מידע בנושא מידע סביבתי- המשרד להגנת הסביבה

רשות
המשרד להגנת הסביבה
תאריך התשובה
2024-01-28
מסמכים
11 מסמכים

מסמך 1 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 141 KB)

פניות ציבור וחוק חופש המידע

כ"ג תשרי ,תשפ"ד

08אוקטובר 2023

מספר בקשה2023-0279 :

לכבוד

שלום רב,

הנדון :בקשתך לקבלת מידע -שכונת אלרואי

בהתייחס לבקשתך שבנדון ,להלן תבוא החלטתי:

.1בדיקות הניטור הסביבתי שנערכו בשכונת אלרואי ,הצמודה לחוות המכלים של תשתיות

נפט ואנרגיה ונמצאת בקרית טבעון .כלל תוצאות הבדיקות בין השנים ,2021-2014לרבות

תוצאות הניטור לגבי תרכובת הבנזן ( ,)Benzeneשנוסחתה הכימית היא – C6H6

מבדיקה שערכתי מול גורמי המקצוע במשרד עולה כי הניטור הסביבתי באזור ,כפי

שהתבקש ,נערך ע"י איגוד ערים חיפה בשנים 2016ו .2017-על כן ,אני מפנה אותך להגיש

בקשת חופש מידע לאיגוד ערים מפרץ חיפה בכתובת https://tinyurl.com/2p8vdehk

וזאת לפי סעיף )5(8לחוק חופש המידע ,התשנ"ח.1998 -

.2תכניות הדיגום הסביבתי של חומרים אורגניים נדיפים של חברת תשתיות נפט ואנרגיה–

מסוף אלרואי כנדרש מהם בתנאים לרישיון עסק לפי חוק רישוי עסקים ,התשכ"ח-

–1968סעיף זה נמצא בבדיקה.

.3כלל המכתבים ו/או ההתכתבויות בין המשרד לאיכות הסביבה לבין נציגי חברת תשתיות

נפט ואנרגיה בנוגע לניטור איכות האוויר בסביבת חוות אלרואי של חברת תשתיות נפט

ואנרגיה – סעיף זה נמצא בבדיקה.

החלטה זו ניתנה בירושלים .על החלטה זו ניתן להגיש עתירה מנהלית לבית המשפט המחוזי

בירושלים ,בשבתו כבית משפט לעניינים מנהליים.

בברכה

מיכל ריבלין

ראש תחום פניות הציבור

וחופש המידע

רחוב בנק ישראל ,7ירושלים 9136002

טל' 073-2733350/51 :דואר אלקטרוניmeyda@sviva.gov.il :

מסמך 2 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 137 KB)

פניות ציבור וחוק חופש המידע

ח' טבת ,תשפ"ד

20דצמבר 2023

מספר בקשה2023-0279 :

לכבוד

שלום רב,

הנדון :בקשתך לקבלת מידע -שכונת אלרואי

בהתייחס לבקשתך ובהמשך למידע שהועבר אלייך בתאריך ,8.10.23להלן החלטתי בעניין הנוסף:

.1בדיקות הניטור הסביבתי שנערכו בשכונת אלרואי ,הצמודה לחוות המכלים של תשתיות

נפט ואנרגיה ונמצאת בקרית טבעון .כלל תוצאות הבדיקות בין השנים ,2021-2014לרבות

תוצאות הניטור לגבי תרכובת הבנזן ( ,)Benzeneשנוסחתה הכימית היא – C6H6לאחר

בדיקה נוספת שערכנו ,מצ"ב דוחות שנתיים לעניין פליטות לאוויר ממסוף אלרואי,

שנמצאו ברשות המשרד.

.2תכניות הדיגום הסביבתי של חומרים אורגניים נדיפים של חברת תשתיות נפט ואנרגיה–

מסוף אלרואי כנדרש מהם בתנאים לרישיון עסק לפי חוק רישוי עסקים ,התשכ"ח-

–1968לחברת תש"ן מספר אתרים ,כאשר אתר אלרואי משמש לאחסון בלבד .באתר

קיימים תוצרי דלק מוגמרים ולא תזקיק נפט .אי לכך ,האתר נדרש בהעברת דו"ח שנתי

אודות הפליטות שבוצעו באותה השנה .הדוחות השנתיים צורפו לסעיף 1לעיל ,לא קיימות

דרישות נוספות לאתר.

.3כלל המכתבים ו/או ההתכתבויות בין המשרד לאיכות הסביבה לבין נציגי חברת תשתיות

נפט ואנרגיה בנוגע לניטור איכות האוויר בסביבת חוות אלרואי של חברת תשתיות נפט

ואנרגיה – מבדיקה שערכתי מול גורמי המקצוע לא נמצאו תכתובות כפי שהתבקשו על

ידך ,וזאת לפי סעיף )3(8לחוק חופש המידע ,התשנ"ח.1998-

החלטה זו ניתנה בירושלים .על החלטה זו ניתן להגיש עתירה מנהלית לבית המשפט המחוזי

בירושלים ,בשבתו כבית משפט לעניינים מנהליים.

בברכה

מיכל ריבלין

ראש תחום פניות הציבור

וחופש המידע

רחוב בנק ישראל ,7ירושלים 9136002

טל' 073-2733350/51 :דואר אלקטרוניmeyda@sviva.gov.il :

מסמך 3 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 1503 KB)

תשתיות נפט ואנרגיה בע"מ

מסו אלרואי

סיכו

פליטות לאוויר

שנת 2014

פרויקט3013.10 :

פברואר 2015

תוכ ענייני

.1מבוא 4.............................................................................................................................

.2נתוני מסו 5.....................................................................................................................

.2.1נתוני מיכלי 5.........................................................................................................

.2.2נתוני עבור מסו מילוי מיכליות כביש 9.....................................................................

.3חישוב פליטות 10 ..............................................................................................................

.3.1כללי 10 ...........................................................................................................................

.3.2סוגי פליטות מחושבות 11 ..................................................................................................

.3.3בחירת חומרי בתוכנת 11 ................................................................................... TANKS

.3.4נתוני מטאורולוגיי11 ....................................................................................................

.4סיכו פליטות לשנת 12 ............................................................................................. 2014

.4.1מיכלי 12 ........................................................................................................................

.4.2מסו מילוי מיכליות כביש 12 .............................................................................................

.4.3מיכל איסו תשטיפי 13 ...................................................................................................

.4.4סיכו ממצאי ניטור 13 .......................................................................................... LDAR

.4.5פליטה שנתית מכלל המתק 13 ...........................................................................................

.5פליטות לא שגרתיות במהל! שנת 13 ............................................................................2014

.6מקורות 14 .......................................................................................................................

10/02/2015

2/31

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טבלאות

טבלה :1נתוני מיכלי – מידע כללי ,מידות ונתוני תפעול – שנת 5 .......................................... 2014

טבלה :2נתוני מעטפת וגגות – שנת 6 ................................................................................. 2014

טבלה :3נתוני אביזרי – שנת 7 ........................................................................................ 2014

טבלה :4צבעי מייצגי לצור! חישובי אקסל ותוכנת 8 .................................................. TANKS

טבלה :5נתוני עבור מסו מילוי מיכליות כביש – שנת 9 ..................................................... 2014

טבלה :6חומרי מייצגי בתוכנת 11 ........................................................................... TANKS

טבלה :7סיכו פליטות מיכלי ) שנת 12 .......................................................................... 2014

טבלה :8סיכו פליטות מסו מילוי מיכליות כביש ) שנת 12 .................................................2014

טבלה :9סיכו פליטות חומרי אורגני נדיפי עבור רכיבי בשנת 13 ................................. 2014

טבלה :10סיכו פליטות שנתי מכלל מסו אלרואי – שנת 13 ................................................2014

נספחי

נספח א'

טבלה (AP-42) 1)5.2

נספח ב'

נתוני ניטור LDARעבור מסו אלרואי – סיכו שנת 2014

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צ מס' 2המאחס בנזי

נספח ד'

דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 3של קרוסי

נספח ה'

חישוב פליטות ממיכל לאיסו תשטיפי

נעמי אלקלעי גבע

ש

עור!

יואב פיסטינר

ש

מאשר

10/02/2015

להערות

תאור

10.02.2015

תארי!

3/31

0

גרסה

3013.10-015.doc

.1מבוא

חברת תשתיות נפט ואנרגיה בע"מ )להל תש"( מפעילה את מסו אלרואי לאחסו ושינוע

דלקי .

המסו כולל:

•

מבני משרדי

•

חוות מכלי לאחסו דלקי מסוגי שוני

•

רציפי מילוי מכליות כביש )לשימוש בעת חירו בלבד(

המסו ממוק בשוליי הדרו מערביי של קריית טבעו ,בצמוד לו וממערב ממוקמת שכונת

אלרואי ומדרו לו שכונת קרית חרושת.

באתר 9מיכלי ,מתוכ 6מיכלי תפעוליי ו) 3מיכלי אסטרטגיי )מיכלי מס' .(5,6,8

מתו! המיכלי האסטרטגיי ,מיכל אחד )מס' (8הינו מיכל "רדו" שאינו ממולא באופ

שוט ,ותכולתו מוחלפת אחת לארבע שני בלבד.

מתו! המיכלי התפעוליי ,מיכל אחד )מס' (1אינו פעיל ב – .2014

מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוס קיימות מערכות תומכות כגו

מערכות כיבוי אש ומערכות פיקוד ובקרה.

כחלק מהתנאי ברישיו עסק מדצמבר ,2010בסו כל שנה קלנדרית על תש" להגיש דו"ח

סיכו פליטות שנתי לגבי השנה שחלפה.

חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקני

הקיימי במסו.

סיכו הפליטות הוכ על ידי חברת "פז" הנדסה וניהול ) (1980בע"מ )להל פז הנדסה( ,והוא

מבוסס על סקר תהליכי ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.

10/02/2015

4/31

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.2נתוני מסו

.2.1נתוני מיכלי

בטבלאות הבאות מפורט מידע טכני של המיכלי בחוות המיכלי אלרואי.

טבלה :1נתוני מיכלי – מידע כללי ,מידות ונתוני תפעול – שנת 2014

לח $אדי

כמות

בטמפ' הנוזל

צריכה

מספר סוג הדלק

הממוצעת

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מיכל

)מ"ק(

)(mmHg

(1

28,768

32,056

גבעה חלקית 48.77

בנזי

1

28,637

405 @ 28°C

28,768

32,056

גבעה חלקית 48.77

14,957

קרוסי

2

0.833 @ 28°C

28,768

32,056

גבעה חלקית 48.77

140

סולר

3

0.507 @ 28°C

28,768

32,056

גבעה חלקית 48.77

0

סולר

0.507 @ 28°C

4

51,614

56,959

68.27

גבעה מלאה

8,342

סולר

5

0.507 @ 28°C

51,614

56,959

68.27

גבעה מלאה

0

סולר

6

0.507 @ 28°C

51,614

56,959

68.27

גבעה מלאה

סולר

7

40,340

0.507 @ 28°C

(2

34,228

36,547

48.8

גבעה חלקית

5,000

סולר

8

0.507 @ 28°C

(3

28,768

32,056

גבעה חלקית 48.77

קרוסי

9

14,957

0.833 @ 28°C

332,913

367,704

112,372

סה"כ

(1מיכל מס' 1מולא בפברואר 2014ואחס כמות קבועה של כ ) 28,600מ"ק בנזי.

(2מיכל מס' 8רוק במחצית הראשונה של ,2014מולא ב – 5,000מ"ק ביולי ואחס כמות קבועה ללא פעילות.

(3מיכל מס' 9לא היה פעיל במחצית הראשונה של 2014ואחס כמות קבועה של 28,768מ"ק קרוסי.

סוג ניקוז

בתחתית

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10/02/2015

קוטר

מיכל

)מטר(

נפח מיכל

)מ"ק(

5/31

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15.4

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9.7

3013.10-015.doc

טבלה :2נתוני מעטפת וגגות – שנת 2014

צורת גג

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צבע

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10/02/2015

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טבלה :3נתוני אביזרי – שנת 2014

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10/02/2015

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3013.10-015.doc

הנחות שנלקחו לצור! החישובי

.1עבור חישוב degassingבמיכל ע גג צ – הונח:

•

גג צ נח על רגליי בגובה ) 9-11 ftבהתא לטבלה לעיל( וזהו ג הגובה המרבי

של הנוזל במיכל.

•

גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.

.2הונח כי ניקיו כללי וריקו של המיכלי מתבצע אחת לכ) 15שני .הניקיו יאר! יו

אחד.

.3הונח כי אירוע של נחיתת גגות צפי מתבצע אחת לכ) 15שני .זמ נחיתת הגג

במקרה זה לא יעלה על 4ימי.

.4יחס הנוזל בבוצה הונח כ) [2] 0.8

.5בהתא לטבלה 7.1)6על פי ] ,[1נבחרו הצבעי הבאי כמייצגי את צבע מעטפת

המיכלי ,לצור! חישובי פליטות לאוויר:

טבלה :4צבעי מייצגי לצור! חישובי אקסל ותוכנת Tanks

צבע לצור! חישובי אקסל

צבע לצור! חישובי

בתוכנת

בהתא

למסמ! EPA AP-42

(*) Tanks

כחול בהיר

Gray Medium

Gray Medium

חאקי

Green Dark

Red/Primer

צהוב קר

Beige/Cream

Aluminium/Specular

צבע מעטפת

מיכל

)*( בתוכנת Tanksמבחר הצבעי מצומצ יותר מאשר בטבלה 7.1)6אשר במסמ!

.[1] EPA AP-42

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.2.2נתוני

עבור מסו מילוי מיכליות כביש

טבלה :5נתוני עבור מסו מילוי מיכליות כביש – שנת 2014

מס'

זרוע

1

2

3

4

5

6

7

8

מוצר

קרוסי

קרוסי

קרוסי

קרוסי

קרוסי

קרוסי

קרוסי

קרוסי

סה"כ

מילוי

עילי /תחתי

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

נפח ממוצע של

מיכלית )מ"ק(

30

30

30

30

30

30

30

30

נפח מילוי שנתי

)מ"ק(

0

0

400

388

0

0

0

0

788

הנחות שנלקחו צור! החישובי

.1

מקד (Tank paint solar absorptance) αממוצע עבור קרוסי חושב כדלקמ:

א .בשלב ראשו חושב המקד αעבור כל אחד ממיכלי הקרוסי:

דוגמת חישוב עבור מיכל מס' :2

0.17 + 0.89

= 0.53

2

=

α roof2 + α Shell2

2

= α tank2

ב .בשלב השני חושב מקד αממוצע עבור הקרוסי:

0.53 + 0.26

= 0.4

2

α tank2 + α tank9

=

number_of_kerosene_tanks

= α Kerosene

.2

זמ מילוי מיכלית חושב על פי נפח ממוצע של מיכלית וקצב מילוי שעתי מרבי של

1000ליטר/דקה.

.3

Vapor collection efficiency ) 70%

.4

Vapor recovery efficiency ) 0%

.5

Saturation factorהונח כ)(Submerged loading, dedicated normal service) 0.6

על פי ] .[1טבלה רלוונטית מצורפת בנספח א'.

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.3חישוב פליטות

.3.1כללי

חישובי הפליטות עבור מיכלי האחסו בוצעו בתוכנת Tanksובעזרת .[1] EPA-AP 42

הערכת פליטות כתוצאה מדליפות ציוד ואביזרי ) (LDARמצורפת בנספח ב'.

דוגמת חישוב עבור מיכל גג חיצוני צ )מיכל מס' (2המאחס קרוסי ,מצורפת כנספח ג'

למסמ! זה.

דוגמת חישוב עבור זרוע מילוי עילי של קרוסי )זרוע מס' (3מצורפת כנספח ד' למסמ! זה.

בדוגמאות אלה נית לראות את נתוני הקלט )כולל הנחות( עליה התבססו החישובי.

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.3.2סוגי פליטות מחושבות

הערכת הפליטות ממיכלי אחסו כוללת ]:[3

• פליטות בזמ אחסו )(Breathing Losses

• פליטות משינויי מפלס )(Working Losses

• פליטות כתוצאה מניקוי וריקו מיכלי )(Degassing Losses

• פליטות כתוצאה מנחיתת גגות צפי )(Roof Landing Losses

• פליטות כתוצאה מהפרשי לח(Flash Losses) 4

• פליטות בזמ מילוי מיכלי ומיכליות

בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לח4

).(Flash Losses

פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלח 4הנוזל ,נתו הגור להפרת שיווי

המשקל הקיי במיכל )בי גז לנוזל( וכתוצאה מכ! נוצר תהלי! הבזקה ,בו מרכיבי קלי

מפאזה הנוזל עוברי לפאזה הגזית .תופעות אלה מתרחשות ,בדר! כלל ,כאשר נוזל

המאוחס בלח 4נשלח לאחסו במיכל בעל לח 4נמו! יותר ].[3

פליטות אלו הוזנחו כיוו שכל החומרי מוחזקי בתנאי אטמוספריי בכל אחד

מהשלבי הנוגעי להובלת ואחסונ ,ולפיכ! לא צפויה פליטת אדי כתוצאה מתהלי!

זה.

.3.3בחירת חומרי

בתוכנת Tanks

על פי נתוני MSDSשל הדלקי במסו ,נבחרו החומרי הבאי הקיימי בתוכנת Tanks

כמייצגי של חומרי אלו:

טבלה :6חומרי מייצגי בתוכנת Tanks

דלק קיי

במסו

חומר מייצג בתוכנת Tanks

סולר )תחבורה והסקה(

Distillate fuel oil no 2

נפט )קרוסי(

Jet kerosene

בנזי

Gasoline RVP 10

.3.4נתוני

מטאורולוגיי

לצור! חישוב הנתוני בתוכנת Tanksהוגדרו נתוני מטאורולוגי המתאימי למפר4

חיפה על פי מקורות ].[4

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.4סיכו

פליטות לשנת 2014

.4.1מיכלי

סיכו חישובי פליטה עבור כל אחד ממיכלי האחסו מפורט בטבלה להל:

טבלה :7סיכו פליטות מיכלי ) שנת 2014

מיכל

חומר

1

בנזי

2

קרוסי

3

סולר

4

סולר

5

סולר

6

סולר

7

סולר

8

סולר

9

קרוסי

סה"כ

פליטות לאוויר

)ק"ג/שנה(

3775

786

816

826

1,701

1,695

1,721

800

798

12,919

.4.2מסו מילוי מיכליות כביש

להל טבלת סיכו חישובי פליטות עבור זרועות המילוי.

טבלה :8סיכו פליטות מסו מילוי מיכליות כביש ) שנת 2014

מס' זרוע

מוצר

מילוי עילי /תחתי

פליטה שנתית )ק"ג(

1

2

3

4

5

6

7

8

סה"כ

קרוסי

קרוסי

קרוסי

קרוסי

קרוסי

קרוסי

קרוסי

קרוסי

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

0.00

0.00

1.39

1.39

0.00

0.00

0.00

0.00

2.77

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.4.3מיכל איסו תשטיפי

ס! הפליטה ממיכל לאיסו תשטיפי הינה כ) 1ק"ג/שנה.

חישוב מצור בנספח ה'.

יצוי #כי החישוב מתבסס על הנחה מחמירה שהמיכל מכיל קרוסי #בלבד .מעשית ,המיכל

מכיל בעיקר ניקוז מי

מהמיכלי

.

.4.4סיכו

ממצאי ניטור LDAR

טבלה :9סיכו פליטות חומרי אורגני נדיפי עבור רכיבי בשנת 2014

סה"כ פליטות )ק"ג/שנה(

סיכו

פליטות LDAR

פליטה שנתית )ק"ג/שנה(

סה"כ

24.82

.4.5פליטה שנתית מכלל המתק#

טבלה :10סיכו פליטות שנתי מכלל מסו אלרואי – שנת 2014

סה"כ פליטות )ק"ג/שנה(

חוות מיכלי

מסו מילוי

מיכליות כביש

מיכל לאיסו

תשטיפי

12,919

2.77

1

סיכו

פליטות

רכיבי

סה"כ

)(LDAR

24.82

12,948

.5פליטות לא שגרתיות במהל! שנת 2014

במהל! שנת 2014לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.

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.6מקורות

[1] EPA-AP42

[2] USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software

Version 4.0 - APPENDIX D

] [3הנחיות הממונה לטיפול בבקשה להיתר פליטה לפי סעי )9א( לתקנות אוויר נקי )היתרי

פליטה( ,התש"ע – ,2010מהדורה ,1ספטמבר 2011

] [4האטלס האקלימי לתכנו פיסי וסביבתי בישראל ,מהדורה שניה1994 ,

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נספח א'

טבלה 5.2

1

AP-42

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נספח ב'

נתוני ניטור LDARעבור אלרואי – סיכו

שנת 2014

)מתו! דיווח שהתקבל ממעבדות אקולוגיה מתארי! (14.12.14

3013.10

002A

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החברה הארצית לבדיקות ושירותי איכות הסביבה

רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.

טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),

E-mail :michael.o@ecologicalab.com

LDAR

דו"ח איתור

דליפות מרכיבי ציוד מס'

R-TASH-AL-R4-14

מפעל :תשתיות נפט ואנרגיה בע"מ

ישוב :קרית טבעון

מחוז :חיפה

מתקן :אלרואי

קטגורייה1-2 :

תקופת הניטור :סבב 5

סבב 6

סיכום שנתי

תאריך הדפסת הדו"ח14-Dec-14 :

שמות אנשי צוות :סלבה פוליק

יאן פורצלן

עורך הדו"ח :מיכאל אורייבסקי

מאשר הדו"ח :אלכסי רטנר ,מנכ"ל

This report produced using Orr LeakDAS software.

תוכן עניינים

1תיאור הפרויקט:

1.1סיכום ביצוע

3

1.2שלבי הפרויקט

3

2מתודולוגיה:

4

2.1הגדרות

2.2מתודולוגיה

4

2.3אופן ביצוע חישובים

4

3סיכום תקופת הניטור:

3.1סיכום נתונים מצטברים לתקופה

01/01/2014 - 31/12/2014

6

3.2סיכום תוצאות הניטור ,סבב 5

7

3.3סיכום תוצאות הניטור ,סבב 6

8

4סיכום שנתי 01/01/2014 - 31/12/2014

4.1טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

10

4.2פילוג לחומרים הנפלטים

11

4.3טופס תיקון דליפות שנתי

13

5תוצאות הניטור במדידה הראשונה:

5.1טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

15

5.2פילוג לחומרים הנפלטים

16

5.3טופס :15דו"ח תיקון דליפות למתקן ייצור

18

6תוצאות הניטור אחרי סבב התיקונים:

page 2 of 22

6.1טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

20

6.2פילוג לחומרים הנפלטים

21

INDEX

TASHAN-LDAR_R-TASH-AL-R4-14

1תיאור הפרוייקט:

1.1סיכום ביצוע:

הניטור בוצע לסוגי הרכיבים הבאים:

קטגוריה :1משאבות ,ציוד ערבוב וערבול ,PRD ,נקודות דגימה.

קטגוריה :2ברזים,שסתומים וצינורות פתוחים פוטנציאליים.

קטגוריה :3מחברים ואוגנים.

1.2שלבי הפרויקט:

● ניטור רכיבים

● במהלך רבעון בוצעו שני סבבי הניטור לרכיבי ציוד מקטגוריה 1במתקן אלרואי

● ניטור חוזר אחרי תיקון הדליפות.

● עדכון בסיס הנתונים.

● עדכון תזרימים .P&ID

1.3יחידות ציוד לניטור )כל המתקנים(:

מסוף

אלרואי

מסוף נמל

הדלק

מס' מיכל

מס' מיכל

מס' מיכל

מס' מיכל

מס' מיכל

מס' מיכל

T-44

T-95

T-133

T-140

T-1

T-113

T-45

T-127

T-136

קווי צנרת

קווי צנרת

T-164

T-69

T-128

T-137

T-74

T-129

T-138

T-94

T-131

T-139

טרמינל קרית חיים

T-165

קווי צנרת

בחוות

המיכלים

מערכת

VRU

הערות:

.1מתקן VRUשבמתקן נמל הדלק לא נבדק עקב חוסר הפעילות.

.2מפלס גג המיכל T-113שבנמל הדלק היה נמוך במשך תקופת הניטור ,לכן

המיכל לא נבדק מטעמי הבטיחות.

הערות כלליות:

.1חברת "מעבדות אקולוגיה א.פ .בע"מ" מוסמכת לתקן ISO-17025

ISO-17025לביצוע בדיקות LDARע"י ) ISRAQהרשות להסמכת מעבדות(.

.2הרשות להסמכת מעבדות אינה אחראית על תוצאות הבדיקות.

page 3 of 22

Project Introduction

TASHAN-LDAR_R-TASH-AL-R4-14

2מתודולוגיה:

2.1הגדרות:

נוזל קל :כל נוזל עם יותר מ 10% -נפחי של VOCהמתנדף ב 150-מעלות צלסיוס.

נוזל כבד :כל נוזל עם 10%נפחי של VOCאו פחות המתנדף ב 150-מעלות צלסיוס.

דליפה :גילוי של ריכוז TOCבפאזה גזית בסך 1,000חל"מ או יותר.

רכיב בלתי נגיש :כל רכיב הממוקם בגובה של יותר מ 5-מ' מעל הקרקע ,כאשר נדרשת גישה מהקרקע,

או כל רכיב הממוקם במרחק של יותר מ 2-מ' מפלטפורמה ,כאשר נדרשת גישה

מפלטפורמה ,ולא ניתן לגשת אליהם בצורה בטיחותית ע"י העובד ,או כל רכיב העלול

להצריך את הרתמתם של אנשי צוות ניטור לגובה של יותר מ 2-מ' מעל למשטחי

תמיכה קבועים ולא ניתן לגשת אליו בצורה בטיחותית.

2.2אופן ביצוע חישובים:

נוסחאות :חישוב הפליטות מדליפות מרכיבי ציוד נעשה בהתאם לגישת הקורלציה המפורטת

בפרוטוקול ה EPA-עבור תעשיה פטרוכימית.

US EPA "Protocol for equipment leak emission estimates",1995

"נתונים מצטברים" :בטבלאות "נתונים מצטברים" אנחנו מציגים תוצאות של כל המדידות שבוצעו מתחילת

השנה ועד סוף תקופת הניטור הנוכחית )שנה(.

חישוב הפליטה המצטברת נעשה בהתאם לModified Trapezoidal Method-

US EPA "Emission Estimation Protocol for Petroleum Refineries",Ver.2.1.1, 2011

page 4 of 22

Methodology

TASHAN-LDAR_R-TASH-AL-R4-14

- חישוב קצב פליטה שעתי ושנתי מרכיבי ציוד בוצע בהתאם ל2.3

)בהמשךProtocol for equipment leak emission estimates,2.0. (EPA,1995)

."Petroleum Industry" "פרוטוקול"( סקטור תעשייה רלוונטי הינו

: חל"מ9 ≤ דליפות

Equipment type

kg/year

Valves/all

2.29E-06 * (measured ppm value)^0.746 * production hours

Pump seals/all

5.03E-05 * (measured ppm value)^0.610 * production hours

Others/all *

1.36E-05 * (measured ppm value)^0.589 * production hours

Connectors/all

1.53E-06 * (measured ppm value)^0.735 * production hours

Flanges/all

4.61E-06 * (measured ppm value)^0.703 * production hours

Open-ended lines/all

2.20E-06 * (measured ppm value)^0.704 * production hours

. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- Others :הערה

: חל"מ9 > דליפות

Equipment type

kg/year

Valves/all

7.80E-06 * production hours

Pump seals/all

2.40E-05 * production hours

Others/all *

4.00E-06 * production hours

Connectors/all

7.50E-06 * production hours

Flanges/all

3.10E-07 * production hours

Open-ended lines/all

2.00E-06 * production hours

. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- "Others" :הערה

: חל"מ100,000 < דליפות

Equipment type

kg/year

Valves/all

0.140 * production hours

Pump seals/all

0.160 * production hours

Others/all *

0.110 * production hours

Connectors/all

0.030 * production hours

Flanges/all

0.084 * production hours

Open-ended lines/all

0.079 * production hours

. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- "Others" :הערה

:( )ק"גVOC חישוב פליטת

Evoc = Etoc * WTvoc/WTtoc

אחוז משקלי- WT כאשר

קצב פליטה- E

TASHAN-LDAR_R-TASH-AL-R4-14

Equations

page 5 of 22

01/01/2014 - 31/12/2014

3.1סיכום שנתי

סיכום לפי סוג הרכיב

סה"כ

רכיבים

אחוז רכיבים

רכיבים

רכיבים

מעל 1,000חל"מ

מעל 1,000חל"מ

לא מתוקנים

סוג

רכיב

מספר

R1

R3

R2

מספר

R5

R4

R1

R6

R3

R2

R5

R4

R1

R6

R2

מצטברת

count

%

R3

פליטה

R4

R5

R1

R6

R3

R2

ק"ג

R4

R6

R5

01/01/2014 - 31/12/2014

משאבות0 :

0

0

0

0

0

0

0

!DIV/0# !DIV/0#

0 !DIV/0#

0

0

0.000

ציוד ערבוב0 :

0

0

0

0

0

0

0

!DIV/0# !DIV/0#

0 !DIV/0#

0

0

0.000

4 :PRD

4

4

4

4

4

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

2.177

נקודות דגימה4 :

4

4

4

4

4

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

3.021

סה"כ קטגוריה 8 :1

8

8

8

8

8

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

5.197

ברזים ושסתומים0 :

0

20

20

0

0

0

0

0

0

0.0% !DIV/0# !DIV/0#

0.0%

0 !DIV/0#

0

0

0

0

1.363

צינורות פתוחים0 :

0

102

102

0

0

0

1

0

0

1.0% !DIV/0# !DIV/0#

0.0%

0 !DIV/0#

0

1

0

0

11.760

סה"כ קטגוריה 0 :2

0

122

122

0

0

0

1

0

0

!DIV/0#

0.8% !DIV/0#

0.0%

0 !DIV/0#

0

1

0

0

13.122

מחברים ואוגנים0 :

0

93

0

0

0

0

0

0.0% !DIV/0# !DIV/0#

0 !DIV/0#

0

0

0

6.501

סה"כ קטגוריה 0 :3

0

93

0

0

0

0

0

!DIV/0#

0.0% !DIV/0#

0 !DIV/0#

0

0

0

6.501

8 :Total

8

223

8

0

0

1

0

0.0%

0.4%

0

0

1

0

24.821

130

8

0

0

0.0%

0.0%

0.0%

0.0%

0

0

סיכום לפי קטגוריית הפליטה

סה"כ רכיבים

R1

#

קטגוריית פליטה

0-9חל"מ 8

R2

#

%

R3

#

%

R4

#

%

R5

#

%

R6

%

%

#

100.0%

7

87.5%

218

97.8%

7

87.5%

130

100.0%

8

100.0%

9-1,000חל"מ 0

0.0%

1

12.5%

4

1.8%

1

12.5%

0

0.0%

0

0.0%

1,000-100,000חל"מ 0

0.0%

1

12.5%

1

0.4%

0

0.0%

0

0.0%

0

0.0%

מעל 100,000חל"מ 0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

סה"כ מעל 1,000חל"מ 0

0.0%

0

0.0%

1

0.4%

0

0.0%

0

0.0%

0

0.0%

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

100.0%

8

112.5%

223

100.0%

8

100.0%

130

100.0%

8

100.0%

רכיבים בלתי נגישים 0

סה"כ8 :

הערות = "R" :מספר של סבב ניטור

page 6 of 22

Cumulative Data

TASHAN-LDAR_R-TASH-AL-R4-14

3.2סיכום תקופת הניטור :סבב 5

3.2.1תוצאות הניטור במדידה הראשונה:

סיכום לפי סוג הרכיב

סוג

סה"כ

רכיבים

רכיבים

קצב פליטה

קצב פליטה

רכיב

רכיבים

9-1000חל"מ

מעל 1,000חל"מ

שעתי

שנתי

מספר

ק"ג/שעה

מספר

משאבות0 :

ציוד ערבוב0 :

4 :PRD

נקודות דגימה4 :

ברזים ושסתומים20 :

צינורות פתוחים102 :

מחברים ואוגנים0 :

סה"כ130 :

מספר

0

0

0

0

0

0

0

0

0.00000

0.00000

0.00002

0.00002

0.00016

0.00020

0.00000

0.00039

0

0

0

0

0

0

0

0

ק"ג/שנה

0.000

0.000

0.140

0.140

1.363

1.782

0.000

3.425

סיכום לפי קטגוריית הפליטה

קטגוריית

סה"כ

אחוז מסה"כ

קצב פליטה

קצב פליטה

אחוז מסה"כ

הפליטה

רכיבים

רכיבים

שעתי

שנתי

קצב פליטה

מספר

%

ק"ג/שעה

שנתי

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

100%

0-9חל"מ 130

9-1,000חל"מ 0

1,000-100,000חל"מ 0

מעל 100,000חל"מ 0

סה"כ מעל 100,000חל"מ 0

רכיבים בלתי נגישים 0

סה"כ130 :

0.00039

0.00000

0.00000

0.00000

0.00000

0.00000

0.00039

ק"ג/שנה

3.425

0.000

0.000

0.000

0.000

0.000

3.425

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

100%

3.2.2תוצאות הניטור אחרי סבב התיקונים:

סיכום לפי סוג הרכיב

סוג

סה"כ

רכיבים

רכיבים

קצב פליטה

קצב פליטה

רכיב

רכיבים

9-1000חל"מ

מעל 1,000חל"מ

שעתי

שנתי

מספר

ק"ג/שעה

מספר

משאבות0 :

ציוד ערבוב0 :

4 :PRD

נקודות דגימה4 :

ברזים ושסתומים20 :

צינורות פתוחים102 :

מחברים ואוגנים0 :

סה"כ130 :

מספר

0

0

0

0

0

0

0

0

0.00000

0.00000

0.00002

0.00002

0.00016

0.00020

0.00000

0.00039

0

0

0

0

0

0

0

0

ק"ג/שנה

0.000

0.000

0.140

0.140

1.363

1.782

0.000

3.425

סיכום לפי קטגוריית הפליטה

קטגוריית

סה"כ

אחוז מסה"כ

קצב פליטה

קצב פליטה

אחוז מסה"כ

הפליטה

רכיבים

רכיבים

שעתי

שנתי

קצב פליטה

מספר

%

ק"ג/שעה

שנתי

0-9חל"מ 130

9-1,000חל"מ 0

1,000-100,000חל"מ 0

מעל 100,000חל"מ 0

סה"כ מעל 100,000חל"מ 0

רכיבים בלתי נגישים 0

סה"כ130 :

page 7 of 22

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

100%

0.00039

0.00000

0.00000

0.00000

0.00000

0.00000

0.00039

Summary

ק"ג/שנה

3.425

0.000

0.000

0.000

0.000

0.000

3.425

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

100%

TASHAN-LDAR_R-TASH-AL-R4-14

3.3סיכום תקופת הניטור :סבב 6

3.3.1תוצאות הניטור במדידה הראשונה:

סיכום לפי סוג הרכיב

סוג

רכיב

רכיבים

9-1000חל"מ

סה"כ

רכיבים

מספר

משאבות0 :

ציוד ערבוב0 :

4 :PRD

נקודות דגימה4 :

ברזים ושסתומים0 :

צינורות פתוחים0 :

מחברים ואוגנים0 :

סה"כ8 :

רכיבים

מעל 1,000חל"מ

קצב פליטה

שעתי

קצב פליטה

שנתי

מספר

ק"ג/שעה

ק"ג/שנה

מספר

0

0

0

0

0

0

0

0

0.00000

0.00000

0.00002

0.00002

0.00000

0.00000

0.00000

0.00003

0

0

0

0

0

0

0

0

0.000

0.000

0.140

0.140

0.000

0.000

0.000

0.280

סיכום לפי קטגוריית הפליטה

קטגוריית

הפליטה

סה"כ

רכיבים

אחוז מסה"כ

רכיבים

קצב פליטה

שעתי

קצב פליטה

שנתי

אחוז מסה"כ

קצב פליטה

שנתי

מספר

%

ק"ג/שעה

ק"ג/שנה

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

100%

0-9חל"מ 8

9-1,000חל"מ 0

1,000-100,000חל"מ 0

מעל 100,000חל"מ 0

סה"כ מעל 100,000חל"מ 0

רכיבים בלתי נגישים 0

סה"כ8 :

0.00003

0.00000

0.00000

0.00000

0.00000

0.00000

0.00003

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

100%

0.280

0.000

0.000

0.000

0.000

0.000

0.280

3.3.2תוצאות הניטור אחרי סבב התיקונים:

סיכום לפי סוג הרכיב

סוג

רכיב

רכיבים

9-1000חל"מ

סה"כ

רכיבים

מספר

משאבות0 :

ציוד ערבוב0 :

4 :PRD

נקודות דגימה4 :

ברזים ושסתומים0 :

צינורות פתוחים0 :

מחברים ואוגנים0 :

סה"כ8 :

מספר

0

0

0

0

0

0

0

0

רכיבים

מעל 1,000חל"מ

קצב פליטה

שעתי

קצב פליטה

שנתי

מספר

ק"ג/שעה

ק"ג/שנה

0.00000

0.00000

0.00002

0.00002

0.00000

0.00000

0.00000

0.00003

0

0

0

0

0

0

0

0

0.000

0.000

0.140

0.140

0.000

0.000

0.000

0.280

סיכום לפי קטגוריית הפליטה

קטגוריית

הפליטה

0-9חל"מ 8

9-1,000חל"מ 0

1,000-100,000חל"מ 0

מעל 100,000חל"מ 0

סה"כ מעל 100,000חל"מ 0

רכיבים בלתי נגישים 0

סה"כ8 :

page 8 of 22

סה"כ

רכיבים

אחוז מסה"כ

רכיבים

קצב פליטה

שעתי

קצב פליטה

שנתי

אחוז מסה"כ

קצב פליטה

שנתי

מספר

%

ק"ג/שעה

ק"ג/שנה

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

100%

0.00003

0.00000

0.00000

0.00000

0.00000

0.00000

0.00003

Summary

0.280

0.000

0.000

0.000

0.000

0.000

0.280

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

100%

TASHAN-LDAR_R-TASH-AL-R4-14

החברה הארצית לבדיקות ושירותי איכות הסביבה

רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.

טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),

E-mail :michael.o@ecologicalab.com

.4סיכום שנתי:

01/01/2014 - 31/12/2014

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

טופס תיקון דליפות שנתי

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור .נתונים מצטברים.

