מפורט מידע טכני של המיכלים בחוות המיכלים אלרואי.
טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 2022
לחץ אדים
בטמפ' הנוזל
הממוצעת
)(mmHg
405 @ 28°C
כמות
צריכה
שנתית
(מ"ק)
0
גבעה חלקית
77,083
גבעה חלקית
48.77
גבעה חלקית
48.77
32,056
48.77
32,056
28,768
56,959
51,614
15.56
51,614
15.56
14.1
15.56
14.1
11.4
18.3
18.3
15.4
9.7
סוג ניקוז
בתחתית
מיכל
קוטר
מיכל
(מטר)
נפח מיכל
(מ"ק)
נפח מיכל
פעיל
(מ"ק)
48.77
32,056
28,768
גובה /אורך
מעטפת
מיכל
(מטר)
17.16
15.4
32,056
28,768
17.16
15.4
10
28,768
17.16
15.4
9.5
17.16
15.4
10.3
14.1
14.1
14.1
מספר
מיכל
סוג הדלק
המאוחסן
)1( 1
בנזין
2
קרוסין
0.833 @ 28°C
3
סולר
0.507 @ 28°C
14,641
4
סולר
0.507 @ 28°C
127,061
גבעה חלקית
5
סולר
0.507 @ 28°C
111,041
גבעה מלאה
68.27
)1( 6
סולר
0.507 @ 28°C
0
גבעה מלאה
68.27
56,959
)1( 7
סולר
0.507 @ 28°C
0
גבעה מלאה
68.27
56,959
51,614
8
קרוסין
0.833 @ 28°C
4,675
גבעה חלקית
48.8
36,547
34,228
19.54
)1( 9
קרוסין
0.833 @ 28°C
0
גבעה חלקית
48.77
32,056
28,768
17.16
367,704
332,913
334,501
סה"כ
( )1מכלים מס' 7 ,6 ,1ו 9-משמשים כמכלי מלאי ,לא היו תנועות במכלים בשנת .2022
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גובה נוזל
מירבי
(מטר)
גובה נוזל
ממוצע
(מטר)
10.5
טבלה :2נתוני מעטפת וגגות – שנת 2022
מספר
מיכל
סוג גג
אטם ראשי
אטם משני
1
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
גג צף
חיצוני
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Mechanical
Shoe
Liquid
mounted
Mechanical
Shoe
Rim
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Shoe
mounted
Rim
mounted
Rim
mounted
2
3
4
5
6
7
8
9
26/02/2023
צורת גג
סוג
חיבורי
גג
צבע
גג
מצב
צבע
גג
צבע
מעטפת
חיצונית
מצב צבע
מעטפת
חיצונית
סוג חיבורי
מעטפת
מצב
מעטפת
פנימית
מיכל
מחומם
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חום
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
לבן
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
חום
ישן
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
כחול בהיר
טוב
מרותך
חלוד הרבה
לא
Pontoon
מרותך
לבן
טוב
צהוב קרם
טוב
מרותך
חלוד הרבה
לא
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טבלה :3נתוני אביזרים – שנת 2022
מספר
מיכל
1
2
3
4
5
6
7
8
9
סה"כ
שובר ואקום
כמות
2
2
2
2
2
2
2
6
2
Vacuum
]set. [psi
0
0
0
0
0
0
0
0
0
Pressure
]set. [psi
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
רגליים מתכווננות התומכות
בגג צף()1
גובה כמות באזור
כמות
במרכז
()ft
pontoon
29
43
11
29
43
11
29
43
11
29
43
11
72
107
11
72
107
11
72
107
11
36
54
9
29
43
11
כמות
מדי
מפלס
Rim
Vent
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
6
כמות בוצה
בנקיון
(מ"ק)
"גרביים" לבאר
הדיגום המחורצת
ולרגלי הגג הצף()1
70
70
70
70
150
150
150
70
70
870
יש
יש
יש
יש
יש
יש
יש
יש
יש
( )1הנ"ל לא נלקחו בחשבון בחישוב הפליטות מתוכנת ה TANKS-מפני שנדגמו במסגרת ניטורי ה.LDAR-
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הנחות שנלקחו לצורך החישובים
.1עבור חישוב Degassingבמיכל עם גג צף – הונח:
•
גג צף נח על רגליים בגובה ( 9-11 ftבהתאם לטבלה לעיל) וזהו גם הגובה המרבי של הנוזל
במיכל.
•
גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.
.2הונח כי ניקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שנים .הניקיון יארך יום אחד.
.3הונח כי אירוע של נחיתת גגות צפים מתבצע אחת ל 15-שנים .זמן נחיתת הגג במקרה זה לא
יעלה על 4ימים.
.4יחס הנוזל בבוצה הונח כ]2[ 0.8 -
.5בהתאם לטבלה 7.1-6על פי [ ,]1נבחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,
לצורך חישובי פליטות לאוויר:
טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת Tanks
צבע מעטפת
מיכל
צבע לצורך חישובי אקסל
צבע לצורך חישובים בתוכנת
בהתאם למסמך EPA AP-42
)*( Tanks
כחול בהיר
Gray Medium
Gray Medium
Brown
Aluminium/Diffuse
Beige/Cream
Aluminium/Specular
White
White
חום
צהוב קרם
לבן
(*) בתוכנת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך
.]1[ EPA AP-42
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.2.2נתונים עבור מסוף מילוי מיכליות כביש
טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 2022
מס'
זרוע
1
2
3
4
5
6
7
8
מוצר
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
קרוסין
סה"כ
מילוי
עילי /תחתי
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
עילי טבול
נפח מילוי שנתי
(מ"ק)
0
0
0
0
0
0
0
0
0
נפח ממוצע של
מיכלית (מ"ק)
30
30
30
30
30
30
30
30
לא התקיימה פעילות מיכליות כביש בשנת .2022
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.3חישוב פליטות
.3.1כללי
חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכנת Tanksובעזרת .]1[ EPA-AP 42
הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ( )LDARמצורפת בנספח ב'.
דוגמת חישוב עבור מיכל גג חיצוני צף (מיכל מס' )2המאחסן קרוסין ,מצורפת כנספח ג' למסמך
זה.
בדוגמאות אלה ניתן לראות את נתוני הקלט (כולל הנחות) עליהם התבססו החישובים.