תאריך12/14/2014 :

שם המפעל :תשתיות נפט ואנרגיה בע"מ

דו"ח מס'R-TASH-AL-R4-14 :

סוג

סוג

רכיב

שירות

תקופת חישוב הפליטות01/01/2014 - 31/12/2014 :

שם המתקן :אלרואי

רכיבים עיקריים

סה"כ רכיבים

סה"כ רכיבים מעל 1,000חל"מ

רכיבים בלתי נגישים

רכיבים מ 0-עד 9חל"מ

רכיבים לא מתוקנים

רכיבים מ 1,000-עד 100,000חל"מ

רכיבים מ 9-עד 1,000חל"מ

פליטה משוקללת

רכיבים מעל 100,000חל"מ

תדירות

רכיבים מ 9-עד 1,000חל"מ

מדידות

מספר

R1

R3

R2

מספר

R5

R4

R6

R1

R2

R3

R4

מספר

R5

R6

R1

R2

R3

R4

מספר

R5

R6

R1

R2

R3

R4

מספר

R5

R6

R1

R2

R3

R4

מספר

R5

R6

R1

R3

R2

מספר

R5

R4

R6

R1

R2

R3

R4

מספר

R5

R6

R1

R2

R3

R4

מספר

R5

R6

R1

R2

R3

R4

ק"ג

R5

R6

סבבים/שנה

%

R1

R2

R3

R4

R6

R5

משאבות

6

גז

נוזל קל

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

6

גז

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

6

ציוד ערבוב

וערבול

נוזל קל

6

גז

6

PRD

נוזל קל

4

4

4

4

4

4

1

1

1

1

1

1

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

4

3

4

4

4

4

0

1

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

6

2.177

נקודות

6

גז

דגימה

4

4

4

4

4

4

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

4

4

4

3

4

4

0

0

0

1

0

0

0

0

0

0

0

0

0

0

0

0

0

0

3.021

סה"כ קטגוריה 8 :1

8

8

8

8

8

1

1

1

1

1

1

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

8

7

8

7

8

8

0

1

0

1

0

0

0

0

0

0

0

0

0

0

0

0

0

0

5.197

נוזל קל

6

0.0

0.0

0.0

0.0

0.0

0.0

שסתומים ,ברזים

2

גז

וציוד תלוי

20

נוזל קל

20

0

16

0

0

0

0

0

0

20

20

0

0

0

0

0

0

2

1.363

צינורות פתוחים

2

גז

פוטנציאלים

102

נוזל קל

סה"כ קטגוריה 0 :2

0

122

102

0

122

0

0

0

0

0

0 16

0

0

0

0

0

0

0

0

0

0

0

1

0

0

1

0

0

0

0

0

0

0

0

0

0

97

0

0

0

117

102

0

122

4

0

0

0

4

0

0

0

1

0

0

0

1

0

0

0

0

0

0

0

0

0

0

0

11.760

0

13.122

2

0.0

0.8 #### ####

מחברים ואוגנים

1

גז

93

נוזל קל

0

סה"כ קטגוריה 0 :3

0

93

סה"כ רכיבים8 :

8

8 223

סה"כ פליטות:

page 10 of 22

24.82

0

0

0

0

0

93

0

0

6.501

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

93

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

6.501

130

8

1

1

1 17

1

1

0

0

0

0

0

0

0

0

1

0

0

0

0

0

0

0

0

0

8

7

218

7

130

8

0

1

4

1

0

0

0

0

1

0

0

0

0

0

0

0

0

0

24.821

1

0.0 #### ####

0.0

0.0

0.4

#### #### ####

0.0

0.0

0.0

kg

Form-07 CU

TASHAN-LDAR_R-TASH-AL-R4-14

Correlation Equations Chemical Summary by Component Class

Report Date: 12/14/2014

Calculation Period:

01/01/2014 - 31/12/2014

Units of Measurement:

KG

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

108883

Emissions

0.0000

0.0000

Cyclohexane

0.0000

MTBE

0.0000

n-Octane

Toluene

0.0000

0.0000

0.0000

Chemical Name

CAS Number

Component Class:

1-Butene

108883

Agitators

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Chemical Name

CAS Number

Component Class:

1-Butene

108883

PRD

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

Emissions

0.2177

0.0218

0.1088

0.2177

0.8706

0.7400

2.1766

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.3021

0.0302

0.1510

0.3021

1.2082

1.0270

3.0206

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1363

0.0136

0.0681

0.1363

0.5450

0.4633

1.3625

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

1.1760

0.1176

0.5880

1.1760

4.7040

3.9984

11.7599

TASHAN-LDAR_R-TASH-AL-R4-14

Chem Cu

page 11 of 22

Correlation Equations Chemical Summary by Component Class

Report Date: 12/14/2014

Calculation Period:

01/01/2014 - 31/12/2014

Units of Measurement:

KG

אלרואי

Unit

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.6501

0.0650

0.3251

0.6501

2.6005

2.2104

6.5013

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

2.4821

0.2482

1.2410

2.4821

9.9284

8.4391

24.8209

Grand Total:

24.8209

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-R4-14

Chem Cu

page 12 of 22

Leaker Detail Report

Report Parameters

Alroy

Report: R304_1

ISRAEL

All Classes

Report Date:

Compliance Leak

12/14/2014

Alroy

Details

Class

Location

Tag: 75

POE

Date

Reported

Drawing:

Top of T-1

06/22/2014

Test

Type

Leak

Def

1st Att. Due

Repair Due

Repaired

07/01/2014

07/01/2014

07/06/2014

Date

Event

Result

Technician

Instrument

Method21 Insp

Repair Attempt

Method21 Insp

12500 ppm

04

Sealing

722 ppm

polik

tva

ourievsky

tva

6006-100-007

M

999

6/22/2014 2:46:09 PM

7/6/2014 10:17:32 AM

7/6/2014 10:17:33 AM

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-R4-14

LDAR Report_015 Annual

page 13 of 22

החברה הארצית לבדיקות ושירותי איכות הסביבה

רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.

טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),

E-mail :michael.o@ecologicalab.com

סבב 5

.5תוצאות הניטור במדידה הראשונה

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

טופס :15דו"ח תיקון דליפות למתקן ייצור

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

תאריך12/14/2014 :

דו"ח מס'R-TASH-AL-R4-14 :

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מ 9-עד

1,000חל"מ

מספר

רכיבים

רכיבים

מ 1,000-עד

מעל

100,000חל"מ 100,000חל"מ

מספר

מספר

מספר

קצב

קצב

אחוז

פליטה

פליטה

רכיבים מעל

שעתי

שנתי

1,000חל"מ

ק"ג/שעה

ק"ג/שנה

%

!#DIV/0

נוזל קל

ציוד ערבור

וערבול

נוזל קל

PRD

גז

נוזל קל

נקודות דגימה

!#DIV/0

4

1

0

0

0

4

0

0

0.000016

0.140

4

0

0

0

4

0

0

0

0.000016

סה"כ קטגוריה 8 :1

1

0

0

8

0

0

0

0.000

וציוד תלוי

נוזל קל

צינורות פתוחים

גז

פוטנציאליים

נוזל קל

6

6

0.0%

2

20

0

0

0

0

20

0

0

0.000156

1.363

2

2

102

0

0

0

102

0

0

0

0.000203

1.782

סה"כ קטגוריה 122 :2

0

0

0

122

0

0

0

0.000

3.145

מחברים ואוגנים

2

0.0%

1

גז

1

נוזל קל

סה"כ קטגוריה 0 :3

סה"כ130 :

page 15 of 22

6

6

0.280

ברזים ,שסתומים

6

6

0.140

גז

סבבים/שנה

6

גז

נוזל קל

הניטור

6

גז

גז

תדירות

0

0

0

0

0

0

0

0.000

0.000

1

0

0

130

0

0

0

0.000

3.425

Form-07

!#DIV/0

0.0%

TASHAN-LDAR_R-TASH-AL-R4-14

Correlation Equations Chemical Summary by Component Class

Report Date: 12/14/2014

Units of Measurement:

KG/year

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

108883

Emissions

0.0000

0.0000

Cyclohexane

0.0000

MTBE

n-Octane

0.0000

0.0000

Toluene

0.0000

0.0000

Chemical Name

CAS Number

Component Class:

1-Butene

108883

Agitators

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1782

0.0178

0.0891

0.1782

0.7128

0.6059

1.7821

TASHAN-LDAR_R-TASH-AL-R4-14

Chem

page 16 of 22

Correlation Equations Chemical Summary by Component Class

Report Date: 12/14/2014

Units of Measurement:

KG/year

אלרואי

Unit

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.3425

0.0342

0.1712

0.3425

1.3698

1.1643

3.4245

Grand Total:

3.4245

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-R4-14

Chem

page 17 of 22

Leaker Detail Report

Report Parameters

Alroy

Report: R304_1

ISRAEL

All Classes

Report Date:

Compliance Leak

12/14/2014

Alroy

Details

Class

Location

Date

Reported

Test

Type

Leak

Def

1st Att. Due

Repair Due

Repaired

Date

Event

Result

Technician

Instrument

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-R4-14

LDAR Report_015

page 18 of 22

החברה הארצית לבדיקות ושירותי איכות הסביבה

רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.

טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),

E-mail :michael.o@ecologicalab.com

סבב 5

.6תוצאות הניטור באחרי סבב התיקונים:

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

תאריך12/14/2014 :

דו"ח מס'R-TASH-AL-R4-14 :

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מ 9-עד

1,000חל"מ

מספר

רכיבים

רכיבים

מ 1,000-עד

מעל

100,000חל"מ 100,000חל"מ

מספר

מספר

מספר

קצב

קצב

אחוז

פליטה

פליטה

רכיבים מעל

שעתי

שנתי

1,000חל"מ

ק"ג/שעה

ק"ג/שנה

%

!#DIV/0

נוזל קל

ציוד ערבור

וערבול

נוזל קל

PRD

גז

נוזל קל

נקודות דגימה

!#DIV/0

4

1

0

0

0

4

0

0

0.000016

0.140

4

0

0

0

4

0

0

0

0.000016

סה"כ קטגוריה 8 :1

1

0

0

8

0

0

0

0.000

וציוד תלוי

נוזל קל

צינורות פתוחים

גז

פוטנציאליים

נוזל קל

6

6

0.0%

2

20

0

0

0

0

20

0

0

0.000156

1.363

2

2

102

0

0

0

102

0

0

0

0.000203

1.782

סה"כ קטגוריה 122 :2

0

0

0

122

0

0

0

0.000

3.145

מחברים ואוגנים

2

0.0%

1

גז

1

נוזל קל

סה"כ קטגוריה 0 :3

סה"כ130 :

page 20 of 22

6

6

0.280

ברזים ,שסתומים

6

6

0.140

גז

סבבים/שנה

6

גז

נוזל קל

הניטור

6

גז

גז

תדירות

0

0

0

0

0

0

0

0.000

0.000

1

0

0

130

0

0

0

0.000

3.425

Form-07 Rep

!#DIV/0

0.0%

TASHAN-LDAR_R-TASH-AL-R4-14

Correlation Equations Chemical Summary by Component Class

Report Date: 12/14/2014

Units of Measurement:

KG/year

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

108883

Emissions

0.0000

0.0000

Cyclohexane

0.0000

MTBE

n-Octane

0.0000

0.0000

Toluene

0.0000

0.0000

Chemical Name

CAS Number

Component Class:

1-Butene

108883

Agitators

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1782

0.0178

0.0891

0.1782

0.7128

0.6059

1.7821

TASHAN-LDAR_R-TASH-AL-R4-14

Chem Rep

page 21 of 22

Correlation Equations Chemical Summary by Component Class

Report Date: 12/14/2014

Units of Measurement:

KG/year

אלרואי

Unit

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.3425

0.0342

0.1712

0.3425

1.3698

1.1643

3.4245

Grand Total:

3.4245

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-R4-14

Chem Rep

page 22 of 22

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צ מס' 2המאחס#

קרוסי#

3013.10-013 T2

10/02/2015

18/31

3013.10-015.doc

T2 - kerosene

External Floating roof

1. Tank data

Diameter of the tank

D

Effective height of the stock liquid (while

roof landing episode)

hle

Shell Color and condition

α

Roof color and condition

α

Tank paint solar absorptance

α

Vapor space outage (while roof landing

episode)

HVO

m

feet

m

feet

color

condition

color

condition

dimensionless

m

Tank data

--Tank data

--חאקי

טובה

לבן

טוב

48.77

160.01

11.00

0.89

Table 7.1-6

Assumption - Green Dark

0.17

Table 7.1-6

0.53

Table 7.1-6

Possible to use also equation

1-15

assumption - equal to legs height

feet

11.00

Volume of the vapor space (while roof

landing episode)

Breather vent pressure setting

VV

ft

3

VV=PI()*D /4*Hvo

221,185

Equation 1-3

∆PBP

psi

Typical value

0.50

Equation 1-11

Breather vent vacuum setting

∆PBV

psi

Typical value

0.00

Equation 1-11

Breather vent pressure setting range

∆PB

psi

∆PB = PBP − PBV

0.50

Equation 1-11

2

2. Material data - קרוסין

Stock vapor molecular weight

MV

Density of the liquid inside the tank

Wl

Vapor density

WV

True vapor pressure of the stock liquid

P

Vapor pressure at daily average liquid

surface temperature

Vapor pressure at the daily maximum

liquid surface temperature, psia

Vapor pressure at the daily minimum

liquid surface temperature

Daily vapor pressure range

3013.10-013.xls - 2

gr/gr-mole

lb/lb-mole

g/ml

lb/gal

kg/m^3

lb/ft3

msds data

130

msds data

--msds data

---

0.80

6.68

4.5

0.28

mm Hg

PEI data

0.833

psia

--הנחה:

Pv=nRT -->

P2=P1*(T2/T1)

0.02

0.02

0.02

0.00

PVA

psia

PVX

psia

PVN

psia

T1(k)=20C+273

T2(k)=37.5C+273

∆PV

psia

∆PV = PVX − PVN

1/3

0

at 20°C

0.02

Equation 1-9

02/02/2015

3. Operation data

Number of days that the tank stands idle

(on roof landing episode)

Number of degassing and cleaning

episode

Number of roof landing episode

nd

days/landing episode

site data

4

landing episode/year

site data

0.07

landing episode/year

site data

0.07

Tanks Program

--Tanks Program

---

29

13

75

34

21

Tanks Program

---

60.05

27

lb per emptying

Tanks Program

67

Kg per emptying

---

30

4. Normal operation (Tanks program)

lb per year

Kg per year

lb per year

Kg per year

Kg per year

Working (withdrawal) losses

Total emissions (Breathing & Working)

Breathing (standing) losses

5. Degassing and Cleaning (Tanks program)

Degassing: emission from one turnover of

lb per emptying

Edegass-floating

floating roof

Kg per emptying

Degassing: fixed roof with a height of roof

legs

Edegass-legs

Liquid fraction in sludge

Fliquid

Sludge volume

Sludge weight

Vs

Ws

Cleaning emissions

Ecleaning

Total Degassing and Cleaning emissions

Edegass-total

3013.10-013.xls - 2

0.8

m3 per emptying

Kg per emptying

lb per emptying

Kg per emptying

lb per emptying

Kg per emptying

Ecleaning = Ws * (1-Fliquid)

Edegass-total =

Edegass-floating + Edegass-legs + Ecleaning

2/3

T2 - B&W 2013

T2 - B&W 2013

T4 - DFloating 2014

T2- DFixed 2014

(Only working losses)

Tanks FAQ - degassing and

cleaning

70

56,000

24,692

11,200

24,818

11,257

02/02/2015

6. Roof landing

Daily average liquid surface temperature

TLA

°R

T LA = 0 . 44 T AA + 0 . 56 T B + 0 . 0079 * α * I

534.97

Equation 1-26

Daily vapor temperature range

∆TV

°R

∆ TV = 0 .72 ∆ T A + 0.028 * α * I

41.01

Equation 1-8

Daily maximum liquid surface temperature

TLX

°R

TLX = TLA + 0.25*∆TV

545.22

Figure 7.1-17

Daily minimum liquid surface temperature

TLN

°R

TLN = TLA - 0.25*∆TV

524.71

Figure 7.1-17

Liquid bulk temperature

Max standing idle losses during roof

landing

TB

°R

TB = TAA + 6α - 1

528.15

Equation 1-28

LSL-max

lb per landing episode

Kg per landing episode

dimensionless

2

LSL-max = 5.9*D *hle*W l

--0.60 for a full liquid heel

0.50 for a partial

0.15 for drain-dry

11,093,038 Equation 2-13

5,031,769

0.50

Equation 2-26

(pages No 33,35)

1

KS =

1 + 0.053 * PVA * H VO

0.5

Equation 1-20

KS is assumed to be less than

or equal to the saturation factor

during filling (S) .

∆ TV ∆ PV − ∆ PB

+

T LA

PA − PVA

0.043

Liquid stock has a true vapor

pressure greater than 0.1psia Equation 1-7.

Filling saturation factor

S

saturation factor

KS

dimensionless

Vapor space expansion factor

KE

dimensionless

Standing idle losses during roof landing

LSL

lb per landing episode

 PV 

L SL = n d K E  V  M V K S

 RT AA 

7

Equation 2-16

Filling losses during roof landing

LFL

lb per landing episode

 P * VV 

 M V * S

L FL = 

 R * T AA 

41

Equation 2-26

Total losses during roof landing

LTL

lb per landing episode

Kg per landing episode

48

22

Equation 2-10

KE =

LTL=LSL+LFL

7. Summary

Working (withdrawal) losses

Breathing (standing) losses

Kg per year

Kg per year

13

21

Total Degassing and Cleaning emissions

Kg per year

750

Total losses during roof landing

Kg per year

1

786

3013.10-013.xls - 2

3/3

Kg per year

02/02/2015

נספח ד'

דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 3של קרוסי#

3013.10-014 arm3

10/02/2015

19/31

3013.10-015.doc

Transportation - Loading losses

Loading arm #3 - Kerosene

Density

Tank paint solar absorptance

Daily average ambient temperature

Wl

α

TAA

Yearly consumption

Myear

Cargo tank volume

V

Ntrucks

t

g/ml

dimensionless

°R

ton

m3

gal

3

m

gal

1/year

min

Saturation factor

S

dimensionless

True vapor pressure of liquid

P

Number of tank trucks

Duration of road truck filling

Molecular weight of vapors

Temperature of bulk liquid loaded

M

T=TB

mmHg

psia

lb/lb-mole

°R

Controlled efficiency for the recovery

unit (vapor recovery efficiency)

eff1

%

vapor collection efficiency

eff2

%

overall reduction efficiency

eff

Total loading losses of petroleum

Annual pollutant emission during

loading

Average pollutant emission

concentration during loading

3013.10-014.xls - 3

T = TB = TAA + 6α - 1

LL

%

lb/10 gal

loaded

LL total lb / loading

lb / min

Q

Kg / min

Kg / hr

Etotal

C

0.80

0.40

525.97

318

400

105,669

30.0

7,925

13

30

0.6

Table 5.2-1

0.833

0.02

130

@ 20°C

527.34

0.000

Truck passed the NSPS-level

annual test

70.0

eff=eff1*eff2/100

0

3

Loading losses of petroleum liquids

(uncontrolled emission rate)

Flow rate of pollutant emission

during loading

msds data

site data

"Site" tab @ 3013-037

--data

--data

--Ntrucks = Myear / V

data

Submerge loading, dedicated

normal service

Kg / year

gr / m3

LL = 12.46

S *P*M 

eff 

1 −

T

 100 

0.030

LLtoatal = LL*V

Q = Lltoatal / t

-----

0.24

0.008

0.004

0.21

Etotal = LLtotal*Ntruks

1.39

C = Q *t / V

1/1

3.6

Table 7.1-2

Equation 1-28

page 5.2-6

can be 90% to over 99%

page 5.2-6

99.2- for tanker truck passed the

MACT-level annual leak test

98.7- for truck passed the NSPS-level

annual test

70 - for trucks not passing one of

these leak tests

Page 5.2-4 Equation 1

Assumption: the mass of the

pollutant is contained in the air

volume inside the tanker which is

replaced by the liquid loaded

10/02/2015

נספח ה'

חישוב פליטות ממיכל לאיסו תשטיפי

10/02/2015

20/31

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תוכנת :Tanksחישוב פליטה כתוצאה מאחסו #ושינוי מפלס

10/02/2015

21/31

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3013.10-015.doc

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10/02/2015

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23/31

10/02/2015

3013.10-015.doc

24/31

10/02/2015

תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקו #מיכל )שלב א'(

10/02/2015

25/31

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3013.10-015.doc

26/31

10/02/2015

3013.10-015.doc

27/31

10/02/2015

תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקו #מיכל )שלב ב'(

10/02/2015

28/31

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3013.10-015.doc

29/31

10/02/2015

3013.10-015.doc

30/31

10/02/2015

חישובי פליטה ממיכל תשטיפי

גיליו #חישוב זה הוכ #על ידי "פז" הנדסה וניהול ) (1980בע"מ.

אי #להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ) (1980בע"מ.

10/02/2015

31/31

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מסמך 4 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 1430 KB)

זהו קובץ סרוק. הטקסט שלו אינו נקרא כאן, ולכן הוא מופיע בחיפוש לפי הכותרת והפרטים בלבד - הקובץ עצמו זמין בקישור שלמעלה.

מסמך 5 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 2151 KB)

תשתיות פט וארגיה בע"מ

מסוף אלרואי

סיכום פליטות לאוויר

שת 2016

פרויקט3013.12 :

פברואר 2016

תוכן עייים

.1מבוא 4.............................................................................................................................

 .2תוי מסוף 5.....................................................................................................................

 .2.1תוי מיכלים 5.........................................................................................................

 .2.2תוים עבור מסוף מילוי מיכליות כביש 9.....................................................................

.3חישוב פליטות 10 ..............................................................................................................

.3.1כללי 10 ............................................................................................................................

.3.2סוגי פליטות מחושבות 11 ..................................................................................................

.3.3בחירת חומרים בתוכת 11 ................................................................................... TANKS

 .3.4תוים מטאורולוגיים11 ....................................................................................................

.4סיכום פליטות לשת 12 ............................................................................................. 2016

.4.1מיכלים 12 ........................................................................................................................

.4.2מסוף מילוי מיכליות כביש 12 .............................................................................................

.4.3מיכל איסוף תשטיפים 13 ...................................................................................................

.4.4סיכום ממצאי יטור 13 .......................................................................................... LDAR

.4.5פליטה שתית מכלל המתקן 13 ...........................................................................................

.5פליטות לא שגרתיות במהלך שת 13 ............................................................................2016

.6מקורות 14 .......................................................................................................................

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טבלאות

טבלה  :1תוי מיכלים – מידע כללי ,מידות ותוי תפעול – שת 5 .......................................... 2016

טבלה  :2תוי מעטפת וגגות – שת 6 ................................................................................. 2016

טבלה  :3תוי אביזרים – שת 7 ........................................................................................ 2016

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכת 8 .................................................. TANKS

טבלה  :5תוים עבור מסוף מילוי מיכליות כביש – שת 9 ..................................................... 2016

טבלה :6חומרים מייצגים בתוכת 11 ........................................................................... TANKS

טבלה :7סיכום פליטות מכלים -שת 12 ........................................................................... 2016

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שת 12 .................................................2016

טבלה :9סיכום פליטות חומרים אורגים דיפים עבור רכיבים בשת 13 ................................. 2016

טבלה :10סיכום פליטות שתי מכלל מסוף אלרואי – שת 13 ................................................2016

ספחים

ספח א'

טבלה (AP-42) 1-5.2

ספח ב'

תוי יטור LDARעבור מסוף אלרואי – סיכום שת 2016

ספח ג'

דוגמת חישוב עבור מיכל גג חיצוי צף מס' 2המאחסן קרוסין

ספח ד'

דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 3של קרוסין

ספח ה'

חישוב פליטות ממיכל לאיסוף תשטיפים

בן דות

שם עורך

27/02/2017

יואב פיסטיר

שם מאשר

להערות

תיאור

27/02/17

תאריך

3/31

0

גרסה

3013.12-015

.1מבוא

חברת תשתיות פט וארגיה בע"מ )להלן תש"ן( מפעילה את מסוף אלרואי לאחסון ושיוע

דלקים .

המסוף כולל:

•

מבי משרדים

•

חוות מכלים לאחסון דלקים מסוגים שוים

•

רציפי מילוי מכליות כביש )לשימוש בעת חירום בלבד(

המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכות

אלרואי ומדרום לו שכות קרית חרושת.

באתר 9מיכלים ,מתוכם 6מיכלים תפעוליים ו 3-מיכלי מלאי סגור )מיכלים מס' 6 ,4ו.(9-

מערכת השיוע היה באמצעות משאבות ובקרת מילוי ובוסף קיימות מערכות תומכות כגון

מערכות כיבוי אש ומערכות פיקוד ובקרה.

כחלק מהתאים ברישיון עסק מדצמבר ,2010בסוף כל שה קלדרית על תש"ן להגיש דו"ח

סיכום פליטות שתי לגבי השה שחלפה.

חישובי הפליטות בוצעו בעזרת תוכת Tanksומסמכי EPA-AP 42על פי תוי המתקים

הקיימים במסוף.

סיכום הפליטות הוכן על ידי חברת "פז" הדסה ויהול ) (1980בע"מ )להלן פז הדסה( ,והוא

מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות יטור LDARשהוגשו לרשויות.

27/02/2017

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 .2תוי מסוף

 .2.1תוי מיכלים

בטבלאות הבאות מפורט מידע טכי של המיכלים בחוות המיכלים אלרואי.

טבלה  :1תוי מיכלים – מידע כללי ,מידות ותוי תפעול – שת 2016

מספר

מיכל

סוג הדלק

המאוחסן

1

2

בזין

קרוסין

סולר

הסקה

סולר

סולר

סולר

סולר

קרוסין

קרוסין

3

(1

(2

4

5

(4

6

7

8

(5

9

סה"כ

(3

(1

(2

(3

(4

(5

לחץ אדים

בטמפ' הוזל

הממוצעת

)(mmHg

405 @ 28°C

0.833 @ 28°C

כמות

צריכה

שתית

)מ"ק(

סוג יקוז

בתחתית

מיכל

קוטר

מיכל

)מטר(

פח מיכל

)מ"ק(

פח מיכל

פעיל

)מ"ק(

23,450

33,812

גבעה חלקית

גבעה חלקית

48.77

48.77

32,056

32,056

28,768

28,768

גובה /אורך

מעטפת

מיכל

)מטר(

17.16

17.16

15.4

15.4

0.507 @ 28°C

52,978

גבעה חלקית

48.77

32,056

28,768

17.16

15.4

0.507 @ 28°C

0.507 @ 28°C

0.507 @ 28°C

0.507 @ 28°C

0.833 @ 28°C

0.833 @ 28°C

0

19,573

0

59,137

18,516

0

גבעה חלקית

גבעה מלאה

גבעה מלאה

גבעה מלאה

גבעה חלקית

גבעה חלקית

207,465

48.77

68.27

68.27

68.27

48.8

48.77

32,056

56,959

56,959

56,959

36,547

32,056

367,704

28,768

51,614

51,614

51,614

34,228

28,768

332,913

מיכל מס' 3שופץ בחודשים יואר-פברואר.

מיכל מס' 4שימש כמיכל מלאי ,לא היו תועות במיכל בשת .2016

מיכל מס'  5וקה ובדק במשך 3שבועות במהלך חודש מרץ.

מיכל מס' 6שימש כמיכל מלאי ,לא היו תועות במיכל בשת .2016

מיכל מס' 9שימש כמיכל מלאי ,לא היו תועות במיכל בשת .2016

27/02/2017

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3013.12-015

17.16

15.56

15.56

15.56

19.54

17.16

גובה וזל

מירבי

)מטר(

גובה וזל

ממוצע

)מטר(

10.5

10

9.5

15.4

14.1

14.1

14.1

18.3

15.4

10.3

14.1

14.1

11.4

18.3

9.7

טבלה  :2תוי מעטפת וגגות – שת 2016

צורת גג

סוג

חיבורי

גג

צבע

גג

מצב

צבע

גג

צבע

מעטפת

חיצוית

מצב צבע

מעטפת

חיצוית

סוג חיבורי

מעטפת

מצב

מעטפת

פימית

מיכל

מחומם

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חאקי

טוב

מרותך

חלוד הרבה

לא

ללא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

ללא

Pontoon

מרותך

לבן

טוב

חאקי

ישן

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

כחול בהיר

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

מספר

מיכל

סוג גג

אטם ראשי

אטם משי

1

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Liquid

mounted

Mechanical

Shoe

Rim

mounted

Shoe

mounted

2

3

4

5

6

7

8

9

27/02/2017

Shoe

mounted

Shoe

mounted

Shoe

mounted

Rim

mounted

ללא

6/31

3013.12-015

טבלה  :3תוי אביזרים – שת 2016

מספר

מיכל

1

2

3

4

5

6

7

8

9

סה"כ

27/02/2017

שובר ואקום

כמות

2

2

2

2

2

2

2

6

2

Vacuum

]set. [psi

0

0

0

0

0

0

0

0

0

Pressure

]set. [psi

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

7/31

רגליים מתכווות התומכות

בגג צף

גובה

כמות באזור

כמות

במרכז

)(ft

pontoon

29

43

11

29

43

11

29

43

11

29

43

11

72

107

11

72

107

11

72

107

11

36

54

9

29

43

11

כמות

מדי

מפלס

Rim

Vent

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

6

3013.12-015

כמות בוצה

בקיון

)מ"ק(

"גרביים" לבאר

הדיגום המחורצת

ולרגלי הגג הצף

70

70

70

70

150

150

150

70

70

870

יש

יש

יש

יש

יש

יש

יש

יש

יש

החות שלקחו לצורך החישובים

.1עבור חישוב degassingבמיכל עם גג צף – הוח:

•

גג צף ח על רגליים בגובה ) 9-11 ftבהתאם לטבלה לעיל( וזהו גם הגובה המרבי של הוזל

במיכל.

•

גובה ממוצע של הוזל במיכל היו 50%מגובה הוזל המרבי.

.2הוח כי יקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שים .היקיון יארך יום אחד.

.3הוח כי אירוע של חיתת גגות צפים מתבצע אחת ל 15-שים .זמן חיתת הגג במקרה זה לא

יעלה על 4ימים.

.4יחס הוזל בבוצה הוח כ[2] 0.8 -

.5בהתאם לטבלה 7.1-6על פי ] ,[1בחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,

לצורך חישובי פליטות לאוויר:

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכת Tanks

צבע מעטפת

מיכל

צבע לצורך חישובי אקסל

צבע לצורך חישובים בתוכת

בהתאם למסמך EPA AP-42

(*) Tanks

כחול בהיר

Gray Medium

Gray Medium

חאקי

Green Dark

Red/Primer

צהוב קרם

Beige/Cream

Aluminium/Specular

)*( בתוכת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך

.[1] EPA AP-42

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 .2.2תוים עבור מסוף מילוי מיכליות כביש

טבלה  :5תוים עבור מסוף מילוי מיכליות כביש – שת 2016

מס'

זרוע

1

2

3

4

5

6

7

8

מוצר

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

סה"כ

מילוי

עילי /תחתי

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

פח ממוצע של

מיכלית )מ"ק(

30

30

30

30

30

30

30

30

פח מילוי שתי

)מ"ק(

400

100

200

200

200

100

100

83

1,383

החות שלקחו צורך החישובים

.1

מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:

א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:

דוגמת חישוב עבור מיכל מס' :2

0.17 + 0.89

= 0.53

2

=

α roof2 + α Shell2

2

= α tank2

ב .בשלב השי חושב מקדם αממוצע עבור הקרוסין:

0.53 + 0.43 + 0.26

= 0.41

3

=

α tank2 + α tank8 + α tank9

number of kerosene tanks

= α Kerosene

.2

זמן מילוי מיכלית חושב על פי פח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000

ליטר/דקה.

.3

Vapor collection efficiency - 70%

.4

Vapor recovery efficiency - 0%

.5

Saturation factorהוח כ (Submerged loading, dedicated normal service) 0.6-על פי

] .[1טבלה רלווטית מצורפת בספח א'.

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.3חישוב פליטות

.3.1כללי

חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכת Tanksובעזרת .[1] EPA-AP 42

הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ) (LDARמצורפת בספח ב'.

דוגמת חישוב עבור מיכל גג חיצוי צף )מיכל מס' (2המאחסן קרוסין ,מצורפת כספח ג' למסמך

זה.

דוגמת חישוב עבור זרוע מילוי עילי של קרוסין )זרוע מס' (2מצורפת כספח ד' למסמך זה.

בדוגמאות אלה יתן לראות את תוי הקלט )כולל החות( עליהם התבססו החישובים.

27/02/2017

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.3.2סוגי פליטות מחושבות

הערכת הפליטות ממיכלי אחסון כוללת ]:[3

• פליטות בזמן אחסון )(Breathing Losses

• פליטות משיויי מפלס )(Working Losses

• פליטות כתוצאה מיקוי וריקון מיכלים )(Degassing Losses

• פליטות כתוצאה מחיתת גגות צפים )(Roof Landing Losses

• פליטות כתוצאה מהפרשי לחץ )(Flash Losses

• פליטות בזמן מילוי מיכלים ומיכליות

בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ

).(Flash Losses

פליטות אלה רלווטיות לשיויי פתאומי\מיידי בלחץ הוזל ,תון הגורם להפרת שיווי המשקל

הקיים במיכל )בין גז לוזל( וכתוצאה מכך וצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הוזל

עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר וזל המאוחסן בלחץ שלח

לאחסון במיכל בעל לחץ מוך יותר ].[3

פליטות אלו הוזחו כיוון שכל החומרים מוחזקים בתאים אטמוספריים בכל אחד מהשלבים

הוגעים להובלתם ואחסום ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.

.3.3בחירת חומרים בתוכת Tanks

על פי תוי MSDSשל הדלקים במסוף ,בחרו החומרים הבאים הקיימים בתוכת Tanks

כמייצגים של חומרים אלו:

טבלה :6חומרים מייצגים בתוכת Tanks

דלק קיים במסוף

חומר מייצג בתוכת Tanks

סולר )תחבורה והסקה(

Distillate fuel oil no 2

פט )קרוסין(

Jet kerosene

בזין

Gasoline RVP 10

 .3.4תוים מטאורולוגיים

לצורך חישוב התוים בתוכת Tanksהוגדרו תוים מטאורולוגים המתאימים למפרץ חיפה על פי

מקורות ].[4

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.4סיכום פליטות לשת 2016

.4.1מיכלים

סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:

טבלה :7סיכום פליטות מכלים -שת 2016

מיכל

חומר

1

בזין

פליטות לאוויר

)ק"ג/שה(

4,114

2

קרוסין

803

3

סולר הסקה

67

4

סולר

826

5

סולר

1,610

6

סולר

1,695

7

סולר

1,733

8

קרוסין

774

9

קרוסין

792

סה"כ

12,414

.4.2מסוף מילוי מיכליות כביש

להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שת 2016

27/02/2017

מס' זרוע

מוצר

מילוי עילי /תחתי

פליטה שתית )ק"ג(

1

2

3

4

5

6

7

8

סה"כ

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

1.39

0.32

0.75

0.75

0.75

0.32

0.32

0.32

4.91

12/31

3013.12-015

.4.3מיכל איסוף תשטיפים

סך הפליטה ממיכל לאיסוף תשטיפים היה כ 1 -ק"ג/שה.

חישוב מצורף בספח ה'.

יצוין כי החישוב מתבסס על החה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל

בעיקר יקוז מים מהמכלים.

.4.4סיכום ממצאי יטור LDAR

טבלה :9סיכום פליטות חומרים אורגים דיפים עבור רכיבים בשת 2016

סה"כ פליטות )ק"ג/שה(

סיכום פליטות LDAR

פליטה שתית )ק"ג/שה(

סה"כ

40.3

.4.5פליטה שתית מכלל המתקן

טבלה :10סיכום פליטות שתי מכלל מסוף אלרואי – שת 2016

סה"כ פליטות )ק"ג/שה(

חוות מיכלים

מסוף מילוי

מיכליות כביש

מיכל לאיסוף

תשטיפים

12,414

4.91

1

סיכום פליטות

רכיבים

סה"כ

)(LDAR

40.3

12,460

.5פליטות לא שגרתיות במהלך שת 2016

במהלך שת 2016לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמיל.

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13/31

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.6מקורות

[1] EPA-AP42

[2] USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version

4.0 - APPENDIX D

] [3החיות הממוה לטיפול בבקשה להיתר פליטה לפי סעיף )9א( לתקות אוויר קי )היתרי פליטה(,

התש"ע – ,2010מהדורה ,4ספטמבר 2014

] [4האטלס האקלימי לתכון פיסי וסביבתי בישראל ,מהדורה שיה1994 ,

27/02/2017

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ספח א'

טבלה 5.2-1

AP-42

27/02/2017

15/31

3013.12-015

3013.12-015

16/31

27/02/2017

ספח ב'

תוי יטור LDARעבור אלרואי – סיכום שת 2016

)מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך (27.02.2016

3013.12-008A

27/02/2017

17/31

3013.12-015

LDAR

דו"ח איתור

דליפות מרכיבי ציוד מס'

R-TASH-AL-A-16

מפעל :תשתיות נפט ואנרגיה בע"מ

ישוב :קרית טבעון

מחוז :חיפה

מתקן :אלרואי

קטגורייה1-3 :

תקופת הניטור :סיכום 2016

תאריך הדפסת הדו"ח27-Feb-17 :

שמות אנשי צוות :מקסים טומרוב

סרגיי קוש

סלבה פוליק

יאן פורצלן

עורך הדו"ח :מיכאל אורייבסקי

מאשר הדו"ח :אלכסי רטנר ,מנכ"ל

This report produced using Orr LeakDAS software.

תוכן עניינים

1תיאור הפרויקט:

• סיכום ביצוע

• שלבי הפרויקט

2מתודולוגיה:

• הגדרות

• מתודולוגיה

• אופן ביצוע חישובים

3סיכום תקופת הניטור:

• סיכום של שנת :2016

3

3

4

4

4

01/01/2016 - 31/12/2016

4סיכום תקופה01/01/2016 - 31/12/2016 :

• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

• פילוג לחומרים הנפלטים

• טופס תיקון דליפות חצי שנתי

6

8

9

11

סבב 1

5תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:

• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

• פילוג לחומרים הנפלטים

• טופס :15דו"ח תיקון דליפות למתקן ייצור

6

סבב 2

6תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:

• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

• פילוג לחומרים הנפלטים

• טופס :15דו"ח תיקון דליפות למתקן ייצור

21

23

27

סבב 3

7תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:

• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

• פילוג לחומרים הנפלטים

• טופס :15דו"ח תיקון דליפות למתקן ייצור

29

31

35

סבב 4

8תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:

• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

• פילוג לחומרים הנפלטים

• טופס :15דו"ח תיקון דליפות למתקן ייצור

37

39

43

סבב 5

9תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:

• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

• פילוג לחומרים הנפלטים

• טופס :15דו"ח תיקון דליפות למתקן ייצור

45

47

51

סבב 6

10תוצאות הניטור במדידה הראשונה ואחרי סבב התיקונים:

• טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

• פילוג לחומרים הנפלטים

• טופס :15דו"ח תיקון דליפות למתקן ייצור

53

55

59

page 2 of 59

INDEX-A

13

15

19

TASHAN-LDAR_R-TASH-AL-A-16

1תיאור הפרוייקט:

1.1סיכום ביצוע:

הניטור בוצע לסוגי הרכיבים הבאים:

קטגוריה :1משאבות ,ציוד ערבוב וערבול ,PRD ,נקודות דגימה.

6סבבי הניטור בשנה.

קטגוריה :2ברזים,שסתומים וצינורות פתוחים פוטנציאליים.

2סבבי הניטור בשנה.

קטגוריה :3מחברים ואוגנים.

סבב ניטור אחד בשנה.

1.2שלבי הפרויקט:

● ניטור רכיבים

● במהלך רבעון בוצעו שני סבבי הניטור לרכיבי ציוד מקטגוריה 1במתקן אלרואי

● ניטור חוזר אחרי תיקון הדליפות.

● עדכון בסיס הנתונים.

● עדכון תזרימים .P&ID

1.3יחידות ציוד לניטור )כל המתקנים(:

מסוף

אלרואי

מסוף נמל

הדלק

מס' מיכל

מס' מיכל

מס' מיכל

מס' מיכל

מס' מיכל

מס' מיכל

T-44

T-95

T-133

T-140

T-1

T-113

T-127

T-134

T-136

קווי צנרת

קווי צנרת

T-164

T-69

T-128

T-137

T-74

T-129

T-138

T-94

T-131

T-139

טרמינל קרית חיים

T-165

קווי צנרת

בחוות

המיכלים

מערכת

VRU

הערות:

.1מתקן VRUשבמתקן נמל הדלק לא נבדק עקב חוסר הפעילות.

מפלס גג המיכל T-113שבנמל הדלק היה נמוך במשך תקופת הניטור ,לכן

המיכל לא נבדק מטעמי הבטיחות.

.3המיכל T-45במתקן טרמינל אינו פעיל ,לכן לא נבדק מ.03/08/2015-

מיכל T-134חזר לפעילות ונבדק במסגרת הסבב.

הערות כלליות:

.1חברת "מעבדות אקולוגיה א.פ .בע"מ" מוסמכת לתקן ISO-17025

ISO-17025לביצוע בדיקות LDARע"י ) ISRACהרשות להסמכת מעבדות(.

.2הרשות להסמכת מעבדות אינה אחראית על תוצאות הבדיקות.

page 3 of 59

Project Introduction

TASHAN-LDAR_R-TASH-AL-A-16

2מתודולוגיה:

2.1הגדרות:

נוזל קל :כל נוזל עם יותר מ 10% -נפחי של VOCהמתנדף ב 150-מעלות צלסיוס.

נוזל כבד :כל נוזל עם 10%נפחי של VOCאו פחות המתנדף ב 150-מעלות צלסיוס.

דליפה :גילוי של ריכוז TOCבפאזה גזית בסך 1,000חל"מ או יותר.