.3.2סוגי פליטות מחושבות
הערכת הפליטות ממיכלי אחסון כוללת [:]3
• פליטות בזמן אחסון )(Breathing Losses
• פליטות משינויי מפלס )(Working Losses
• פליטות כתוצאה מניקוי וריקון מיכלים )(Degassing Losses
• פליטות כתוצאה מנחיתת גגות צפים )(Roof Landing Losses
• פליטות כתוצאה מהפרשי לחץ )(Flash Losses
• פליטות בזמן מילוי מיכלים ומיכליות
בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ
).(Flash Losses
פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלחץ הנוזל ,נתון הגורם להפרת שיווי המשקל
הקיים במיכל (בין גז לנוזל) וכתוצאה מכך נוצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הנוזל
עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר נוזל המאוחסן בלחץ נשלח
לאחסון במיכל בעל לחץ נמוך יותר [.]3
פליטות אלו הוזנחו כיוון שכל החומרים מוחזקים בתנאים אטמוספריים בכל אחד מהשלבים
הנוגעים להובלתם ואחסונם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.
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.3.3בחירת חומרים בתוכנת Tanks
על פי נתוני MSDSשל הדלקים במסוף ,נבחרו החומרים הבאים הקיימים בתוכנת Tanks
כמייצגים של חומרים אלו:
טבלה :6חומרים מייצגים בתוכנת Tanks
דלק קיים במסוף
חומר מייצג בתוכנת Tanks
סולר (תחבורה והסקה)
Distillate fuel oil no 2
נפט (קרוסין)
Jet kerosene
בנזין
Gasoline RVP 10
.3.4נתונים מטאורולוגיים
לצורך חישוב הנתונים בתוכנת Tanksהוגדרו נתונים מטאורולוגים המתאימים למפרץ חיפה על פי
מקורות [.]4
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.4סיכום פליטות לשנת 2022
.4.1מיכלים
סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:
טבלה :7סיכום פליטות מכלים -שנת 2022
מיכל
חומר
1
בנזין
פליטות לאוויר
(ק"ג/שנה)
3,603
2
קרוסין
836
3
סולר
23
4
סולר
911
5
סולר
1,764
6
סולר
1,693
7
סולר
1,693
8
קרוסין
760
9
קרוסין
758
12,041
סה"כ
.4.2מסוף מילוי מיכליות כביש
לא התקיימה פעילות מיכליות כביש בשנת ,2022ועל כן אין פליטות ממסוף מילוי מיכליות כביש.
.4.3מיכל איסוף תשטיפים
סך הפליטה ממיכל לאיסוף תשטיפים הינה כ 1 -ק"ג/שנה.
חישוב מצורף בנספח ד'.
יצוין כי החישוב מתבסס על הנחה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל
בעיקר ניקוז מים מהמכלים.
.4.4סיכום ממצאי ניטור LDAR
טבלה :8סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 2022
סה"כ פליטות (ק"ג/שנה)
סיכום פליטות LDAR
פליטה שנתית (ק"ג/שנה)
סה"כ
6
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.4.5פליטה שנתית מכלל המתקן
טבלה :9סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 2022
סה"כ פליטות (ק"ג/שנה)
חוות מיכלים
מסוף מילוי
מיכליות כביש
מיכל לאיסוף
תשטיפים
12,041
0
1
סיכום פליטות
רכיבים
סה"כ
()LDAR
6
12,048
.5פליטות לא שגרתיות במהלך שנת 2022
במהלך שנת 2022לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.
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.6מקורות
]1[ EPA-AP42
]2[ USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version
4.0 - APPENDIX D
[ ]3הנחיות להגשת בקשה להיתר פליטה ושינוי הפעלה משמעותי הנחיות הממונה לטיפול בבקשה
להיתר פליטה לפי סעיף (9א) לתקנות אוויר נקי (היתרי פליטה) ,התש"ע – ,2010מהדורה ,5
נובמבר 2020
[ ]4האטלס האקלימי לתכנון פיסי וסביבתי בישראל ,מהדורה שנייה1994 ,
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נספח א'
טבלה 5.2-1
AP-42
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נספח ב'
נתוני ניטור LDARעבור אלרואי – סיכום שנת 2022
(מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך )12.01.2023
3013.19-003A
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LDAR
Fugi ve Emission Monitoring
Report No.
RL-EI-R1-6-22
Plant: Energy Infrastructures LTD
City: Haifa
District: Haifa
Production Unit: Alroy
Reporting period: Annual Summary
Report printing date:
12-Jan-2023
Report editor:
Michael Ourievsky
Approved by:
Alexey Ratner
Table of Content
1. Executive Summary
2. Project introduction
2.1 Scope of work
2.2 Project phases
3. Monitoring Results
Table 3.1 – Overview by component class
Table 3.2 – Overview by reading range
Table 3.3 – Overview per Unit
Table 3.4 – Monitoring results, last known situation
Graph 3.5 – Total overview by chemicals
4. Detailed monitoring summary
Table 4.1 - Cumulative summary, Fugitive emission component classification and emission estimation for
production facilities
Table 4.2 – Chemical Summary by Component Class
Table 4.3 - LDAR report for production facilities
Table 4.4 - Components with more than 5 significant leaks detected during last 12 months
Graph 4.5 - Comparison between count of components & kg/year, by components
5. Attachments
5.1 General Remarks
Table 5.1.1 Monitored components
Table 5.1.2 Unmonitored P&IDs
Table 5.2 Project schedule
5.3 Methodology
5.4 Calibration Log list
5.5 Calibration gas certificates
5.6 Stream Composition Summary
5.6 Quarterly Validation of LDAR Devices, Quarter 1
5.7 Quarterly Validation of LDAR Devices, Quarter 2
5.8 Quarterly Validation of LDAR Devices, Quarter 3
5.9 Quarterly Validation of LDAR Devices, Quarter 4
5.10 Cumulative production hours template
4
5
5
5
6
6
6
7
7
9
9
10
11
13
14
15
17
17
17
17
17
18
19
20
22
23
24
25
26
27
1. Executive Summary
The total number of active components at Energy Infrastructures LTD is 223.
Six rounds of measurements have been performed in the Quarter 1-4 of 2022.
The total calculated emission from 01/01/2022 to 31/12/2022 is 6.08 kg.
The number of components above leak definition found from the beginning of the year – 0
The number of pegged readings (above 100,000 ppm) found from the beginning of the year - 0
The last known situation of Energy Infrastructures LTD indicates there are no leaks
4/27
2 Project introduction
2.1 Scope of work
Following measurements have been performed in 2022:
Round
Round 1, Quarter 1
Round 2, Quarter 1
Round 3, Quarter 2
Round 4, Quarter 3
Round 5, Quarter 4
Round 6, Quarter 4
Unit
G1
Monitored group
G2
G3
Alroy
Alroy
Alroy
Alroy
Alroy
Alroy
2.2 Project phases
Monitoring
Re-measurement after repair
Revision of equipment and production processes
Inventory: adding or deleting components
General
1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory Accreditation Authority).