רכיב בלתי נגיש :כל רכיב הממוקם בגובה של יותר מ 5-מ' מעל הקרקע ,כאשר נדרשת גישה מהקרקע,

או כל רכיב הממוקם במרחק של יותר מ 2-מ' מפלטפורמה ,כאשר נדרשת גישה

מפלטפורמה ,ולא ניתן לגשת אליהם בצורה בטיחותית ע"י העובד ,או כל רכיב העלול

להצריך את הרתמתם של אנשי צוות ניטור לגובה של יותר מ 2-מ' מעל למשטחי

תמיכה קבועים ולא ניתן לגשת אליו בצורה בטיחותית.

2.2אופן ביצוע חישובים:

נוסחאות :חישוב הפליטות מדליפות מרכיבי ציוד נעשה בהתאם לגישת הקורלציה המפורטת

בפרוטוקול ה EPA-עבור תעשיה פטרוכימית.

US EPA "Protocol for equipment leak emission estimates",1995

"נתונים מצטברים" :בטבלאות "נתונים מצטברים" אנחנו מציגים תוצאות של כל המדידות שבוצעו מתחילת

השנה ועד סוף תקופת הניטור הנוכחית )שנה(.

חישוב הפליטה המצטברת נעשה בהתאם לModified Trapezoidal Method-

US EPA "Emission Estimation Protocol for Petroleum Refineries",Ver.2.1.1, 2011

page 4 of 59

Methodology

TASHAN-LDAR_R-TASH-AL-A-16

- חישוב קצב פליטה שעתי ושנתי מרכיבי ציוד בוצע בהתאם ל2.3

)בהמשךProtocol for equipment leak emission estimates,2.0. (EPA,1995)

."Petroleum Industry" "פרוטוקול"( סקטור תעשייה רלוונטי הינו

: חל"מ9 ≤ דליפות

Equipment type

kg/year

Valves/all

2.29E-06 * (measured ppm value)^0.746 * production hours

Pump seals/all

5.03E-05 * (measured ppm value)^0.610 * production hours

Others/all *

1.36E-05 * (measured ppm value)^0.589 * production hours

Connectors/all

1.53E-06 * (measured ppm value)^0.735 * production hours

Flanges/all

4.61E-06 * (measured ppm value)^0.703 * production hours

Open-ended lines/all

2.20E-06 * (measured ppm value)^0.704 * production hours

. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- Others :הערה

: חל"מ9 > דליפות

Equipment type

kg/year

Valves/all

7.80E-06 * production hours

Pump seals/all

2.40E-05 * production hours

Others/all *

4.00E-06 * production hours

Connectors/all

7.50E-06 * production hours

Flanges/all

3.10E-07 * production hours

Open-ended lines/all

2.00E-06 * production hours

. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- "Others" :הערה

: חל"מ100,000 < דליפות

Equipment type

kg/year

Valves/all

0.140 * production hours

Pump seals/all

0.160 * production hours

Others/all *

0.110 * production hours

Connectors/all

0.030 * production hours

Flanges/all

0.084 * production hours

Open-ended lines/all

0.079 * production hours

. משאבות או ברזים, צינורות פתוחים פוטנציאליים, אוגנים, כל רכיבי ציוד אחרים פרט ל מחברים- "Others" :הערה

:( )ק"גVOC חישוב פליטת

Evoc = Etoc * WTvoc/WTtoc

אחוז משקלי- WT כאשר

קצב פליטה- E

TASHAN-LDAR_R-TASH-AL-A-16

Equations

page 5 of 59

31/12/2016 - 01/01/2016

סיכום התוצאות:

סוג

רכיב

R2

R1

סיכום לפי סוג הרכיב

סה"כ

רכיבים

רכיבים

מעל 1,000חל"מ

מעל 1,000חל"מ

מספר

מספר

%

R3

R5

R4

R1

R6

R3

R2

R5

R4

R1

R6

R2

אחוז רכיבים

רכיבים

לא מתוקנים

count

R3

R4

R5

R1

R6

R3

R2

פליטה

מצטברת

ק"ג

R4

R6

R5

01/01/2016 - 31/12/2016

משאבות0 :

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.000

ציוד ערבוב0 :

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.000

4 :PRD

4

4

4

4

4

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

0.198

נקודות דגימה4 :

4

4

4

4

4

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

1.389

סה"כ קטגוריה 8 :1

8

8

8

8

8

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

1.587

ברזים ושסתומים0 :

0

20

0

20

0

0

0

0

0

0

0

0.0%

0.0%

0

0

0

0

0

0

1.366

צינורות פתוחים0 :

0

102

0

102

0

0

0

0

0

0

0

0.0%

0.0%

0

0

0

0

0

0

29.041

סה"כ קטגוריה 0 :2

0

122

0

122

0

0

0

0

0

0

0

0.0%

0.0%

0

0

0

0

0

0

30.407

מחברים ואוגנים0 :

0

93

0

0

0

0

0

0

0

0

0

0.0%

0

0

0

0

0

0

8.342

סה"כ קטגוריה 0 :3

0

93

0

0

0

0

0

0

0

0

0

8 :Total

8

223

8

130

8

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

8.342

0

0

0

0

0

0

40.337

סיכום לפי קטגוריית הפליטה

סה"כ רכיבים

R1

#

קטגוריית פליטה

0-9חל"מ 8

R2

#

%

R3

#

%

R4

#

%

R5

#

%

R6

%

%

#

100.0%

7

87.5%

185

83.0%

7

87.5%

123

94.6%

8

100.0%

9-1,000חל"מ 0

0.0%

1

12.5%

38

17.0%

1

12.5%

7

5.4%

0

0.0%

1,000-100,000חל"מ 0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

מעל 100,000חל"מ 0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

סה"כ מעל 1,000חל"מ 0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

רכיבים בלתי נגישים 0

סה"כ8 :

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

0

0.0%

100.0%

8

100.0%

223

100.0%

8

100.0%

130

100.0%

8

100.0%

הערות = "R" :מספר של סבב ניטור

page 6 of 59

Cumulative Data

TASHAN-LDAR_R-TASH-AL-A-16

.4סיכום:

01/01/2016 - 31/12/2016

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

טופס תיקון דליפות

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור .נתונים מצטברים.

תאריך:

2/27/2017

שם המפעל :תשתיות נפט ואנרגיה בע"מ

דו"ח מס'R-TASH-AL-A-16 :

סוג

סוג

רכיב

שירות

סה"כ רכיבים

שם המתקן :אלרואי

רכיבים עיקריים

סה"כ רכיבים מעל 1,000חל"מ

רכיבים בלתי נגישים

תקופת חישוב הפליטות01/01/2016 - 31/12/2016 :

רכיבים מ 0-עד 9חל"מ

רכיבים לא מתוקנים

רכיבים מ 1,000-עד 100,000חל"מ

רכיבים מ 9-עד 1,000חל"מ

פליטה משוקללת

רכיבים מעל 100,000חל"מ

תדירות

רכיבים מעל 1,000חל"מ

מדידות

מספר

R1

R3

R2

מספר

R4

R6

R5

מספר

מספר

מספר

מספר

R1

R3

R2

מספר

R4

R6

R5

מספר

מספר

R1

R2

R3

R4

R5

R6

R1

R2

R3

R4

R5

R6

R1

R2

R3

R4

R5

R6

R1

R2

R3

R4

R5

R6

גז

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

נוזל קל

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

גז

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

נוזל קל

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

גז

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

נוזל קל

4

4

4

4

4

4

1

1

1

1

1

1

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

4

4

4

4

4

4

גז

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

נוזל קל

4

4

4

4

4

4

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

4

3

3

3

4

4

0

1

סה"כ קטגוריה 8 :1

8

8

8

8

8

1

1

1

1

1

1

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

8

7

7

7

8

8

0

1

1

גז

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

נוזל קל

0

0

20

0

20

0

0

0

0 16

0 16

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

20

0

20

0

0

0

0

0

0

גז

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

נוזל קל

0

0

102

0

102

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

67

0

95

0

0

0

0 35

7

0

0

סה"כ קטגוריה 0 :2

0

122

0

122

0

0

0

0 16

0 16

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

87

0

115

0

0

0

0 35

7

0

0

0

גז

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

נוזל קל

0

0

93

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

91

0

0

0

0

0

2

0

0

0

0

0

0

0

סה"כ קטגוריה 0 :3

0

93

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

91

0

0

0

0

0

2

0

0

0

0

0

0

0

0

סה"כ רכיבים8 :

8

223

8

130

8

1

1

1 17

1 17

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

8

7

185

7

123

8

0

1

1 38

7

0

0

0

0

0

0

סה"כ פליטות:

40.34

kg

%

ק"ג

R1

R2

R3

סבבים/שנה

R4

R6

R5

R1

R2

R3

R4

R5

R6

R1

R2

R3

R4

R5

R6

R1

R2

R3

R4

R5

R6

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

6

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

6

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

6

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

6

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

6

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

1

1

0

0

0

0

0

0

0

0

0

0

0

0

0

0

1.389

1

0

0

0

0

0

0

0

0

0

0

0

0

0

0

1.587

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

29.041

0

0

0

0

0

0

0

0

0

0

30.407

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

8.342

0

0

0

0

0

0

0

8.342

0

0

0

0

0

0

0

40.337

משאבות

ציוד ערבוב

וערבול

PRD

6

0.198

נקודות

6

דגימה

6

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

שסתומים ,ברזים

2

וציוד תלוי

2

1.366

צינורות פתוחים

2

פוטנציאלים

2

0.0%

0.0%

מחברים ואוגנים

page 8 of 59

Form-07 CU

1

1

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

TASHAN-LDAR_R-TASH-AL-A-16

Correlation Equations Chemical Summary by Component Class

Report Date: 2/27/2017

Calculation Period: 01/01/2016 - 31/12/2016

Units of Measurement:

KG

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0198

0.0020

0.0099

0.0198

0.0794

0.0675

0.1984

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1389

0.0139

0.0695

0.1389

0.5556

0.4723

1.3890

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1366

0.0137

0.0683

0.1366

0.5465

0.4645

1.3662

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

2.9041

0.2904

1.4521

2.9041

11.6164

9.8739

29.0410

TASHAN-LDAR_R-TASH-AL-A-16

Chem Cu

page 9 of 59

Correlation Equations Chemical Summary by Component Class

Report Date: 2/27/2017

Calculation Period: 01/01/2016 - 31/12/2016

Units of Measurement:

KG

אלרואי

Unit

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.8342

0.0834

0.4171

0.8342

3.3369

2.8364

8.3423

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

4.0337

0.4034

2.0168

4.0337

16.1348

13.7145

40.3369

Grand Total:

40.3369

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem Cu

page 10 of 59

Leaker Detail Report

Report Parameters

Alroy

Report: R304_1

ISRAEL

All Classes

Monitoring Period:

Compliance Leak

01/01/2016 - 31/12/2016

Alroy

Details

Class

Location

Date

Reported

Test

Type

Leak

Def

1st Att. Due

Repair Due

Repaired

Date

Event

Result

Technician

Instrument

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

LDAR Report_015 A

page 11 of 59

החברה הארצית לבדיקות ושירותי איכות הסביבה

רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.

טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),

E-mail :michael.o@ecologicalab.com

סבב 1

תוצאות הניטור:

מדידה ראשונה ואחרי סבב התיקונים

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

טופס :15דו"ח תיקון דליפות למתקן ייצור

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R1 :

שלב הניטור :מדידה ראשונה

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

0.140

גז

נוזל קל

page 13 of 59

4

1

0

0

4

0

0

0

0.000016

6

6

4

0

0

0

4

0

0

0

0.000016

6

0.140

סה"כ קטגוריה 8 :1

1

0

0

8

0

0

0

0.000

0.280

0.0%

סה"כ8 :

1

0

0

8

0

0

0

0.000

0.280

0.0%

Form-07 R1

TASHAN-LDAR_R-TASH-AL-A-16

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R1 :

שלב הניטור :אחרי סבב תיקונים

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

0.140

גז

נוזל קל

page 14 of 59

4

1

0

0

4

0

0

0

0.000016

6

6

4

0

0

0

4

0

0

0

0.000016

6

0.140

סה"כ קטגוריה 8 :1

1

0

0

8

0

0

0

0.000

0.280

0.0%

סה"כ8 :

1

0

0

8

0

0

0

0.000

0.280

0.0%

Form-07 R1

TASHAN-LDAR_R-TASH-AL-A-16

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R1

KG/year

First measurement

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

TASHAN-LDAR_R-TASH-AL-A-16

Chem R1

page 15 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

Connections & Flanges

Units of Measurement:

R1

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0280

0.0028

0.0140

0.0280

0.1118

0.0951

0.2796

Grand Total:

0.2796

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R1

page 16 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R1

KG/year

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

TASHAN-LDAR_R-TASH-AL-A-16

Chem R1

page 17 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

All

Units of Measurement:

R1

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0280

0.0028

0.0140

0.0280

0.1118

0.0951

0.2796

Grand Total:

0.2796

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R1

page 18 of 59

Leaker Detail Report

Report Parameters

Alroy

Report: R304_1

ISRAEL

All Classes

Monitoring Period:

Compliance Leak

R1

Alroy

Details

Class

Location

Date

Reported

Test

Type

Leak

Def

1st Att. Due

Repair Due

Repaired

Date

Event

Result

Technician

Instrument

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

LDAR Report_015 R1

page 19 of 59

החברה הארצית לבדיקות ושירותי איכות הסביבה

רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.

טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),

E-mail :michael.o@ecologicalab.com

סבב 2

תוצאות הניטור:

מדידה ראשונה ואחרי סבב התיקונים

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

טופס :15דו"ח תיקון דליפות למתקן ייצור

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R2 :

שלב הניטור :מדידה ראשונה

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

0.140

גז

נוזל קל

page 21 of 59

4

1

0

0

4

0

0

0

0.000016

6

6

4

0

0

0

3

1

0

0

0.000201

6

1.765

סה"כ קטגוריה 8 :1

1

0

0

7

1

0

0

0.000

1.905

0.0%

סה"כ8 :

1

0

0

7

1

0

0

0.000

1.905

0.0%

Form-07 R2

TASHAN-LDAR_R-TASH-AL-A-16

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R2 :

שלב הניטור :אחרי סבב תיקונים

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

0.140

גז

נוזל קל

page 22 of 59

4

1

0

0

4

0

0

0

0.000016

6

6

4

0

0

0

3

1

0

0

0.000201

6

1.765

סה"כ קטגוריה 8 :1

1

0

0

7

1

0

0

0.000

1.905

0.0%

סה"כ8 :

1

0

0

7

1

0

0

0.000

1.905

0.0%

Form-07 R2

TASHAN-LDAR_R-TASH-AL-A-16

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R2

KG/year

First measurement

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1765

0.0177

0.0883

0.1765

0.7060

0.6001

1.7650

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

TASHAN-LDAR_R-TASH-AL-A-16

Chem R2

page 23 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

Connections & Flanges

Units of Measurement:

R2

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1905

0.0190

0.0952

0.1905

0.7619

0.6476

1.9048

Grand Total:

1.9048

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R2

page 24 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R2

KG/year

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1765

0.0177

0.0883

0.1765

0.7060

0.6001

1.7650

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

TASHAN-LDAR_R-TASH-AL-A-16

Chem R2

page 25 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

All

Units of Measurement:

R2

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1905

0.0190

0.0952

0.1905

0.7619

0.6476

1.9048

Grand Total:

1.9048

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R2

page 26 of 59

Leaker Detail Report

Report Parameters

Alroy

Report: R304_1

ISRAEL

All Classes

Monitoring Period:

Compliance Leak

R2

Alroy

Details

Class

Location

Date

Reported

Test

Type

Leak

Def

1st Att. Due

Repair Due

Repaired

Date

Event

Result

Technician

Instrument

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

LDAR Report_015 R2

page 27 of 59

סבב 3

תוצאות הניטור:

מדידה ראשונה ואחרי סבב התיקונים

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

טופס :15דו"ח תיקון דליפות למתקן ייצור

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R3 :

שלב הניטור :מדידה ראשונה

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

מספר

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

6

4

0

0

0

3

1

0

0

0.000111

0.968

סה"כ קטגוריה 8 :1

1

0

0

7

1

0

0

0.000

1.108

ברזים ,שסתומים

גז

וציוד תלוי

נוזל קל

צינורות פתוחים

גז

פוטנציאליים

נוזל קל

6

0.0%

2

20

16

0

0

0

20

0

0

0.000156

1.363

2

2

102

0

0

0

67

35

0

0

0.004336

37.986

סה"כ קטגוריה 122 :2

16

0

0

87

35

0

0

0.004

39.349

2

0.0%

גז

93

1

93

סה"כ קטגוריה 93 :3

סה"כ223 :

page 29 of 59

4

0.140

גז

נוזל קל

מחברים ואוגנים

4

1

0

0

0

0

0

0.000016

6

0

0

0

2

91

0

0

0.001074

1

9.407

0

0

0

91

2

0

0

0.001

9.407

0.0%

17

0

0

185

38

0

0

0.006

49.864

0.0%

Form-07 R3

TASHAN-LDAR_R-TASH-AL-A-16

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R3 :

שלב הניטור :אחרי סבב תיקונים

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

מספר

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

6

4

0

0

0

3

1

0

0

0.000111

0.968

סה"כ קטגוריה 8 :1

1

0

0

7

1

0

0

0.000

1.108

ברזים ,שסתומים

גז

וציוד תלוי

נוזל קל

צינורות פתוחים

גז

פוטנציאליים

נוזל קל

6

0.0%

2

20

16

0

0

0

20

0

0

0.000156

1.363

2

2

102

0

0

0

67

35

0

0

0.004336

37.986

סה"כ קטגוריה 122 :2

16

0

0

87

35

0

0

0.004

39.349

2

0.0%

גז

נוזל קל

1

93

סה"כ קטגוריה 93 :3

סה"כ223 :

page 30 of 59

4

0.140

גז

נוזל קל

מחברים ואוגנים

4

1

0

0

0

0

0

0.000016

6

0

0

0

2

91

0

0

0.001074

1

9.407

0

0

0

91

2

0

0

0.001

9.407

0.0%

17

0

0

185

38

0

0

0.006

49.864

0.0%

Form-07 R3

TASHAN-LDAR_R-TASH-AL-A-16

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R3

KG/year

First measurement

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0968

0.0097

0.0484

0.0968

0.3873

0.3292

0.9682

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

3.7986

0.3799

1.8993

3.7986

15.1945

12.9153

37.9862

TASHAN-LDAR_R-TASH-AL-A-16

Chem R3

page 31 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

Connections & Flanges

Units of Measurement:

R3

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.9407

0.0941

0.4704

0.9407

3.7630

3.1985

9.4074

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

4.9864

0.4986

2.4932

4.9864

19.9458

16.9539

49.8644

Grand Total:

49.8644

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R3

page 32 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R3

KG/year

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0968

0.0097

0.0484

0.0968

0.3873

0.3292

0.9682

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

3.7986

0.3799

1.8993

3.7986

15.1945

12.9153

37.9862

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.9407

0.0941

0.4704

0.9407

3.7630

3.1985

9.4074

TASHAN-LDAR_R-TASH-AL-A-16

Chem R3

page 33 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

All

Units of Measurement:

R3

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

4.9864

0.4986

2.4932

4.9864

19.9458

16.9539

49.8644

Grand Total:

49.8644

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R3

page 34 of 59

Leaker Detail Report

Report Parameters

Alroy

Report: R304_1

ISRAEL

All Classes

Monitoring Period:

Compliance Leak

R3

Alroy

Details

Class

Location

Date

Reported

Test

Type

Leak

Def

1st Att. Due

Repair Due

Repaired

Date

Event

Result

Technician

Instrument

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

LDAR Report_015 R3

page 35 of 59

החברה הארצית לבדיקות ושירותי איכות הסביבה

רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.

טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),

E-mail :michael.o@ecologicalab.com

סבב 4

תוצאות הניטור:

מדידה ראשונה ואחרי סבב התיקונים

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

טופס :15דו"ח תיקון דליפות למתקן ייצור

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R4 :

שלב הניטור :מדידה ראשונה

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

0.140

גז

נוזל קל

page 37 of 59

4

1

0

0

4

0

0

0

0.000016

6

6

4

0

0

0

3

1

0

0

0.000154

6

1.350

סה"כ קטגוריה 8 :1

1

0

0

7

1

0

0

0.000

1.490

0.0%

סה"כ8 :

1

0

0

7

1

0

0

0.000

1.490

0.0%

Form-07 R4

TASHAN-LDAR_R-TASH-AL-A-16

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R4 :

שלב הניטור :אחרי סבב תיקונים

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

0.140

גז

נוזל קל

page 38 of 59

4

1

0

0

4

0

0

0

0.000016

6

6

4

0

0

0

3

1

0

0

0.000154

6

1.350

סה"כ קטגוריה 8 :1

1

0

0

7

1

0

0

0.000

1.490

0.0%

סה"כ8 :

1

0

0

7

1

0

0

0.000

1.490

0.0%

Form-07 R4

TASHAN-LDAR_R-TASH-AL-A-16

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R4

KG/year

First measurement

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1350

0.0135

0.0675

0.1350

0.5400

0.4590

1.3500

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

TASHAN-LDAR_R-TASH-AL-A-16

Chem R4

page 39 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

Connections & Flanges

Units of Measurement:

R4

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1490

0.0149

0.0745

0.1490

0.5959

0.5065

1.4898

Grand Total:

1.4898

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R4

page 40 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R4

KG/year

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1350

0.0135

0.0675

0.1350

0.5400

0.4590

1.3500

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

TASHAN-LDAR_R-TASH-AL-A-16

Chem R4

page 41 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

All

Units of Measurement:

R4

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1490

0.0149

0.0745

0.1490

0.5959

0.5065

1.4898

Grand Total:

1.4898

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R4

page 42 of 59

Leaker Detail Report

Report Parameters

Alroy

Report: R304_1

ISRAEL

All Classes

Monitoring Period:

Compliance Leak

R4

Alroy

Details

Class

Location

Date

Reported

Test

Type

Leak

Def

1st Att. Due

Repair Due

Repaired

Date

Event

Result

Technician

Instrument

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

LDAR Report_015 R4

page 43 of 59

החברה הארצית לבדיקות ושירותי איכות הסביבה

רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.

טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),

E-mail :michael.o@ecologicalab.com

סיכום 2016

תוצאות הניטור:

מדידה ראשונה ואחרי סבב התיקונים

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

טופס :15דו"ח תיקון דליפות למתקן ייצור

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R5 :

שלב הניטור :מדידה ראשונה

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

4

0.140

גז

נוזל קל

6

4

0

0

0

4

0

0

0

0.000016

0.140

סה"כ קטגוריה 8 :1

1

0

0

8

0

0

0

0.000

0.280

ברזים ,שסתומים

גז

וציוד תלוי

נוזל קל

צינורות פתוחים

גז

פוטנציאליים

נוזל קל

page 45 of 59

4

1

0

0

0

0

0

0.000016

6

6

0.0%

2

20

16

0

0

0

20

0

0

0.000156

2

1.363

2

102

0

0

0

7

95

0

0

0.001233

2

10.802

סה"כ קטגוריה 122 :2

16

0

0

115

7

0

0

0.001

12.165

0.0%

סה"כ130 :

17

0

0

123

7

0

0

0.001

12.445

0.0%

Form-07 R5

TASHAN-LDAR_R-TASH-AL-A-16

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R5 :

שלב הניטור :אחרי סבב תיקונים

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

4

0.140

גז

נוזל קל

6

4

0

0

0

4

0

0

0

0.000016

0.140

סה"כ קטגוריה 8 :1

1

0

0

8

0

0

0

0.000

0.280

ברזים ,שסתומים

גז

וציוד תלוי

נוזל קל

צינורות פתוחים

גז

פוטנציאליים

נוזל קל

page 46 of 59

4

1

0

0

0

0

0

0.000016

6

6

0.0%

2

20

16

0

0

0

20

0

0

0.000156

2

1.363

2

102

0

0

0

7

95

0

0

0.001233

2

10.802

סה"כ קטגוריה 122 :2

16

0

0

115

7

0

0

0.001

12.165

0.0%

סה"כ130 :

17

0

0

123

7

0

0

0.001

12.445

0.0%

Form-07 R5

TASHAN-LDAR_R-TASH-AL-A-16

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R5

KG/year

First measurement

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

1.0802

0.1080

0.5401

1.0802

4.3208

3.6727

10.8021

TASHAN-LDAR_R-TASH-AL-A-16

Chem R5

page 47 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

Connections & Flanges

Units of Measurement:

R5

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

1.2445

0.1244

0.6222

1.2445

4.9778

4.2311

12.4445

Grand Total:

12.4445

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R5

page 48 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R5

KG/year

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

1.0802

0.1080

0.5401

1.0802

4.3208

3.6727

10.8021

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

TASHAN-LDAR_R-TASH-AL-A-16

Chem R5

page 49 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

All

Units of Measurement:

R5

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

1.2445

0.1244

0.6222

1.2445

4.9778

4.2311

12.4445

Grand Total:

12.4445

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R5

page 50 of 59

Leaker Detail Report

Report Parameters

Alroy

Report: R304_1

ISRAEL

All Classes

Monitoring Period:

Compliance Leak

R5

Alroy

Details

Class

Location

Date

Reported

Test

Type

Leak

Def

1st Att. Due

Repair Due

Repaired

Date

Event

Result

Technician

Instrument

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

LDAR Report_015 R5

page 51 of 59

החברה הארצית לבדיקות ושירותי איכות הסביבה

רח 'הפרת ,2יבנה .ת.ד . 13337,מיקוד 81227.

טל : 08-9322115,פקס : 08-9322116,נייד:(טלפון נייד הושמט),

E-mail :michael.o@ecologicalab.com

סבב 6

תוצאות הניטור:

מדידה ראשונה ואחרי סבב התיקונים

טופס :07מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

פילוג לחומרים הנפלטים

טופס :15דו"ח תיקון דליפות למתקן ייצור

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R6 :

שלב הניטור :מדידה ראשונה

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

0.140

גז

נוזל קל

page 53 of 59

4

1

0

0

4

0

0

0

0.000016

6

6

4

0

0

0

4

0

0

0

0.000016

6

0.140

סה"כ קטגוריה 8 :1

1

0

0

8

0

0

0

0.000

0.280

0.0%

סה"כ8 :

1

0

0

8

0

0

0

0.000

0.280

0.0%

Form-07 R6

TASHAN-LDAR_R-TASH-AL-A-16

מצאי רכיבי ציוד והערכת פליטות למתקן ייצור

שם המפעל :תשתיות נפט ואנרגיה בע"מ

סבב ניטור מס'R6 :

שלב הניטור :אחרי סבב תיקונים

סוג רכיב

משאבות

שם המתקן :אלרואי

סוג

סה"כ

רכיבים

רכיבים

שירות

רכיבים

עיקריים

מספר

מספר

סה"כ

בלתי

רכיבים מעל

נגישים

1,000חל"מ

מספר

מספר

רכיבים

רכיבים

מ 0-עד 9חל"מ

מספר

רכיבים

רכיבים

קצב

קצב

אחוז

מ 9-עד

מ 1,000-עד

מעל

פליטה

פליטה

רכיבים מעל

1,000חל"מ

100,000חל"מ

100,000חל"מ

שעתי

שנתי

1,000חל"מ

מספר

מספר

מספר

ק"ג/שעה

ק"ג/שנה

%

תדירות

הניטור

סבבים/שנה

גז

6

נוזל קל

6

ציוד ערבור

גז

6

וערבול

נוזל קל

6

PRD

גז

6

נוזל קל

נקודות דגימה

0.140

גז

נוזל קל

page 54 of 59

4

1

0

0

4

0

0

0

0.000016

6

6

4

0

0

0

4

0

0

0

0.000016

6

0.140

סה"כ קטגוריה 8 :1

1

0

0

8

0

0

0

0.000

0.280

0.0%

סה"כ8 :

1

0

0

8

0

0

0

0.000

0.280

0.0%

Form-07 R6

TASHAN-LDAR_R-TASH-AL-A-16

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R6

KG/year

First measurement

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

TASHAN-LDAR_R-TASH-AL-A-16

Chem R6

page 55 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

Connections & Flanges

Units of Measurement:

R6

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

All

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0280

0.0028

0.0140

0.0280

0.1118

0.0951

0.2796

Grand Total:

0.2796

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R6

page 56 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Units of Measurement:

R6

KG/year

אלרואי

Unit

Component Class:

Pumps

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Agitators

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PRD

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Sample Points

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0140

0.0014

0.0070

0.0140

0.0559

0.0475

0.1398

Component Class:

Valves

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

PO End

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

Component Class:

Connections & Flanges

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

TASHAN-LDAR_R-TASH-AL-A-16

Chem R6

page 57 of 59

Correlation Equations Chemical Summary by Component Class

Monitoring Period:

Component Class:

All

Units of Measurement:

R6

KG/year

Chemical Name

CAS Number

1-Butene

Benzene

Cyclohexane

MTBE

n-Octane

Toluene

108883

Emissions

0.0280

0.0028

0.0140

0.0280

0.1118

0.0951

0.2796

Grand Total:

0.2796

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

Chem R6

page 58 of 59

Leaker Detail Report

Report Parameters

Alroy

Report: R304_1

ISRAEL

All Classes

Monitoring Period:

Compliance Leak

R6

Alroy

Details

Class

Location

Date

Reported

Test

Type

Leak

Def

1st Att. Due

Repair Due

Repaired

Date

Event

Result

Technician

Instrument

This report produced using Orr LeakDAS software.

TASHAN-LDAR_R-TASH-AL-A-16

LDAR Report_015 R6

page 59 of 59

ספח ג'

דוגמת חישוב עבור מיכל גג חיצוי צף מס' 2המאחסן קרוסין

3013.12-025-T2

3013.12-013

27/02/2017

18/31

3013.12-015

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - B&W 2016

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.11

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Red/Primer

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock

Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

1

2

29

43

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

13/02/2017

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - B&W 2016 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

All

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

81.75

66.81

96.69

Liquid

Bulk

Temp

(deg F)

70.60

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0161

N/A

N/A

Vapor

Mol.

Weight.

130.0000

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

Liquid

Mass

Fract.

Vapor

Mass

Fract.

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

13/02/2017

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - B&W 2016 - External Floating Roof Tank

Haifa, Israel

Annual Emission Calcaulations

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

0.0161

160.0100

130.0000

1.0000

Withdrawal Losses (lb):

Annual Net Throughput (gal/yr.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

65.8011

8,932,199.0000

0.0075

7.0000

160.0100

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

5.3401

0.0003

130.0000

1.0000

150.3024

6.2000

Total Losses (lb):

111.8364

40.6952

1.6000

0.3000

6.2000

1.6000

0.0003

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock

Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

1

2

29

43

1

KFa(lb-mole/yr)

1.60

11.00

6.20

1.20

0.49

0.71

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

9.90

1.20

0.14

0.16

0.10

m

0.00

0.89

0.94

0.65

0.14

1.00

Losses(lb)

0.1705

1.6897

0.7794

1.6109

1.0488

0.0406

13/02/2017

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

13/02/2017

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - B&W 2016 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

40.70

65.80

5.34

0.00

111.84

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

13/02/2017

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

13/02/2017

TANKS 4.0 Report

Page 1 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFixed 2014

Haifa

Israel

PEI

Vertical Fixed Roof Tank

kerosene

Tank Dimensions

Shell Height (ft):

Diameter (ft):

Liquid Height (ft) :

Avg. Liquid Height (ft):

Volume (gallons):

Turnovers:

Net Throughput(gal/yr):

Is Tank Heated (y/n):

N

Paint Characteristics

Shell Color/Shade:

Shell Condition

Roof Color/Shade:

Roof Condition:

Red/Primer

Good

White/White

Good

Roof Characteristics

Type:

Height (ft)

Slope (ft/ft) (Cone Roof)

Breather Vent Settings

Vacuum Settings (psig):

Pressure Settings (psig)

11.00

160.01

11.00

5.50

1,654,664.74

1.00

1,654,664.74

Cone

0.00

0.00

0.00

0.50

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

01/02/2015

TANKS 4.0 Report

Page 2 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFixed 2014 - Vertical Fixed Roof Tank

Haifa, Israel

Mixture/Component

Month

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

Liquid

Bulk

Temp

(deg F)

Vapor Pressure (psia)

Avg.

Min.

Max.

Vapor

Mol.

Weight.

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

Liquid

Mass

Fract.

Vapor

Mass

Fract.

Mol.

Weight

Basis for Vapor Pressure

Calculations

01/02/2015

TANKS 4.0 Report

Page 3 of 5

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

01/02/2015

TANKS 4.0 Report

Page 4 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFixed 2014 - Vertical Fixed Roof Tank

Haifa, Israel

Losses(lbs)

Components

Working Loss

Breathing Loss

Total Emissions

Jet kerosene

66.66

51.49

118.15

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

01/02/2015

TANKS 4.0 Report

Page 5 of 5

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

01/02/2015

TANKS 4.0 Report

Page 1 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFloating 2014

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.00

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Red/Primer

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock

Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

1

2

29

43

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

01/02/2015

TANKS 4.0 Report

Page 2 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFloating 2014 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Month

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

Liquid

Bulk

Temp

(deg F)

Vapor Pressure (psia)

Avg.

Min.

Max.

Vapor

Mol.

Weight.

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

Liquid

Mass

Fract.

Vapor

Mass

Fract.

Mol.

Weight

Basis for Vapor Pressure

Calculations

01/02/2015

TANKS 4.0 Report

Page 3 of 5

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

01/02/2015

TANKS 4.0 Report

Page 4 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFloating 2014 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

3.61

55.99

0.46

0.00

60.05

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

01/02/2015

TANKS 4.0 Report

Page 5 of 5

file:///C:/Program%20Files/Tanks409d/summarydisplay.htm

01/02/2015

T2 - kerosene

External Floating roof

1. Tank data

Diameter of the tank

D

Effective height of the stock liquid (while

roof landing episode)

hle

Shell Color and condition

α

Roof color and condition

α

Tank paint solar absorptance

α

Vapor space outage (while roof landing

episode)

HVO

m

feet

m

feet

color

condition

color

condition

dimensionless

m

Tank data

--Tank data

--חאקי

טובה

לבן

טוב

48.77

160.01

11.00

0.89

Table 7.1-6

Assumption - Green Dark

0.17

Table 7.1-6

0.53

Table 7.1-6

Possible to use also equation

1-15

assumption - equal to legs height

feet

11.00

Volume of the vapor space (while roof

landing episode)

Breather vent pressure setting

VV

ft

3

VV=PI()*D /4*Hvo

221,185

Equation 1-3

∆PBP

psi

Typical value

0.50

Equation 1-11

Breather vent vacuum setting

∆PBV

psi

Typical value

0.00

Equation 1-11

Breather vent pressure setting range

∆PB

psi

∆PB = PBP − PBV

0.50

Equation 1-11

2

2. Material data - קרוסין

Stock vapor molecular weight

MV

Density of the liquid inside the tank

Wl

Vapor density

WV

True vapor pressure of the stock liquid

P

Vapor pressure at daily average liquid

surface temperature

Vapor pressure at the daily maximum

liquid surface temperature, psia

Vapor pressure at the daily minimum

liquid surface temperature

Daily vapor pressure range

3013.12-013.xls - 2

gr/gr-mole

lb/lb-mole

g/ml

lb/gal

kg/m^3

lb/ft3

msds data

130

msds data

--msds data

---

0.80

6.68

4.5

0.28

mm Hg

PEI data

0.833

psia

--הנחה:

Pv=nRT -->

P2=P1*(T2/T1)

0.02

0.02

0.02

0.00

PVA

psia

PVX

psia

PVN

psia

T1(k)=20C+273

T2(k)=37.5C+273

∆PV

psia

∆PV = PVX − PVN

1/3

0

at 20°C

0.02

Equation 1-9

15/02/2017

3. Operation data

Number of days that the tank stands idle

(on roof landing episode)

Number of degassing and cleaning

episode

Number of roof landing episode

nd

days/landing episode

site data

4

landing episode/year

site data

0.07

landing episode/year

site data

0.07

Tanks Program

--Tanks Program

---

66

30

112

51

21

T2 - B&W 2015

Tanks Program

---

60.05

27

T2 - DFloating 2014

lb per emptying

Tanks Program

67

Kg per emptying

---

30

4. Normal operation (Tanks program)

lb per year

Kg per year

lb per year

Kg per year

Kg per year

Working (withdrawal) losses

Total emissions (Breathing & Working)

Breathing (standing) losses

5. Degassing and Cleaning (Tanks program)

Degassing: emission from one turnover of

lb per emptying

Edegass-floating

floating roof

Kg per emptying

Degassing: fixed roof with a height of roof

legs

Edegass-legs

Liquid fraction in sludge

Fliquid

Sludge volume

Sludge weight

Vs

Ws

Cleaning emissions

Ecleaning

Total Degassing and Cleaning emissions

Edegass-total

3013.12-013.xls - 2

0.8

m3 per emptying

Kg per emptying

lb per emptying

Kg per emptying

lb per emptying

Kg per emptying

Ecleaning = Ws * (1-Fliquid)

Edegass-total =

Edegass-floating + Edegass-legs + Ecleaning

2/3

T2 - B&W 2015

T2- DFixed 2014

(Only working losses)

Tanks FAQ - degassing and

cleaning

70

56,000

24,692

11,200

24,818

11,257

15/02/2017

6. Roof landing

Daily average liquid surface temperature

TLA

°R

T LA = 0 . 44 T AA + 0 . 56 T B + 0 . 0079 * α * I

534.97

Equation 1-26

Daily vapor temperature range

∆TV

°R

∆ TV = 0 .72 ∆ T A + 0.028 * α * I

41.01

Equation 1-8

Daily maximum liquid surface temperature

TLX

°R

TLX = TLA + 0.25*∆TV

545.22

Figure 7.1-17

Daily minimum liquid surface temperature

TLN

°R

TLN = TLA - 0.25*∆TV

524.71

Figure 7.1-17

Liquid bulk temperature

Max standing idle losses during roof

landing

TB

°R

TB = TAA + 6α - 1

528.15

Equation 1-28

LSL-max

lb per landing episode

Kg per landing episode

dimensionless

2

LSL-max = 5.9*D *hle*W l

--0.60 for a full liquid heel

0.50 for a partial

0.15 for drain-dry

11,093,038 Equation 2-13

5,031,769

0.50

Equation 2-26

(pages No 33,35)

1

KS =

1 + 0.053 * PVA * H VO

0.5

Equation 1-20

KS is assumed to be less than

or equal to the saturation factor

during filling (S) .

∆ TV ∆ PV − ∆ PB

+

T LA

PA − PVA

0.043

Liquid stock has a true vapor

pressure greater than 0.1psia Equation 1-7.