2. ISRAC is not responsible for the test results.
3. The following data is provided by the customer: production hours, P&IDs, and stream information.
5/27
3. Monitoring results
The table “Overview by component class” below shows the number of active components, number of leaks above leak definitions and number of components that are still leaking in each class
(according to the monitoring round), and total calculated emissions in the specified period.
Table 3.1 Overview by component class,
Component Class
01/01/2022-31/12/2022
Total
Components
count
Total Components above
leak definition
count
% of components above
leak definition
%
Unrepaired Components
Total
Emissions
kg
count
Round 1
Round 2
Round 3
Round 4
Round 5
Round 6
Round 1
Round 2
Round 3
Round 4
Round 5
Round 6
Average
Round 1
Round 2
Round 3
Round 4
Round 5
Round 6
01/01/202231/12/2022
PRD
Sampling Point
Total Group 1:
Stem Valve
Open End
Total Group 2:
Flange
Connection
Total Group 3:
4
4
8
20
102
122
55
38
93
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.14
0.14
0.28
1.367
1.787
3.154
0.149
2.497
2.646
Total:
223
0
0
0
0
0
0
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0
0
0
0
0
0
6.08
In table “Overview by reading range” all the components divided by their reading range at first measurement according to the monitoring round.
Table 3.2 Overview by reading range
Total Components
Reading Range
Round 1
#
0 ppm
1-499 ppm
500-749 ppm
750-999 ppm
1,000-100,000 ppm
Above 100,000 ppm
Total above leak definition
Difficult to Monitor
Total:
Round 2
%
8
0
0
0
0
0
0
0
8
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
Round 3
%
8
0
0
0
0
0
0
0
8
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
Round 4
%
223
0
0
0
0
0
0
0
223
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
Round 5
%
8
0
0
0
0
0
0
0
8
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
Round 6
%
130
0
0
0
0
0
0
0
130
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
#
%
8
0
0
0
0
0
0
0
8
100.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
100.0%
6/27
Table 3.3 Overview per Unit, Group 1-3
Unit
Total
components
Components above leak definition
count
Alroy
Total:
R1
223
223
R2
0
0
R3
R4
0
0
R5
0
0
0
0
R6
0
0
Total emission
kg
01/01/202231/12/2022
0
6.08
0
6.08
Table 3.4 – Monitoring results, Group 1-3, last known situation.
The last known situation of Energy Infrastructures LTD indicates there are no leaks.
0 "difficult to monitor" sources.
223 default-zero sources (0ppm).
0 registered sources (1-999ppm).
0 components above leak definition
Component Class
Total
components
count
PRD
Sampling Point
Stem Valve
Open End
Flange
Connection
Total:
Components 1- Components 500- Components 750499ppm
749ppm
999ppm
count
4
4
20
102
55
38
223
count
0
0
0
0
0
0
0
count
0
0
0
0
0
0
0
Components % of components
% of
above leak
1-999ppm
components
definition (1,000
above leak
ppm)
definition
count
%
%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
0
0
0.00%
0.00%
7/27
Graph 3-5 - Total overview by chemicals, 01/01/2022-31/12/2022.
8/27
4. Detailed monitoring summary
01/01/2022-31/12/2022
9/27
Fugitive emission component classification and emission estimation for production facilities
01/01/2022-31/12/2022 Calculation period
Monitoring
Frequency
cycles/year
Components above 1,000 ppm
%
R6
R5
R4
R3 R2 R1
6
6 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
6
6
6 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
6
0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
2
2 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
2
2
2 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
2
0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
1
1 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
1
1
1 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
1
0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
Cumulative Components above
Components in reading
Components in reading
Emission
100,000 ppm
range 1,000-100,000 ppm
range 750-999 ppm
kg
Count
Count
Count
R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1
0.14 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
0.14 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
0.28 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
1.367 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
1.787 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
3.154 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
0.149 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
2.497 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
2.646 0 0 0 0 0 0
6.08 0 0 0 0 0 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Energy Infrastructures LTD Company name
12-Jan-2023 Date
Alroy Production
Report Number
Unit
Components in reading
Components in reading Components in reading
Unrepaired
Total Components Difficult to
Total
Chemical Component Class Group
range 500-749 ppm
range 1-499 ppm
range 0 ppm
Components
above 1,000 ppm
Monitor Components
State
Count
Count
Count
Count
Count
Count
R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 Count
GV
PRD
G1
0 0 0 0 0 0 0 0 0 0 0 0 4 4 4 4 4 4 0 0 0 0 0 0 0 0 0 0 0 0
0
4
LL
HL
GV
Sampling Point
0 0 0 0 0 0 0 0 0 0 0 0 4 4 4 4 4 4 0 0 0 0 0 0 0 0 0 0 0 0
0
4
LL
HL
0 0 0 0 0 0 0 0 0 0 0 0 8 8 8 8 8 8 0 0 0 0 0 0 0 0 0 0 0 0
0
8 Subtotal G1
GV
Stem Valve
G2
0 0 0 0 0 0 0 0 0 0 0 0 0 20 0 20 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
20
LL
HL
GV
Open End
0 0 0 0 0 0 0 0 0 0 0 0 0 102 0 102 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
102
LL
HL
0 0 0 0 0 0 0 0 0 0 0 0 0 122 0 122 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
122 Subtotal G2
GV
Flange
G3
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 55 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
55
LL
HL
GV
Connection
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 38 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
38
LL
HL
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 93 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0