Filling saturation factor

S

saturation factor

KS

dimensionless

Vapor space expansion factor

KE

dimensionless

Standing idle losses during roof landing

LSL

lb per landing episode

 PV 

L SL = n d K E  V  M V K S

 RT AA 

7

Equation 2-16

Filling losses during roof landing

LFL

lb per landing episode

 P * VV 

 M V * S

L FL = 

 R * T AA 

41

Equation 2-26

Total losses during roof landing

LTL

lb per landing episode

Kg per landing episode

48

22

Equation 2-10

KE =

LTL=LSL+LFL

7. Summary

Working (withdrawal) losses

Breathing (standing) losses

Kg per year

Kg per year

30

21

Total Degassing and Cleaning emissions

Kg per year

750

Total losses during roof landing

Kg per year

1

803

3013.12-013.xls - 2

3/3

Kg per year

15/02/2017

ספח ד'

דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 2של קרוסין

3013.12-014

27/02/2017

19/31

3013.12-015

Transportation - Loading losses

Loading arm #1 - Kerosene

Density

Tank paint solar absorptance

Daily average ambient temperature

Wl

α

TAA

Yearly consumption

Myear

Cargo tank volume

V

Ntrucks

t

g/ml

dimensionless

°R

ton

m3

gal

m3

gal

1/year

min

Saturation factor

S

dimensionless

True vapor pressure of liquid

P

Molecular weight of vapors

M

Number of tank trucks

Duration of road truck filling

Table 5.2-1

mmHg

psia

0.833

0.02

@ 20°C

lb/lb-mole

130

Table 7.1-2

T=TB

°R

Controlled efficiency for the recovery

unit (vapor recovery efficiency)

eff1

%

vapor collection efficiency

eff2

%

overall reduction efficiency

eff

%

Loading losses of petroleum liquids

(uncontrolled emission rate)

LL

lb/103 gal

loaded

Flow rate of pollutant emission during

loading

Annual pollutant emission during

loading

T = TB = TAA + 6α - 1

527.40

0

LL total lb / loading

lb / min

Q

Kg / min

Kg / hr

Etotal

0.80

0.41

525.97

318

400

105,669

30.0

7,925

13

30

0.6

Temperature of bulk liquid loaded

Total loading losses of petroleum

msds data

site data

"Site" tab @ 3013-037

--data

--data

--Ntrucks = Myear / V

data

Submerge loading, dedicated

normal service

Kg / year

Truck passed the NSPS-level

annual test

70.0

eff=eff1*eff2/100

0

LL = 12.46

S *P*M 

eff 

1 −

T

 100 

0.030

LLtotal = LL*V

Q = Lltotal / t

-----

0.24

0.008

0.004

0.21

Etotal = LLtotal*Ntruks

1.39

Equation 1-28

page 5.2-6

can be 90% to over 99%

page 5.2-6

99.2- for tanker truck passed the

MACT-level annual leak test

98.7- for truck passed the NSPS-level

annual test

70 - for trucks not passing one of

these leak tests

Page 5.2-4 Equation 1

Assumption: the mass of the

Average pollutant emission

concentration during loading

3013.12-014.xls - 1

C

gr / m3

C = Q *t / V

3.6

1/1

pollutant is contained in the air

volume inside the tanker which is

replaced by the liquid loaded

15/02/2017

ספח ה'

חישוב פליטות ממיכל לאיסוף תשטיפים

27/02/2017

20/31

3013.12-015

תוכת :Tanksחישוב פליטה כתוצאה מאחסון ושיוי מפלס

27/02/2017

21/31

3013.12-015

3013.12-015

22/31

27/02/2017

3013.12-015

23/31

27/02/2017

3013.12-015

24/31

27/02/2017

תוכת :Tanksחישוב פליטה כתוצאה מיקוי וריקון מיכל )שלב א'(

27/02/2017

25/31

3013.12-015

3013.12-015

26/31

27/02/2017

3013.12-015

27/31

27/02/2017

תוכת :Tanksחישוב פליטה כתוצאה מיקוי וריקון מיכל )שלב ב'(

27/02/2017

28/31

3013.12-015

3013.12-015

29/31

27/02/2017

3013.12-015

30/31

27/02/2017

חישובי פליטה ממיכל תשטיפים

גיליון חישוב זה הוכן על ידי "פז" הדסה ויהול ) (1980בע"מ.

אין להעתיק ו\או לעשות שימוש כלשהו במידע ה"ל ללא הרשאה כתובה מ"פז" הדסה ויהול ) (1980בע"מ.

27/02/2017

31/31

3013.12-015

מסמך 6 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 2461 KB)

תשתיות פט וארגיה בע"מ

מסוף אלרואי

סיכום פליטות לאוויר

שת 2017

פרויקט3013.13 :

סימוכין3013.3-015 :

פברואר 2018

תוכן עייים

.1מבוא 4 ...............................................................................................................

 .2תוי מסוף 5 ........................................................................................................

 .2.1תוי מיכלים 5.........................................................................................................

 .2.2תוים עבור מסוף מילוי מיכליות כביש 9.....................................................................

.3חישוב פליטות 10 .................................................................................................

.3.1כללי10 ...................................................................................................... ............

.3.2סוגי פליטות מחושבות 10 .........................................................................................

.3.3

בחירת חומרים בתוכת 11 ......................................................................... TANKS

 .3.4תוים מטאורולוגיים 11 ..........................................................................................

.4סיכום פליטות לשת 12 .................................................................................. 2017

.4.1

מיכלים12 ...................................................................................................................... ...........

.4.2

מסוף מילוי מיכליות כביש 12 ...................................................................................................

.4.3

מיכל איסוף תשטיפים 13 ..........................................................................................................

.4.4

סיכום ממצאי יטור 13 ................................................................................................ LDAR

.4.5פליטה שתית מכלל המתקן 13 .................................................................................

.5פליטות לא שגרתיות במהלך שת 13 .................................................................. 2017

.6מקורות 14 ..........................................................................................................

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טבלאות

טבלה  :1תוי מיכלים – מידע כללי ,מידות ותוי תפעול – שת 5........................................... 2017

טבלה  :2תוי מעטפת וגגות – שת 6.................................................................................. 2017

טבלה  :3תוי אביזרים – שת 7........................................................................................ 2017

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכת 8................................................... TANKS

טבלה  :5תוים עבור מסוף מילוי מיכליות כביש – שת 9...................................................... 2017

טבלה :6חומרים מייצגים בתוכת 11 ............................................................................ TANKS

טבלה :7סיכום פליטות מכלים -שת 12 ............................................................................ 2017

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שת 12 ..................................................2017

טבלה :9סיכום פליטות חומרים אורגים דיפים עבור רכיבים בשת 13 .................................. 2017

טבלה :10סיכום פליטות שתי מכלל מסוף אלרואי – שת 13 .................................................2017

ספחים

ספח א'

טבלה (AP-42) 1-5.2

ספח ב'

תוי יטור LDARעבור מסוף אלרואי – סיכום שת 2017

ספח ג'

דוגמת חישוב עבור מיכל גג חיצוי צף מס' 2המאחסן קרוסין

ספח ד'

דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 1של קרוסין

ספח ה'

חישוב פליטות ממיכל לאיסוף תשטיפים

שירן שחר

שם עורך

26/02/2018

יואב פיסטיר

שם מאשר

להערות

תיאור

26.02.2018

תאריך

3/31

0

גרסה

3013.13-015.doc

.1מבוא

חברת תשתיות פט וארגיה בע"מ )להלן תש"ן( מפעילה את מסוף אלרואי לאחסון ושיוע

דלקים .

המסוף כולל:

•

מבי משרדים

•

חוות מכלים לאחסון דלקים מסוגים שוים

•

רציפי מילוי מכליות כביש )לשימוש בעת חירום בלבד(

המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכות

אלרואי ומדרום לו שכות קרית חרושת.

באתר 9מיכלים ,מתוכם 6מיכלים תפעוליים ו 3-מיכלי מלאי סגור )מיכלים מס' 6 ,1ו.(9-

מערכת השיוע היה באמצעות משאבות ובקרת מילוי ובוסף קיימות מערכות תומכות כגון

מערכות כיבוי אש ומערכות פיקוד ובקרה.

כחלק מהתאים ברישיון עסק מדצמבר ,2010בסוף כל שה קלדרית על תש"ן להגיש דו"ח

סיכום פליטות שתי לגבי השה שחלפה.

חישובי הפליטות בוצעו בעזרת תוכת Tanksומסמכי EPA-AP 42על פי תוי המתקים

הקיימים במסוף.

סיכום הפליטות הוכן על ידי חברת "פז" הדסה ויהול ) (1980בע"מ )להלן פז הדסה( ,והוא

מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות יטור LDARשהוגשו לרשויות.

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 .2תוי מסוף

 .2.1תוי מיכלים

בטבלאות הבאות מפורט מידע טכי של המיכלים בחוות המיכלים אלרואי.

טבלה  :1תוי מיכלים – מידע כללי ,מידות ותוי תפעול – שת 2017

מספר

מיכל

סוג הדלק

המאוחסן

לחץ אדים

בטמפ' הוזל

הממוצעת

)(mmHg

405 @ 28°C

כמות

צריכה

שתית

)מ"ק(

0

גבעה חלקית

24,598

גבעה חלקית

48.77

גבעה חלקית

48.77

32,056

48.77

32,056

28,768

56,959

51,614

15.56

51,614

15.56

14.1

15.56

14.1

11.4

18.3

18.3

15.4

9.7

סוג יקוז

בתחתית

מיכל

קוטר

מיכל

)מטר(

פח מיכל

)מ"ק(

פח מיכל

פעיל

)מ"ק(

48.77

32,056

28,768

גובה /אורך

מעטפת

מיכל

)מטר(

17.16

15.4

32,056

28,768

17.16

15.4

10

28,768

17.16

15.4

9.5

17.16

15.4

10.3

14.1

14.1

14.1

)(1

בזין

2

קרוסין

0.833 @ 28°C

3

סולר

0.507 @ 28°C

49,118

4

סולר

0.507 @ 28°C

23,773

גבעה חלקית

5

סולר

0.507 @ 28°C

91,328

גבעה מלאה

68.27

)(2

סולר

0.507 @ 28°C

0

גבעה מלאה

68.27

56,959

7

סולר

0.507 @ 28°C

11,989

גבעה מלאה

68.27

56,959

51,614

8

קרוסין

0.833 @ 28°C

982

גבעה חלקית

48.8

36,547

34,228

19.54

)(3

קרוסין

0.833 @ 28°C

0

גבעה חלקית

48.77

32,056

28,768

17.16

367,704

332,913

1

6

9

201,787

סה"כ

) (1מיכל מס' 1שימש כמיכל מלאי ,וקה במערכת סגורה בחודש ספטמבר 2017וכס לשיפוץ לאחר ביצוע היקוי.

) (2מיכל מס' 6שימש כמיכל מלאי ,היה בשיפוץ ממרץ עד יוי .2017

) (3מיכל מס' 9שימש כמיכל מלאי ,לא היו תועות במיכל בשת .2017

הערה כללית :מיכלים  1,4,5,6,7,8וקו במהלך שת .2017

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גובה וזל

מירבי

)מטר(

גובה וזל

ממוצע

)מטר(

10.5

טבלה  :2תוי מעטפת וגגות – שת 2017

מספר

מיכל

סוג גג

אטם ראשי

אטם משי

1

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

גג צף

חיצוי

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Liquid

mounted

Mechanical

Shoe

Rim

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Rim

mounted

Shoe

mounted

2

3

4

5

6

7

8

9

26/02/2018

צורת גג

סוג

חיבורי

גג

צבע

גג

מצב

צבע

גג

צבע

מעטפת

חיצוית

מצב צבע

מעטפת

חיצוית

סוג חיבורי

מעטפת

מצב

מעטפת

פימית

מיכל

מחומם

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חאקי

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חאקי

ישן

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

כחול בהיר

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

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טבלה  :3תוי אביזרים – שת 2017

מספר

מיכל

1

2

3

4

5

6

7

8

9

סה"כ

שובר ואקום

כמות

2

2

2

2

2

2

2

6

2

26/02/2018

Vacuum

]set. [psi

0

0

0

0

0

0

0

0

0

Pressure

]set. [psi

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

רגליים מתכווות התומכות

בגג צף

גובה

כמות באזור

כמות

במרכז

)(ft

pontoon

29

43

11

29

43

11

29

43

11

29

43

11

72

107

11

72

107

11

72

107

11

36

54

9

29

43

11

7/31

כמות

מדי

מפלס

Rim

Vent

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

6

כמות בוצה

בקיון

)מ"ק(

"גרביים" לבאר

הדיגום המחורצת

ולרגלי הגג הצף

70

70

70

70

150

150

150

70

70

870

יש

יש

יש

יש

יש

יש

יש

יש

יש

3013.13-015.doc

החות שלקחו לצורך החישובים

.1עבור חישוב Degassingבמיכל עם גג צף – הוח:

•

גג צף ח על רגליים בגובה ) 9-11 ftבהתאם לטבלה לעיל( וזהו גם הגובה המרבי של הוזל

במיכל.

•

גובה ממוצע של הוזל במיכל היו 50%מגובה הוזל המרבי.

.2הוח כי יקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שים .היקיון יארך יום אחד.

.3הוח כי אירוע של חיתת גגות צפים מתבצע אחת ל 15-שים .זמן חיתת הגג במקרה זה לא

יעלה על 4ימים.

.4יחס הוזל בבוצה הוח כ[2] 0.8 -

.5בהתאם לטבלה 7.1-6על פי ] ,[1בחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,

לצורך חישובי פליטות לאוויר:

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכת Tanks

צבע מעטפת

מיכל

צבע לצורך חישובי אקסל

צבע לצורך חישובים בתוכת

בהתאם למסמך EPA AP-42

(*) Tanks

כחול בהיר

Gray Medium

Gray Medium

חאקי

Green Dark

Red/Primer

צהוב קרם

Beige/Cream

Aluminium/Specular

)*( בתוכת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך

.[1] EPA AP-42

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 .2.2תוים עבור מסוף מילוי מיכליות כביש

טבלה  :5תוים עבור מסוף מילוי מיכליות כביש – שת 2017

מס'

זרוע

1

2

3

4

5

6

7

8

מוצר

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

סה"כ

מילוי

עילי /תחתי

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

פח ממוצע של

מיכלית )מ"ק(

30

30

30

30

30

30

30

30

פח מילוי שתי

)מ"ק(

151

0

0

0

0

0

0

0

151

החות שלקחו צורך החישובים

.1

מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:

א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:

דוגמת חישוב עבור מיכל מס' :1

0.17 + 0.834

= 0.25

2

=

)α roof(1) + α Shell(1

2

= α tank2

ב .בשלב השי חושב מקדם αממוצע עבור הקרוסין:

0.26 + 0.43 + 0.26

= 0.31

3

=

)α tank(1) + α tank(8) + α tank(9

number of kerosene tanks

= α Kerosene

.2

זמן מילוי מיכלית חושב על פי פח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000

ליטר/דקה.

.3

Vapor collection efficiency - 70%

.4

Vapor recovery efficiency - 0%

.5

Saturation factorהוח כ (Submerged loading, dedicated normal service) 0.6-על פי

] .[1טבלה רלווטית מצורפת בספח א'.

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.3חישוב פליטות

.3.1כללי

חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכת Tanksובעזרת .[1] EPA-AP 42

הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ) (LDARמצורפת בספח ב'.

דוגמת חישוב עבור מיכל גג חיצוי צף )מיכל מס' (2המאחסן קרוסין ,מצורפת כספח ג' למסמך

זה.

דוגמת חישוב עבור זרוע מילוי עילי של קרוסין )זרוע מס' (1מצורפת כספח ד' למסמך זה.

בדוגמאות אלה יתן לראות את תוי הקלט )כולל החות( עליהם התבססו החישובים.

.3.2סוגי פליטות מחושבות

הערכת הפליטות ממיכלי אחסון כוללת ]:[3

• פליטות בזמן אחסון )(Breathing Losses

• פליטות משיויי מפלס )(Working Losses

• פליטות כתוצאה מיקוי וריקון מיכלים )(Degassing Losses

• פליטות כתוצאה מחיתת גגות צפים )(Roof Landing Losses

• פליטות כתוצאה מהפרשי לחץ )(Flash Losses

• פליטות בזמן מילוי מיכלים ומיכליות

בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ

).(Flash Losses

פליטות אלה רלווטיות לשיויי פתאומי\מיידי בלחץ הוזל ,תון הגורם להפרת שיווי המשקל

הקיים במיכל )בין גז לוזל( וכתוצאה מכך וצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הוזל

עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר וזל המאוחסן בלחץ שלח

לאחסון במיכל בעל לחץ מוך יותר ].[3

פליטות אלו הוזחו כיוון שכל החומרים מוחזקים בתאים אטמוספריים בכל אחד מהשלבים

הוגעים להובלתם ואחסום ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.

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.3.3בחירת חומרים בתוכת Tanks

על פי תוי MSDSשל הדלקים במסוף ,בחרו החומרים הבאים הקיימים בתוכת Tanks

כמייצגים של חומרים אלו:

טבלה :6חומרים מייצגים בתוכת Tanks

דלק קיים במסוף

חומר מייצג בתוכת Tanks

סולר )תחבורה והסקה(

Distillate fuel oil no 2

פט )קרוסין(

Jet kerosene

בזין

Gasoline RVP 10

 .3.4תוים מטאורולוגיים

לצורך חישוב התוים בתוכת Tanksהוגדרו תוים מטאורולוגים המתאימים למפרץ חיפה על פי

מקורות ].[4

26/02/2018

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.4סיכום פליטות לשת 2017

.4.1מיכלים

סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:

טבלה :7סיכום פליטות מכלים -שת 2017

מיכל

חומר

1

בזין

פליטות לאוויר

)ק"ג/שה(

1,168

2

קרוסין

795

3

סולר

57

4

סולר

822

5

סולר

1,754

6

סולר

1,129

7

סולר

1,703

8

קרוסין

758

9

קרוסין

767

סה"כ

9,518

.4.2מסוף מילוי מיכליות כביש

להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שת 2017

מס' זרוע

מוצר

מילוי עילי /תחתי

1

2

3

4

5

6

7

8

סה"כ

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

26/02/2018

12/31

פליטה שתית

)ק"ג/שה(

0.53

0

0

0

0

0

0

0

0.53

3013.13-015.doc

.4.3מיכל איסוף תשטיפים

סך הפליטה ממיכל לאיסוף תשטיפים היה כ 1 -ק"ג/שה.

חישוב מצורף בספח ה'.

יצוין כי החישוב מתבסס על החה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל

בעיקר יקוז מים מהמכלים.

.4.4סיכום ממצאי יטור LDAR

טבלה :9סיכום פליטות חומרים אורגים דיפים עבור רכיבים בשת 2017

סה"כ פליטות )ק"ג/שה(

סיכום פליטות LDAR

פליטה שתית )ק"ג/שה(

סה"כ

12

.4.5פליטה שתית מכלל המתקן

טבלה :10סיכום פליטות שתי מכלל מסוף אלרואי – שת 2017

סה"כ פליטות )ק"ג/שה(

חוות מיכלים

מסוף מילוי

מיכליות כביש

מיכל לאיסוף

תשטיפים

9,518

0.53

1

סיכום פליטות

רכיבים

סה"כ

)(LDAR

12

9,532

.5פליטות לא שגרתיות במהלך שת 2017

במהלך שת 2017לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמיל.

26/02/2018

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3013.13-015.doc

.6מקורות

[1] EPA-AP42

[2] USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version

4.0 - APPENDIX D

] [3החיות הממוה לטיפול בבקשה להיתר פליטה לפי סעיף )9א( לתקות אוויר קי )היתרי פליטה(,

התש"ע – ,2010מהדורה ,4ספטמבר 2014

] [4האטלס האקלימי לתכון פיסי וסביבתי בישראל ,מהדורה שיה1994 ,

26/02/2018

14/31

3013.13-015.doc

ספח א'

טבלה 5.2-1

AP-42

26/02/2018

15/31

3013.13-015.doc

3013.13-015.doc

16/31

26/02/2018

ספח ב'

תוי יטור LDARעבור אלרואי – סיכום שת 2017

)מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך (05.02.2018

3013.13-004A

26/02/2018

17/31

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LDAR

Fugitive Emission Monitoring

Report No.

RL-TS-R1-17

Plant:TASHAN

City:Haifa

District:Haifa

Production Unit:Alroy

Group:Group 1-2-3

Reporting period:Annual Summary

Report printing date: 05-Feb-2018

Technicians names:

Porcelan

Polik

Report editor:

Michael Ourievsky

Approved by:

Alexey Ratner, CEO

Table of Content

1. Project introduction

1.1 Scope of work

1.2 Project phases

2. Methodology

2.1 Definitions

2.2 Methodology

3. Summary of Monitoring Period

3.1 Cumulative Data of Monitoring Period

3.2 Summary of Monitoring Period

3.3 Form 07: component classification and emission estimations for production facilities

3.4 Chemical Summary

3.5 LDAR report for production facilities

4. First Measurement and Measurement After Repair Round 1

4.1 Form-07 by Round

4.2 Chemical Summary First Measurement

4.3 Chemical Summary After Repair

4.4 LDAR report for production facilities

5. Attachments

5.1 Calibration log list

5.2 Calibration gas certificates

5.3 Composition list & Response Factors

5.4 Quarterly equipment check Q1

5.5 Quarterly equipment check Q2

5.6 Quarterly equipment check Q3

5.7 Quarterly equipment check Q4

5.8 Quarterly production hours

3

3

4

4

6

7

9

10

12

14

15

17

19

21

22

24

25

26

27

28

29

1 Project introduction

1.1 Scope of work

1 rounds of measurements (from 01/01/2017 to 31/12/2017)

Measurements performed for following classes:

Group 1: PRD, Sampling Point

Group 2: Open End, Stem Valve

Group 3: Connection, Flange

The following equipment was out of service. Emission estimation was performed using the previous

measurements.

Round

Unit

2

Alroy

3

Alroy

Equipment

Round

Unit

Equipment

Remarks

T-01+pipe (from

19/09/17)

T-01+pipe (from

19/09/17)

1.2 Project phases

 Monitoring: Group 1-2-3

 Re-measurement after repair action

 Revision of equipment and production processes

 Inventorisation: adding or deleting components

 Mapping of components on P&ID's

General

1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory

Accreditation Authority).

2. ISRAC is not responsible for the test results.

Project Introduction

page 3 of 29

2 Methodology

1.1 Definitions

Chemical State:

Gas/Vapor: stream which is in process conditions under gaseous or vapor form.

Light Liquid: a liquid having a VOC content greater than 10% (by volume) hat evaporates at 150°C

Heavy Liquid: a liquid having a VOC content of 10% or less (by volume) that evaporates at 150°C

Leak definition: 1,000 ppm (all sources)

Difficult to monitor components:

Any component situated at a level higher than five meters above ground level or any component situated at a distance further than two

meters from a platform and which cannot be accessed by employees in a safe way.

Any component which access requires the elevation of a person to a level higher than two meters above regular surfaces, and which

cannot be accessed in a safe.

Registered sources:

Sources with a leak value equal or greater than 9 ppm.

Default-zero:

This equation is valid for sources with a leak value of 0 ppm.A fixed EPA emission calculation rule is used for all these sources.

Total components:

All of the existing active components.

Total measured components:

All of the components, measured in specific monitoring round.

2.2 Methodology

Formulas:

Measured ppm values are converted to emission loss (kg/year) and these calculations are based on the E.P.A. “Correlation method SOCMI”

Modified Trapezoidal Emission Calculation Method:

The modified trapezoid method assumes that the mass leak rate changes linearly between any two monitoring points, except for

periods between leak detection and repair; the leak monitor reading is used from the time the leak is detected to the time it is repaired (i.e.,

re-screened).

Cumulative data:

In "Cumulative data" tables we provide the results of all of the measurements that performed from beginning of the year till the end of

current monitoring period (quarter). We also calculate the real sum of previous emissions based on the all rounds of the measurements

(before and after repairing attempts).(US EPA "Emission Estimation Protocol for Petroleum Refineries",Ver.2.1.1, 2011)

Methodology

page 4 of 29

Equation Set Details Report

Equation Set

Class

Chemical State

Default Zero

Pegged 100k

Multiplier

Exponent

Avg. Factor

Refinery

Connection

Light Liquid

7.5E-06

0.03

1.53E-06

0.735

0.00025

Refinery

Flange

Light Liquid

3.1E-07

0.084

4.61E-06

0.703

0.00025

Refinery

Open End

Light Liquid

2E-06

0.079

2.2E-06

0.704

0.0023

Refinery

PRD

Light Liquid

4E-06

0.11

1.36E-05

0.589

0.16

Refinery

Sampling Point

Light Liquid

4E-06

0.11

1.36E-05

0.589

0.015

Refinery

Stem Valve

Light Liquid

7.8E-06

0.14

2.29E-06

0.746

0.0109

Equations

page 5 of 29

Summary of Period: 01/01/2017-31/12/2017

The total emissions: 11.790kg

Component

Class

Total Components

count

PRD

Sampling

Point

Total Group 1:

Stem Valve

Open End

Total Group 2:

Flange

Connection

Total Group 3:

Total:

Overview by component class

Total Components above leak definition

(1,000 ppm)

count

R1

% of components above leak definition

(1,000 ppm)

%

R1

4

0

0.0%

0

0.1

4

0

0.0%

0

0.306

8

20

102

122

55

38

93

0

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

0

0.406

0.977

7.79

8.767

0.832

1.785

2.617

223

0

Unrepaired Components

Total Emissions

count

R1

kg

01/01/2017- 31/12/2017

0.0%

0

11.79

Overview by reading range

Reading Range

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000

ppm

Difficult to Monitor

Total:

Cumulative Data

Total Components

#

Round 1

%

220

3

0

0

98.7%

1.3%

0.0%

0.0%

0

0.0%

0

223

0.0%

100.0%

page 6 of 29

Summary of Monitoring Period Round 1

First measurement:

0 "difficult to monitor" sources.

220 default-zero sources with a calculated emission rate:

3 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

definition (1,000 ppm)

components above leak

definition

count

count

%

Total components

count

PRD

Sampling Point

Stem Valve

Open End

Flange

Connection

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

220

3

0

0

0

0

Total:

223

5.284 kg/year

2.125 kg/year

7.409 kg/year

Emission rate of

Total annual emission rate

components above leak

(all components)

definition

kg/year

kg/year

4

0

0

0.00%

0

0.123

4

0

0

0.00%

0

0.123

20

0

0

0.00%

0

1.198

102

3

0

0.00%

0

3.646

55

0

0

0.00%

0

0.131

38

0

0

0.00%

0

2.189

223

3

0

0.00%

0

7.41

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

98.65%

5.284

71.32%

1.35%

2.125

28.68%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

7.409

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

220 default-zero sources with a calculated emission rate:

3 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

5.284 kg/year

2.125 kg/year

7.409 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.123

Sampling Point

4

0

0

0.00%

0

0.123

Stem Valve

20

0

0

0.00%

0

1.198

Open End

102

3

0

0.00%

0

3.646

Flange

55

0

0

0.00%

0

0.131

Connection

38

0

0

0.00%

0

2.189

223

3

0

0.00%

0

7.41

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

220

3

0

0

0

0

Total:

223

Summary R1

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

98.65%

5.284

71.32%

1.35%

2.125

28.68%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

7.409

Comments

100%

page 7 of 29

Cumulative data for period

01/01/2017-31/12/2017

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Fugitive emission component classification and emission estimation for production facilities

01/01/2017-31/12/2017 Calculation period

Monitoring

Components Cumulative Components

Frequency above 1,000 ppm Emission above 100,000

ppm

cycles/year

6

6

6

6

6

6

2

2

2

2

2

2

1

1

1

1

1

1

Form-07 CU

%

R1

kg

Count

R1

Components in Components in Components in

reading range reading range reading range

1,000-100,000

9-999 ppm

0-8 ppm

ppm

Count

Count

Count

R1

R1

R1

TASHAN Company name

AlroyProduction Unit

Unrepaired

Total

Components

Components

above 1,000

ppm

Count

Count

R1

R1

Difficult

Major

Total

to

Components Components

Monitor

Count

Count

05-Feb-2018Date

Report Number

Chemical State Component Class Group

Count

0.00%

0.1

0

0

0

4

0

0

0

1

0.00%

0.306

0

0

0

4

0

0

0

0

0.00%

0.406

0

0

0

8

0

0

0

1

0.00%

0.977

0

0

0

20

0

0

0

16

0.00%

7.79

0

0

3

99

0

0

0

0

0.00%

8.767

0

0

3

119

0

0

0

16

0.00%

0.832

0

0

0

55

0

0

0

0

0.00%

1.785

0

0

0

38

0

0

0

0

0.00%

0.00%

2.617

11.79

0

0

0

0

0

3

93

220

0

0

0

0

0

0

0

17

GV

PRD

LL

HL

GV

Sampling Point

4

LL

HL

8

Subtotal G1

GV

Stem Valve

20

LL

HL

GV

Open End

102

LL

HL

122 Subtotal G2

GV

Flange

55

LL

HL

GV

Connection

38

LL

HL

93

Subtotal G3

223 Total Components

11.79 Total Cumulative Emission

G1

4

G2

G3

page 9 of 29

Chemical Summary by Component Class

Report Chemical Summary Cumulative

Calculation Period: 01/01/2017- 31/12/2017

Equation Set: Refinery

Units of Measurement: KG

Report Date: 05.02.2018

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

108883

Emissions

0.01

0.001

0.005

0.01

0.0401

0.0341

0.1002

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.0306

0.0031

0.0153

0.0306

0.1225

0.1041

0.3062

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.0977

0.0098

0.0489

0.0977

0.3909

0.3322

0.9772

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.779

0.0779

0.3895

0.779

3.1158

2.6485

7.7897

Chemical CU

page 10 of 29

Chemical Summary by Component Class

Report Chemical Summary Cumulative

Calculation Period: 01/01/2017- 31/12/2017

Equation Set: Refinery

Units of Measurement: KG

Report Date: 05.02.2018

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

108883

Emissions

0.0832

0.0083

0.0416

0.0832

0.3328

0.2829

0.832

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.1785

0.0179

0.0893

0.1785

0.7141

0.607

1.7853

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

1.179

0.118

0.5896

1.179

4.7162

4.0088

11.7906

Grand Total

Chemical CU

11.7906

page 11 of 29

LDAR report for production facilities

Plant

TASHAN

Unit

Drawing

LDAR 015

Component

Tag

Component

Type

Component

Class

Location Description

Unit

Monitoring Round

Alroy

Round 1

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 12 of 29

Round 1

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 1

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.123

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.123

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.246

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.198

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

0.0%

3.646

0

0

3

99

0

0

0

102

LL

2

HL

0.0%

4.844

0

0

3

119

0

0

16

122

Subtotal G2

1

GV

Flange

G3

1

0.0%

0.131

0

0

0

55

0

0

0

55

LL

1

HL

1

GV

Connection

1

0.0%

2.189

0

0

0

38

0

0

0

38

LL

1

HL

0.0%

2.32

0

0

0

93

0

0

0

93

Subtotal G3

0.0%

7.41

0

0

3

220

0

0

17

223 Total Components

7.41 Total Annual Emission Rate

TASHAN Company name

Round 1

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.123

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.123

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.246

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.198

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

0.0%

3.646

0

0

3

99

0

0

0

102

LL

2

HL

0.0%

4.844

0

0

3

119

0

0

16

122

Subtotal G2

1

GV

Flange

G3

1

0.0%

0.131

0

0

0

55

0

0

0

55

LL

1

HL

1

GV

Connection

1

0.0%

2.189

0

0

0

38

0

0

0

38

LL

1

HL

0.0%

2.32

0

0

0

93

0

0

0

93

Subtotal G3

0.0%

7.41

0

0

3

220

0

0

17

223 Total Components

7.41 Total Annual Emission Rate

Form-07 R1

page 14 of 29

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2017- 30/07/2017

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 05.02.2018

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

108883

Emissions

0.0123

0.0012

0.0061

0.0123

0.0492

0.0418

0.1229

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.0123

0.0012

0.0061

0.0123

0.0492

0.0418

0.1229

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.1198

0.012

0.0599

0.1198

0.4792

0.4073

1.198

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.3646

0.0365

0.1823

0.3646

1.4584

1.2397

3.6461

Chemical FM R1

page 15 of 29

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2017- 30/07/2017

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 05.02.2018

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

108883

Emissions

0.0131

0.0013

0.0065

0.0131

0.0524

0.0445

0.1309

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.2189

0.0219

0.1094

0.2189

0.8755

0.7442

2.1888

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.741

0.0741

0.3703

0.741

2.9639

2.5193

7.4096

Grand Total

Chemical FM R1

7.4096

page 16 of 29

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2017- 30/07/2017

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 05.02.2018

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

108883

Emissions

0.0123

0.0012

0.0061

0.0123

0.0492

0.0418

0.1229

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.0123

0.0012

0.0061

0.0123

0.0492

0.0418

0.1229

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.1198

0.012

0.0599

0.1198

0.4792

0.4073

1.198

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.3646

0.0365

0.1823

0.3646

1.4584

1.2397

3.6461

Chemical AR R1

page 17 of 29

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2017- 30/07/2017

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 05.02.2018

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

108883

Emissions

0.0131

0.0013

0.0065

0.0131

0.0524

0.0445

0.1309

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.2189

0.0219

0.1094

0.2189

0.8755

0.7442

2.1888

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TER-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

108883

0.741

0.0741

0.3703

0.741

2.9639

2.5193

7.4096

Grand Total

Chemical AR R1

7.4096

page 18 of 29

LDAR report for production facilities

Plant

TASHAN

Unit

Drawing

Component

Tag

LDAR 015 R1

Component

Type

Component

Class

Location Description

Unit

Monitoring Round

Alroy

Round 1

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 19 of 29

General

Calibration log list

Calibration gas certificates

Composition list & Response Factors

Quarterly production hours

Quarterly equipment check

Calibration log list

Plant

Round Equipment Analyzer

Type

Type

Ultra-Zero

Span Gas

Span gas Cylinder

Span

Check gas Check gas Cylinder

Check gas

No

concentration

No

concentration

Date

Equipment

No

Equipment

Serial

No

Check

Calibration Result

error

1-st 2-st 3-st

check check check

(A1) (A2) (A3)

(CP)

ppm ppm ppm

(A)

ppm

ppm

TASHAN

1

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

514

26-Jul-2017

1

0715622657

503

505

503

-0.07%

OK

TASHAN

1

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

514

26-Jul-2017

5

202016061436 506

500

500

-0.40%

OK

TASHAN

1

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

514

13-Aug-2017

1

0715622657

505

501

505

-0.07%

OK

TASHAN

1

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

514

13-Aug-2017

5

202016061436 503

504

506

0.07%

OK

TASHAN

1

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

514

31-Aug-2017

1

0715622657

499

505

505

-0.20%

OK

TASHAN

1

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

514

31-Aug-2017

5

202016061436 502

500

503

-0.46%

OK

TASHAN

1

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

514

05-Sep-2017

1

0715622657

501

502

501

-0.53%

OK

TASHAN

1

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

514

05-Sep-2017

5

202016061436 505

505

504

0.13%

OK

Cal-Log

page 21 of 29

Certificate

page 22 of 29

Certificate

page 23 of 29

Stream Composition Summary

Stream Name

Gasoline

Stream Content

TOLUENE-34 %, n-Octane-40 %, METHYL TER-BUTYL ETHER-10 %, CYCLOHEXANE-5

%, BENZENE-1 %, 1-Butene-10 %

Stream Summary

Stream Content

Dates

TVA

MiniRAE 10.6 MiniRAE 11.7

A=0.39, B=0.31

page 24 of 29

Quarterly Validation of LDAR Devices

Sampling Flow

Rate

Accuracy Check

Response Time

Comparison between two Devices

Date: 02-Jan-2017

1

Check

Quarter:

Span Gas Samplin

Check Gas

90%

Respons Respons Respons

Span gas

Check gas

1-st 2nd 3rd

Concentratio g Flow Resul

Concentratio

Equipmen

Equipment Anlyze

Calibratio Resul of

Resul Measure Differenc Differenc Resul

e Time 1 e Time 2 e Time 3

Equip.Ser. No

Span Gas Cylinder

Check Gas Cylinder

chec chec chec

n

Rate

n

t No

Type

r Type

t

n error

t Span

t

d ppm

e ppm

e%

t

No

No

k

k

k

ppm

l/min

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

EA000939

3

972

0.88

OK

Methane FF524456

514

509 510 511

1.19%

OK

875.

4

3

3

4

OK

2.18

0.05

-2.35%

OK

2

0115248185

TVA1000B

FID

Methane

EA000939

3

972

0.92

OK

Methane FF524456

514

510 510 513

1.39%

OK

875.

4

3

3

3

OK

2.14

-0.04

-1.87%

OK

3

0115248937

TVA1000B

FID

Methane

EA000939

3

972

1.01

OK

Methane FF524456

514

513 512 512

1.65%

OK

875.

4

4

4

3

OK

2.13

-0.16

6.99%

OK

4

0115248938

TVA1000B

FID

Methane

EA000939

3

972

1.24

OK

Methane FF524456

514

515 514 512

1.92%

OK

875.

4

4

3

4

OK

2.29

0.16

-7.51%

OK

5

20201606143

6

TVA2020

FID

Methane

EA000939

3

972

0.97

OK

Methane FF524456

514

510 513 514

1.65%

OK

875.

4

3

3

3

OK

2.74

-0.03

1.08%

OK

MiniRAE200

0

PID

Isobutylen EA000996

e

2

997

0.52

OK

Isobutylen EA000996

e

2

997

996 995 995

-0.25%

OK

898

3

3

2

OK

2.77

0.03

-1.09%

OK

6

Quarterly Validation

page 25 of 29

Quarterly Validation of LDAR Devices

Sampling Flow

Rate

Accuracy Check

Response Time

Comparison between two Devices

Date: 30-Mar-2017

2

Check

Quarter:

Span Gas Samplin

Check Gas

90%

Respons Respons Respons

Span gas

Check gas

1-st 2nd 3rd

Concentratio g Flow Resul

Concentratio

Equipmen

Equipment Anlyze

Calibratio Resul of

Resul Measure Differenc Differenc Resul

e Time 1 e Time 2 e Time 3

Equip.Ser. No

Span Gas Cylinder

Check Gas Cylinder

chec chec chec

n

Rate

n

t No

Type

r Type

t

n error

t Span

t

d ppm

e ppm

e%

t

No

No

k

k

k

ppm

l/min

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

EA000939

3

972

0.97

OK

Methane FF524456

514

512 513 511

1.59%

OK

875.

2

4

4

5

OK

1.24

0.02

-1.64%

OK

2

0115248185

TVA1000B

FID

Methane

EA000939

3

972

0.99

OK

Methane FF524456

514

503 507 506

0.26%

OK

875.

2

3

3

4

OK

1.22

-0.02

-1.64%

OK

3

0115248937

TVA1000B

FID

Methane

EA000939

3

972

1.02

OK

Methane FF524456

514

508 509 507

0.79%

OK

875.

2

4

4

4

OK

1.37

-0.02

1.44%

OK

4

0115248938

TVA1000B

FID

Methane

EA000939

3

972

1.14

OK

Methane FF524456

514

515 512 512

1.79%

OK

875.

2

3

3

4

OK

1.39

0.02

-1.46%

OK

5

20201606143

6

TVA2020

FID

Methane

EA000939

3

972

0.92

OK

Methane FF524456

514

510 513 512

1.52%

OK

875.

2

3

3

4

OK

1.22

0.22

-22%

OK

MiniRAE200

0

PID

Isobutylen EA000996

e

2

997

0.51

OK

Isobutylen EA000996

e

2

997

995 996 996

-0.21%

OK

898

3

3

3

OK

1

-0.22

18.03%

OK

6

Quarterly Validation

page 26 of 29

Quarterly Validation of LDAR Devices

Sampling Flow

Rate

Accuracy Check

Response Time

Comparison between two Devices

Date: 30-Jun-2017

3

Check

Quarter:

Span Gas Samplin

Check Gas

90%

Respons Respons Respons

Span gas

Check gas

1-st 2nd 3rd

Concentratio g Flow Resul

Concentratio

Equipmen

Equipment Anlyze

Calibratio Resul of

Resul Measure Differenc Differenc Resul

e Time 1 e Time 2 e Time 3

Equip.Ser. No

Span Gas Cylinder

Check Gas Cylinder

chec chec chec

n

Rate

n

t No

Type

r Type

t

n error

t Span

t

d ppm

e ppm

e%

t

No

No

k

k

k

ppm

l/min

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

EA000939

3

972

0.97

OK

Methane FF524456

514

500 503 506

-0.2%

OK

875.

2

4

4

4

OK

1.62

-0.09

5.26%

OK

2

0115248185

TVA1000B

FID

Methane

EA000939

3

972

0.99

OK

Methane FF524456

514

506 505 507

0.4%

OK

875.

2

4

3

4

OK

1.71

0.09

5.26%

OK

3

0115248937

TVA1000B

FID

Methane

EA000939

3

972

1.02

OK

Methane FF524456

514

500 504 500

-0.53%

OK

875.

2

4

4

4

OK

1.88

0.15

-8.67%

OK

4

0115248938

TVA1000B

FID

Methane

EA000939

3

972

1.14

OK

Methane FF524456

514

507 504 504

0.2%

OK

875.

2

4

3

4

OK

1.73

-0.15

7.98%

OK

5

20201606143

6

TVA2020

FID

Methane

EA000939

3

972

0.92

OK

Methane FF524456

514

501 501 507

-0.2%

OK

875.

2

3

4

4

OK

1.17

-0.05

4.1%

OK

MiniRAE200

0

PID

Isobutylen EA000996

e

2

997

0.51

OK

Isobutylen EA000996

e

2

997

997 998 998

-0.01%

OK

898

3

4

3

OK

1.22

0.05

-4.27%

OK

6

Quarterly Validation

page 27 of 29

Quarterly Validation of LDAR Devices

Sampling Flow

Rate

Accuracy Check

Response Time

Comparison between two Devices

Date: 03-Oct-2017

4

Check

Quarter:

Span Gas Samplin

Check Gas

90%

Respons Respons Respons

Span gas

Check gas

1-st 2nd 3rd

Concentratio g Flow Resul

Concentratio

Equipmen

Equipment Anlyze

Calibratio Resul of

Resul Measure Differenc Differenc Resul

e Time 1 e Time 2 e Time 3

Equip.Ser. No

Span Gas Cylinder

Check Gas Cylinder

chec chec chec

n

Rate

n

t No

Type

r Type

t

n error

t Span

t

d ppm

e ppm

e%

t

No

No

k

k

k

ppm

l/min

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

EA000943

1

971

0.82

OK

Methane FF524456

514

505 504 505

-1.82%

OK

874.

3

3

3

3

OK

1.41

-0.31

18.02%

OK

2

0115248185

TVA1000B

FID

Methane

EA000943

1

971

1

OK

Methane FF524456

514

500 501 501

-2.78%

OK

874.

3

3

3

3

OK

1.72

0.31

18.02%

OK

3

0115248937

TVA1000B

FID

Methane

EA000943

1

971

1.1

OK

Methane FF524456

514

476 476 473

-7.95%

OK

874.

3

4

4

4

OK

2.14

0.09

-4.39%

OK

4

0115248938

TVA1000B

FID

Methane

EA000943

1

971

1.16

OK

Methane FF524456

514

496 487 485

-5.35%

OK

874.

3

4

4

4

OK

2.05

-0.09

4.21%

OK

5

20201606143

6

TVA2020

FID

Methane

EA000943

1

971

0.96

OK

Methane FF524456

514

486 487 486

-6.11%

OK

874.

3

3

3

3

OK

1.73

0.23

-15.33%

OK

MiniRAE200

0

PID

Isobutylen EA000996

e

2

997

0.51

OK

Isobutylen EA000996

e

2

997

994 995 995

-0.31%

OK

898

4

4

3

OK

1.5

-0.23

13.29%

OK

6

Quarterly Validation

page 28 of 29

CUMULATIVE PRODUCTION HOURS TEMPLATE 2017

Plant

TASHAN

Unit

Drawing

Stream Name

Remark

Annual Production

Hours

Alroy

6006-100-006

Gasoline

6,264

Alroy

6006-100-007

Gasoline

6,264

Production Hours

Q1

01/01-31/03

Quarter =

Quarterly Production

hours

2,160

2,160

Q2

01/04-30/06

Quarter =

Quarterly Production

hours

2,184

2,184

Q3

01/07-30/09

Quarter =

Quarterly Production

hours

1,920

1,920

Q4

01/10-31/12

Quarter =

Quarterly Production

hours

0

0

page 29 of 29

ספח ג'

דוגמת חישוב עבור מיכל גג חיצוי צף מס' 2המאחסן קרוסין

3013.13-013-T2

3013.13-026

26/02/2018

18/31

3013.13-015.doc

T2 - kerosene

External Floating roof

1. Tank data

Diameter of the tank

D

Effective height of the stock liquid (while

roof landing episode)

hle

Shell Color and condition

α

Roof color and condition

α

Tank paint solar absorptance

α

Vapor space outage (while roof landing

episode)

HVO

m

feet

m

feet

color

condition

color

condition

dimensionless

m

Tank data

--Tank data

--חאקי

טובה

לבן

טוב

48.77

160.01

11.00

0.89

Table 7.1-6

Assumption - Green Dark

0.17

Table 7.1-6

0.53

Table 7.1-6

Possible to use also equation

1-15

assumption - equal to legs height

feet

11.00

Volume of the vapor space (while roof

landing episode)

Breather vent pressure setting

VV

ft

3

VV=PI()*D /4*Hvo

221,185

Equation 1-3

∆PBP

psi

Typical value

0.50

Equation 1-11

Breather vent vacuum setting

∆PBV

psi

Typical value

0.00

Equation 1-11

Breather vent pressure setting range

∆PB

psi

∆PB = PBP − PBV

0.50

Equation 1-11

2

2. Material data - קרוסין

Stock vapor molecular weight

MV

Density of the liquid inside the tank

Wl

Vapor density

WV

True vapor pressure of the stock liquid

P

Vapor pressure at daily average liquid

surface temperature

Vapor pressure at the daily maximum

liquid surface temperature, psia

Vapor pressure at the daily minimum

liquid surface temperature

Daily vapor pressure range

3013.13-013 - 2

gr/gr-mole

lb/lb-mole

g/ml

lb/gal

kg/m^3

lb/ft3

msds data

130

msds data

--msds data

---

0.80

6.68

4.5

0.28

mm Hg

PEI data

0.833

psia

--הנחה:

Pv=nRT -->

P2=P1*(T2/T1)

0.02

0.02

0.02

0.00

PVA

psia

PVX

psia

PVN

psia

T1(k)=20C+273

T2(k)=37.5C+273

∆PV

psia

∆PV = PVX − PVN

1/3

0

at 20°C

0.02

Equation 1-9

22/02/2018

3. Operation data

Number of days that the tank stands idle

(on roof landing episode)

Number of degassing and cleaning

episode

Number of roof landing episode

nd

days/landing episode

site data

4

landing episode/year

site data

0.07

landing episode/year

site data

0.07

Tanks Program

--Tanks Program

---

48

22

94

43

21

Tanks Program

---

60.05

27

lb per emptying

Tanks Program

67

Kg per emptying

---

30

4. Normal operation (Tanks program)

lb per year

Kg per year

lb per year

Kg per year

Kg per year

Working (withdrawal) losses

Total emissions (Breathing & Working)

Breathing (standing) losses

5. Degassing and Cleaning (Tanks program)

Degassing: emission from one turnover of

lb per emptying

Edegass-floating

floating roof

Kg per emptying

Degassing: fixed roof with a height of roof

legs

Edegass-legs

Liquid fraction in sludge

Fliquid

Sludge volume

Sludge weight

Vs

Ws

Cleaning emissions

Ecleaning

Total Degassing and Cleaning emissions

Edegass-total

3013.13-013 - 2

0.8

m3 per emptying

Kg per emptying

lb per emptying

Kg per emptying

lb per emptying

Kg per emptying

Ecleaning = Ws * (1-Fliquid)

Edegass-total =

Edegass-floating + Edegass-legs + Ecleaning

2/3

T2 - B&W 2017

T2 - B&W 2017

T2 - DFloating 2014

T2- DFixed 2014

(Only working losses)

Tanks FAQ - degassing and

cleaning

70

56,000

24,692

11,200

24,818

11,257

22/02/2018

6. Roof landing

Daily average liquid surface temperature

TLA

°R

T LA = 0 . 44 T AA + 0 . 56 T B + 0 . 0079 * α * I

534.97

Equation 1-26

Daily vapor temperature range

∆TV

°R

∆ TV = 0 .72 ∆ T A + 0.028 * α * I

41.01

Equation 1-8

Daily maximum liquid surface temperature

TLX

°R

TLX = TLA + 0.25*∆TV

545.22

Figure 7.1-17

Daily minimum liquid surface temperature

TLN

°R

TLN = TLA - 0.25*∆TV

524.71

Figure 7.1-17

Liquid bulk temperature

Max standing idle losses during roof

landing

TB

°R

TB = TAA + 6α - 1

528.15

Equation 1-28

LSL-max

lb per landing episode

Kg per landing episode

dimensionless

2

LSL-max = 5.9*D *hle*W l

--0.60 for a full liquid heel

0.50 for a partial

0.15 for drain-dry

11,093,038 Equation 2-13

5,031,769

0.50

Equation 2-26

(pages No 33,35)

1

KS =

1 + 0.053 * PVA * H VO

0.5

Equation 1-20

KS is assumed to be less than

or equal to the saturation factor

during filling (S) .

∆ TV ∆ PV − ∆ PB

+

T LA

PA − PVA

0.043

Liquid stock has a true vapor

pressure greater than 0.1psia Equation 1-7.

Filling saturation factor

S

saturation factor

KS

dimensionless

Vapor space expansion factor

KE

dimensionless

Standing idle losses during roof landing

LSL

lb per landing episode

 PV 

L SL = n d K E  V  M V K S

 RT AA 

7

Equation 2-16

Filling losses during roof landing

LFL

lb per landing episode

 P * VV 

 M V * S

L FL = 

 R * T AA 

41

Equation 2-26

Total losses during roof landing

LTL

lb per landing episode

Kg per landing episode

48

22

Equation 2-10

KE =

LTL=LSL+LFL

7. Summary

Working (withdrawal) losses

Breathing (standing) losses

Kg per year

Kg per year

22

21

Total Degassing and Cleaning emissions

Kg per year

750

Total losses during roof landing

Kg per year

1

795

3013.13-013 - 2

3/3

Kg per year

22/02/2018

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - B&W 2017

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

0.86

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Red/Primer

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock

Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

1

2

29

43

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

14/02/2018

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - B&W 2017 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

All

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

81.75

66.81

96.69

Liquid

Bulk

Temp

(deg F)

70.60

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0161

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

14/02/2018

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - B&W 2017 - External Floating Roof Tank

Haifa, Israel

Annual Emission Calcaulations

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

0.0161

160.0100

130.0000

1.0000

Withdrawal Losses (lb):

Annual Net Throughput (gal/yr.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

47.8696

6,498,077.0000

0.0075

7.0000

160.0100

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

5.3401

0.0003

130.0000

1.0000

150.3024

6.2000

Total Losses (lb):

93.9049

40.6952

1.6000

0.3000

6.2000

1.6000

0.0003

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock

Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

1

2

29

43

1

KFa(lb-mole/yr)

1.60

11.00

6.20

1.20

0.49

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

9.90

1.20

0.14

0.16

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.89

0.94

0.65

0.14

1.00

Losses(lb)

0.1705

1.6897

0.7794

1.6109

1.0488

0.0406

14/02/2018

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

14/02/2018

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - B&W 2017 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

40.70

47.87

5.34

0.00

93.90

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

14/02/2018

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

14/02/2018

TANKS 4.0 Report

Page 1 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFloating 2014

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.00

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Red/Primer

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock

Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

1

2

29

43

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

25/02/2018

TANKS 4.0 Report

Page 2 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFloating 2014 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Month

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

Liquid

Bulk

Temp

(deg F)

Vapor Pressure (psia)

Avg.

Min.

Max.

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

25/02/2018

TANKS 4.0 Report

Page 3 of 5

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

25/02/2018

TANKS 4.0 Report

Page 4 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFloating 2014 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

3.61

55.99

0.46

0.00

60.05

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

25/02/2018

TANKS 4.0 Report

Page 5 of 5

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

25/02/2018

TANKS 4.0 Report

Page 1 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFixed 2014

Haifa

Israel

PEI

Vertical Fixed Roof Tank

kerosene

Tank Dimensions

Shell Height (ft):

Diameter (ft):

Liquid Height (ft) :

Avg. Liquid Height (ft):

Volume (gallons):

Turnovers:

Net Throughput(gal/yr):

Is Tank Heated (y/n):

N

Paint Characteristics

Shell Color/Shade:

Shell Condition

Roof Color/Shade:

Roof Condition:

Red/Primer

Good

White/White

Good

Roof Characteristics

Type:

Height (ft)

Slope (ft/ft) (Cone Roof)

Breather Vent Settings

Vacuum Settings (psig):

Pressure Settings (psig)

11.00

160.01

11.00

5.50

1,654,664.74

1.00

1,654,664.74

Cone

0.00

0.00

0.00

0.50

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

25/02/2018

TANKS 4.0 Report

Page 2 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFixed 2014 - Vertical Fixed Roof Tank

Haifa, Israel

Mixture/Component

Month

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

Liquid

Bulk

Temp

(deg F)

Vapor Pressure (psia)

Avg.

Min.

Max.

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

25/02/2018

TANKS 4.0 Report

Page 3 of 5

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

25/02/2018

TANKS 4.0 Report

Page 4 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFixed 2014 - Vertical Fixed Roof Tank

Haifa, Israel

Losses(lbs)

Components

Working Loss

Breathing Loss

Total Emissions

Jet kerosene

66.66

51.49

118.15

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

25/02/2018

TANKS 4.0 Report

Page 5 of 5

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

25/02/2018

ספח ד'

דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 1של קרוסין

3013.13-014

26/02/2018

19/31

3013.13-015.doc

Transportation - Loading losses

Loading arm #1 - Kerosene

Density

Tank paint solar absorptance

Daily average ambient temperature

Wl

α

TAA

Yearly consumption

Myear

Cargo tank volume

V

Ntrucks

t

g/ml

dimensionless

°R

ton

m3

gal

m3

gal

1/year

min

Saturation factor

S

dimensionless

True vapor pressure of liquid

P

Molecular weight of vapors

M

Number of tank trucks

Duration of road truck filling

Table 5.2-1

mmHg

psia

0.833

0.02

@ 20°C

lb/lb-mole

130

Table 7.1-2

T=TB

°R

Controlled efficiency for the recovery

unit (vapor recovery efficiency)

eff1

%

vapor collection efficiency

eff2

%

overall reduction efficiency

eff

Flow rate of pollutant emission during

loading

Annual pollutant emission during

loading

T = TB = TAA + 6α - 1

LL

%

lb/10 gal

loaded

LL total lb / loading

lb / min

Q

Kg / min

Kg / hr

Etotal

527.40

0

Truck passed the NSPS-level

annual test

70.0

eff=eff1*eff2/100

0

3

Loading losses of petroleum liquids

(uncontrolled emission rate)

0.80

0.41

525.97

120

151

39,864

30.0

7,925

5

30

0.6

Temperature of bulk liquid loaded

Total loading losses of petroleum

msds data

site data

"Site" tab @ 3013-037

--data

--data

--Ntrucks = Myear / V

data

Submerge loading, dedicated

normal service

Kg / year

L L = 12.46

S *P*M 

eff 

1 −

T

 100 

0.030

LLtotal = LL*V

Q = Lltotal / t

-----

0.24

0.008

0.004

0.21

Etotal = LLtotal*Ntruks

0.53

Equation 1-28

page 5.2-6

can be 90% to over 99%

page 5.2-6

99.2- for tanker truck passed the

MACT-level annual leak test

98.7- for truck passed the NSPS-level

annual test

70 - for trucks not passing one of

these leak tests

Page 5.2-4 Equation 1

Assumption: the mass of the

Average pollutant emission

concentration during loading

3013.13-014.xls - 1

C

gr / m

3

C = Q *t / V

3.6

1/1

pollutant is contained in the air

volume inside the tanker which is

replaced by the liquid loaded

26/02/2018

ספח ה'

חישוב פליטות ממיכל לאיסוף תשטיפים

26/02/2018

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תוכת :Tanksחישוב פליטה כתוצאה מאחסון ושיוי מפלס

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תוכת :Tanksחישוב פליטה כתוצאה מיקוי וריקון מיכל )שלב א'(

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תוכת :Tanksחישוב פליטה כתוצאה מיקוי וריקון מיכל )שלב ב'(

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חישובי פליטה ממיכל תשטיפים

גיליון חישוב זה הוכן על ידי "פז" הדסה ויהול ) (1980בע"מ.

אין להעתיק ו\או לעשות שימוש כלשהו במידע ה"ל ללא הרשאה כתובה מ"פז" הדסה ויהול ) (1980בע"מ.

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מסמך 7 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 3707 KB)

תשתיות נפט ואנרגיה בע"מ

מסוף אלרואי

סיכום פליטות לאוויר

שנת 2018

פרויקט3013.15 :

סימוכין3013.15-036 :

פברואר 2019

תוכן עניינים

.1מבוא 4.............................................................................................................................

.2נתוני מסוף 5.....................................................................................................................

.2.1נתוני מיכלים 5.........................................................................................................

.2.2נתונים עבור מסוף מילוי מיכליות כביש 9.....................................................................

.3חישוב פליטות 10 ..............................................................................................................

כללי10 ....................................................................................................... ...........

.3.1

סוגי פליטות מחושבות 10 .........................................................................................

.3.2

בחירת חומרים בתוכנת 11 ......................................................................... TANKS

.3.3

נתונים מטאורולוגיים 11 ..........................................................................................

.3.4

.4סיכום פליטות לשנת 12 ............................................................................................. 2018

מיכלים 12 ..................................................................................................

.4.1

מסוף מילוי מיכליות כביש 12 ..........................................................................

.4.2

מיכל איסוף תשטיפים 13 ...............................................................................

.4.3

סיכום ממצאי ניטור 13 ....................................................................... LDAR

.4.4

פליטה שנתית מכלל המתקן 13 ........................................................................

.4.5

.5פליטות לא שגרתיות במהלך שנת 13 ............................................................................2018

.6מקורות 14 .......................................................................................................................

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טבלאות

טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 5........................................... 2018

טבלה :2נתוני מעטפת וגגות – שנת 6.................................................................................. 2018

טבלה :3נתוני אביזרים – שנת 7......................................................................................... 2018

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת 8................................................... TANKS

טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 9...................................................... 2018

טבלה :6חומרים מייצגים בתוכנת 11 ............................................................................ TANKS

טבלה :7סיכום פליטות מכלים -שנת 12 ............................................................................ 2018

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שנת 12 ..................................................2018

טבלה :9סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 13 .................................. 2018

טבלה :10סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 13 .................................................2018

נספחים

נספח א'

טבלה )AP-42( 1-5.2

נספח ב'

נתוני ניטור LDARעבור מסוף אלרואי – סיכום שנת 2018

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין

נספח ד'

דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 1של קרוסין

נספח ה'

חישוב פליטות ממיכל לאיסוף תשטיפים

שניר דרור

שם עורך

25/02/2019

יואב פיסטינר

שם מאשר

להערות

תיאור

25.02.2019

תאריך

3/31

0

גרסה

3013.15-036.doc

.1מבוא

חברת תשתיות נפט ואנרגיה בע"מ (להלן תש"ן) מפעילה את מסוף אלרואי לאחסון ושינוע

דלקים .

המסוף כולל:

מבני משרדים

חוות מכלים לאחסון דלקים מסוגים שונים

רציפי מילוי מכליות כביש (לשימוש בעת חירום בלבד)

המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכונת

אלרואי ומדרום לו שכונת קרית חרושת.

באתר 9מיכלים ,מתוכם 5מיכלים תפעוליים ו 4-מיכלים אסטרטגים (מיכלים מס' 7,6,1ו.)9-

מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוסף קיימות מערכות תומכות כגון

מערכות כיבוי אש ומערכות פיקוד ובקרה.

כחלק מהתנאים ברישיון עסק מדצמבר ,2010בסוף כל שנה קלנדרית על תש"ן להגיש דו"ח

סיכום פליטות שנתי לגבי השנה שחלפה.

חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקנים

הקיימים במסוף.

סיכום הפליטות הוכן על ידי חברת "פז" הנדסה וניהול ( )1980בע"מ (להלן פז הנדסה) ,והוא

מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.

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.2נתוני מסוף

.2.1נתוני מיכלים

בטבלאות הבאות מפורט מידע טכני של המיכלים בחוות המיכלים אלרואי.

טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 2018

לחץ אדים

בטמפ' הנוזל

הממוצעת

)(mmHg

405 @ 28°C

כמות

צריכה

שנתית

(מ"ק)

28,206

גבעה חלקית

37,445

גבעה חלקית

48.77

גבעה חלקית

48.77

32,056

48.77

32,056

28,768

56,959

51,614

15.56

51,614

15.56

14.1

15.56

14.1

11.4

18.3

18.3

15.4

9.7

סוג ניקוז

בתחתית

מיכל

קוטר

מיכל

(מטר)

נפח מיכל

(מ"ק)

נפח מיכל

פעיל

(מ"ק)

48.77

32,056

28,768

גובה /אורך

מעטפת

מיכל

(מטר)

17.16

15.4

32,056

28,768

17.16

15.4

10

28,768

17.16

15.4

9.5

17.16

15.4

10.3

14.1

14.1

14.1

מספר

מיכל

סוג הדלק

המאוחסן

() 1

בנזין

2

קרוסין

0.833 @ 28°C

3

סולר

0.507 @ 28°C

37,035

4

סולר

0.507 @ 28°C

43,547

גבעה חלקית

5

סולר

0.507 @ 28°C

57,578

גבעה מלאה

68.27

6

() 3

סולר

0.507 @ 28°C

0

גבעה מלאה

68.27

56,959

7

()3

סולר

0.507 @ 28°C

0

גבעה מלאה

68.27

56,959

51,614

8

()4

קרוסין

0.833 @ 28°C

51,102

גבעה חלקית

48.8

36,547

34,228

19.54

9

() 2

קרוסין

0.833 @ 28°C

28,732

גבעה חלקית

48.77

32,056

28,768

17.16

367,704

332,913

1

289,645

סה"כ

( )1מכל מס' 1משמש כמכל מלאי ,בחודש פברואר עד אפריל המיכל עבר ריקון ומילוי חומר.

( )2מכל מס' 9משמש כמכל מלאי ,עבר שיפוץ ורק במהלך חודש אוקטובר נובמבר אוחסן חומר במיכל.

( )3מכלים מס' 6ו 7-משמשים כמכלי מלאי ,לא היו תנועות במכלים בשנת .2018

( )4מכל 8בשיפוץ מחודש נובמבר.

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גובה נוזל

מירבי

(מטר)

גובה נוזל

ממוצע

(מטר)

10.5

טבלה :2נתוני מעטפת וגגות – שנת 2018

מספר

מיכל

סוג גג

אטם ראשי

אטם משני

1

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Liquid

mounted

Mechanical

Shoe

Rim

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Rim

mounted

Rim

mounted

2

3

4

5

6

7

8

9

25/02/2019

צורת גג

סוג

חיבורי

גג

צבע

גג

מצב

צבע

גג

צבע

מעטפת

חיצונית

מצב צבע

מעטפת

חיצונית

סוג חיבורי

מעטפת

מצב

מעטפת

פנימית

מיכל

מחומם

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חאקי

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חאקי

ישן

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

כחול בהיר

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

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טבלה :3נתוני אביזרים – שנת 2018

מספר

מיכל

1

2

3

4

5

6

7

8

9

סה"כ

שובר ואקום

כמות

2

2

2

2

2

2

2

6

2

25/02/2019

Vacuum

]set. [psi

0

0

0

0

0

0

0

0

0

Pressure

]set. [psi

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

רגליים מתכווננות התומכות

בגג צף

גובה

כמות באזור

כמות

במרכז

()ft

pontoon

29

43

11

29

43

11

29

43

11

29

43

11

72

107

11

72

107

11

72

107

11

36

54

9

29

43

11

7/31

כמות

מדי

מפלס

Rim

Vent

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

6

כמות בוצה

בנקיון

(מ"ק)

"גרביים" לבאר

הדיגום המחורצת

ולרגלי הגג הצף

70

70

70

70

150

150

150

70

70

870

יש

יש

יש

יש

יש

יש

יש

יש

יש

3013.15-036.doc

הנחות שנלקחו לצורך החישובים

.1עבור חישוב Degassingבמיכל עם גג צף – הונח:

גג צף נח על רגליים בגובה ( 9-11 ftבהתאם לטבלה לעיל) וזהו גם הגובה המרבי של הנוזל

במיכל.

גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.

.2הונח כי ניקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שנים .הניקיון יארך יום אחד.

.3הונח כי אירוע של נחיתת גגות צפים מתבצע אחת ל 15-שנים .זמן נחיתת הגג במקרה זה לא

יעלה על 4ימים.

.4יחס הנוזל בבוצה הונח כ]2[ 0.8 -

.5בהתאם לטבלה 7.1-6על פי [ ,]1נבחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,

לצורך חישובי פליטות לאוויר:

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת Tanks

צבע מעטפת

מיכל

צבע לצורך חישובי אקסל

צבע לצורך חישובים בתוכנת

בהתאם למסמך EPA AP-42

)*( Tanks

כחול בהיר

Gray Medium

Gray Medium

חאקי

Green Dark

Red/Primer

צהוב קרם

Beige/Cream

Aluminium/Specular

(*) בתוכנת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך

.]1[ EPA AP-42

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.2.2נתונים עבור מסוף מילוי מיכליות כביש

טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 2018

מס'

זרוע

1

2

3

4

5

6

7

8

מוצר

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

סה"כ

מילוי

עילי /תחתי

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

נפח ממוצע של

מיכלית (מ"ק)

30

30

30

30

30

30

30

30

נפח מילוי שנתי

(מ"ק)

2,066

0

0

0

0

0

0

0

2,066

הנחות שנלקחו צורך החישובים

.1

מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:

א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:

דוגמת חישוב עבור מיכל מס' :2

0.17  0.834

 0.25

2

) roof(2)   Shell(2

2

 tank2 

ב .בשלב השני חושב מקדם αממוצע עבור הקרוסין:

0.25  0.43  0.26

 0.31

3

) tank(2)   tank(8)   tank(9

number of kerosene tanks

 Kerosene 

.2

זמן מילוי מיכלית חושב על פי נפח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000

ליטר/דקה.

.3

Vapor collection efficiency - 70%

.4

Vapor recovery efficiency - 0%

.5

Saturation factorהונח כ (Submerged loading, dedicated normal service) 0.6-על פי

[ .]1טבלה רלוונטית מצורפת בנספח א'.

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.3חישוב פליטות

.3.1כללי

חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכנת Tanksובעזרת .]1[ EPA-AP 42

הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ( )LDARמצורפת בנספח ב'.

דוגמת חישוב עבור מיכל גג חיצוני צף (מיכל מס' )2המאחסן קרוסין ,מצורפת כנספח ג' למסמך

זה.

דוגמת חישוב עבור זרוע מילוי עילי של קרוסין (זרוע מס' )1מצורפת כנספח ד' למסמך זה.

בדוגמאות אלה ניתן לראות את נתוני הקלט (כולל הנחות) עליהם התבססו החישובים.

.3.2סוגי פליטות מחושבות

הערכת הפליטות ממיכלי אחסון כוללת [:]3

פליטות בזמן אחסון )(Breathing Losses

פליטות משינויי מפלס )(Working Losses

פליטות כתוצאה מניקוי וריקון מיכלים )(Degassing Losses

פליטות כתוצאה מנחיתת גגות צפים )(Roof Landing Losses

פליטות כתוצאה מהפרשי לחץ )(Flash Losses

פליטות בזמן מילוי מיכלים ומיכליות

בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ

).(Flash Losses

פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלחץ הנוזל ,נתון הגורם להפרת שיווי המשקל

הקיים במיכל (בין גז לנוזל) וכתוצאה מכך נוצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הנוזל

עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר נוזל המאוחסן בלחץ נשלח

לאחסון במיכל בעל לחץ נמוך יותר [.]3

פליטות אלו הוזנחו כיוון שכל החומרים מוחזקים בתנאים אטמוספריים בכל אחד מהשלבים

הנוגעים להובלתם ואחסונם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.

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.3.3בחירת חומרים בתוכנת Tanks

על פי נתוני MSDSשל הדלקים במסוף ,נבחרו החומרים הבאים הקיימים בתוכנת Tanks

כמייצגים של חומרים אלו:

טבלה :6חומרים מייצגים בתוכנת Tanks

דלק קיים במסוף

חומר מייצג בתוכנת Tanks

סולר (תחבורה והסקה)

Distillate fuel oil no 2

נפט (קרוסין)

Jet kerosene

בנזין

Gasoline RVP 10

.3.4נתונים מטאורולוגיים

לצורך חישוב הנתונים בתוכנת Tanksהוגדרו נתונים מטאורולוגים המתאימים למפרץ חיפה על פי

מקורות [.]4

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.4סיכום פליטות לשנת 2018

.4.1מיכלים

סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:

טבלה :7סיכום פליטות מכלים -שנת 2018

מיכל

חומר

פליטות לאוויר

(ק"ג/שנה)

1

בנזין (*)

3,092

2

קרוסין

806

3

סולר

46

4

סולר

839

5

סולר

1,732

6

סולר

1,695

7

סולר

1,695

8

קרוסין (ינואר – אוקטובר)

682

9

קרוסין (אוקטובר-נובמבר)

152

10,740

סה"כ

(*) מכל מס' – 1לא אוחסן חומר בחודש פברואר – אפריל במהלך השנה.

.4.2מסוף מילוי מיכליות כביש

להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שנת 2018

מס' זרוע

מוצר

מילוי עילי /תחתי

1

2

3

4

5

6

7

8

סה"כ

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

25/02/2019

12/31

פליטה שנתית

(ק"ג/שנה)

7.36

0

0

0

0

0

0

0

7.36

3013.15-036.doc

.4.3מיכל איסוף תשטיפים

סך הפליטה ממיכל לאיסוף תשטיפים הינה כ 1 -ק"ג/שנה.

חישוב מצורף בנספח ה'.

יצוין כי החישוב מתבסס על הנחה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל

בעיקר ניקוז מים מהמכלים.

.4.4סיכום ממצאי ניטור LDAR

טבלה :9סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 2018

סה"כ פליטות (ק"ג/שנה)

סיכום פליטות LDAR

פליטה שנתית (ק"ג/שנה)

סה"כ

22

.4.5פליטה שנתית מכלל המתקן

טבלה :10סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 2018

סה"כ פליטות (ק"ג/שנה)

חוות מיכלים

מסוף מילוי

מיכליות כביש

מיכל לאיסוף

תשטיפים

10,740

7.36

1

סיכום פליטות

רכיבים

סה"כ

()LDAR

22

10,770

.5פליטות לא שגרתיות במהלך שנת 2018

במהלך שנת 2018לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.

25/02/2019

13/31

3013.15-036.doc

.6מקורות

]1[ EPA-AP42

]2[ USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version

4.0 - APPENDIX D

[ ]3הנחיות הממונה לטיפול בבקשה להיתר פליטה לפי סעיף (9א) לתקנות אוויר נקי (היתרי פליטה),

התש"ע – ,2010מהדורה ,4ספטמבר 2014

[ ]4האטלס האקלימי לתכנון פיסי וסביבתי בישראל ,מהדורה שנייה1994 ,

25/02/2019

14/31

3013.15-036.doc

נספח א'

טבלה 5.2-1

AP-42

25/02/2019

15/31

3013.15-036.doc

3013.15-036.doc

16/31

25/02/2019

נספח ב'

נתוני ניטור LDARעבור אלרואי – סיכום שנת 2018

(מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך )03.02.2019

3013.15-004A

25/02/2019

17/31

3013.15-036.doc

LDAR

Fugitive Emission Monitoring

Report No.

RL-TS-R-A-18

Plant:TASHAN

City:Haifa

District:Haifa

Production Unit:Alroy

Group:Group 1-2-3

Reporting period:Annual Summary

Report printing date:03-Feb-2019

Technicians names:Polik

Portselan

Tomarov

Report editor:

Michael Ourievsky

Approved by:

Alexey Ratner, CEO

1

Table of Content

1. Project introduction

1.1 Scope of work

1.2 Project phases

2. Methodology

2.1 Definitions

2.2 Methodology

3. Summary of Monitoring Period

3.1 Cumulative Data of Monitoring Period

3.2 Summary of Monitoring Period

3.3 Form 07: component classification and emission estimations for production facilities

3.4 Chemical Summary

3.5 LDAR report for production facilities

4. First Measurement and Measurement After Repair Round 1

4.1 Form-07 by Round

4.2 Chemical Summary First Measurement

4.3 Chemical Summary After Repair

4.4 LDAR report for production facilities

5. First Measurement and Measurement After Repair Round 2

5.1 Form-07 by Round

5.2 Chemical Summary First Measurement

5.3 Chemical Summary After Repair

5.4 LDAR report for production facilities

6. First Measurement and Measurement After Repair Round 3

6.1 Form-07 by Round

6.2 Chemical Summary First Measurement

6.3 Chemical Summary After Repair

6.4 LDAR report for production facilities

7. First Measurement and Measurement After Repair Round 4

7.1 Form-07 by Round

7.2 Chemical Summary First Measurement

7.3 Chemical Summary After Repair

7.4 LDAR report for production facilities

8. First Measurement and Measurement After Repair Round 5

8.1 Form-07 by Round

8.2 Chemical Summary First Measurement

8.3 Chemical Summary After Repair

8.4 LDAR report for production facilities

9. First Measurement and Measurement After Repair Round 6

9.1 Form-07 by Round

9.2 Chemical Summary First Measurement

9.3 Chemical Summary After Repair

9.4 LDAR report for production facilities

Table Of Content

5

5

6

6

8

9

16

17

19

21

22

23

24

26

27

28

29

31

32

34

36

38

39

40

41

43

44

46

48

50

51

52

53

page 2 of 116

10. Graphs First Measurement Round 1

10.1 Overview by Reading Range

10.2 Comparison between count of sources & kg/year, by sources

10.3 Total overview by chemicals

11. Graphs Measurement After Repair Round 1

11.1 Overview by Reading Range

11.2 Comparison between count of sources & kg/year, by sources

11.3 Total overview by chemicals

12. Graphs First Measurement Round 2

12.1 Overview by Reading Range

12.2 Comparison between count of sources & kg/year, by sources

12.3 Total overview by chemicals

13. Graphs Measurement After Repair Round 2

13.1 Overview by Reading Range

13.2 Comparison between count of sources & kg/year, by sources

13.3 Total overview by chemicals

14. Graphs First Measurement Round 3

14.1 Overview by Reading Range

14.2 Comparison between count of sources & kg/year, by sources

14.3 Total overview by chemicals

15. Graphs Measurement After Repair Round 3

15.1 Overview by Reading Range

15.2 Comparison between count of sources & kg/year, by sources

15.3 Total overview by chemicals

16. Graphs First Measurement Round 4

16.1 Overview by Reading Range

16.2 Comparison between count of sources & kg/year, by sources

16.3 Total overview by chemicals

17. Graphs Measurement After Repair Round 4

17.1 Overview by Reading Range

17.2 Comparison between count of sources & kg/year, by sources

17.3 Total overview by chemicals

18. Graphs First Measurement Round 5

18.1 Overview by Reading Range

18.2 Comparison between count of sources & kg/year, by sources

18.3 Total overview by chemicals

19. Graphs Measurement After Repair Round 5

19.1 Overview by Reading Range

19.2 Comparison between count of sources & kg/year, by sources

19.3 Total overview by chemicals

20. Graphs First Measurement Round 6

20.1 Overview by Reading Range

20.2 Comparison between count of sources & kg/year, by sources

20.3 Total overview by chemicals

Table Of Content

55

57

56

59

61

60

63

65

64

67

69

68

71

73

72

75

77

76

79

81

80

83

85

84

87

89

88

91

93

92

95

97

96

page 3 of 116

21. Graphs Measurement After Repair Round 6

21.1 Overview by Reading Range

21.2 Comparison between count of sources & kg/year, by sources

21.3 Total overview by chemicals

22. Graphs Cumulative

22.1 Comparison between count of sources above leak definition, by quarter

22.2 Comparison between % of components above leak definition by quarter

22.3 Comparison between count of sources & kg/year, by sources Cumulative

22.4 Total overview by chemicals

23. Attachments

23.1 Calibration loglist

23.2 Calibration gas certificates

23.3 Composition list & Response Factors

23.4 Quarterly equipment check Q1

23.5 Quarterly equipment check Q2

23.6 Quarterly equipment check Q3

23.7 Quarterly equipment check Q4

23.8 Quarterly production hours

Table Of Content

99

101

100

103

104

105

106

108

109

111

112

113

114

115

116

page 4 of 116

1 Project introduction

1.1 Scope of work

6 rounds of measurements (from 01/01/2018 to 31/12/2018)

Measurements performed for following classes:

Group 1: PRD, Sampling Point

Group 2: Open End, Stem Valve

Group 3: Connection, Flange

1.2 Project phases

 Monitoring: Group 1-2-3

 Re-measurement after repair action

 Revision of equipment and production processes

 Inventorisation: adding or deleting components

 Mapping of components on P&ID's

General

1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory

Accreditation Authority).

2. ISRAC is not responsible for the test results.

Project Introduction

page 5 of 116

2 Methodology

1.1 Definitions

Chemical State:

Gas/Vapor: stream which is in process conditions under gaseous or vapor form.

Light Liquid: a liquid having a VOC content greater than 10% (by volume) hat evaporates at 150°C

Heavy Liquid: a liquid having a VOC content of 10% or less (by volume) that evaporates at 150°C

Leak definition: 1,000 ppm (all sources)

Difficult to monitor components:

Any component situated at a level higher than five meters above ground level or any component situated at a distance further than

two meters from a platform and which cannot be accessed by employees in a safe way.

Any component which access requires the elevation of a person to a level higher than two meters above regular surfaces, and which

cannot be accessed in a safe.

Registered sources:

Sources with a leak value equal or greater than 9 ppm.

Default-zero:

This equation is valid for sources with a leak value of 0 ppm.A fixed EPA emission calculation rule is used for all these sources.

Total components:

All of the existing active components.

Total measured components:

All of the components, measured in specific monitoring round.

2.2 Methodology

Formulas:

Measured ppm values are converted to emission loss (kg/year) and these calculations are based on the E.P.A. “Correlation method

Refinery”

Modified Trapezoidal Emission Calculation Method:

The modified trapezoid method assumes that the mass leak rate changes linearly between any two monitoring points, except for

periods between leak detection and repair; the leak monitor reading is used from the time the leak is detected to the time it is repaired (i.e.,

re-screened).

Cumulative data:

In "Cumulative data" tables we provide the results of all of the measurements that performed from beginning of the year till the end of

current monitoring period (quarter). We also calculate the real sum of previous emissions based on the all rounds of the measurements

(before and after repairing attempts).(US EPA "Emission Estimation Protocol for Petroleum Refineries")

Methodology

page 6 of 116

Equation Set Details Report

Equation Set

Class

Chemical State

Default Zero

Pegged 100k

Multiplier

Exponent

Avg. Factor

Refinery

Connection

Light Liquid

7.5E-06

0.03

1.53E-06

0.735

0.00025

Refinery

Flange

Light Liquid

3.1E-07

0.084

4.61E-06

0.703

0.00025

Refinery

Open End

Light Liquid

2E-06

0.079

2.2E-06

0.704

0.0023

Refinery

PRD

Light Liquid

4E-06

0.11

1.36E-05

0.589

0.16

Refinery

Sampling Point

Light Liquid

4E-06

0.11

1.36E-05

0.589

0.015

Refinery

Stem Valve

Light Liquid

7.8E-06

0.14

2.29E-06

0.746

0.0109

Equations

page 7 of 116

Summary of Period: 01/01/2018-31/12/2018

The total emissions: 22.275kg

Component

Class

Total Components

count

PRD

Sampling Point

Total Group 1:

Stem Valve

Open End

Total Group 2:

Flange

Connection

Total Group 3:

4

4

8

20

102

122

55

38

93

Total:

Overview by component class

Total Components above leak definition

% of components above leak definition

Unrepaired Components

(1,000 ppm)

(1,000 ppm)

count

%

count

Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round

1

2

3

4

5

6

1

2

3

4

5

6

1

2

3

4

5

6

223

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

1

1

0

0

0

0

0

0

0

0

0

0

0

0

1

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

1.0%

0.8%

0.0%

0.0%

0.0%

0.4%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Total Emissions

kg

01/01/2018- 31/12/2018

0

0

0

0

0

0

0

0

0

0.548

0.14

0.688

1.367

17.574

18.941

0.149

2.497

2.646

0

22.275

Overview by reading range

Reading Range

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

Total:

Cumulative Data

#

Round 1

6

2

0

0

0

0

8

%

#

75.0%

25.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 2

8

0

0

0

0

0

8

%

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 3

183

40

0

0

0

0

223

Total Components

%

#

82.1%

17.9%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 4

8

0

0

0

0

0

8

%

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 5

126

3

1

0

1

0

130

%

#

96.9%

2.3%

0.8%

0.0%

0.8%

0.0%

100.0%

Round 6

8

0

0

0

0

0

8

%

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

page 8 of 116

Summary of Monitoring Period Round 1

First measurement:

0 "difficult to monitor" sources.