93 Subtotal G3
0 0 0 0 0 0 0 0 0 0 0 0 8 130 8 223 8 8 0 0 0 0 0 0 0 0 0 0 0 0
0
223 Total Components
6.08 Total Cumulative Emission
10/27
Table 4.2 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2022- 31/12/2022
Report Chemica l Summa ry Cumula tive
Equa tion Set:
Refinery
Units of Mea s urement:
KG
Report Da te: 12.01.2023
Alroy
Unit
Component Class:
PRD
Chemical Name (Stream Name if Not Speciated)
CAS Number
Emissions
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Sa mpling Point
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.014
0.0014
0.007
0.014
0.0561
0.0477
0.1402
Component Class:
Stem Va lve
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.1367
0.0137
0.0683
0.1367
0.5466
0.4646
1.3666
Component Class:
Open End
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.1787
0.0179
0.0894
0.1787
0.7148
0.6076
1.7871
11/27
Table 4.2 Chemical Summary by Component Class
Ca lcula tion Period:
01/01/2022- 31/12/2022
Report Chemica l Summa ry Cumula tive
Equa tion Set:
Refinery
Units of Mea s urement:
KG
Report Da te: 12.01.2023
Alroy
Unit
Component Class:
Fla nge
Chemical Name (Stream Name if Not Speciated)
CAS Number
Emissions
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.0149
0.0015
0.0075
0.0149
0.0597
0.0508
0.1493
Component Class:
Connection
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.2497
0.025
0.1248
0.2497
0.9986
0.8488
2.4966
Component Class:
All
1-Butene
BENZENE
CYCLOHEXANE
METHYL TERT-BUTYL ETHER
n-Octa ne
TOLUENE
106-98-9
71-43-2
110-82-7
1634-04-4
111-65-9
108-88-3
0.608
0.0609
0.304
0.608
2.4319
2.0672
6.08
Grand Total
6.08
12/27
n t Typ e
n t Cla s s
Co m p o n e
Co m p o n e
t
e nt
p a ir
d a te
a e r re op f re m e a s u re m e
a ir a e m n t
pt
p p m va lu
a e r re p e o f re m e a s u
a ir a e m
re m e n t
pt
Re p a ir ty
pe
D a te o f re
Plant
Energy Infra s tructures LTD
d a te
a e r re op f re m e a s u re m e
a ir a e m n t
pt
p p m va lu
a e r re p e o f re m e a s u
a ir a e m
re m e n t
pt
Re p a ir ty
pe
p a ir
ue
irs t Me a
D a te o f re
Re p a ir D
D a te o f F
e a s u re m
n
s u re m e n
e , Firs t M
Mo re
3 d ro p s th a n
p e r m in u
te
p p m va lu
e s cri p o
n t Ta g
Co m p o n e
Lo ca o n
D
Sta te
Ch e m ica
l
D ra w in g
Un it
Ro u n d
Table 4.3-LDAR report for production facilities
Unit
Alroy
13/27
n t Typ e
n t Cla s s
Co m p o n e
Co m p o n e
t
p a ir
d a te
a e r re op f re m e a s u re m e
a ir a e m n t
pt
ppm v
a e r re pa lu e o f re m e a s u
a ir a e m
re m e n t
pt
Unit
Alroy
Re p a ir ty
pe
D a te o f re
d a te
a e r re op f re m e a s u re m e
a ir a e m n t
pt
ppm v
a e r re pa lu e o f re m e a s u
a ir a e m
re m e n t
pt
Re p a ir ty
pe
p a ir
ue
irs t Me a
e nt
Plant
Energy Infra s tructures LTD
D a te o f re
Re p a ir D
D a te o f F
e a s u re m
n
s u re m e n
e , Firs t M
Mo re
3 d ro p s th a n
p e r m in u
te
p p m va lu
e s cri p o
n t Ta g
Co m p o n e
Lo ca o n
D
Sta te
Ch e m ica
l
D ra w in g
Un it
Table 4.4-Components with more than 5 significant leaks detected in the last 12 months
In the table below we provided a list of components with more than 5 Leaks during the last 12 months as follows: ≥ 10,000 ppm, or more than 3 drops per minute or ≥ 1,000 ppm for PRDs
Monitoring Round
Round 1-2-3-4-5-6
14/27
Graph 4-5 – Comparison between count of components & emissions, 01/01/2022-31/12/2022.
15/27
Attachments
16/27
5.1 General remarks
Table 5-1-1 - Monitored components
Unit
Round 1
In scope
Round 2
Measured
In scope
Round 3
Measured
In scope
Round 4
Measured
In scope
Round 5
Measured
In scope
Round 6
Measured
In scope
Measured
Alroy
8
8
8
8
223
223
8
8
130
130
8
8
Total
8
8
8
8
223
223
8
8
130
130
8
8
5.2 Project schedule (excluding measurements after repair)
Unit
Alroy
Start date
Round 1
End date
03/02/2022
03/02/2022
Start date
Round 2
End date
06/03/2022
06/03/2022
Start date
Round 3
End date
05/07/2022
05/07/2022
Start date
Round 4
End date
30/08/2022
30/08/2022
Start date
Round 5
End date
18/10/2022
18/10/2022
Start date
Round 6
End date
20/12/2022
20/12/2022
17/27
5.3 Methodology
Definitions
Chemical State:
Gas/Vapor:
Light Liquid:
stream which is in process conditions under gaseous or vapor form.
a liquid having a VOC content greater than 10% (by volume)
that evaporates at 150°C
Heavy Liquid:
a liquid having a VOC content of 10% or less (by volume)
that evaporates at 150°C
Leak definition:
1,000 ppm (all sources)
Difficult to monitor components:
Any component positioned at a level higher than five meters above ground level or any
component situated at a distance further than two meters from a platform and which
cannot be accessed by employees in a safe way.
Any component which access requires the elevation of a person to a level higher
than two meters above regular surfaces, and which cannot be accessed safetly.
Registered components:
Components with a leak value greater than 0 ppm.
Default-zero:
This equation is valid for sources with a leak value of 0 ppm.
A fixed EPA emission calculation rule is used for all these components.
Total components:
All of the existing active components.
Total measured components:
All of the components, measured in specific monitoring round.
Methodology
Formulas:
Measured ppm values are converted to emission loss (kg/year) and these
calculations are based on the E.P.A. “Correlation method”
Modified Trapezoidal Emission Calculation Method:
The modified trapezoid method assumes that the mass leak rate changes
linearly between any two monitoring points, except for periods between leak
leak detection and repair; the leak monitor reading is used from the time the
leak is detected to the time it is repaired (i.e., re-screened).
Cumulative data:
In "Cumulative data" tables we provide the results of all of the measurements
that performed from the beginning of the year till the end of current monitoring
period (quarter). We also calculate the real sum of previous emissions based on
the all rounds of the measurements (before and after repairing attempts).
(US EPA "Emission Estimation Protocol for Petroleum Refineries")
18/27
Table 5.4 - Calibration log list
Plant
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Energy Infrastructures LTD
Round
1
2
2
2
2
3
3
3
3
3
3
3
3
4
4
4
4
4
5
5
5
5
5
6
Equipment Type
TVA2020
TVA2020
TVA1000B
TVA2020
TVA2020
TVA2020
TVA1000B
TVA2020
TVA2020
TVA2020
TVA1000B
TVA2020
TVA1000B
TVA2020
TVA1000B
TVA1000B
TVA2020
TVA1000B
TVA2020
TVA1000B
TVA2020
TVA1000B
TVA2020
TVA2020
Analyzer Type
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
FID
Ultra-Zero
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Air, THC < 0.5ppm
Span Gas
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Span gas Cylinder No
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
12663
Span concentration
ppm
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
1,000
Check gas
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Methane
Check gas Cylinder No
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
93531
Check gas
concentration
(A)
ppm
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
500
Date
03-Feb-2022
14-Feb-2022
14-Feb-2022
06-Mar-2022
07-Mar-2022
12-May-2022
12-May-2022
19-May-2022
06-Jun-2022
13-Jun-2022
13-Jun-2022
14-Jun-2022
14-Jun-2022
05-Jul-2022
05-Jul-2022
30-Aug-2022
30-Aug-2022
15-Sep-2022
13-Oct-2022
13-Oct-2022
18-Oct-2022
18-Oct-2022
07-Nov-2022
20-Dec-2022
Equipment No
5
5
9
5
5
5
9
5
5
5
9
5
9
5
8
9
5
9
5
9
5
9
5
5
Equipment Serial
No
202016061436
202016061436
33461300
202016061436
202016061436
202016061436
33461300
202016061436
202016061436
202016061436
33461300
202016061436
33461300
202016061436
05355151349
33461300
202016061436
33461300
202016061436
33461300
202016061436
33461300
202016061436
202016061436
Check
1-st check 2-st check
(A1)
(A2)
ppm
ppm
509
507
512
510
495
493
501
506
490
492
499
507
497
495
490
491
492
490
507
503
502
507
495
493
490
488
508
499
499
485
493
490
497
500
501
503
501
494
499
505
504
506
498
496
514
515
502
506
Calibration error
3-st check
(A3)
ppm
504
510
499
499
488
503
490
488
488
499
510
499
487
502
483
495
499
501
490
502
501
499
515
504
Result
(CP)
1.33%
2.13%
-0.87%
0.40%
-2.00%
0.60%
-1.20%
-2.07%
-2.00%
0.60%
1.27%
-0.87%
-2.33%
0.60%
-2.20%
-1.47%
-0.27%
0.33%
-1.00%
0.40%
0.73%
-0.47%
2.93%
0.80%
19/27
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
20/27
21/27
Table 5.6 - Stream Composition Summary
Stream Name
Gasoline
Petroleum
Stream Content
1-Butene-10 %, BENZENE-1 %, CYCLOHEXANE-5 %, METHYL TERT-BUTYL ETHER-10 %, n-Octane-40 %, TOLUENE-34 %
BENZENE-2 %, CYCLOHEXANE-35.2 %, n-Octane-55.3 %, TOLUENE-7.5 %
Stream Content Dates
TVA
MiniRAE 10.6
MiniRAE 11.7
22/27
Table 5.6 - Quarterly Validation of LDAR Devices
Date: 04-Jan-2022
Equipment
Equip.Ser. No
No
1
2
3
5
6
7
8
9
1
2
3
5
6
7
8
9
Quarter:
Equipment
Analyzer Span Gas
Type
0715622657 TVA1000B
0115248185 TVA1000B
0115248937 TVA1000B
202016061436 TVA2020
MiniRAE2000
110219070002
NEO
05355151349 TVA1000B
33461300
TVA1000B
0715622657 TVA1000B
0115248185 TVA1000B
0115248937 TVA1000B
202016061436 TVA2020
MiniRAE2000
110219070002
NEO
05355151349 TVA1000B
33461300
TVA1000B
Qua rterly Va lida tion Qua rter 1
FID
FID
FID
FID
PID
PID
FID
FID
FID
FID
FID
FID
PID
PID
FID
FID
Sampling Flow Rate
Check
1
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Span gas
Cylinder No
ET0022865
ET0022865
ET0022865
ET0022865
EA0010369
EA0010369
ET0022865
ET0022865
ET0022865
ET0022865
ET0022865
ET0022865
EA0010369
EA0010369
ET0022865
ET0022865
Span Gas
Concentration
Sampling
Flow Rate
ppm
l/min
995
995
995
995
996
996
995
995
995
995
995
995
996
996
995
995
0.91
1.02
1.26
1.15
0.41
0.51
0.99
1.31
0.91
1.02
1.26
1.15
0.41
0.51
0.99
1.31
Accuracy Check
Result Check Gas
Check gas
Cylinder No
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
FF16599
FF16599
FF16599
FF16599
995-286088
995-286088
FF16599
FF16599
FF16599
FF16599
FF16599
FF16599
995-286088
995-286088
FF16599
FF16599
Check Gas
Concentration
Response Time
90% of Response
1-st
2nd
3rd Calibration
Time 1
Result Span
check check check
error
ppm
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
501
501
501
501
500
500
501
501
501
501
501
501
500
500
501
501
510
505
495
497
490
511
509
503
510
505
495
497
490
511
509
503
506
499
493
502
488
509
501
508
506
499
493
502
488
509
501
508
513
501
490
507
493
510
507
496
513
501
490
507
493
510
507
496
1.53%
-0.07%
-1.86%
0%
-2.07%
1.86%
0.73%
0.07%
1.53%
-0.07%
-1.86%
0%
-2.07%
1.86%
0.73%
0.07%
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
Response
Time 2
Response
Time 3 Result
ppm
sec
sec
sec
895.5
895.5
895.5
895.5
896.9
896.9
895.5
895.5
895.5
895.5
895.5
895.5
896.9
896.9
895.5
895.5
4
4
4
3
5
5
4
3
4
4
4
3
5
5
4
3
4
4
3
4
5
5
4
4
4
4
3
4
5
5
4
4
4
4
4
4
5
5
4
4
4
4
4
4
5
5
4
4
23/27
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
OK
Table 5.7 - Quarterly Validation of LDAR Devices
Date: 01-Apr-2022
Quarter:
Equipment
Equip.Ser. No
No
Equipment
Analyzer Span Gas
Type
1
2
3
5
6
7
8
9
0715622657 TVA1000B
0115248185 TVA1000B
0115248937 TVA1000B
202016061436 TVA2020
MiniRAE2000
110219070002
NEO
05355151349 TVA1000B
33461300
TVA1000B
Qua rterly Va lida tion Qua rter 2
FID
FID
FID
FID
PID
PID
FID
FID
Sampling Flow Rate
Check
2
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Span gas
Cylinder No
ET0022865
ET0022865
ET0022865
ET0022865
EA0010369
EA0010369
ET0022865
ET0022865
Span Gas
Concentration
Sampling
Flow Rate
ppm
l/min
995
995
995
995
996
996
995
995
1.08
1.1
1.21
1.09
0.47
0.51
0.96
1.28
Accuracy Check
Result Check Gas
Check gas
Cylinder No
OK Methane
OK Methane
OK Methane
OK Methane
OK Isobutylene
OK Isobutylene
OK Methane
OK Methane
FF16599
FF16599
FF16599
FF16599
995-286088
995-286088
FF16599
FF16599
Check Gas
Concentration
Response Time
90% of Response
1-st
2nd