6 default-zero sources with a calculated emission rate:

2 registered sources with a calculated emission rate:

0.21 kg/year

2.886 kg/year

3.096 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

6

2

0

0

0

0

Total:

8

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

2

0

0.00%

0

2.956

4

0

0

0.00%

0

0.14

8

2

0

0.00%

0

3.096

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

75.00%

0.21

6.78%

25.00%

2.886

93.22%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

3.096

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

6 default-zero sources with a calculated emission rate:

2 registered sources with a calculated emission rate:

0.21 kg/year

2.886 kg/year

3.096 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

2

0

0.00%

0

2.956

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

2

0

0.00%

0

3.096

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

6

2

0

0

0

0

Total:

8

Summary R1

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

75.00%

0.21

6.78%

25.00%

2.886

93.22%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

3.096

Comments

100%

page 9 of 116

Summary of Monitoring Period Round 2

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

0

0

0.00%

0

0.14

8

0

0

0.00%

0

0.28

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Summary R2

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

page 10 of 116

Summary of Monitoring Period Round 3

First measurement:

0 "difficult to monitor" sources.

183 default-zero sources with a calculated emission rate:

40 registered sources with a calculated emission rate:

5.379 kg/year

25.571 kg/year

30.95 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Stem Valve

Open End

Flange

Connection

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

183

40

0

0

0

0

Total:

223

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

0

0

0.00%

0

0.14

20

0

0

0.00%

0

1.367

102

40

0

0.00%

0

26.658

55

0

0

0.00%

0

0.149

38

0

0

0.00%

0

2.497

223

40

0

0.00%

0

30.951

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

82.06%

5.379

17.38%

17.94%

25.571

82.62%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

30.95

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

183 default-zero sources with a calculated emission rate:

40 registered sources with a calculated emission rate:

5.379 kg/year

25.571 kg/year

30.95 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Stem Valve

20

0

0

0.00%

0

1.367

Open End

102

40

0

0.00%

0

26.658

Flange

55

0

0

0.00%

0

0.149

Connection

38

0

0

0.00%

0

2.497

223

40

0

0.00%

0

30.951

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

183

40

0

0

0

0

Total:

223

Summary R3

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

82.06%

5.379

17.38%

17.94%

25.571

82.62%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

30.95

Comments

100%

page 11 of 116

Summary of Monitoring Period Round 4

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

0

0

0.00%

0

0.14

8

0

0

0.00%

0

0.28

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Summary R4

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

page 12 of 116

Summary of Monitoring Period Round 5

First measurement:

0 "difficult to monitor" sources.

126 default-zero sources with a calculated emission rate:

4 registered sources with a calculated emission rate:

3.364 kg/year

5.694 kg/year

9.058 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Stem Valve

Open End

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

126

3

1

0

1

0

Total:

130

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

0

0

0.00%

0

0.14

20

0

0

0.00%

0

1.367

102

3

1

33.21%

3.008

7.411

130

3

1

33.21%

3.008

9.058

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

96.92%

3.364

37.14%

2.31%

2.686

29.65%

0.77%

3.008

33.21%

0.00%

0

0.00%

0.77%

3.008

33.21%

0.00%

0

0.00%

100%

9.058

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

126 default-zero sources with a calculated emission rate:

4 registered sources with a calculated emission rate:

3.364 kg/year

3.257 kg/year

6.621 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Stem Valve

20

0

0

0.00%

0

1.367

Open End

102

4

0

0.00%

0

4.974

Total:

130

4

0

0.00%

0

6.621

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

126

4

0

0

0

0

Total:

130

Summary R5

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

96.92%

3.364

50.81%

3.08%

3.257

49.19%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

6.621

Comments

100%

page 13 of 116

Summary of Monitoring Period Round 6

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

0

0

0.00%

0

0.14

8

0

0

0.00%

0

0.28

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Summary R6

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

page 14 of 116

Cumulative data for period

01/01/2018-31/12/2018

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph Cumulative

page 15 of 116

Fugitive emission component classification and emission estimation for production facilities

01/01/2018-31/12/2018

Monitoring

Frequency

Components above 1,000 ppm

cycles/year

Cumulative Components above

Emission

100,000 ppm

%

R6

6

6 0.00%

6

6

6 0.00%

6

0.00%

2

2 0.00%

2

2

2 0.00%

2

0.00%

1

1 0.00%

1

1

1 0.00%

1

0.00%

0.00%

R5

R4

kg

R3

R2

Count

R1

Calculation period TASHAN

Alroy

Components in

Components in

Components in

reading range

reading range 9-999 reading range 0-8 ppm

1,000-100,000 ppm

ppm

Count

Count

Count

Unrepaired

Components

Count

Company name 22-Jan-2019

Date

Production Unit

Report Number

Total Components Difficult

Major

Total

Chemical State Component Class Group

above 1,000 ppm

to

Components Components

Monitor

Count

R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1

Count

Count

Count

0.00% 0.00% 0.00% 0.00% 0.00%

0.548

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

2

4

4

4

4

4

2 0

0

0

0

0

0 0

0

0

0

0

0

0

1

4

0.00% 0.00% 0.00% 0.00% 0.00%

0.14

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

4

4

4

4

4

4 0

0

0

0

0

0 0

0

0

0

0

0

0

0

4

0.00% 0.00% 0.00% 0.00% 0.00%

0.688

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

2

8

8

8

8

8

6 0

0

0

0

0

0 0

0

0

0

0

0

0

1

8

0.00% 0.00% 0.00% 0.00% 0.00%

1.367

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

20

0

20

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

16

20

0.98% 0.00% 0.00% 0.00% 0.00%

17.574

0 0

0

0

0

0 0

1

0

0

0

0 0

3

0 40

0

0

0

98

0

62

0

0 0

0

0

0

0

0 0

1

0

0

0

0

0

0

102

0.82% 0.00% 0.00% 0.00% 0.00%

18.941

0 0

0

0

0

0 0

1

0

0

0

0 0

3

0 40

0

0

0 118

0

82

0

0 0

0

0

0

0

0 0

1

0

0

0

0

0

16

122

0.00% 0.00% 0.00% 0.00% 0.00%

0.149

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0

55

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

55

0.00% 0.00% 0.00% 0.00% 0.00%

2.497

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0

38

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

38

0.00% 0.00% 0.00% 0.00% 0.00%

0.45% 0.00% 0.00% 0.00% 0.00%

2.646

22.275

0 0

0 0

0

0

0

0

0

0

0 0

0 0

0

1

0

0

0

0

0

0

0 0

0 0

0

3

0 0

0 40

0

0

0

2

0

0

8 126

0 93

8 183

0

8

0 0

6 0

0

0

0

0

0

0

0

0

0 0

0 0

0

1

0

0

0

0

0

0

0

0

0

0

0

17

93

223

22.275

GV

LL

HL

GV

LL

HL

Subtotal G1

GV

LL

HL

GV

LL

HL

Subtotal G2

GV

LL

HL

GV

LL

HL

Subtotal G3

PRD

G1

Sampling Point

Stem Valve

G2

Open End

Flange

G3

Connection

Total Components

Total Cumulative Emission

Chemical Summary by Component Class

Report Chemical Summary Cumulative

Calculation Period: 01/01/2018- 31/12/2018

Equation Set: Refinery

Units of Measurement: KG

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.0548

0.0055

0.0274

0.0548

0.2192

0.1863

0.548

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.1367

0.0137

0.0683

0.1367

0.5466

0.4646

1.3666

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

1.7574

0.1757

0.8787

1.7574

7.0294

5.975

17.5736

Chemical CU

page 17 of 116

Chemical Summary by Component Class

Report Chemical Summary Cumulative

Calculation Period: 01/01/2018- 31/12/2018

Equation Set: Refinery

Units of Measurement: KG

Report Date: 03.02.2019

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.0149

0.0015

0.0075

0.0149

0.0597

0.0508

0.1493

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.2497

0.025

0.1248

0.2497

0.9986

0.8488

2.4966

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

2.2275

0.2228

1.1137

2.2275

8.9096

7.5732

22.2743

Grand Total

Chemical CU

22.2743

page 18 of 116

LDAR report for production facilities

Plant

TASHAN

Unit

Alroy

Drawing

Component

Tag

6006-100-007 75

LDAR 015

Component

Type

Component

Class

Blind Flange

Open End

Location Description

Top of T-1

Unit

Monitoring Round

Alroy

Round 1-2-3-4-5-6

ppm value, First

Measurement

Date of First

Measurement

1,305 29-Nov-2018

Repair Due Date of repair

Repair type

08-Dec-2018 29-Nov-2018 Tightening

date of

remeasurement

after repair

attempt

29-Nov-2018

Technicians

ppm value of

remeasurement

after repair

attempt

Date of

repair

Remarks

Repair type

date of

remeasurement

after repair

attempt

ppm value of

remeasurement

after repair attempt

123

page 19 of 116

Round 1

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R1

page 20 of 116

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 1

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

2.956

0

0

2

2

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

3.096

0

0

2

6

0

0

1

8

Subtotal G1

0.0%

3.096

0

0

2

6

0

0

1

8 Total Components

3.096 Total Annual Emission Rate

TASHAN Company name

Round 1

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

2.956

0

0

2

2

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

3.096

0

0

2

6

0

0

1

8

Subtotal G1

0.0%

3.096

0

0

2

6

0

0

1

8 Total Components

3.096 Total Annual Emission Rate

Form-07 R1

page 21 of 116

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2018- 01/03/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.2956

0.0296

0.1478

0.2956

1.1824

1.005

2.956

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.3096

0.031

0.1548

0.3096

1.2385

1.0527

3.0962

Grand Total

Chemical FM R1

3.0962

page 22 of 116

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2018- 01/03/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.2956

0.0296

0.1478

0.2956

1.1824

1.005

2.956

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.3096

0.031

0.1548

0.3096

1.2385

1.0527

3.0962

Grand Total

Chemical AR R1

3.0962

page 23 of 116

LDAR report for production facilities

Plant

TASHAN

Unit

Drawing

Component

Tag

LDAR 015 R1

Component

Type

Component

Class

Location Description

Unit

Monitoring Round

Alroy

Round 1

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 24 of 116

Round 2

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R2

page 25 of 116

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 2

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

TASHAN Company name

Round 2

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

Form-07 R2

page 26 of 116

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2018- 05/03/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1122

0.0954

0.2804

Grand Total

Chemical FM R2

0.2804

page 27 of 116

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2018- 05/03/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1122

0.0954

0.2804

Grand Total

Chemical AR R2

0.2804

page 28 of 116

LDAR report for production facilities

Plant

TASHAN

Unit

Drawing

Component

Tag

LDAR 015 R2

Component

Type

Component

Class

Location Description

Unit

Monitoring Round

Alroy

Round 2

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 29 of 116

Round 3

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R3

page 30 of 116

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 3

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.367

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

0.0%

26.658

0

0

40

62

0

0

0

102

LL

2

HL

0.0%

28.025

0

0

40

82

0

0

16

122

Subtotal G2

1

GV

Flange

G3

1

0.0%

0.149

0

0

0

55

0

0

0

55

LL

1

HL

1

GV

Connection

1

0.0%

2.497

0

0

0

38

0

0

0

38

LL

1

HL

0.0%

2.646

0

0

0

93

0

0

0

93

Subtotal G3

0.0%

30.951

0

0

40

183

0

0

17

223 Total Components

30.951 Total Annual Emission Rate

TASHAN Company name

Round 3

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.367

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

0.0%

26.658

0

0

40

62

0

0

0

102

LL

2

HL

0.0%

28.025

0

0

40

82

0

0

16

122

Subtotal G2

1

GV

Flange

G3

1

0.0%

0.149

0

0

0

55

0

0

0

55

LL

1

HL

1

GV

Connection

1

0.0%

2.497

0

0

0

38

0

0

0

38

LL

1

HL

0.0%

2.646

0

0

0

93

0

0

0

93

Subtotal G3

0.0%

30.951

0

0

40

183

0

0

17

223 Total Components

30.951 Total Annual Emission Rate

Form-07 R3

page 31 of 116

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2018- 17/05/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.1367

0.0137

0.0683

0.1367

0.5466

0.4646

1.3666

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

2.6658

0.2666

1.3329

2.6658

10.6631

9.0636

26.6578

Chemical FM R3

page 32 of 116

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2018- 17/05/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.0149

0.0015

0.0075

0.0149

0.0597

0.0508

0.1493

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.2497

0.025

0.1248

0.2497

0.9986

0.8488

2.4966

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

3.0951

0.3096

1.5475

3.0951

12.3802

10.5232

30.9507

Grand Total

Chemical FM R3

30.9507

page 33 of 116

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2018- 17/05/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.1367

0.0137

0.0683

0.1367

0.5466

0.4646

1.3666

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

2.6658

0.2666

1.3329

2.6658

10.6631

9.0636

26.6578

Chemical AR R3

page 34 of 116

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2018- 17/05/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.0149

0.0015

0.0075

0.0149

0.0597

0.0508

0.1493

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.2497

0.025

0.1248

0.2497

0.9986

0.8488

2.4966

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

3.0951

0.3096

1.5475

3.0951

12.3802

10.5232

30.9507

Grand Total

Chemical AR R3

30.9507

page 35 of 116

LDAR report for production facilities

Plant

TASHAN

Unit

Drawing

Component

Tag

LDAR 015 R3

Component

Type

Component

Class

Location Description

Unit

Monitoring Round

Alroy

Round 3

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 36 of 116

Round 4

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R4

page 37 of 116

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 4

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

TASHAN Company name

Round 4

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

Form-07 R4

page 38 of 116

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2018- 20/08/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1122

0.0954

0.2804

Grand Total

Chemical FM R4

0.2804

page 39 of 116

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2018- 20/08/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1122

0.0954

0.2804

Grand Total

Chemical AR R4

0.2804

page 40 of 116

LDAR report for production facilities

Plant

TASHAN

Unit

Drawing

Component

Tag

LDAR 015 R4

Component

Type

Component

Class

Location Description

Unit

Monitoring Round

Alroy

Round 4

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 41 of 116

Round 5

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R5

page 42 of 116

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 5

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.367

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

1.0%

7.411

0

1

3

98

1

0

0

102

LL

2

HL

0.8%

8.778

0

1

3

118

1

0

16

122

Subtotal G2

0.8%

9.058

0

1

3

126

1

0

17

130 Total Components

9.058 Total Annual Emission Rate

TASHAN Company name

Round 5

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.367

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

0.0%

4.974

0

0

4

98

0

0

0

102

LL

2

HL

0.0%

6.341

0

0

4

118

0

0

16

122

Subtotal G2

0.0%

6.621

0

0

4

126

0

0

17

130 Total Components

6.621 Total Annual Emission Rate

Form-07 R5

page 43 of 116

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2018- 29/11/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.1367

0.0137

0.0683

0.1367

0.5466

0.4646

1.3666

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.7411

0.0741

0.3706

0.7411

2.9645

2.5199

7.4113

Chemical FM R5

page 44 of 116

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2018- 29/11/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

All

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.9058

0.0906

0.4529

0.9058

3.6233

3.0799

9.0583

Grand Total

Chemical FM R5

9.0583

page 45 of 116

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2018- 29/11/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.1367

0.0137

0.0683

0.1367

0.5466

0.4646

1.3666

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.4974

0.0497

0.2487

0.4974

1.9894

1.691

4.9736

Chemical AR R5

page 46 of 116

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2018- 29/11/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

All

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.6621

0.0662

0.331

0.6621

2.6482

2.251

6.6206

Grand Total

Chemical AR R5

6.6206

page 47 of 116

LDAR report for production facilities

Plant

TASHAN

Unit

Alroy

Drawing

Component

Tag

6006-100-007 75

LDAR 015 R5

Component

Type

Component

Class

Blind Flange

Open End

Location Description

Top of T-1

Unit

Monitoring Round

Alroy

Round 5

ppm value, First

Measurement

Date of First

Measurement

1,305 29-Nov-2018

Repair Due Date of repair

Repair type

08-Dec-2018 29-Nov-2018 Tightening

date of

remeasurement

after repair

attempt

29-Nov-2018

Technicians

ppm value of

remeasurement

after repair

attempt

Date of

repair

Remarks

Repair type

date of

remeasurement

after repair

attempt

ppm value of

remeasurement

after repair attempt

123

page 48 of 116

Round 6

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R6

page 49 of 116

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 6

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

TASHAN Company name

Round 6

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

Form-07 R6

page 50 of 116

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2018- 16/12/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1122

0.0954

0.2804

Grand Total

Chemical FM R6

0.2804

page 51 of 116

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2018- 16/12/2018

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 03.02.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1122

0.0954

0.2804

Grand Total

Chemical AR R6

0.2804

page 52 of 116

LDAR report for production facilities

Plant

TASHAN

Unit

Drawing

Component

Tag

LDAR 015 R6

Component

Type

Component

Class

Location Description

Unit

Monitoring Round

Alroy

Round 6

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 53 of 116

Graphs

Round 1

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R1

page 54 of 116

Graph6.1.1 R1

page 55 of 116

Graph6.1.3 R1

page 56 of 116

Graph6.1.2 R1

page 57 of 116

Graphs

Round 1

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R1

page 58 of 116

Graph6.2.1 R1

page 59 of 116

Graph6.2.3 R1

page 60 of 116

Graph6.2.2 R1

page 61 of 116

Graphs

Round 2

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R2

page 62 of 116

Graph6.1.1 R2

page 63 of 116

Graph6.1.3 R2

page 64 of 116

Graph6.1.2 R2

page 65 of 116

Graphs

Round 2

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R2

page 66 of 116

Graph6.2.1 R2

page 67 of 116

Graph6.2.3 R2

page 68 of 116

Graph6.2.2 R2

page 69 of 116

Graphs

Round 3

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R3

page 70 of 116

Graph6.1.1 R3

page 71 of 116

Graph6.1.3 R3

page 72 of 116

Graph6.1.2 R3

page 73 of 116

Graphs

Round 3

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R3

page 74 of 116

Graph6.2.1 R3

page 75 of 116

Graph6.2.3 R3

page 76 of 116

Graph6.2.2 R3

page 77 of 116

Graphs

Round 4

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R4

page 78 of 116

Graph6.1.1 R4

page 79 of 116

Graph6.1.3 R4

page 80 of 116

Graph6.1.2 R4

page 81 of 116

Graphs

Round 4

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R4

page 82 of 116

Graph6.2.1 R4

page 83 of 116

Graph6.2.3 R4

page 84 of 116

Graph6.2.2 R4

page 85 of 116

Graphs

Round 5

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R5

page 86 of 116

Graph6.1.1 R5

page 87 of 116

Graph6.1.3 R5

page 88 of 116

Graph6.1.2 R5

page 89 of 116

Graphs

Round 5

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R5

page 90 of 116

Graph6.2.1 R5

page 91 of 116

Graph6.2.3 R5

page 92 of 116

Graph6.2.2 R5

page 93 of 116

Graphs

Round 6

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R6

page 94 of 116

Graph6.1.1 R6

page 95 of 116

Graph6.1.3 R6

page 96 of 116

Graph6.1.2 R6

page 97 of 116

Graphs

Round 6

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R6

page 98 of 116

Graph6.2.1 R6

page 99 of 116

Graph6.2.3 R6

page 100 of 116

Graph6.2.2 R6

page 101 of 116

Graphs

Cumulative data for period

01/01/2018-31/12/2018

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph Graphs Cumul

page 102 of 116

Graph6.3.1

page 103 of 116

Graph6.3.2

page 104 of 116

Graph6.3.3

page 105 of 116

Graph6.3.4

page 106 of 116

General

Calibration loglist

Calibration gas certificates

Composition list & Response Factors

Quarterly production hours

Quarterly equipment check

Paragraph General

page 107 of 116

Calibration log list

Plant

Round Equipment Analyzer

Type

Type

Ultra-Zero

Span Gas

Span gas Cylinder

Span

Check gas Check gas Cylinder

Check gas

No

concentration

No

concentration

Date

Equipment

No

Equipment

Serial

No

(A)

ppm

ppm

Check

Calibration Result

error

1-st 2-st 3-st

check check check

(A1) (A2) (A3)

(CP)

ppm ppm ppm

TASHAN

1

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF51428

1,000

01-Mar-2018

5

202016061436 504

505

504

0.07%

OK

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

05-Mar-2018

2

0115248185

511

513

513

1.65%

OK

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

05-Mar-2018

3

0115248937

501

501

502

-0.53%

OK

TASHAN

2

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

19-Mar-2018

5

202016061436 511

510

510

1.26%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

16-May-2018

2

0115248185

500

493

499

-1.32%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

16-May-2018

5

202016061436 504

502

501

-0.33%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

17-May-2018

2

0115248185

503

504

504

-0.07%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

17-May-2018

5

202016061436 507

507

507

0.60%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

24-May-2018

5

202016061436 504

505

505

0.13%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

30-May-2018

5

202016061436 508

504

506

0.40%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

30-May-2018

2

0115248185

512

511

511

1.46%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

04-Jun-2018

3

0115248937

508

508

506

0.66%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

04-Jun-2018

5

202016061436 504

504

505

0.07%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

12-Jun-2018

1

0715622657

502

500

497

-0.86%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

12-Jun-2018

3

0115248937

505

502

500

-0.33%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

13-Jun-2018

3

0115248937

507

509

509

0.86%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

20-Aug-2018

1

0715622657

496

498

500

-1.19%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

21-Aug-2018

1

0715622657

499

501

500

-0.79%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

06-Sep-2018

3

0115248937

489

502

503

-1.19%

OK

TASHAN

5

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

29-Nov-2018

2

0115248185

502

501

501

-0.53%

OK

TASHAN

5

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

29-Nov-2018

3

0115248937

500

499

500

-0.86%

OK

TASHAN

5

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

02-Dec-2018

2

0115248185

503

502

502

-0.33%

OK

TASHAN

5

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

02-Dec-2018

3

0115248937

499

500

501

-0.79%

OK

TASHAN

5

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

03-Dec-2018

3

0115248937

487

498

497

-1.98%

OK

TASHAN

5

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

03-Dec-2018

2

0115248185

500

499

502

-0.73%

OK

TASHAN

6

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

16-Dec-2018

5

202016061436 504

505

505

0.13%

OK

TASHAN

5

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

25-Dec-2018

3

0115248937

498

499

498

-1.12%

OK

TASHAN

5

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

13-Jan-2019

5

202016061436 505

505

505

0.20%

OK

Cal-Log

page 108 of 116

Certificate

page 109 of 116

Certificate

page 110 of 116

Stream Composition Summary

Stream Name

Stream Content

Stream Content

Dates

TVA

Gasoline

TOLUENE-34 %, n-Octane-40 %, METHYL TERT-BUTYL ETHER-10 %,

CYCLOHEXANE-5 %, BENZENE-1 %, 1-Butene-10 %

A=0.42, B=0.29

Petroleum

TOLUENE-7.5 %, n-Octane-55.3 %, CYCLOHEXANE-35.2 %, BENZENE-2 %

A=0.39, B=0.31

Stream Summary

MiniRAE 10.6 MiniRAE 11.7

page 111 of 116

Quarterly Validation of LDAR Devices

Date: 28-Dec-2017

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Anlyzer Type

Span Gas

Sampling Flow

Rate

1

Check

Sampling

Span Gas

Flow

Span gas

Concentration

Result Check Gas

Rate

Cylinder No

ppm

l/min

Accuracy Check

Response Time

Comparison between two Devices

90%

Check Gas

Response Response Response

Second

of

Check gas

1-st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Time 1 Time 2 Time 3 Result

Result

Device

Result

Span

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

FF51428

1,000

1.1

OK

Methane

FF524456

504

492 490 486

-2.91%

OK

900

3

3

3

OK

1.94

1.8

0.14

-7.78%

OK

2

0115248185

TVA1000B

FID

Methane

FF51428

1,000

0.99

OK

Methane

FF524456

504

501 501 502

-0.53%

OK

900

4

4

4

OK

1.62

1.74

-0.12

6.9%

OK

3

0115248937

TVA1000B

FID

Methane

FF51428

1,000

1.25

OK

Methane

FF524456

504

489 486 486

-3.37%

OK

900

3

3

3

OK

1.8

1.94

-0.14

7.22%

OK

5

202016061436

TVA2020

FID

Methane

FF51428

1,000

0.96

OK

Methane

FF524456

504

481 479 479

-4.83%

OK

900

3

3

3

OK

1.74

1.8

-0.06

3.33%

OK

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.51

OK

Isobutylene EA0009962

997

996 996 997

-0.15%

OK

898

4

4

4

OK

1.88

1.68

0.2

-11.9%

OK

6

Quarterly Validation

page 112 of 116

Quarterly Validation of LDAR Devices

Date: 04-Apr-2018

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Anlyzer Type

Span Gas

Sampling Flow

Rate

2

Check

Sampling

Span Gas

Flow

Span gas

Concentration

Result Check Gas

Rate

Cylinder No

ppm

l/min

Accuracy Check

Response Time

Comparison between two Devices

90%

Check Gas

Response Response Response

Second

of

Check gas

1-st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Time 1 Time 2 Time 3 Result

Result

Device

Result

Span

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

FF51430

1,000

1.01

OK

Methane

FF524456

504

508 508 507

0.73%

OK

900

3

3

3

OK

1.12

1.22

-0.1

8.2%

OK

2

0115248185

TVA1000B

FID

Methane

FF51430

1,000

1.09

OK

Methane

FF524456

504

511 512 512

1.52%

OK

900

3

3

3

OK

1.18

1.3

-0.12

9.23%

OK

3

0115248937

TVA1000B

FID

Methane

FF51430

1,000

0.96

OK

Methane

FF524456

504

506 504 504

0.13%

OK

900

3

3

3

OK

1.22

1.12

0.1

-8.93%

OK

5

202016061436

TVA2020

FID

Methane

FF51430

1,000

1.01

OK

Methane

FF524456

504

513 512 512

1.65%

OK

900

3

3

3

OK

1.3

1.22

0.08

-6.56%

OK

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.5

OK

Isobutylene EA0009962

997

995 995 995

-0.28%

OK

898

4

4

4

OK

1.15

1.3

-0.15

11.54%

OK

6

Quarterly Validation

page 113 of 116

Quarterly Validation of LDAR Devices

Date: 04-Jul-2018

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Anlyzer Type

Span Gas

Sampling Flow

Rate

3

Check

Sampling

Span Gas

Flow

Span gas

Concentration

Result Check Gas

Rate

Cylinder No

ppm

l/min

Accuracy Check

Response Time

Comparison between two Devices

90%

Check Gas

Response Response Response

Second

of

Check gas

1-st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Time 1 Time 2 Time 3 Result

Result

Device

Result

Span

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

FF51430

1,000

1.06

OK

Methane

FF524456

504

503 504 503

-0.13%

OK

900

3

3

3

OK

2.85

2.44

0.41

-16.8%

OK

2

0115248185

TVA1000B

FID

Methane

FF51430

1,000

0.97

OK

Methane

FF524456

504

504 505 503

0%

OK

900

3

3

3

OK

1.18

1.22

-0.04

3.28%

OK

3

0115248937

TVA1000B

FID

Methane

FF51430

1,000

1.23

OK

Methane

FF524456

504

502 503 503

-0.26%

OK

900

3

3

3

OK

2.15

2.61

-0.46

17.62%

OK

5

202016061436

TVA2020

FID

Methane

FF51430

1,000

0.95

OK

Methane

FF524456

504

506 503 505

0.13%

OK

900

3

3

3

OK

3.41

3.05

0.36

-11.8%

OK

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.5

OK

Isobutylene EA0009962

997

997 996 996

-0.15%

OK

898

4

4

3

OK

2.5

2.1

0.4

-19.05%

OK

6

Quarterly Validation

page 114 of 116

Quarterly Validation of LDAR Devices

Date: 02-Oct-2018

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Anlyzer Type

Span Gas

Sampling Flow

Rate

4

Check

Sampling

Span Gas

Flow

Span gas

Concentration

Result Check Gas

Rate

Cylinder No

ppm

l/min

Accuracy Check

Response Time

Comparison between two Devices

90%

Check Gas

Response Response Response

Second

of

Check gas

1-st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Time 1 Time 2 Time 3 Result

Result

Device

Result

Span

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

FF51430

1,000

0.96

OK

Methane

FF524456

504

495 494 494

-1.92%

OK

900

4

4

4

OK

1.55

1.48

0.07

-4.73%

OK

2

0115248185

TVA1000B

FID

Methane

FF51430

1,000

1.31

OK

Methane

FF524456

504

491 492 492

-2.45%

OK

900

4

4

4

OK

1.79

1.82

-0.03

1.65%

OK

3

0115248937

TVA1000B

FID

Methane

FF51430

1,000

1.4

OK

Methane

FF524456

504

506 507 506

0.46%

OK

900

3

4

4

OK

1.99

1.95

0.04

-2.05%

OK

5

202016061436

TVA2020

FID

Methane

FF51430

1,000

1.02

OK

Methane

FF524456

504

518 518 518

2.78%

OK

900

3

3

3

OK

1.52

1.59

-0.07

4.4%

OK

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.51

OK

Isobutylene EA0009962

997

996 995 995

-0.25%

OK

898

4

4

4

OK

2.5

2.1

0.4

-19.05%

OK

6

Quarterly Validation

page 115 of 116

CUMULATIVE PRODUCTION HOURS TEMPLATE 2018

Plant

TASHAN

Unit

Drawing

Stream Name

Remark

Annual Production

Hours

Alroy

6006-100-006

Gasoline

8,760

Alroy

6006-100-007

Gasoline

8,760

Production Hours

Q1

01/01-31/03

Quarter =

Quarterly Production

hours

2,190

2,190

Q2

01/04-30/06

Quarter =

Quarterly Production

hours

2,190

2,190

Q3

01/07-30/09

Quarter =

Quarterly Production

hours

2,190

2,190

Q4

01/10-31/12

Quarter =

Quarterly Production

hours

2,190

2,190

page 116 of 116

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין

3013.15-034-T2

3013.15-025

25/02/2019

18/31

3013.15-036.doc

T2 - kerosene

External Floating roof

1. Tank data

Diameter of the tank

D

Effective height of the stock liquid (while

roof landing episode)

hle

Shell Color and condition

α

Roof color and condition

α

Tank paint solar absorptance

α

Vapor space outage (while roof landing

episode)

HVO

m

feet

m

feet

color

condition

color

condition

dimensionless

m

Tank data

--Tank data

--חאקי

טובה

לבן

טוב

48.77

160.01

11.00

0.89

Table 7.1-6

Assumption - Green Dark

0.17

Table 7.1-6

0.53

Table 7.1-6

Possible to use also equation

1-15

assumption - equal to legs height

feet

11.00

Volume of the vapor space (while roof

landing episode)

Breather vent pressure setting

VV

ft

3

VV=PI()*D /4*Hvo

221,185

Equation 1-3

ΔPBP

psi

Typical value

0.50

Equation 1-11

Breather vent vacuum setting

ΔPBV

psi

Typical value

0.00

Equation 1-11

Breather vent pressure setting range

ΔPB

psi

∆PB = PBP − PBV

0.50

Equation 1-11

2

2. Material data - קרוסין

Stock vapor molecular weight

MV

Density of the liquid inside the tank

Wl

Vapor density

WV

True vapor pressure of the stock liquid

P

Vapor pressure at daily average liquid

surface temperature

Vapor pressure at the daily maximum

liquid surface temperature, psia

Vapor pressure at the daily minimum

liquid surface temperature

Daily vapor pressure range

3013.15-034.xls - 2

gr/gr-mole

lb/lb-mole

g/ml

lb/gal

kg/m^3

lb/ft3

msds data

130

msds data

--msds data

---

0.80

6.68

4.5

0.28

mm Hg

PEI data

0.833

psia

--הנחה:

Pv=nRT -->

P2=P1*(T2/T1)

0.02

0.02

0.02

0.00

PVA

psia

PVX

psia

PVN

psia

T1(k)=20C+273

T2(k)=37.5C+273

ΔPV

psia

∆PV = PVX − PVN

1/3

0

at 20°C

0.02

Equation 1-9

20/02/2019

3. Operation data

Number of days that the tank stands idle

(on roof landing episode)

Number of degassing and cleaning

episode

Number of roof landing episode

nd

days/landing episode

site data

4

landing episode/year

site data

0.07

landing episode/year

site data

0.07

Tanks Program

--Tanks Program

---

73

33

119

54

21

T2 - B&W 2018

Tanks Program

---

60.05

27

T2 - DFloating 2018

lb per emptying

Tanks Program

67

Kg per emptying

---

30

4. Normal operation (Tanks program)

lb per year

Kg per year

lb per year

Kg per year

Kg per year

Working (withdrawal) losses

Total emissions (Breathing & Working)

Breathing (standing) losses

5. Degassing and Cleaning (Tanks program)

Degassing: emission from one turnover of

lb per emptying

Edegass-floating

floating roof

Kg per emptying

Degassing: fixed roof with a height of roof

legs

Edegass-legs

Liquid fraction in sludge

Fliquid

Sludge volume

Sludge weight

Vs

Ws

Cleaning emissions

Ecleaning

Total Degassing and Cleaning emissions

Edegass-total

3013.15-034.xls - 2

0.8

m3 per emptying

Kg per emptying

lb per emptying

Kg per emptying

lb per emptying

Kg per emptying

Ecleaning = Ws * (1-Fliquid)

Edegass-total =

Edegass-floating + Edegass-legs + Ecleaning

2/3

T2 - B&W 2018

T2- DFixed 2018

(Only working losses)

Tanks FAQ - degassing and

cleaning

70

56,000

24,692

11,200

24,818

11,257

20/02/2019

6. Roof landing

Daily average liquid surface temperature

TLA

°R

T LA = 0 . 44 T AA + 0 . 56 T B + 0 . 0079 * α * I

541.74

Equation 1-26

Daily vapor temperature range

ΔTV

°R

∆ TV = 0 .72 ∆ T A + 0.028 * α * I

56.73

Equation 1-8

Daily maximum liquid surface temperature

TLX

°R

TLX = TLA + 0.25*ΔTV

555.92

Figure 7.1-17

Daily minimum liquid surface temperature

TLN

°R

TLN = TLA - 0.25*ΔTV

527.56

Figure 7.1-17

Liquid bulk temperature

Max standing idle losses during roof

landing

TB

°R

TB = TAA + 6α - 1

530.06

Equation 1-28

LSL-max

lb per landing episode

Kg per landing episode

dimensionless

2

LSL-max = 5.9*D *hle*W l

--0.60 for a full liquid heel

0.50 for a partial

0.15 for drain-dry

11,093,038 Equation 2-13

5,031,769

0.50

Equation 2-26

(pages No 33,35)

1

KS =

1 + 0.053 * PVA * H VO

0.5

Equation 1-20

KS is assumed to be less than

or equal to the saturation factor

during filling (S) .

∆ TV ∆ PV − ∆ PB

+

T LA

PA − PVA

0.071

Liquid stock has a true vapor

pressure greater than 0.1psia Equation 1-7.

Filling saturation factor

S

saturation factor

KS

dimensionless

Vapor space expansion factor

KE

dimensionless

Standing idle losses during roof landing

LSL

lb per landing episode

 PV 

L SL = n d K E  V  M V K S

 RT AA 

12

Equation 2-16

Filling losses during roof landing

LFL

lb per landing episode

 P * VV 

 M V * S

L FL = 

 R * T AA 

41

Equation 2-26

Total losses during roof landing

LTL

lb per landing episode

Kg per landing episode

52

24

Equation 2-10

KE =

LTL=LSL+LFL

7. Summary

Working (withdrawal) losses

Breathing (standing) losses

Kg per year

Kg per year

33

21

Total Degassing and Cleaning emissions

Kg per year

750

Total losses during roof landing

Kg per year

2

806

3013.15-034.xls - 2

3/3

Kg per year

20/02/2019

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - B&W 2018

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.30

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Red/Primer

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock

Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

1

2

29

43

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.7 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

20/02/2019

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - B&W 2018 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

All

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

81.75

66.81

96.69

Liquid

Bulk

Temp

(deg F)

70.60

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0161

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

20/02/2019

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - B&W 2018 - External Floating Roof Tank

Haifa, Israel

Annual Emission Calcaulations

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

0.0161

160.0100

130.0000

1.0000

Withdrawal Losses (lb):

Annual Net Throughput (gal/yr.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

72.8711

9,891,924.0000

0.0075

7.0000

160.0100

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

5.3380

0.0003

130.0000

1.0000

150.3024

6.2000

Total Losses (lb):

118.8887

40.6796

1.6000

0.3000

6.2000

1.6000

0.0003

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock

Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

1

2

29

43

1

KFa(lb-mole/yr)

1.60

11.00

6.20

1.20

0.49

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

9.90

1.20

0.14

0.16

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.89

0.94

0.65

0.14

1.00

Losses(lb)

0.1705

1.6891

0.7791

1.6103

1.0484

0.0406

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TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - B&W 2018 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

40.68

72.87

5.34

0.00

118.89

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TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFixed 2018

Haifa

Israel

PEI

Vertical Fixed Roof Tank

kerosene

Tank Dimensions

Shell Height (ft):

Diameter (ft):

Liquid Height (ft) :

Avg. Liquid Height (ft):

Volume (gallons):

Turnovers:

Net Throughput(gal/yr):

Is Tank Heated (y/n):

N

Paint Characteristics

Shell Color/Shade:

Shell Condition

Roof Color/Shade:

Roof Condition:

Red/Primer

Good

White/White

Good

Roof Characteristics

Type:

Height (ft)

Slope (ft/ft) (Cone Roof)

Breather Vent Settings

Vacuum Settings (psig):

Pressure Settings (psig)

11.00

160.01

11.00

5.50

1,654,664.74

1.00

1,654,664.74

Cone

0.00

0.00

0.00

0.50

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.7 psia)

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TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFixed 2018 - Vertical Fixed Roof Tank

Haifa, Israel

Mixture/Component

Month

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

Liquid

Bulk

Temp

(deg F)

Vapor Pressure (psia)

Avg.

Min.

Max.

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

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TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFixed 2018 - Vertical Fixed Roof Tank

Haifa, Israel

Losses(lbs)

Components

Working Loss

Breathing Loss

Total Emissions

Jet kerosene

66.66

51.50

118.16

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Page 1 of 5

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFloating 2018

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.00

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Red/Primer

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Slotted Guide-Pole/Sample Well/Gask Sliding Covr, w. Float,Sleeve,Wiper

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Roof Leg (3-in. Diameter)/Adjustable, Pontoon Area, Sock

Roof Leg (3-in. Diameter)/Adjustable, Center Area, Sock

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

1

2

29

43

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.7 psia)

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TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFloating 2018 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Month

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

Liquid

Bulk

Temp

(deg F)

Vapor Pressure (psia)

Avg.

Min.

Max.

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

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TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFloating 2018 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

3.60

55.99

0.46

0.00

60.05

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נספח ד'

דוגמת חישוב עבור זרוע מילוי עילי טבול מס' 1של קרוסין

3013.15-035

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Transportation - Loading losses

Loading arm #1 - Kerosene

Density

Tank paint solar absorptance

Daily average ambient temperature

Wl

α

TAA

Yearly consumption

Myear

Cargo tank volume

V

Ntrucks

t

g/ml

dimensionless

°R

ton

m3

gal

m3

gal

1/year

min

Saturation factor

S

dimensionless

True vapor pressure of liquid

P

Molecular weight of vapors

M

Number of tank trucks

Duration of road truck filling

Table 5.2-1

mmHg

psia

0.833

0.02

@ 20°C

lb/lb-mole

130

Table 7.1-2

T=TB

°R

Controlled efficiency for the recovery

unit (vapor recovery efficiency)

eff1

%

vapor collection efficiency

eff2

%

overall reduction efficiency

eff

%

Loading losses of petroleum liquids

(uncontrolled emission rate)

LL

lb/103 gal

loaded

Flow rate of pollutant emission during

loading

Annual pollutant emission during

loading

T = TB = TAA + 6α - 1

527.40

0

LL total lb / loading

lb / min

Q

Kg / min

Kg / hr

Etotal

0.80

0.41

525.97

1,642

2,066

545,780

30.0

7,925

69

30

0.6

Temperature of bulk liquid loaded

Total loading losses of petroleum

msds data

site data

"Site" tab @ 3013-037

--data

--data

--Ntrucks = Myear / V

data

Submerge loading, dedicated

normal service

Kg / year

Truck passed the NSPS-level

annual test

70.0

eff=eff1*eff2/100

0

LL = 12.46

S *P*M 

eff 

1 −

T

 100 

0.030

LLtotal = LL*V

Q = Lltotal / t

-----

0.24

0.008

0.004

0.21

Etotal = LLtotal*Ntruks

7.36

Equation 1-28

page 5.2-6

can be 90% to over 99%

page 5.2-6

99.2- for tanker truck passed the

MACT-level annual leak test

98.7- for truck passed the NSPS-level

annual test

70 - for trucks not passing one of

these leak tests

Page 5.2-4 Equation 1

Assumption: the mass of the

Average pollutant emission

concentration during loading

3013.15-035.xls - 1

C

gr / m3

C = Q *t / V

3.6

1/1

pollutant is contained in the air

volume inside the tanker which is

replaced by the liquid loaded

17/02/2019

נספח ה'

חישוב פליטות ממיכל לאיסוף תשטיפים

25/02/2019

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תוכנת :Tanksחישוב פליטה כתוצאה מאחסון ושינוי מפלס

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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב א')

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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב ב')

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חישובי פליטה ממיכל תשטיפים

גיליון חישוב זה הוכן על ידי "פז" הנדסה וניהול ( )1980בע"מ.

אין להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ( )1980בע"מ.

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מסמך 8 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 5957 KB)

תשתיות נפט ואנרגיה בע"מ

מסוף אלרואי

סיכום פליטות לאוויר

שנת 2019

פרויקט3013.16 :

סימוכין3013.16-036 :

פברואר 2020

תוכן עניינים

.1מבוא 4 ...............................................................................................................

.2נתוני מסוף 5 ........................................................................................................

.2.1נתוני מיכלים 5.........................................................................................................

.2.2נתונים עבור מסוף מילוי מיכליות כביש 9.....................................................................

.3חישוב פליטות 10 .................................................................................................

.3.1כללי 10 ............................................................................................................

.3.2סוגי פליטות מחושבות 10 .......................................................................................

.3.3בחירת חומרים בתוכנת 11 ......................................................................... TANKS

.3.4נתונים מטאורולוגיים 11 ........................................................................................

.4סיכום פליטות לשנת 12 .................................................................................. 2019

.4.1מיכלים 12 ..........................................................................................................

.4.2מסוף מילוי מיכליות כביש 12 ..................................................................................

.4.3מיכל איסוף תשטיפים 13 .......................................................................................

.4.4סיכום ממצאי ניטור 13 ............................................................................... LDAR

.4.5פליטה שנתית מכלל המתקן 13 ................................................................................

.5פליטות לא שגרתיות במהלך שנת 13 .................................................................. 2019

.6מקורות 14 ..........................................................................................................

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3013.16-036

טבלאות

טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 5........................................... 2019

טבלה :2נתוני מעטפת וגגות – שנת 6.................................................................................. 2019

טבלה :3נתוני אביזרים – שנת 7......................................................................................... 2019

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת 8................................................... TANKS

טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 9...................................................... 2019

טבלה :6חומרים מייצגים בתוכנת 11 ............................................................................ TANKS

טבלה :7סיכום פליטות מכלים -שנת 12 ............................................................................ 2019

טבלה :9סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 13 .................................. 2019

טבלה :10סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 13 .................................................2019

נספחים

נספח א'

טבלה )AP-42( 1-5.2

נספח ב'

נתוני ניטור LDARעבור מסוף אלרואי – סיכום שנת 2019

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין

נספח ד'

חישוב פליטות ממיכל לאיסוף תשטיפים

אביטל בלניק

שם עורך

17/02/2020

יואב פיסטינר

שם מאשר

להערות

תיאור

17.02.2020

תאריך

3/30

0

גרסה

3013.16-036

.1מבוא

חברת תשתיות נפט ואנרגיה בע"מ (להלן תש"ן) מפעילה את מסוף אלרואי לאחסון ושינוע

דלקים .

המסוף כולל:

•

מבני משרדים

•

חוות מכלים לאחסון דלקים מסוגים שונים

•

רציפי מילוי מכליות כביש (לשימוש בעת חירום בלבד)

המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכונת

אלרואי ומדרום לו שכונת קרית חרושת.

באתר 9מיכלים ,מתוכם 6מיכלים תפעוליים ו 3-מיכלים אסטרטגים (מיכלים מס' 6,1ו.)9-

מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוסף קיימות מערכות תומכות כגון

מערכות כיבוי אש ומערכות פיקוד ובקרה.

כחלק מהתנאים ברישיון עסק מדצמבר ,2010בסוף כל שנה קלנדרית על תש"ן להגיש דו"ח

סיכום פליטות שנתי לגבי השנה שחלפה.

חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקנים

הקיימים במסוף.

סיכום הפליטות הוכן על ידי חברת "פז" הנדסה וניהול ( )1980בע"מ (להלן פז הנדסה) ,והוא

מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.

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3013.16-036

.2נתוני מסוף

.2.1נתוני מיכלים

בטבלאות הבאות מפורט מידע טכני של המיכלים בחוות המיכלים אלרואי.

טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 2019

לחץ אדים

בטמפ' הנוזל

הממוצעת

)(mmHg

405 @ 28°C

כמות

צריכה

שנתית

(מ"ק)

0

גבעה חלקית

22,511

גבעה חלקית

48.77

גבעה חלקית

48.77

32,056

48.77

32,056

28,768

56,959

51,614

15.56

51,614

15.56

14.1

15.56

14.1

11.4

18.3

18.3

15.4

9.7

סוג ניקוז

בתחתית

מיכל

קוטר

מיכל

(מטר)

נפח מיכל

(מ"ק)

נפח מיכל

פעיל

(מ"ק)

48.77

32,056

28,768

גובה /אורך

מעטפת

מיכל

(מטר)

17.16

15.4

32,056

28,768

17.16

15.4

10

28,768

17.16

15.4

9.5

17.16

15.4

10.3

14.1

14.1

14.1

מספר

מיכל

סוג הדלק

המאוחסן

) 1( 1

בנזין

2

קרוסין

0.833 @ 28°C

3

סולר

0.507 @ 28°C

30,507

4

סולר

0.507 @ 28°C

32,549

גבעה חלקית

5

סולר

0.507 @ 28°C

12,286

גבעה מלאה

68.27

) 1( 6

סולר

0.507 @ 28°C

0

גבעה מלאה

68.27

56,959

7

סולר

0.507 @ 28°C

46,565

גבעה מלאה

68.27

56,959

51,614

)2( 8

קרוסין

0.833 @ 28°C

41,306

גבעה חלקית

48.8

36,547

34,228

19.54

) 1( 9

קרוסין

0.833 @ 28°C

0

גבעה חלקית

48.77

32,056

28,768

17.16

367,704

332,913

סה"כ

185,724

( )1מכלים מס' 6 ,1ו 9-משמשים כמכלי מלאי ,לא היו תנועות במכלים בשנת .2019

( )2מכל 8עבר חידוש צביעת גג בפברואר ,2019והחלפת אטם ראשוני מסוג Liquid mountedבמרץ .2019

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3013.16-036

גובה נוזל

מירבי

(מטר)

גובה נוזל

ממוצע

(מטר)

10.5

טבלה :2נתוני מעטפת וגגות – שנת 2019

מספר

מיכל

סוג גג

אטם ראשי

אטם משני

1

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Liquid

mounted

Mechanical

Shoe

Rim

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Rim

mounted

Rim

mounted

2

3

4

5

6

7

8

9

17/02/2020

צורת גג

סוג

חיבורי

גג

צבע

גג

מצב

צבע

גג

צבע

מעטפת

חיצונית

מצב צבע

מעטפת

חיצונית

סוג חיבורי

מעטפת

מצב

מעטפת

פנימית

מיכל

מחומם

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חום

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חום

ישן

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

כחול בהיר

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

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טבלה :3נתוני אביזרים – שנת 2019

מספר

מיכל

1

2

3

4

5

6

7

8

9

סה"כ

שובר ואקום

כמות

2

2

2

2

2

2

2

6

2

Vacuum

]set. [psi

0

0

0

0

0

0

0

0

0

Pressure

]set. [psi

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

רגליים מתכווננות התומכות

בגג צף()1

גובה כמות באזור

כמות

במרכז

()ft

pontoon

29

43

11

29

43

11

29

43

11

29

43

11

72

107

11

72

107

11

72

107

11

36

54

9

29

43

11

כמות

מדי

מפלס

Rim

Vent

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

6

כמות בוצה

בנקיון

(מ"ק)

"גרביים" לבאר

הדיגום המחורצת

ולרגלי הגג הצף()1

70

70

70

70

150

150

150

70

70

870

יש

יש

יש

יש

יש

יש

יש

יש

יש

( )1הנ"ל לא נלקחו בחשבון בחישוב הפליטות מתוכנת ה TANKS-מפני שנדגמו במסגרת ניטורי ה.LDAR-

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הנחות שנלקחו לצורך החישובים

.1עבור חישוב Degassingבמיכל עם גג צף – הונח:

•

גג צף נח על רגליים בגובה ( 9-11 ftבהתאם לטבלה לעיל) וזהו גם הגובה המרבי של הנוזל

במיכל.

•

גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.

.2הונח כי ניקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שנים .הניקיון יארך יום אחד.

.3הונח כי אירוע של נחיתת גגות צפים מתבצע אחת ל 15-שנים .זמן נחיתת הגג במקרה זה לא

יעלה על 4ימים.

.4יחס הנוזל בבוצה הונח כ]2[ 0.8 -

.5בהתאם לטבלה 7.1-6על פי [ ,]1נבחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,

לצורך חישובי פליטות לאוויר:

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת Tanks

צבע מעטפת

מיכל

צבע לצורך חישובי אקסל

צבע לצורך חישובים בתוכנת

בהתאם למסמך EPA AP-42

)*( Tanks

כחול בהיר

Gray Medium

Gray Medium

Brown

Aluminium/Diffuse

Beige/Cream

Aluminium/Specular

White

White

חום

צהוב קרם

לבן

(*) בתוכנת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך

.]1[ EPA AP-42

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.2.2נתונים עבור מסוף מילוי מיכליות כביש

טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 2019

מס'

זרוע

1

2

3

4

5

6

7

8

מוצר

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

סה"כ

מילוי

עילי /תחתי

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

נפח מילוי שנתי

(מ"ק)

0

0

0

0

0

0

0

0

0

נפח ממוצע של

מיכלית (מ"ק)

30

30

30

30

30

30

30

30

הנחות שנלקחו צורך החישובים

.1

מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:

א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:

דוגמת חישוב עבור מיכל מס' :2

ב .בשלב השני חושב מקדם αממוצע עבור הקרוסין:

.2

זמן מילוי מיכלית חושב על פי נפח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000

ליטר/דקה.

.3

Vapor collection efficiency - 70%

.4

Vapor recovery efficiency - 0%

.5

Saturation factorהונח כ (Submerged loading, dedicated normal service) 0.6-על פי

[ .]1טבלה רלוונטית מצורפת בנספח א'.

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.3חישוב פליטות

.3.1כללי

חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכנת Tanksובעזרת .]1[ EPA-AP 42

הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ( )LDARמצורפת בנספח ב'.

דוגמת חישוב עבור מיכל גג חיצוני צף (מיכל מס' )2המאחסן קרוסין ,מצורפת כנספח ג' למסמך

זה.

בדוגמאות אלה ניתן לראות את נתוני הקלט (כולל הנחות) עליהם התבססו החישובים.

.3.2סוגי פליטות מחושבות

הערכת הפליטות ממיכלי אחסון כוללת [:]3

• פליטות בזמן אחסון )(Breathing Losses

• פליטות משינויי מפלס )(Working Losses

• פליטות כתוצאה מניקוי וריקון מיכלים )(Degassing Losses

• פליטות כתוצאה מנחיתת גגות צפים )(Roof Landing Losses

• פליטות כתוצאה מהפרשי לחץ )(Flash Losses

• פליטות בזמן מילוי מיכלים ומיכליות

בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ

).(Flash Losses

פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלחץ הנוזל ,נתון הגורם להפרת שיווי המשקל

הקיים במיכל (בין גז לנוזל) וכתוצאה מכך נוצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הנוזל

עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר נוזל המאוחסן בלחץ נשלח

לאחסון במיכל בעל לחץ נמוך יותר [.]3

פליטות אלו הוזנחו כיוון שכל החומרים מוחזקים בתנאים אטמוספריים בכל אחד מהשלבים

הנוגעים להובלתם ואחסונם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.

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.3.3בחירת חומרים בתוכנת Tanks

על פי נתוני MSDSשל הדלקים במסוף ,נבחרו החומרים הבאים הקיימים בתוכנת Tanks

כמייצגים של חומרים אלו:

טבלה :6חומרים מייצגים בתוכנת Tanks

דלק קיים במסוף

חומר מייצג בתוכנת Tanks

סולר (תחבורה והסקה)

Distillate fuel oil no 2

נפט (קרוסין)

Jet kerosene

בנזין

Gasoline RVP 10

.3.4נתונים מטאורולוגיים

לצורך חישוב הנתונים בתוכנת Tanksהוגדרו נתונים מטאורולוגים המתאימים למפרץ חיפה על פי

מקורות [.]4

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.4סיכום פליטות לשנת 2019

.4.1מיכלים

סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:

טבלה :7סיכום פליטות מכלים -שנת 2019

מיכל

חומר

פליטות לאוויר

(ק"ג/שנה)

1

בנזין

3,603

2

קרוסין

788

3

סולר

38

4

סולר

826

5

סולר

1,701

6

סולר

1,693

7

סולר

1,723

8

קרוסין

792

9

קרוסין

758

11,921

סה"כ

.4.2מסוף מילוי מיכליות כביש

עבור זרועות המילוי לא חושבו פליטות לשנת ,2019מאחר וזרועות המילוי לא פעלו במהלך השנה.

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.4.3מיכל איסוף תשטיפים

סך הפליטה ממיכל לאיסוף תשטיפים הינה כ 1 -ק"ג/שנה.

חישוב מצורף בנספח ד'.

יצוין כי החישוב מתבסס על הנחה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל

בעיקר ניקוז מים מהמכלים.

.4.4סיכום ממצאי ניטור LDAR

טבלה :8סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 2019

סה"כ פליטות (ק"ג/שנה)

סיכום פליטות LDAR

פליטה שנתית (ק"ג/שנה)

סה"כ

8

.4.5פליטה שנתית מכלל המתקן

טבלה :9סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 2019

סה"כ פליטות (ק"ג/שנה)

חוות מיכלים

מסוף מילוי

מיכליות כביש

מיכל לאיסוף

תשטיפים

11,921

0

1

סיכום פליטות

רכיבים

סה"כ

()LDAR

8

11,930

.5פליטות לא שגרתיות במהלך שנת 2019

במהלך שנת 2019לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.

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.6מקורות

]1[ EPA-AP42

]2[ USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version

4.0 - APPENDIX D

[ ]3הנחיות הממונה לטיפול בבקשה להיתר פליטה לפי סעיף (9א) לתקנות אוויר נקי (היתרי פליטה),

התש"ע – ,2010מהדורה ,4ספטמבר 2014

[ ]4האטלס האקלימי לתכנון פיסי וסביבתי בישראל ,מהדורה שנייה1994 ,

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נספח א'

טבלה 5.2-1

AP-42

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נספח ב'

נתוני ניטור LDARעבור אלרואי – סיכום שנת 2019

(מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך )26.12.2019

3013.16-006A

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LDAR

Fugitive Emission Monitoring

Report No.

RL-TS-R-A-19

Plant:TASHAN

City:Haifa

District:Haifa

Production Unit:Alroy

Group:Group 1-2-3

Reporting period:Annual Summary

Report printing date:26-Dec-2019

Technicians names:Polik

Portselan

Tomarov

Report editor:

Michael Ourievsky

Approved by:

Alexey Ratner, CEO

1

Table of Content

1. Project introduction

1.1 Scope of work

1.2 Project phases

2. Methodology

2.1 Definitions

2.2 Methodology

3. Summary of Monitoring Period

3.1 Cumulative Data of Monitoring Period

3.2 Summary of Monitoring Period

3.3 Form 07: component classification and emission estimations for production facilities

3.4 Chemical Summary

3.5 LDAR report for production facilities

4. First Measurement and Measurement After Repair Round 1

4.1 Form-07 by Round

4.2 Chemical Summary First Measurement

4.3 Chemical Summary After Repair

4.4 LDAR report for production facilities

5. First Measurement and Measurement After Repair Round 2

5.1 Form-07 by Round

5.2 Chemical Summary First Measurement

5.3 Chemical Summary After Repair

5.4 LDAR report for production facilities

6. First Measurement and Measurement After Repair Round 3

6.1 Form-07 by Round

6.2 Chemical Summary First Measurement

6.3 Chemical Summary After Repair

6.4 LDAR report for production facilities

7. First Measurement and Measurement After Repair Round 4

7.1 Form-07 by Round

7.2 Chemical Summary First Measurement

7.3 Chemical Summary After Repair

7.4 LDAR report for production facilities

8. First Measurement and Measurement After Repair Round 5

8.1 Form-07 by Round

8.2 Chemical Summary First Measurement

8.3 Chemical Summary After Repair

8.4 LDAR report for production facilities

9. First Measurement and Measurement After Repair Round 6

9.1 Form-07 by Round

9.2 Chemical Summary First Measurement

9.3 Chemical Summary After Repair

9.4 LDAR report for production facilities

Table Of Content

5

5

6

6

8

9

16

17

19

21

22

23

24

26

27

28

29

31

32

34

36

38

39

40

41

43

44

46

48

50

51

52

53

page 2 of 120

10. Graphs First Measurement Round 1

10.1 Overview by Reading Range

10.2 Comparison between count of sources & kg/year, by sources

10.3 Total overview by chemicals

11. Graphs Measurement After Repair Round 1

11.1 Overview by Reading Range

11.2 Comparison between count of sources & kg/year, by sources

11.3 Total overview by chemicals

12. Graphs First Measurement Round 2

12.1 Overview by Reading Range

12.2 Comparison between count of sources & kg/year, by sources

12.3 Total overview by chemicals

13. Graphs Measurement After Repair Round 2

13.1 Overview by Reading Range

13.2 Comparison between count of sources & kg/year, by sources

13.3 Total overview by chemicals

14. Graphs First Measurement Round 3

14.1 Overview by Reading Range

14.2 Comparison between count of sources & kg/year, by sources

14.3 Total overview by chemicals

15. Graphs Measurement After Repair Round 3

15.1 Overview by Reading Range

15.2 Comparison between count of sources & kg/year, by sources

15.3 Total overview by chemicals

16. Graphs First Measurement Round 4

16.1 Overview by Reading Range

16.2 Comparison between count of sources & kg/year, by sources

16.3 Total overview by chemicals

17. Graphs Measurement After Repair Round 4

17.1 Overview by Reading Range

17.2 Comparison between count of sources & kg/year, by sources

17.3 Total overview by chemicals

18. Graphs First Measurement Round 5

18.1 Overview by Reading Range

18.2 Comparison between count of sources & kg/year, by sources

18.3 Total overview by chemicals

19. Graphs Measurement After Repair Round 5

19.1 Overview by Reading Range

19.2 Comparison between count of sources & kg/year, by sources

19.3 Total overview by chemicals

20. Graphs First Measurement Round 6

20.1 Overview by Reading Range

20.2 Comparison between count of sources & kg/year, by sources

20.3 Total overview by chemicals

Table Of Content

55

57

56

59

61

60

63

65

64

67

69

68

71

73

72

75

77

76

79

81

80

83

85

84

87

89

88

91

93

92

95

97

96

page 3 of 120

21. Graphs Measurement After Repair Round 6

21.1 Overview by Reading Range

21.2 Comparison between count of sources & kg/year, by sources

21.3 Total overview by chemicals

22. Graphs Cumulative

22.1 Comparison between count of sources above leak definition, by quarter

22.2 Comparison between % of components above leak definition by quarter

22.3 Comparison between count of sources & kg/year, by sources Cumulative

22.4 Total overview by chemicals

23. Attachments

23.1 Calibration loglist

23.2 Calibration gas certificates

23.3 Composition list & Response Factors

23.4 Quarterly equipment check Q1

23.5 Quarterly equipment check Q2

23.6 Quarterly equipment check Q3

23.7 Quarterly equipment check Q4

23.8 Quarterly production hours

Table Of Content

99

101

100

103

104

105

106

108

109

115

116

117

118

119

120

page 4 of 120

1 Project introduction

1.1 Scope of work

6 rounds of measurements (from 01/01/2019 to 31/12/2019)

Measurements performed for following classes:

Group 1: PRD, Sampling Point

Group 2: Open End, Stem Valve

Group 3: Connection, Flange

1.2 Project phases

 Monitoring: Group 1-2-3

 Re-measurement after repair action

 Revision of equipment and production processes

 Inventorisation: adding or deleting components

 Mapping of components on P&ID's

General

1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory

Accreditation Authority).

2. ISRAC is not responsible for the test results.

Project Introduction

page 5 of 120

2 Methodology

1.1 Definitions

Chemical State:

Gas/Vapor: stream which is in process conditions under gaseous or vapor form.

Light Liquid: a liquid having a VOC content greater than 10% (by volume) hat evaporates at 150°C

Heavy Liquid: a liquid having a VOC content of 10% or less (by volume) that evaporates at 150°C

Leak definition: 1,000 ppm (all sources)

Difficult to monitor components:

Any component situated at a level higher than five meters above ground level or any component situated at a distance further than

two meters from a platform and which cannot be accessed by employees in a safe way.

Any component which access requires the elevation of a person to a level higher than two meters above regular surfaces, and which

cannot be accessed in a safe.

Registered sources:

Sources with a leak value equal or greater than 9 ppm.

Default-zero:

This equation is valid for sources with a leak value of 0 ppm.A fixed EPA emission calculation rule is used for all these sources.

Total components:

All of the existing active components.

Total measured components:

All of the components, measured in specific monitoring round.

2.2 Methodology

Formulas:

Measured ppm values are converted to emission loss (kg/year) and these calculations are based on the E.P.A. “Correlation method

Refinery”

Modified Trapezoidal Emission Calculation Method:

The modified trapezoid method assumes that the mass leak rate changes linearly between any two monitoring points, except for

periods between leak detection and repair; the leak monitor reading is used from the time the leak is detected to the time it is repaired (i.e.,

re-screened).

Cumulative data:

In "Cumulative data" tables we provide the results of all of the measurements that performed from beginning of the year till the end of

current monitoring period (quarter). We also calculate the real sum of previous emissions based on the all rounds of the measurements

(before and after repairing attempts).(US EPA "Emission Estimation Protocol for Petroleum Refineries")

Methodology

page 6 of 120

Equation Set Details Report

Equation Set

Class

Chemical State

Default Zero

Pegged 100k

Multiplier

Exponent

Avg. Factor

Refinery

Connection

Light Liquid

7.5E-06

0.03

1.53E-06

0.735

0.00025

Refinery

Flange

Light Liquid

3.1E-07

0.084

4.61E-06

0.703

0.00025

Refinery

Open End

Light Liquid

2E-06

0.079

2.2E-06

0.704

0.0023

Refinery

PRD

Light Liquid

4E-06

0.11

1.36E-05

0.589

0.16

Refinery

Sampling Point

Light Liquid

4E-06

0.11

1.36E-05

0.589

0.015

Refinery

Stem Valve

Light Liquid

7.8E-06

0.14

2.29E-06

0.746

0.0109

Equations

page 7 of 120

Summary of Period: 01/01/2019-31/12/2019

The total emissions: 7.755kg

Overview by component class

Component

Class

Total Components

count

Total Components above leak definition

% of components above leak definition

Unrepaired Components

(1,000 ppm)

(1,000 ppm)

count

%

count

Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round

1

2

3

4

5

6

1

2

3

4

5

6

1

2

3

4

5

6

Total Emissions

kg

01/01/2019- 31/12/2019

PRD

Sampling Point

Total Group 1:

Stem Valve

Open End

Total Group 2:

Flange

Connection

Total Group 3:

4

4

8

20

102

122

55

38

93

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.14

1.354

1.494

1.367

2.248

3.615

0.149

2.497

2.646

Total:

223

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

7.755

Overview by reading range

Total Components

Round 1

Reading Range

#

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

Total:

Cumulative Data

Round 2

%

6

2

0

0

0

0

8

#

75.0%

25.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 3

%

7

1

0

0

0

0

8

#

87.5%

12.5%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 4

%

223

0

0

0

0

0

223

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 5

%

8

0

0

0

0

0

8

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 6

%

130

0

0

0

0

0

130

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

%

8

0

0

0

0

0

8

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

page 8 of 120

Summary of Monitoring Period Round 1

First measurement:

0 "difficult to monitor" sources.

6 default-zero sources with a calculated emission rate:

2 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

6

2

0

0

0

0

Total:

8

0.21 kg/year

6.524 kg/year

6.734 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

2

0

0.00%

0

6.594

8

2

0

0.00%

0

6.734

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

75.00%

0.21

3.12%

25.00%

6.524

96.88%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

6.734

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

6 default-zero sources with a calculated emission rate:

2 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

0.21 kg/year

6.524 kg/year

6.734 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

2

0

0.00%

0

6.594

Total:

8

2

0

0.00%

0

6.734

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

6

2

0

0

0

0

Total:

8

Summary R1

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

75.00%

0.21

3.12%

25.00%

6.524

96.88%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

6.734

Comments

100%

page 9 of 120

Summary of Monitoring Period Round 2

First measurement:

0 "difficult to monitor" sources.

7 default-zero sources with a calculated emission rate:

1 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

7

1

0

0

0

0

Total:

8

0.245 kg/year

3.515 kg/year

3.76 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

1

0

0.00%

0

3.62

8

1

0

0.00%

0

3.76

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

87.50%

0.245

6.52%

12.50%

3.515

93.48%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

3.76

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

7 default-zero sources with a calculated emission rate:

1 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

0.245 kg/year

3.515 kg/year

3.76 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

1

0

0.00%

0

3.62

Total:

8

1

0

0.00%

0

3.76

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

7

1

0

0

0

0

Total:

8

Summary R2

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

87.50%

0.245

6.52%

12.50%

3.515

93.48%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

3.76

Comments

100%

page 10 of 120

Summary of Monitoring Period Round 3

First measurement:

0 "difficult to monitor" sources.

223 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Stem Valve

Open End

Flange

Connection

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

223

0

0

0

0

0

Total:

223

6.063 kg/year

0 kg/year

6.063 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

0

0

0.00%

0

0.14

20

0

0

0.00%

0

1.363

102

0

0

0.00%

0

1.782

55

0

0

0.00%

0

0.149

38

0

0

0.00%

0

2.49

223

0

0

0.00%

0

6.064

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

6.063

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

6.063

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

223 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

6.063 kg/year

0 kg/year

6.063 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Stem Valve

20

0

0

0.00%

0

1.363

Open End

102

0

0

0.00%

0

1.782

Flange

55

0

0

0.00%

0

0.149

Connection

38

0

0

0.00%

0

2.49

223

0

0

0.00%

0

6.064

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

223

0

0

0

0

0

Total:

223

Summary R3

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

6.063

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

6.063

Comments

100%

page 11 of 120

Summary of Monitoring Period Round 4

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

0.283 kg/year

0 kg/year

0.283 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

4

0

0

0.00%

0

0.141

8

0

0

0.00%

0

0.282

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.283

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.283

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

0.283 kg/year

0 kg/year

0.283 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

Sampling Point

4

0

0

0.00%

0

0.141

Total:

8

0

0

0.00%

0

0.282

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Summary R4

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.283

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.283

Comments

100%

page 12 of 120

Summary of Monitoring Period Round 5

First measurement:

0 "difficult to monitor" sources.

130 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Stem Valve

Open End

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

130

0

0

0

0

0

Total:

130

3.462 kg/year

0 kg/year

3.462 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

4

0

0

0.00%

0

0.141

20

0

0

0.00%

0

1.378

102

0

0

0.00%

0

1.802

130

0

0

0.00%

0

3.462

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

3.462

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

3.462

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

130 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

3.462 kg/year

0 kg/year

3.462 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

Sampling Point

4

0

0

0.00%

0

0.141

Stem Valve

20

0

0

0.00%

0

1.378

Open End

102

0

0

0.00%

0

1.802

Total:

130

0

0

0.00%

0

3.462

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

130

0

0

0

0

0

Total:

130

Summary R5

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

3.462

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

3.462

Comments

100%

page 13 of 120

Summary of Monitoring Period Round 6

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

0.283 kg/year

0 kg/year

0.283 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

4

0

0

0.00%

0

0.141

8

0

0

0.00%

0

0.282

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.283

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.283

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

0.283 kg/year

0 kg/year

0.283 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

Sampling Point

4

0

0

0.00%

0

0.141

Total:

8

0

0

0.00%

0

0.282

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Summary R6

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.283

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.283

Comments

100%

page 14 of 120

Cumulative data for period

01-01-2019-31-12-2019

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph Cumulative

page 15 of 120

Fugitive emission component classification and emission estimation for production facilities

01/01/2018-31/12/2018 Calculation period

Monitoring

Frequency

Components above 1,000 ppm

cycles/year

Cumulative Components above

Emission

100,000 ppm

%

R6

6

6 0.00%

6

6

6 0.00%

6

0.00%

2

2 0.00%

2

2

2 0.00%

2

0.00%

1

1 0.00%

1

1

1 0.00%

1

0.00%

0.00%

R5

R4

kg

R3

R2

Count

R1

Components in

Components in

Components in

reading range

reading range 9-999 reading range 0-8 ppm

1,000-100,000 ppm

ppm

Count

Count

Count

Unrepaired

Components

Count

TASHAN Company name

22-Jan-2019 Date

Alroy Production Unit

Report Number

Total Components Difficult

Major

Total

Chemical State Component Class Group

above 1,000 ppm

to

Components Components

Monitor

Count

R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1

Count

Count

Count

0.00% 0.00% 0.00% 0.00% 0.00%

0.14

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

4

4

4

4

4

4 0

0

0

0

0

0 0

0

0

0

0

0

0

1

0.00% 0.00% 0.00% 0.00% 0.00%

1.354

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

1

2

4

4

4

4

3

2 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0.00% 0.00% 0.00% 0.00% 0.00%

1.494

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

1

2

8

8

8

8

7

6 0

0

0

0

0

0 0

0

0

0

0

0

0

1

0.00% 0.00% 0.00% 0.00% 0.00%

1.367

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

20

0

20

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

16

0.00% 0.00% 0.00% 0.00% 0.00%

2.248

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0 102

0 102

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0.00% 0.00% 0.00% 0.00% 0.00%

3.615

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0 122

0 122

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

16

0.00% 0.00% 0.00% 0.00% 0.00%

0.149

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0

55

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0.00% 0.00% 0.00% 0.00% 0.00%

2.497

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0

38

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0.00% 0.00% 0.00% 0.00% 0.00%

0.00% 0.00% 0.00% 0.00% 0.00%

2.646

7.755

0 0

0 0

0

0

0

0

0

0

0 0

0 0

0

0

0

0

0

0

0

0

0 0

0 0

0

0

0

0

0

0

0

1

0

2

0

0

8 130

0 93

8 223

0

7

0 0

6 0

0

0

0

0

0

0

0

0

0 0

0 0

0

0

0

0

0

0

0

0

0

0

0

0

0

17

GV

PRD

LL

HL

GV

Sampling Point

4

LL

HL

8 Subtotal G1

GV

Stem Valve

20

LL

HL

GV

Open End

102

LL

HL

122 Subtotal G2

GV

Flange

55

LL

HL

GV

Connection

38

LL

HL

93 Subtotal G3

223 Total Components

G1

4

7.755 Total Cumulative Emission

G2

G3

Chemical Summary by Component Class

Report Chemical Summary Cumulative

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: Refinery

Units of Measurement: KG

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1354

0.0135

0.0677

0.1354

0.5416

0.4604

1.354

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1367

0.0137

0.0683

0.1367

0.5466

0.4646

1.3666

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.2248

0.0225

0.1124

0.2248

0.8993

0.7644

2.2482

Chemical CU

page 17 of 120

Chemical Summary by Component Class

Report Chemical Summary Cumulative

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: Refinery

Units of Measurement: KG

Report Date: 26.12.2019

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0149

0.0015

0.0075

0.0149

0.0597

0.0508

0.1493

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.2497

0.025

0.1248

0.2497

0.9986

0.8488

2.4966

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.7755

0.0776

0.3877

0.7755

3.1019

2.6367

7.7549

Grand Total

Chemical CU

7.7549

page 18 of 120

LDAR report for production facilities

Unit

Drawing

LDAR 015

Component

Tag

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 1-2-3-4-5-6

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 19 of 120

Round 1

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R1

page 20 of 120

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 1

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.14

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

6.594

0

0

2

2

0

0

0

4

HL

6

0.0%

6.734

0

0

2

6

0

0

1

8

Subtotal G1

0.0%

6.734

0

0

2

6

0

0

1

8 Total Components

6.734 Total Annual Emission Rate

TASHAN Company name

Round 1

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.14

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

6.594

0

0

2

2

0

0

0

4

HL

6

0.0%

6.734

0

0

2

6

0

0

1

8

Subtotal G1

0.0%

6.734

0

0

2

6

0

0

1

8 Total Components

6.734 Total Annual Emission Rate

Form-07 R1

page 21 of 120

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.6594

0.0659

0.3297

0.6594

2.6377

2.2421

6.5942

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.6734

0.0673

0.3367

0.6734

2.6938

2.2898

6.7344

Grand Total

Chemical FM R1

6.7344

page 22 of 120

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.6594

0.0659

0.3297

0.6594

2.6377

2.2421

6.5942

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.6734

0.0673

0.3367

0.6734

2.6938

2.2898

6.7344

Grand Total

Chemical AR R1

6.7344

page 23 of 120

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R1

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 1

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 24 of 120

Round 2

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R2

page 25 of 120

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 2

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.14

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

3.62

0

0

1

3

0

0

0

4

HL

6

0.0%

3.76

0

0

1

7

0

0

1

8

Subtotal G1

0.0%

3.76

0

0

1

7

0

0

1

8 Total Components

3.76 Total Annual Emission Rate

TASHAN Company name

Round 2

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.14

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

3.62

0

0

1

3

0

0

0

4

HL

6

0.0%

3.76

0

0

1

7

0

0

1

8

Subtotal G1

0.0%

3.76

0

0

1

7

0

0

1

8 Total Components

3.76 Total Annual Emission Rate

Form-07 R2

page 26 of 120

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.362

0.0362

0.181

0.362

1.448

1.2308

3.62

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.376

0.0376

0.188

0.376

1.5041

1.2785

3.7602

Grand Total

Chemical FM R2

3.7602

page 27 of 120

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.362

0.0362

0.181

0.362

1.448

1.2308

3.62

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.376

0.0376

0.188

0.376

1.5041

1.2785

3.7602

Grand Total

Chemical AR R2

3.7602

page 28 of 120

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R2

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 2

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 29 of 120

Round 3

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R3

page 30 of 120

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 3

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.14

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

0.14

0

0

0

4

0

0

0

4

HL

6

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

GV

Stem Valve

G2

2

LL

2

0.0%

1.363

0

0

0

20

0

0

16

20

HL

2

GV

Open End

2

LL

2

0.0%

1.782

0

0

0

102

0

0

0

102

HL

2

0.0%

3.145

0

0

0

122

0

0

16

122

Subtotal G2

GV

Flange

G3

1

LL

1

0.0%

0.149

0

0

0

55

0

0

0

55

HL

1

GV

Connection

1

LL

1

0.0%

2.49

0

0

0

38

0

0

0

38

HL

1

0.0%

2.639

0

0

0

93

0

0

0

93

Subtotal G3

0.0%

6.064

0

0

0

223

0

0

17

223 Total Components

6.064 Total Annual Emission Rate

TASHAN Company name

Round 3

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.14

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

0.14

0

0

0

4

0

0

0

4

HL

6

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

GV

Stem Valve

G2

2

LL

2

0.0%

1.363

0

0

0

20

0

0

16

20

HL

2

GV

Open End

2

LL

2

0.0%

1.782

0

0

0

102

0

0

0

102

HL

2

0.0%

3.145

0

0

0

122

0

0

16

122

Subtotal G2

GV

Flange

G3

1

LL

1

0.0%

0.149

0

0

0

55

0

0

0

55

HL

1

GV

Connection

1

LL

1

0.0%

2.49

0

0

0

38

0

0

0

38

HL

1

0.0%

2.639

0

0

0

93

0

0

0

93

Subtotal G3

0.0%

6.064

0

0

0

223

0

0

17

223 Total Components

6.064 Total Annual Emission Rate

Form-07 R3

page 31 of 120

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1782

0.0178

0.0891

0.1782

0.7129

0.6059

1.7821

Chemical FM R3

page 32 of 120

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0149

0.0015

0.0074

0.0149

0.0596

0.0506

0.1489

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.249

0.0249

0.1245

0.249

0.9959

0.8465

2.4898

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.6064

0.0606

0.3031

0.6064

2.4253

2.0614

6.0632

Grand Total

Chemical FM R3

6.0632

page 33 of 120

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1782

0.0178

0.0891

0.1782

0.7129

0.6059

1.7821

Chemical AR R3

page 34 of 120

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0149

0.0015

0.0074

0.0149

0.0596

0.0506

0.1489

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.249

0.0249

0.1245

0.249

0.9959

0.8465

2.4898

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.6064

0.0606

0.3031

0.6064

2.4253

2.0614

6.0632

Grand Total

Chemical AR R3

6.0632

page 35 of 120

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R3

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 3

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 36 of 120

Round 4

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R4

page 37 of 120

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 4

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.141

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

0.141

0

0

0

4

0

0

0

4

HL

6

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.282

0

0

0

8

0

0

1

8 Total Components

0.282 Total Annual Emission Rate

TASHAN Company name

Round 4

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.141

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

0.141

0

0

0

4

0

0

0

4

HL

6

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.282

0

0

0

8

0

0

1

8 Total Components

0.282 Total Annual Emission Rate

Form-07 R4

page 38 of 120

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0282

0.0028

0.0142

0.0282

0.113

0.096

0.2824

Grand Total

Chemical FM R4

0.2824

page 39 of 120

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0282

0.0028

0.0142

0.0282

0.113

0.096

0.2824

Grand Total

Chemical AR R4

0.2824

page 40 of 120

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R4

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 4

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 41 of 120

Round 5

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R5

page 42 of 120

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 5

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.141

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

0.141

0

0

0

4

0

0

0

4

HL

6

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

GV

Stem Valve

G2

2

LL

2

0.0%

1.378

0

0

0

20

0

0

16

20

HL

2

GV

Open End

2

LL

2

0.0%

1.802

0

0

0

102

0

0

0

102

HL

2

0.0%

3.18

0

0

0

122

0

0

16

122

Subtotal G2

0.0%

3.462

0

0

0

130

0

0

17

130 Total Components

3.462 Total Annual Emission Rate

TASHAN Company name

Round 5

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.141

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

0.141

0

0

0

4

0

0

0

4

HL

6

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

GV

Stem Valve

G2

2

LL

2

0.0%

1.378

0

0

0

20

0

0

16

20

HL

2

GV

Open End

2

LL

2

0.0%

1.802

0

0

0

102

0

0

0

102

HL

2

0.0%

3.18

0

0

0

122

0

0

16

122

Subtotal G2

0.0%

3.462

0

0

0

130

0

0

17

130 Total Components

3.462 Total Annual Emission Rate

Form-07 R5

page 43 of 120

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1378

0.0138

0.0689

0.1378

0.5511

0.4684

1.3778

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1802

0.018

0.0901

0.1802

0.7207

0.6126

1.8018

Chemical FM R5

page 44 of 120

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

All

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.3462

0.0346

0.1732

0.3462

1.3848

1.177

3.462

Grand Total

Chemical FM R5

3.462

page 45 of 120

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1378

0.0138

0.0689

0.1378

0.5511

0.4684

1.3778

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1802

0.018

0.0901

0.1802

0.7207

0.6126

1.8018

Chemical AR R5

page 46 of 120

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

All

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.3462

0.0346

0.1732

0.3462

1.3848

1.177

3.462

Grand Total

Chemical AR R5

3.462

page 47 of 120

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R5

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 5

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 48 of 120

Round 6

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R6

page 49 of 120

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 6

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.141

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

0.141

0

0

0

4

0

0

0

4

HL

6

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.282

0

0

0

8

0

0

1

8 Total Components

0.282 Total Annual Emission Rate

TASHAN Company name

Round 6

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999 range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