3rd Calibration
Time 1
Result Span
check check check
error
ppm
501
501
501
501
500
500
501
501
501
510
490
492
488
515
501
510
502
514
491
492
488
513
501
510
502
513
488
493
493
512
502
508
-0.07%
2.06%
-2.46%
-1.93%
-2.2%
2.52%
-0.13%
1.46%
OK
OK
OK
OK
OK
OK
OK
OK
Response
Time 2
Response
Time 3 Result
ppm
sec
sec
sec
895.5
895.5
895.5
895.5
896.9
896.9
895.5
895.5
4
4
4
3
6
5
4
4
4
4
4
4
5
5
4
4
4
4
4
4
5
6
4
4
24/27
OK
OK
OK
OK
OK
OK
OK
OK
Table 5.8 - Quarterly Validation of LDAR Devices
Date: 01-Jul-2022
Quarter:
Equipment
Equip.Ser. No
No
Equipment
Analyzer Span Gas
Type
1
2
3
5
6
7
8
9
0715622657 TVA1000B
0115248185 TVA1000B
0115248937 TVA1000B
202016061436 TVA2020
MiniRAE2000
110219070002
NEO
05355151349 TVA1000B
33461300
TVA1000B
Qua rterly Va lida tion Qua rter 3
FID
FID
FID
FID
PID
PID
FID
FID
Sampling Flow Rate
Check
3
Methane
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Span gas
Cylinder No
ET0022865
ET0022865
ET0022865
ET0022865
EA0010369
EA0010369
ET0022865
ET0022865
Span Gas
Concentration
Sampling
Flow Rate
ppm
l/min
995
995
995
995
996
996
995
995
1.16
1.11
1.25
1.12
0.49
0.52
0.93
1.21
Accuracy Check
Result Check Gas
Check gas
Cylinder No
OK Methane
OK Methane
OK Methane
OK Methane
OK Isobutylene
OK Isobutylene
OK Methane
OK Methane
FF16599
FF16599
FF16599
FF16599
995-286088
995-286088
FF16599
FF16599
Check Gas
Concentration
Response Time
90% of Response
1-st
2nd
3rd Calibration
Time 1
Result Span
check check check
error
ppm
501
501
501
501
500
500
501
501
512
502
475
491
482
517
505
515
512
503
477
491
482
515
505
516
511
503
477
491
48
516
504
516
1.93%
0.13%
-5.11%
-2.19%
-32.63%
3.06%
0.53%
2.72%
OK
OK
OK
OK
FAIL
OK
OK
OK
Response
Time 2
Response
Time 3 Result
ppm
sec
sec
sec
895.5
895.5
895.5
895.5
896.9
896.9
895.5
895.5
4
4
4
4
5
5
4
4
3
4
4
4
5
6
4
4
4
4
4
4
5
5
4
4
25/27
OK
OK
OK
OK
OK
OK
OK
OK
Table 5.9 - Quarterly Validation of LDAR Devices
Date: 30-Sep-2022
Equipment
Equip.Ser. No
No
1
2
5
6
7
8
9
10
Quarter:
Equipment
Analyzer Span Gas
Type
0715622657 TVA1000B
0115248185 TVA1000B
202016061436 TVA2020
MiniRAE2000
110219070002
NEO
05355151349 TVA1000B
33461300
TVA1000B
0115248463 TVA1000B
Qua rterly Va lida tion Qua rter 4
FID
FID
FID
PID
PID
FID
FID
FID
Sampling Flow Rate
Check
4
Methane
Methane
Methane
Isobutylene
Isobutylene
Methane
Methane
Methane
Span gas
Cylinder No
ET0022865
ET0022865
ET0022865
EA0010369
EA0010369
ET0022865
ET0022865
ET0022865
Span Gas
Concentration
Sampling
Flow Rate
ppm
l/min
995
995
995
996
996
995
995
995
0.86
1.14
1.26
0.5
0.92
0.98
1.18
1.39
Accuracy Check
Result Check Gas
Check gas
Cylinder No
OK Methane
OK Methane
OK Methane
OK Isobutylene
OK Isobutylene
OK Methane
OK Methane
OK Methane
FF16599
FF16599
FF16599
995-286088
995-286088
FF16599
FF16599
FF16599
Check Gas
Concentration
Response Time
90% of Response
1-st
2nd
3rd Calibration
Time 1
Result Span
check check check
error
ppm
501
501
501
500
500
501
501
501
508
503
499
506
504
497
501
501
509
506
501
506
503
494
502
499
507
501
502
507
501
501
502
502
1.2%
0.27%
-0.27%
1.13%
0.39%
-0.93%
-0.07%
-0.27%
OK
OK
OK
OK
OK
OK
OK
OK
Response
Time 2
Response
Time 3 Result
ppm
sec
sec
sec
895.5
895.5
895.5
896.9
896.9
895.5
895.5
895.5
4
4
4
6
4
4
4
4
4
4
4
6
4
4
4
4
4
4
4
6
4
4
4
4
26/27
OK
OK
OK
OK
OK
OK
OK
OK
Table 5.10 - PRODUCTION HOURS TEMPLATE
Plant
Energy Infrastructures LTD
Unit
Alroy
Alroy
Drawing
6006-100-006
6006-100-007
Stream Name
Gasoline
Gasoline
Remark
Annual Production Hours
8,760
8,760
Q1
01/01-31/03
Quarter =
Quarterly Production hours
2,160
2,160
Q2
01/04-30/06
Quarter =
Quarterly Production hours
2,184
2,184
Q3
01/07-30/09
Quarter =
Quarterly Production hours
2,208
2,208
Q4
01/10-31/12
Quarter =
Quarterly Production hours
2,208
2,208
27/27
נספח ג'
דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין
3013.19-034-T2
3013.19-025
26/02/2023
18/30
3013.19-036.doc
T2 - kerosene
External Floating roof
1. Tank data
Diameter of the tank
D
Effective height of the stock liquid (while
roof landing episode)
hle
Shell Color and condition
α
Roof color and condition
α
Tank paint solar absorptance
α
Vapor space outage (while roof landing
episode)
HVO
m
feet
m
feet
color
condition
color
condition
dimensionless
m
Tank data
--Tank data
--חום
טובה
לבן
טוב
VV
ft
3
ΔPBP
Breather vent vacuum setting
ΔPBV
Breather vent pressure setting range
ΔPB
11.00
0.58
Table 7.1-6
Brown
0.17
Table 7.1-6
0.38
Table 7.1-6
Possible to use also equation
1-15
assumption - equal to legs height
feet
Volume of the vapor space (while roof
landing episode)
Breather vent pressure setting
48.77
160.01
11.00
2
VV=PI()*D /4*Hvo
221,185
Equation 1-3
psi
Typical value
0.50
Equation 1-11
psi
Typical value
0.00
Equation 1-11
psi
PB = PBP − PBV
0.50
Equation 1-11
msds data
130
msds data
--msds data
---
0.80
6.68
4.5
0.28
mm Hg
PEI data
0.833
psia
--הנחה:
Pv=nRT -->
P2=P1*(T2/T1)
0.02
2. Material data - קרוסין
Stock vapor molecular weight
MV
Density of the liquid inside the tank
Wl
Vapor density
WV
True vapor pressure of the stock liquid
P
Vapor pressure at daily average liquid
surface temperature
Vapor pressure at the daily maximum
liquid surface temperature, psia
Vapor pressure at the daily minimum
liquid surface temperature
Daily vapor pressure range
3013.19-034.xls - 2
gr/gr-mole
lb/lb-mole
g/ml
lb/gal
kg/m^3
lb/ft3
PVA
psia
PVX
psia
PVN
psia
T1(k)=20C+273
T2(k)=37.5C+273
0.02
ΔPV
psia
PV = PVX − PVN
0.00
1/3
0
at 20°C
0.02
0.02
Equation 1-9
26/02/2023
3. Operation data
Number of days that the tank stands idle
(on roof landing episode)
Number of degassing and cleaning
episode
Number of roof landing episode
nd
days/landing episode
site data
4
landing episode/year
site data
0.07
landing episode/year
site data
0.07
Tanks Program
--Tanks Program
---
150
68
185
84
16
T2 - B&W 2022
Tanks Program
---
59
27
T2 - DFloating 2019
lb per emptying
Tanks Program
61
Kg per emptying
---
28
4. Normal operation (Tanks program)
lb per year
Kg per year
lb per year
Kg per year
Kg per year
Working (withdrawal) losses
Total emissions (Breathing & Working)
Breathing (standing) losses
5. Degassing and Cleaning (Tanks program)
Degassing: emission from one turnover of
Edegass-floating lb per emptying
floating roof
Kg per emptying
Degassing: fixed roof with a height of roof
legs
Edegass-legs
Liquid fraction in sludge
Fliquid
Sludge volume
Sludge weight
Vs
Ws
Cleaning emissions
Ecleaning
Total Degassing and Cleaning emissions
Edegass-total
3013.19-034.xls - 2
0.8
m3 per emptying
Kg per emptying
lb per emptying
Kg per emptying
lb per emptying
Kg per emptying
Ecleaning = Ws * (1-Fliquid)
Edegass-total =
Edegass-floating + Edegass-legs + Ecleaning
2/3
T2 - B&W 2022
T2- DFixed 2019
(Only working losses)
Tanks FAQ - degassing and
cleaning
70
56,000
24,692
11,200
24,811
11,254
26/02/2023
6. Roof landing
Daily average liquid surface temperature
TLA
°R
Daily vapor temperature range
ΔTV
°R
Daily maximum liquid surface temperature
TLX
Daily minimum liquid surface temperature
Liquid bulk temperature
Max standing idle losses during roof
landing
Filling saturation factor
TLA = 0.44 TAA + 0.56 TB + 0.0079 * * I
532.17
Equation 1-26
TV = 0.72TA + 0.028 * * I
32.95
Equation 1-8
°R
TLX = TLA + 0.25*ΔTV
540.41
Figure 7.1-17
TLN
°R
TLN = TLA - 0.25*ΔTV
523.93
Figure 7.1-17
TB
°R
527.22
Equation 1-28
LSL-max
S
lb per landing episode
Kg per landing episode
dimensionless
TB = TAA + 6α - 1
2
LSL-max = 5.9*D *hle*W l
--0.60 for a full liquid heel
0.50 for a partial
0.15 for drain-dry
11,093,038 Equation 2-13
5,031,769
0.50
Equation 2-26
(pages No 33,35)
1
KS =
1 + 0.053 * PVA * H VO
0.5
Equation 1-20
KS is assumed to be less than
or equal to the saturation factor
during filling (S) .
TV PV − PB
+
TLA
PA − PVA
0.028
Liquid stock has a true vapor
pressure greater than 0.1psia Equation 1-7.
saturation factor
KS
dimensionless
Vapor space expansion factor
KE
dimensionless
Standing idle losses during roof landing
LSL
lb per landing episode
PV
L SL = n d K E V M V K S
RT AA
5
Equation 2-16
Filling losses during roof landing
LFL
lb per landing episode
P * VV
M V * S
LFL =
R * T AA
41
Equation 2-26
Total losses during roof landing
LTL
lb per landing episode
Kg per landing episode
46
21
Equation 2-10
KE =
LTL=LSL+LFL
7. Summary
Working (withdrawal) losses
Breathing (standing) losses
Kg per year
Kg per year
68
16
Total Degassing and Cleaning emissions
Kg per year
750
Total losses during roof landing
Kg per year
1
836
3013.19-034.xls - 2
3/3
Kg per year
26/02/2023
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - B&W 2022
Haifa-2
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
2.68
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Aluminum/Diffuse
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
Meterological Data used in Emissions Calculations: Haifa-2, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - B&W 2022 - External Floating Roof Tank
Haifa-2, Israel
Mixture/Component
Jet kerosene
Month
All
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
76.52
65.35
87.69
Liquid
Bulk
Temp
(deg F)
68.86
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0136
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
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Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - B&W 2022 - External Floating Roof Tank
Haifa-2, Israel
Annual Emission Calcaulations
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
0.0136
160.0100
130.0000
1.0000
Withdrawal Losses (lb):
Annual Net Throughput (gal/yr.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
150.0107
20,363,275.0000
0.0075
7.0000
160.0100
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
0.8398
0.0002
130.0000
1.0000
27.8819
6.2000
Total Losses (lb):
185.3510
34.5005
1.6000
0.3000
6.2000
1.6000
0.0002
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
KFa(lb-mole/yr)
1.60
6.20
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
1.20
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.94
1.00
Losses(lb)
0.1446
0.6608
0.0345
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Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
23/02/2023
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - B&W 2022 - External Floating Roof Tank
Haifa-2, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
34.50
150.01
0.84
0.00
185.35
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
23/02/2023
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFixed 2019
Haifa
Israel
PEI
Vertical Fixed Roof Tank
kerosene
Tank Dimensions
Shell Height (ft):
Diameter (ft):
Liquid Height (ft) :
Avg. Liquid Height (ft):
Volume (gallons):
Turnovers:
Net Throughput(gal/yr):
Is Tank Heated (y/n):
N
Paint Characteristics
Shell Color/Shade:
Shell Condition
Roof Color/Shade:
Roof Condition:
Aluminum/Diffuse
Good
White/White
Good
Roof Characteristics
Type:
Height (ft)
Slope (ft/ft) (Cone Roof)
Breather Vent Settings
Vacuum Settings (psig):
Pressure Settings (psig)
11.00
160.01
11.00
5.50
1,654,664.74
1.00
1,654,664.74
Cone
0.00
0.00
0.00
0.50
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
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TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
Apr
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
72.10
62.74
81.45
Liquid
Bulk
Temp
(deg F)
67.57
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0118
0.0092
0.0159
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
02/02/2020
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Month:
Standing Losses (lb):
Vapor Space Volume (cu ft):
Vapor Density (lb/cu ft):
Vapor Space Expansion Factor:
Vented Vapor Saturation Factor:
January
February
March
April
May
June
July
August
September
October
November
December
Tank Vapor Space Volume:
Vapor Space Volume (cu ft):
Tank Diameter (ft):
Vapor Space Outage (ft):
Tank Shell Height (ft):
Average Liquid Height (ft):
Roof Outage (ft):
Roof Outage (Cone Roof)
Roof Outage (ft):
Roof Height (ft):
Roof Slope (ft/ft):
Shell Radius (ft):
Vapor Density
Vapor Density (lb/cu ft):
Vapor Molecular Weight (lb/lb-mole):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Daily Avg. Liquid Surface Temp. (deg. R):
Daily Average Ambient Temp. (deg. F):
Ideal Gas Constant R
(psia cuft / (lb-mol-deg R)):
Liquid Bulk Temperature (deg. R):
Tank Paint Solar Absorptance (Shell):
Tank Paint Solar Absorptance (Roof):
Daily Total Solar Insulation
Factor (Btu/sqft day):
Vapor Space Expansion Factor
Vapor Space Expansion Factor:
Daily Vapor Temperature Range (deg. R):
Daily Vapor Pressure Range (psia):
Breather Vent Press. Setting Range(psia):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Vapor Pressure at Daily Minimum Liquid
Surface Temperature (psia):
Vapor Pressure at Daily Maximum Liquid
Surface Temperature (psia):
Daily Avg. Liquid Surface Temp. (deg R):
Daily Min. Liquid Surface Temp. (deg R):
Daily Max. Liquid Surface Temp. (deg R):
Daily Ambient Temp. Range (deg. R):
Vented Vapor Saturation Factor
Vented Vapor Saturation Factor:
Vapor Pressure at Daily Average Liquid:
Surface Temperature (psia):
Vapor Space Outage (ft):
Working Losses (lb):
Vapor Molecular Weight (lb/lb-mole):
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Net Throughput (gal/mo.):
Annual Turnovers:
Turnover Factor:
Maximum Liquid Volume (gal):
Maximum Liquid Height (ft):
Tank Diameter (ft):
Working Loss Product Factor:
Total Losses (lb):
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Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFixed 2019 - Vertical Fixed Roof Tank
Haifa, Israel
Losses(lbs)
Components
Working Loss
Breathing Loss
Total Emissions
Jet kerosene
60.63
32.78
93.41
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 1 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Tank Indentification and Physical Characteristics
Identification
User Identification:
City:
State:
Company:
Type of Tank:
Description:
T2 - DFloating 2019
Haifa
Israel
PEI
External Floating Roof Tank
kerosene
Tank Dimensions
Diameter (ft):
Volume (gallons):
Turnovers:
160.01
7,599,816.00
1.00
Paint Characteristics
Internal Shell Condition:
Shell Color/Shade:
Shell Condition
Dense Rust
Aluminum/Diffuse
Good
Roof Characteristics
Type:
Fitting Category
Pontoon
Detail
Tank Construction and Rim-Seal System
Construction:
Welded
Primary Seal:
Mechanical Shoe
Secondary Seal
Shoe-mounted
Deck Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 2 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Liquid Contents of Storage Tank
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Mixture/Component
Jet kerosene
Month
Apr
Daily Liquid Surf.
Temperature (deg F)
Avg.
Min.
Max.
76.46
63.88
89.04
Liquid
Bulk
Temp
(deg F)
68.86
Vapor Pressure (psia)
Avg.
Min.
Max.
0.0136
N/A
N/A
Vapor
Mol.
Weight.
Liquid
Mass
Fract.
Vapor
Mass
Fract.
130.0000
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
Mol.
Weight
Basis for Vapor Pressure
Calculations
162.00
Option 1: VP70 = .011 VP80 = .015
02/02/2020
TANKS 4.0 Report
Page 3 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Detail Calculations (AP-42)
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Month:
Rim Seal Losses (lb):
Seal Factor A (lb-mole/ft-yr):
Seal Factor B (lb-mole/ft-yr (mph)^n):
Average Wind Speed (mph):
Seal-related Wind Speed Exponent:
Value of Vapor Pressure Function:
Vapor Pressure at Daily Average Liquid
Surface Temperature (psia):
Tank Diameter (ft):
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
January
February
March
April
May
June
July
August
September
October
November
December
Withdrawal Losses (lb):
Net Throughput (gal/mo.):
Shell Clingage Factor (bbl/1000 sqft):
Average Organic Liquid Density (lb/gal):
Tank Diameter (ft):
Roof Fitting Losses (lb):
Value of Vapor Pressure Function:
Vapor Molecular Weight (lb/lb-mole):
Product Factor:
Tot. Roof Fitting Loss Fact.(lb-mole/yr):
Average Wind Speed (mph):
Total Losses (lb):
Roof Fitting/Status
Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed
Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.
Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.
Quantity
3
2
1
KFa(lb-mole/yr)
1.60
6.20
0.71
Roof Fitting Loss Factors
KFb(lb-mole/(yr mph^n))
0.00
1.20
0.10
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
m
0.00
0.94
1.00
Losses(lb)
0.0000
0.0000
0.0000
02/02/2020
TANKS 4.0 Report
Page 4 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 5 of 6
TANKS 4.0.9d
Emissions Report - Detail Format
Individual Tank Emission Totals
Emissions Report for: Annual
T2 - DFloating 2019 - External Floating Roof Tank
Haifa, Israel
Losses(lbs)
Components
Rim Seal Loss
Withdrawl Loss
Deck Fitting Loss
Deck Seam Loss
Total Emissions
Jet kerosene
2.99
55.99
0.07
0.00
59.04
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
TANKS 4.0 Report
Page 6 of 6
file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm
02/02/2020
נספח ד'
חישוב פליטות ממיכל לאיסוף תשטיפים
26/02/2023
19/30
3013.19-036.doc
תוכנת :Tanksחישוב פליטה כתוצאה מאחסון ושינוי מפלס
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26/02/2023
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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב ב')
26/02/2023
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חישובי פליטה ממיכל תשטיפים
גיליון חישוב זה הוכן על ידי "פז" הנדסה וניהול ( )1980בע"מ.
אין להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ( )1980בע"מ.
26/02/2023
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