GV

PRD

G1

6

LL

6

0.0%

0.141

0

0

0

4

0

0

1

4

HL

6

GV

Sampling Point

6

LL

6

0.0%

0.141

0

0

0

4

0

0

0

4

HL

6

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.282

0

0

0

8

0

0

1

8 Total Components

0.282 Total Annual Emission Rate

Form-07 R6

page 50 of 120

Chemical Summary by Component Class

Report Chemical Summary First Measurement

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0282

0.0028

0.0142

0.0282

0.113

0.096

0.2824

Grand Total

Chemical FM R6

0.2824

page 51 of 120

Chemical Summary by Component Class

Report Chemical Summary After Repair

Calculation Period: 01/01/2019- 31/12/2019

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 26.12.2019

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0282

0.0028

0.0142

0.0282

0.113

0.096

0.2824

Grand Total

Chemical AR R6

0.2824

page 52 of 120

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R6

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 6

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 53 of 120

Graphs

Round 1

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R1

page 54 of 120

Graph6.1.1 R1

page 55 of 120

Graph6.1.3 R1

page 56 of 120

Graph6.1.2 R1

page 57 of 120

Graphs

Round 1

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R1

page 58 of 120

Graph6.2.1 R1

page 59 of 120

Graph6.2.3 R1

page 60 of 120

Graph6.2.2 R1

page 61 of 120

Graphs

Round 2

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R2

page 62 of 120

Graph6.1.1 R2

page 63 of 120

Graph6.1.3 R2

page 64 of 120

Graph6.1.2 R2

page 65 of 120

Graphs

Round 2

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R2

page 66 of 120

Graph6.2.1 R2

page 67 of 120

Graph6.2.3 R2

page 68 of 120

Graph6.2.2 R2

page 69 of 120

Graphs

Round 3

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R3

page 70 of 120

Graph6.1.1 R3

page 71 of 120

Graph6.1.3 R3

page 72 of 120

Graph6.1.2 R3

page 73 of 120

Graphs

Round 3

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R3

page 74 of 120

Graph6.2.1 R3

page 75 of 120

Graph6.2.3 R3

page 76 of 120

Graph6.2.2 R3

page 77 of 120

Graphs

Round 4

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R4

page 78 of 120

Graph6.1.1 R4

page 79 of 120

Graph6.1.3 R4

page 80 of 120

Graph6.1.2 R4

page 81 of 120

Graphs

Round 4

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R4

page 82 of 120

Graph6.2.1 R4

page 83 of 120

Graph6.2.3 R4

page 84 of 120

Graph6.2.2 R4

page 85 of 120

Graphs

Round 5

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R5

page 86 of 120

Graph6.1.1 R5

page 87 of 120

Graph6.1.3 R5

page 88 of 120

Graph6.1.2 R5

page 89 of 120

Graphs

Round 5

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R5

page 90 of 120

Graph6.2.1 R5

page 91 of 120

Graph6.2.3 R5

page 92 of 120

Graph6.2.2 R5

page 93 of 120

Graphs

Round 6

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R6

page 94 of 120

Graph6.1.1 R6

page 95 of 120

Graph6.1.3 R6

page 96 of 120

Graph6.1.2 R6

page 97 of 120

Graphs

Round 6

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R6

page 98 of 120

Graph6.2.1 R6

page 99 of 120

Graph6.2.3 R6

page 100 of 120

Graph6.2.2 R6

page 101 of 120

Graphs

Cumulative data for period

01-01-2019-31-12-2019

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph Graphs Cumul

page 102 of 120

Graph6.3.1

page 103 of 120

Graph6.3.2

page 104 of 120

Graph6.3.3

page 105 of 120

Graph6.3.4

page 106 of 120

General

Calibration loglist

Calibration gas certificates

Composition list & Response Factors

Quarterly production hours

Quarterly equipment check

Paragraph General

page 107 of 120

Calibration log list

Plant

Round Equipment Analyzer

Type

Type

Ultra-Zero

Span Gas

Span gas Cylinder

Span

Check gas Check gas Cylinder

Check gas

No

concentration

No

concentration

Date

Equipment

No

Equipment

Serial

No

(A)

ppm

ppm

Check

Calibration Result

error

1-st 2-st 3-st

check check check

(A1) (A2) (A3)

(CP)

ppm ppm ppm

TASHAN

1

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

07-Jan-2019

5

202016061436 505

507

507

0.46%

OK

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

10-Jan-2019

1

0715622657

501

501

501

-0.60%

OK

TASHAN

2

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

10-Jan-2019

5

202016061436 506

505

505

0.26%

OK

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

25-Jan-2019

1

0715622657

491

491

491

-2.58%

OK

TASHAN

2

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

25-Jan-2019

5

202016061436 503

502

503

-0.26%

OK

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

07-Mar-2019

1

0715622657

496

496

495

-1.65%

OK

TASHAN

2

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

07-Mar-2019

5

202016061436 503

503

503

-0.20%

OK

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

03-Apr-2019

1

0715622657

500

500

500

-0.79%

OK

TASHAN

2

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

03-Apr-2019

5

202016061436 504

504

504

0.00%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

02-May-2019

3

0115248937

502

503

504

-0.20%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

02-May-2019

5

202016061436 502

504

504

-0.13%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

05-May-2019

3

0115248937

511

510

510

1.26%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

05-May-2019

5

202016061436 503

503

504

-0.13%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

12-May-2019

1

0715622657

502

502

503

-0.33%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

12-May-2019

2

0115248185

505

505

507

0.33%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF16599

501

13-May-2019

5

202016061436 504

505

504

0.46%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF16599

501

12-Jun-2019

2

0115248185

510

510

511

1.66%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF16599

501

12-Jun-2019

3

0115248937

503

503

503

0.20%

OK

TASHAN

4

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51430

1,000

Methane

FF524456

504

02-Sep-2019

5

202016061436 503

502

502

-0.33%

OK

TASHAN

4

TVA2020

FID

Air, THC < 0.5ppm

Methane

FF51430

1,000

Methane

FF524456

504

15-Sep-2019

5

202016061436 509

508

508

0.86%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51430

1,000

Methane

FF524456

504

15-Sep-2019

3

0115248937

488

487

487

-3.31%

OK

TASHAN

5

TVA2020

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF524456

504

21-Nov-2019

5

202016061436 503

502

503

-0.26%

OK

TASHAN

6

TVA2020

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF524456

504

04-Dec-2019

5

202016061436 499

500

497

-1.06%

OK

TASHAN

5

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF524456

504

04-Dec-2019

2

0115248185

502

501

503

-0.40%

OK

TASHAN

5

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF524456

504

04-Dec-2019

3

0115248937

500

501

502

-0.60%

OK

Cal-Log

page 108 of 120

Certificate

page 109 of 120

Certificate

page 110 of 120

Certificate

page 111 of 120

Certificate

page 112 of 120

Certificate

page 113 of 120

Certificate

page 114 of 120

Stream Composition Summary

Stream Name

Stream Content

Stream Content

Dates

TVA

Gasoline

TOLUENE-34 %, n-Octane-40 %, METHYL TERT-BUTYL ETHER-10 %,

CYCLOHEXANE-5 %, BENZENE-1 %, 1-Butene-10 %

A=0.42, B=0.29

Petroleum

TOLUENE-7.5 %, n-Octane-55.3 %, CYCLOHEXANE-35.2 %, BENZENE-2 %

A=0.39, B=0.31

Stream Summary

MiniRAE 10.6 MiniRAE 11.7

page 115 of 120

Quarterly Validation of LDAR Devices

Date: 26-Dec-2018

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Analyzer

Span Gas

Sampling Flow

Rate

1

Check

Sampling

Span Gas

Flow

Span gas

Concentration

Result Check Gas

Rate

Cylinder No

ppm

l/min

Accuracy Check

Response Time

Comparison between two Devices

90%

Check Gas

Response Response Response

Second

of

Check gas

1-st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Time 1 Time 2 Time 3 Result

Result

Device

Result

Span

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

FF51430

1,000

1.01

OK

Methane

FF524456

504

507 513 507

0.99%

OK

900

4

4

4

OK

1.45

1.74

-0.29

16.67%

OK

2

0115248185

TVA1000B

FID

Methane

FF51430

1,000

1.13

OK

Methane

FF524456

504

495 497 497

-1.52%

OK

900

4

4

4

OK

2.11

1.98

0.13

-6.57%

OK

3

0115248937

TVA1000B

FID

Methane

FF51430

1,000

1.13

OK

Methane

FF524456

504

515 510 512

1.65%

OK

900

4

4

4

OK

1.22

1.15

0.07

-6.09%

OK

5

202016061436

TVA2020

FID

Methane

FF51430

1,000

1.09

OK

Methane

FF524456

504

501 500 501

-0.66%

OK

900

3

3

3

OK

2.24

2.11

0.13

-6.16%

OK

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.5

OK

Isobutylene EA0009962

997

995 994 994

-0.35%

OK

898

4

4

4

OK

2.5

2.1

0.4

-19.05%

OK

6

Quarterly Validation

page 116 of 120

Quarterly Validation of LDAR Devices

Date: 31-Mar-2019

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Analyzer

Span Gas

Sampling Flow

Rate

2

Check

Sampling

Span Gas

Flow

Span gas

Concentration

Result Check Gas

Rate

Cylinder No

ppm

l/min

Accuracy Check

Response Time

Comparison between two Devices

90%

Check Gas

Response Response Response

Second

of

Check gas

1-st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Time 1 Time 2 Time 3 Result

Result

Device

Result

Span

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

FF51430

1,000

1

OK

Methane

FF524456

504

495 502 501

-0.93%

OK

900

3

3

3

OK

2.2

2.14

0.06

-2.8%

OK

2

0115248185

TVA1000B

FID

Methane

FF51430

1,000

1.36

OK

Methane

FF524456

504

497 500 502

-0.86%

OK

900

3

3

3

OK

2.14

2.2

-0.06

2.73%

OK

3

0115248937

TVA1000B

FID

Methane

FF51430

1,000

1.26

OK

Methane

FF524456

504

495 501 502

-0.93%

OK

900

3

3

3

OK

2.18

2.35

-0.17

7.23%

OK

5

202016061436

TVA2020

FID

Methane

FF51430

1,000

0.99

OK

Methane

FF524456

504

504 505 505

0.13%

OK

900

3

3

3

OK

2.35

2.18

0.17

-7.8%

OK

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.5

OK

Isobutylene EA0009962

997

988 987 987

-1.05%

OK

898

3

3

3

OK

2.04

2.11

-0.07

3.32%

OK

6

Quarterly Validation

page 117 of 120

Quarterly Validation of LDAR Devices

Date: 02-Jul-2019

Quarter:

Equipment No Equip.Ser. No Equipment Type

3

Analyzer

Span Gas

Span gas

Cylinder No

Sampling Flow

Rate

Check

Sampling

Span Gas

Flow

Concentration

Result

Rate

Accuracy Check

Response Time

Comparison between two Devices

Check Gas

90%

Check Gas

Response Response Response

Second

of

Check gas

1-st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Time 1 Time 2 Time 3 Result

Result

Device

Result

Span

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

ppm

sec

sec

sec

ppm

l/min

1

0715622657

TVA1000B

FID

Methane

ET0022842

995

0.98

OK

Methane

FF524456

504

496 498 498

-1.32%

OK 895.5

4

4

4

OK

2.51

2.53

-0.02

0.79%

OK

2

0115248185

TVA1000B

FID

Methane

ET0022842

995

1.12

OK

Methane

FF524456

504

501 500 500

-0.73%

OK 895.5

4

4

4

OK

1.72

1.69

0.03

-1.78%

OK

3

0115248937

TVA1000B

FID

Methane

ET0022842

995

1.09

OK

Methane

FF524456

504

502 502 502

-0.4%

OK 895.5

4

4

4

OK

1.44

1.5

-0.06

4%

OK

5

202016061436

TVA2020

FID

Methane

ET0022842

995

1.05

OK

Methane

FF524456

504

504 504 504

0%

OK 895.5

4

4

4

OK

2.1

2.08

0.02

-0.96%

OK

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.51

OK

Isobutylene

EA0009962

997

995 995 995

-0.28%

OK

4

4

4

OK

3

3

0

0%

OK

6

Quarterly Validation

898

page 118 of 120

Quarterly Validation of LDAR Devices

Date: 01-Oct-2019

Quarter:

Equipment No Equip.Ser. No Equipment Type

4

Analyzer

Span Gas

Span gas

Cylinder No

Sampling Flow

Rate

Check

Sampling

Span Gas

Flow

Concentration

Result

Rate

Accuracy Check

Response Time

Comparison between two Devices

Check Gas

90%

Check Gas

Response Response Response

Second

of

Check gas

1-st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Time 1 Time 2 Time 3 Result

Result

Device

Result

Span

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

ppm

sec

sec

sec

ppm

l/min

1

0715622657

TVA1000B

FID

Methane

ET0022842

995

0.98

OK

Methane

FF524456

504

507 506 507

0.53%

OK 895.5

3

4

3

OK

2.17

2.22

-0.05

2.25%

OK

2

0115248185

TVA1000B

FID

Methane

ET0022842

995

1.12

OK

Methane

FF524456

504

500 500 501

-0.73%

OK 895.5

4

4

3

OK

1.47

1.8

-0.33

18.33%

OK

3

0115248937

TVA1000B

FID

Methane

ET0022842

995

1.09

OK

Methane

FF524456

504

503 506 505

0.13%

OK 895.5

3

4

4

OK

2.85

2.71

0.14

-5.17%

OK

5

202016061436

TVA2020

FID

Methane

ET0022842

995

1.05

OK

Methane

FF524456

504

500 502 499

-0.73%

OK 895.5

3

3

4

OK

2.03

1.88

0.15

-7.98%

OK

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.51

OK

Isobutylene

EA0009962

997

995 995 995

-0.28%

OK

4

4

4

OK

3

3

0

0%

OK

6

Quarterly Validation

898

page 119 of 120

CUMULATIVE PRODUCTION HOURS TEMPLATE 2019

Plant

TASHAN

Unit

Drawing

Stream Name

Remark

Annual Production

Hours

Alroy

6006-100-006

Gasoline

8,760

Alroy

6006-100-007

Gasoline

8,760

Production Hours

Q1

01/01-31/03

Quarter =

Quarterly Production

hours

2,160

2,160

Q2

01/04-30/06

Quarter =

Quarterly Production

hours

2,184

2,184

Q3

01/07-30/09

Quarter =

Quarterly Production

hours

2,208

2,208

Q4

01/10-31/12

Quarter =

Quarterly Production

hours

2,208

2,208

page 120 of 120

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין

3013.16-034-T2

3013.16-025

17/02/2020

18/30

3013.16-036

T2 - kerosene

External Floating roof

1. Tank data

Diameter of the tank

D

Effective height of the stock liquid (while

roof landing episode)

hle

Shell Color and condition

α

Roof color and condition

α

Tank paint solar absorptance

α

Vapor space outage (while roof landing

episode)

HVO

m

feet

m

feet

color

condition

color

condition

dimensionless

m

Tank data

--Tank data

--חום

טובה

לבן

טוב

48.77

160.01

11.00

0.58

Table 7.1-6

Brown

0.17

Table 7.1-6

0.38

Table 7.1-6

Possible to use also equation

1-15

assumption - equal to legs height

feet

11.00

Volume of the vapor space (while roof

landing episode)

Breather vent pressure setting

VV

ft

3

VV=PI()*D /4*Hvo

221,185

Equation 1-3

ΔPBP

psi

Typical value

0.50

Equation 1-11

Breather vent vacuum setting

ΔPBV

psi

Typical value

0.00

Equation 1-11

Breather vent pressure setting range

ΔPB

psi

PB  PBP  PBV

0.50

Equation 1-11

2

2. Material data - קרוסין

Stock vapor molecular weight

MV

Density of the liquid inside the tank

Wl

Vapor density

WV

True vapor pressure of the stock liquid

P

Vapor pressure at daily average liquid

surface temperature

Vapor pressure at the daily maximum

liquid surface temperature, psia

Vapor pressure at the daily minimum

liquid surface temperature

Daily vapor pressure range

3013.16-034 - 2

gr/gr-mole

lb/lb-mole

g/ml

lb/gal

kg/m^3

lb/ft3

msds data

130

msds data

--msds data

---

0.80

6.68

4.5

0.28

mm Hg

PEI data

0.833

psia

--הנחה:

Pv=nRT -->

P2=P1*(T2/T1)

0.02

0.02

0.02

0.00

PVA

psia

PVX

psia

PVN

psia

T1(k)=20C+273

T2(k)=37.5C+273

ΔPV

psia

 PV  PVX  PVN

1/3

0

at 20°C

0.02

Equation 1-9

13/02/2020

3. Operation data

Number of days that the tank stands idle

(on roof landing episode)

Number of degassing and cleaning

episode

Number of roof landing episode

nd

days/landing episode

site data

4

landing episode/year

site data

0.07

landing episode/year

site data

0.07

Tanks Program

--Tanks Program

---

44

20

79

36

16

Tanks Program

---

59.04

27

lb per emptying

Tanks Program

61

Kg per emptying

---

28

4. Normal operation (Tanks program)

lb per year

Kg per year

lb per year

Kg per year

Kg per year

Working (withdrawal) losses

Total emissions (Breathing & Working)

Breathing (standing) losses

5. Degassing and Cleaning (Tanks program)

Degassing: emission from one turnover

Edegass-floating lb per emptying

of floating roof

Kg per emptying

Degassing: fixed roof with a height of

roof legs

Edegass-legs

Liquid fraction in sludge

Fliquid

Sludge volume

Sludge weight

Vs

Ws

Cleaning emissions

Ecleaning

Total Degassing and Cleaning emissions

Edegass-total

3013.16-034 - 2

0.8

m3 per emptying

Kg per emptying

lb per emptying

Kg per emptying

lb per emptying

Kg per emptying

Ecleaning = Ws * (1-Fliquid)

Edegass-total =

Edegass-floating + Edegass-legs + Ecleaning

2/3

T2 - B&W 2019

T2 - B&W 2019

T2 - DFloating 2019

T2- DFixed 2019

(Only working losses)

Tanks FAQ - degassing and

cleaning

70

56,000

24,692

11,200

24,811

11,254

13/02/2020

6. Roof landing

Daily average liquid surface temperature

TLA

°R

Daily vapor temperature range

Daily maximum liquid surface

temperature

ΔTV

°R

TLX

Daily minimum liquid surface temperature

Liquid bulk temperature

Max standing idle losses during roof

landing

T LA  0 .44 T AA  0 .56 T B  0 .0079 *  * I

532.17

Equation 1-26

 TV  0.72 T A  0.028 *  * I

32.95

Equation 1-8

°R

TLX = TLA + 0.25*ΔTV

540.41

Figure 7.1-17

TLN

°R

TLN = TLA - 0.25*ΔTV

523.93

Figure 7.1-17

TB

°R

527.22

Equation 1-28

LSL-max

lb per landing episode

Kg per landing episode

TB = TAA + 6α - 1

LSL-max = 5.9*D2*hle*W l

--0.60 for a full liquid heel

0.50 for a partial

0.15 for drain-dry

11,093,038 Equation 2-13

5,031,769

0.50

Equation 2-26

(pages No 33,35)

1

KS 

1  0.053 * PVA * H VO

0.5

Equation 1-20

KS is assumed to be less than

or equal to the saturation

factor during filling (S) .

 TV  PV   PB

T LA

PA  PVA

0.028

Liquid stock has a true vapor

pressure greater than 0.1psia Equation 1-7.

Filling saturation factor

S

dimensionless

saturation factor

KS

dimensionless

Vapor space expansion factor

KE

dimensionless

Standing idle losses during roof landing

LSL

lb per landing episode

 PV 

L SL  n d K E  V  M V K S

 RT AA 

5

Equation 2-16

Filling losses during roof landing

LFL

lb per landing episode

 P * VV 

 M V * S

L FL  

 R * T AA 

41

Equation 2-26

Total losses during roof landing

LTL

lb per landing episode

Kg per landing episode

46

21

Equation 2-10

KE 

LTL=LSL+LFL

7. Summary

Working (withdrawal) losses

Breathing (standing) losses

Kg per year

Kg per year

20

16

Total Degassing and Cleaning emissions

Kg per year

750

Total losses during roof landing

Kg per year

1

788

3013.16-034 - 2

3/3

Kg per year

13/02/2020

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - B&W 2019

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

0.78

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Aluminum/Diffuse

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - B&W 2019 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

All

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

76.52

65.35

87.69

Liquid

Bulk

Temp

(deg F)

68.86

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0136

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

02/02/2020

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - B&W 2019 - External Floating Roof Tank

Haifa, Israel

Annual Emission Calcaulations

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

0.0136

160.0100

130.0000

1.0000

Withdrawal Losses (lb):

Annual Net Throughput (gal/yr.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

43.8093

5,946,910.0000

0.0075

7.0000

160.0100

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

0.8398

0.0002

130.0000

1.0000

27.8819

6.2000

Total Losses (lb):

79.1496

34.5005

1.6000

0.3000

6.2000

1.6000

0.0002

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

KFa(lb-mole/yr)

1.60

6.20

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

1.20

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.94

1.00

Losses(lb)

0.1446

0.6608

0.0345

02/02/2020

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - B&W 2019 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

34.50

43.81

0.84

0.00

79.15

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFixed 2019

Haifa

Israel

PEI

Vertical Fixed Roof Tank

kerosene

Tank Dimensions

Shell Height (ft):

Diameter (ft):

Liquid Height (ft) :

Avg. Liquid Height (ft):

Volume (gallons):

Turnovers:

Net Throughput(gal/yr):

Is Tank Heated (y/n):

N

Paint Characteristics

Shell Color/Shade:

Shell Condition

Roof Color/Shade:

Roof Condition:

Aluminum/Diffuse

Good

White/White

Good

Roof Characteristics

Type:

Height (ft)

Slope (ft/ft) (Cone Roof)

Breather Vent Settings

Vacuum Settings (psig):

Pressure Settings (psig)

11.00

160.01

11.00

5.50

1,654,664.74

1.00

1,654,664.74

Cone

0.00

0.00

0.00

0.50

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

Apr

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

72.10

62.74

81.45

Liquid

Bulk

Temp

(deg F)

67.57

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0118

0.0092

0.0159

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

02/02/2020

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Month:

Standing Losses (lb):

Vapor Space Volume (cu ft):

Vapor Density (lb/cu ft):

Vapor Space Expansion Factor:

Vented Vapor Saturation Factor:

January

February

March

April

May

June

July

August

September

October

November

December

Tank Vapor Space Volume:

Vapor Space Volume (cu ft):

Tank Diameter (ft):

Vapor Space Outage (ft):

Tank Shell Height (ft):

Average Liquid Height (ft):

Roof Outage (ft):

Roof Outage (Cone Roof)

Roof Outage (ft):

Roof Height (ft):

Roof Slope (ft/ft):

Shell Radius (ft):

Vapor Density

Vapor Density (lb/cu ft):

Vapor Molecular Weight (lb/lb-mole):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Daily Avg. Liquid Surface Temp. (deg. R):

Daily Average Ambient Temp. (deg. F):

Ideal Gas Constant R

(psia cuft / (lb-mol-deg R)):

Liquid Bulk Temperature (deg. R):

Tank Paint Solar Absorptance (Shell):

Tank Paint Solar Absorptance (Roof):

Daily Total Solar Insulation

Factor (Btu/sqft day):

Vapor Space Expansion Factor

Vapor Space Expansion Factor:

Daily Vapor Temperature Range (deg. R):

Daily Vapor Pressure Range (psia):

Breather Vent Press. Setting Range(psia):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Vapor Pressure at Daily Minimum Liquid

Surface Temperature (psia):

Vapor Pressure at Daily Maximum Liquid

Surface Temperature (psia):

Daily Avg. Liquid Surface Temp. (deg R):

Daily Min. Liquid Surface Temp. (deg R):

Daily Max. Liquid Surface Temp. (deg R):

Daily Ambient Temp. Range (deg. R):

Vented Vapor Saturation Factor

Vented Vapor Saturation Factor:

Vapor Pressure at Daily Average Liquid:

Surface Temperature (psia):

Vapor Space Outage (ft):

Working Losses (lb):

Vapor Molecular Weight (lb/lb-mole):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Net Throughput (gal/mo.):

Annual Turnovers:

Turnover Factor:

Maximum Liquid Volume (gal):

Maximum Liquid Height (ft):

Tank Diameter (ft):

Working Loss Product Factor:

Total Losses (lb):

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Losses(lbs)

Components

Working Loss

Breathing Loss

Total Emissions

Jet kerosene

60.63

32.78

93.41

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFloating 2019

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.00

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Aluminum/Diffuse

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

Apr

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

76.46

63.88

89.04

Liquid

Bulk

Temp

(deg F)

68.86

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0136

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

02/02/2020

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Month:

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

January

February

March

April

May

June

July

August

September

October

November

December

Withdrawal Losses (lb):

Net Throughput (gal/mo.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

Total Losses (lb):

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

KFa(lb-mole/yr)

1.60

6.20

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

1.20

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.94

1.00

Losses(lb)

0.0000

0.0000

0.0000

02/02/2020

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

2.99

55.99

0.07

0.00

59.04

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 6 of 6

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חישובי פליטה ממיכל תשטיפים

גיליון חישוב זה הוכן על ידי "פז" הנדסה וניהול ( )1980בע"מ.

אין להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ( )1980בע"מ.

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מסמך 9 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 3655 KB)

תשתיות נפט ואנרגיה בע"מ

מסוף אלרואי

סיכום פליטות לאוויר

שנת 2020

פרויקט3013.17 :

סימוכין3013.17-036 :

פברואר 2021

תוכן עניינים

.1מבוא 4 ...............................................................................................................

.2נתוני מסוף 5 ........................................................................................................

.2.1נתוני מיכלים 5.........................................................................................................

.2.2נתונים עבור מסוף מילוי מיכליות כביש 9.....................................................................

.3חישוב פליטות 10 .................................................................................................

.3.1כללי 10 ............................................................................................................

.3.2סוגי פליטות מחושבות 10 .......................................................................................

.3.3בחירת חומרים בתוכנת 11 ......................................................................... TANKS

.3.4נתונים מטאורולוגיים 11 ........................................................................................

.4סיכום פליטות לשנת 12 .................................................................................. 2020

.4.1מיכלים 12 ..........................................................................................................

.4.2מסוף מילוי מיכליות כביש 12 ..................................................................................

.4.3מיכל איסוף תשטיפים 13 .......................................................................................

.4.4סיכום ממצאי ניטור 13 ............................................................................... LDAR

.4.5פליטה שנתית מכלל המתקן 13 ................................................................................

.5פליטות לא שגרתיות במהלך שנת 13 .................................................................. 2020

.6מקורות 14 ..........................................................................................................

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טבלאות

טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 5........................................... 2020

טבלה :2נתוני מעטפת וגגות – שנת 6.................................................................................. 2020

טבלה :3נתוני אביזרים – שנת 7......................................................................................... 2020

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת 8................................................... TANKS

טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 9...................................................... 2020

טבלה :6חומרים מייצגים בתוכנת 11 ............................................................................ TANKS

טבלה :7סיכום פליטות מכלים -שנת 12 ............................................................................ 2020

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שנת 12 ..................................................2020

נספחים

נספח א'

טבלה )AP-42( 1-5.2

נספח ב'

נתוני ניטור LDARעבור מסוף אלרואי – סיכום שנת 2020

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין

נספח ד'

חישוב פליטות ממיכל לאיסוף תשטיפים

אביטל בלניק

שם עורך

28/02/2021

יואב פיסטינר

שם מאשר

להערות

תיאור

28.02.2021

תאריך

3/30

0

גרסה

3013.17-036.doc

.1מבוא

חברת תשתיות נפט ואנרגיה בע"מ (להלן תש"ן) מפעילה את מסוף אלרואי לאחסון ושינוע

דלקים .

המסוף כולל:

•

מבני משרדים

•

חוות מכלים לאחסון דלקים מסוגים שונים

•

רציפי מילוי מכליות כביש (לשימוש בעת חירום בלבד)

המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכונת

אלרואי ומדרום לו שכונת קרית חרושת.

באתר 9מיכלים ,מתוכם 7מכלים תפעוליים ו 2-מכלים המשמשים כמכלים אסטרטגיים

(מכלים מס' 1ו.)9-

מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוסף קיימות מערכות תומכות כגון

מערכות כיבוי אש ומערכות פיקוד ובקרה.

כחלק מהתנאים ברישיון עסק מדצמבר ,2010בסוף כל שנה קלנדרית על תש"ן להגיש דו"ח

סיכום פליטות שנתי לגבי השנה שחלפה.

חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקנים

הקיימים במסוף.

סיכום הפליטות הוכן על ידי חברת "פז" הנדסה וניהול ( )1980בע"מ (להלן פז הנדסה) ,והוא

מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.

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.2נתוני מסוף

.2.1נתוני מיכלים

בטבלאות הבאות מפורט מידע טכני של המיכלים בחוות המיכלים אלרואי.

טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 2020

לחץ אדים

בטמפ' הנוזל

הממוצעת

)(mmHg

405 @ 28°C

כמות

צריכה

שנתית

(מ"ק)

0

גבעה חלקית

38,648

גבעה חלקית

48.77

גבעה חלקית

48.77

32,056

48.77

32,056

28,768

56,959

51,614

15.56

51,614

15.56

14.1

15.56

14.1

11.4

18.3

18.3

15.4

9.7

סוג ניקוז

בתחתית

מיכל

קוטר

מיכל

(מטר)

נפח מיכל

(מ"ק)

נפח מיכל

פעיל

(מ"ק)

48.77

32,056

28,768

גובה /אורך

מעטפת

מיכל

(מטר)

17.16

15.4

32,056

28,768

17.16

15.4

10

28,768

17.16

15.4

9.5

17.16

15.4

10.3

14.1

14.1

14.1

מספר

מיכל

סוג הדלק

המאוחסן

)1( 1

בנזין

2

קרוסין

0.833 @ 28°C

3

סולר

0.507 @ 28°C

15,794

4

סולר

0.507 @ 28°C

38,116

גבעה חלקית

5

סולר

0.507 @ 28°C

6,852

גבעה מלאה

68.27

6

סולר

0.507 @ 28°C

20,092

גבעה מלאה

68.27

56,959

7

סולר

0.507 @ 28°C

3,078

גבעה מלאה

68.27

56,959

51,614

8

קרוסין

0.833 @ 28°C

118

גבעה חלקית

48.8

36,547

34,228

19.54

)1( 9

קרוסין

0.833 @ 28°C

0

גבעה חלקית

48.77

32,056

28,768

17.16

367,704

332,913

122,698

סה"כ

( )1מכלים מס' 1ו 9-משמשים כמכלי מלאי ,לא היו תנועות במכלים בשנת .2020

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גובה נוזל

מירבי

(מטר)

גובה נוזל

ממוצע

(מטר)

10.5

טבלה :2נתוני מעטפת וגגות – שנת 2020

מספר

מיכל

סוג גג

אטם ראשי

אטם משני

1

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Liquid

mounted

Mechanical

Shoe

Rim

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Rim

mounted

Rim

mounted

2

3

4

5

6

7

8

9

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צורת גג

סוג

חיבורי

גג

צבע

גג

מצב

צבע

גג

צבע

מעטפת

חיצונית

מצב צבע

מעטפת

חיצונית

סוג חיבורי

מעטפת

מצב

מעטפת

פנימית

מיכל

מחומם

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חום

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חום

ישן

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

כחול בהיר

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

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טבלה :3נתוני אביזרים – שנת 2020

מספר

מיכל

1

2

3

4

5

6

7

8

9

סה"כ

שובר ואקום

כמות

2

2

2

2

2

2

2

6

2

Vacuum

]set. [psi

0

0

0

0

0

0

0

0

0

Pressure

]set. [psi

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

רגליים מתכווננות התומכות

בגג צף()1

גובה כמות באזור

כמות

במרכז

()ft

pontoon

29

43

11

29

43

11

29

43

11

29

43

11

72

107

11

72

107

11

72

107

11

36

54

9

29

43

11

כמות

מדי

מפלס

Rim

Vent

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

6

כמות בוצה

בנקיון

(מ"ק)

"גרביים" לבאר

הדיגום המחורצת

ולרגלי הגג הצף()1

70

70

70

70

150

150

150

70

70

870

יש

יש

יש

יש

יש

יש

יש

יש

יש

( )1הנ"ל לא נלקחו בחשבון בחישוב הפליטות מתוכנת ה TANKS-מפני שנדגמו במסגרת ניטורי ה.LDAR-

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הנחות שנלקחו לצורך החישובים

.1עבור חישוב Degassingבמיכל עם גג צף – הונח:

•

גג צף נח על רגליים בגובה ( 9-11 ftבהתאם לטבלה לעיל) וזהו גם הגובה המרבי של הנוזל

במיכל.

•

גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.

.2הונח כי ניקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שנים .הניקיון יארך יום אחד.

.3הונח כי אירוע של נחיתת גגות צפים מתבצע אחת ל 15-שנים .זמן נחיתת הגג במקרה זה לא

יעלה על 4ימים.

.4יחס הנוזל בבוצה הונח כ]2[ 0.8 -

.5בהתאם לטבלה 7.1-6על פי [ ,]1נבחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,

לצורך חישובי פליטות לאוויר:

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת Tanks

צבע מעטפת

מיכל

צבע לצורך חישובי אקסל

צבע לצורך חישובים בתוכנת

בהתאם למסמך EPA AP-42

)*( Tanks

כחול בהיר

Gray Medium

Gray Medium

Brown

Aluminium/Diffuse

Beige/Cream

Aluminium/Specular

White

White

חום

צהוב קרם

לבן

(*) בתוכנת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך

.]1[ EPA AP-42

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.2.2נתונים עבור מסוף מילוי מיכליות כביש

טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 2020

מס'

זרוע

1

2

3

4

5

6

7

8

מוצר

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

סה"כ

מילוי

עילי /תחתי

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

נפח מילוי שנתי

(מ"ק)

12

0

0

0

0

0

0

0

12

נפח ממוצע של

מיכלית (מ"ק)

30

30

30

30

30

30

30

30

הנחות שנלקחו צורך החישובים

.1

מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:

א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:

דוגמת חישוב עבור מיכל מס' :2

ב .בשלב השני חושב מקדם αממוצע עבור הקרוסין:

.2

זמן מילוי מיכלית חושב על פי נפח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000

ליטר/דקה.

.3

Vapor collection efficiency - 70%

.4

Vapor recovery efficiency - 0%

.5

Saturation factorהונח כ (Submerged loading, dedicated normal service) 0.6-על פי

[ .]1טבלה רלוונטית מצורפת בנספח א'.

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.3חישוב פליטות

.3.1כללי

חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכנת Tanksובעזרת .]1[ EPA-AP 42

הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ( )LDARמצורפת בנספח ב'.

דוגמת חישוב עבור מיכל גג חיצוני צף (מיכל מס' )2המאחסן קרוסין ,מצורפת כנספח ג' למסמך

זה.

בדוגמאות אלה ניתן לראות את נתוני הקלט (כולל הנחות) עליהם התבססו החישובים.

.3.2סוגי פליטות מחושבות

הערכת הפליטות ממיכלי אחסון כוללת [:]3

• פליטות בזמן אחסון )(Breathing Losses

• פליטות משינויי מפלס )(Working Losses

• פליטות כתוצאה מניקוי וריקון מיכלים )(Degassing Losses

• פליטות כתוצאה מנחיתת גגות צפים )(Roof Landing Losses

• פליטות כתוצאה מהפרשי לחץ )(Flash Losses

• פליטות בזמן מילוי מיכלים ומיכליות

בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ

).(Flash Losses

פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלחץ הנוזל ,נתון הגורם להפרת שיווי המשקל

הקיים במיכל (בין גז לנוזל) וכתוצאה מכך נוצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הנוזל

עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר נוזל המאוחסן בלחץ נשלח

לאחסון במיכל בעל לחץ נמוך יותר [.]3

פליטות אלו הוזנחו כיוון שכל החומרים מוחזקים בתנאים אטמוספריים בכל אחד מהשלבים

הנוגעים להובלתם ואחסונם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.

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.3.3בחירת חומרים בתוכנת Tanks

על פי נתוני MSDSשל הדלקים במסוף ,נבחרו החומרים הבאים הקיימים בתוכנת Tanks

כמייצגים של חומרים אלו:

טבלה :6חומרים מייצגים בתוכנת Tanks

דלק קיים במסוף

חומר מייצג בתוכנת Tanks

סולר (תחבורה והסקה)

Distillate fuel oil no 2

נפט (קרוסין)

Jet kerosene

בנזין

Gasoline RVP 10

.3.4נתונים מטאורולוגיים

לצורך חישוב הנתונים בתוכנת Tanksהוגדרו נתונים מטאורולוגים המתאימים למפרץ חיפה על פי

מקורות [.]4

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.4סיכום פליטות לשנת 2020

.4.1מיכלים

סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:

טבלה :7סיכום פליטות מכלים -שנת 2020

מיכל

חומר

פליטות לאוויר

(ק"ג/שנה)

1

בנזין

3,603

2

קרוסין

802

3

סולר

25

4

סולר

831

5

סולר

1,697

6

סולר

1,706

7

סולר

1,695

8

קרוסין

756

9

קרוסין

758

11,873

סה"כ

.4.2מסוף מילוי מיכליות כביש

להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -שנת 2020

מס' זרוע

מוצר

מילוי עילי /תחתי

1

2

3

4

5

6

7

8

סה"כ

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

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פליטה שנתית

(ק"ג/שנה)

0.04

0

0

0

0

0

0

0

0.04

3013.17-036.doc

.4.3מיכל איסוף תשטיפים

סך הפליטה ממיכל לאיסוף תשטיפים הינה כ 1 -ק"ג/שנה.

חישוב מצורף בנספח ד'.

יצוין כי החישוב מתבסס על הנחה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל

בעיקר ניקוז מים מהמכלים.

.4.4סיכום ממצאי ניטור LDAR

טבלה :9סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 2020

סה"כ פליטות (ק"ג/שנה)

סיכום פליטות LDAR

פליטה שנתית (ק"ג/שנה)

סה"כ

6.26

.4.5פליטה שנתית מכלל המתקן

טבלה :10סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 2020

סה"כ פליטות (ק"ג/שנה)

חוות מיכלים

מסוף מילוי

מיכליות כביש

מיכל לאיסוף

תשטיפים

11,873

0.04

1

סיכום פליטות

רכיבים

סה"כ

()LDAR

6.26

11,880

.5פליטות לא שגרתיות במהלך שנת 2020

במהלך שנת 2020לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.

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.6מקורות

]1[ EPA-AP42

]2[ USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version

4.0 - APPENDIX D

[ ]3הנחיות הממונה לטיפול בבקשה להיתר פליטה לפי סעיף (9א) לתקנות אוויר נקי (היתרי פליטה),

התש"ע – ,2010מהדורה ,4ספטמבר 2014

[ ]4האטלס האקלימי לתכנון פיסי וסביבתי בישראל ,מהדורה שנייה1994 ,

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נספח א'

טבלה 5.2-1

AP-42

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16/30

28/02/2021

נספח ב'

נתוני ניטור LDARעבור אלרואי – סיכום שנת 2020

(מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך )25.02.2021

3013.17-008A

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LDAR

Fugitive Emission Monitoring

Report No.

RL-TS-R-A-20

Plant:TASHAN

City:Haifa

District:Haifa

Production Unit:Alroy

Group:Group 1-2-3

Reporting period:Annual Summary

Report printing date:25-Feb-2021

Technicians names:Mancarj

Polik

Portselan

Report editor:

Michael Ourievsky

Approved by:

Alexey Ratner, CEO

1

Table of Content

1. Project introduction

1.1 Scope of work

1.2 Project phases

2. Methodology

2.1 Definitions

2.2 Methodology

3. Summary of Monitoring Period

3.1 Cumulative Data of Monitoring Period

3.2 Summary of Monitoring Period

3.3 Form 07: component classification and emission estimations for production facilities

3.4 Chemical Summary

3.5 LDAR report for production facilities

4. First Measurement and Measurement After Repair Round 1

4.1 Form-07 by Round

4.2 Chemical Summary First Measurement

4.3 Chemical Summary After Repair

4.4 LDAR report for production facilities

5. First Measurement and Measurement After Repair Round 2

5.1 Form-07 by Round

5.2 Chemical Summary First Measurement

5.3 Chemical Summary After Repair

5.4 LDAR report for production facilities

6. First Measurement and Measurement After Repair Round 3

6.1 Form-07 by Round

6.2 Chemical Summary First Measurement

6.3 Chemical Summary After Repair

6.4 LDAR report for production facilities

7. First Measurement and Measurement After Repair Round 4

7.1 Form-07 by Round

7.2 Chemical Summary First Measurement

7.3 Chemical Summary After Repair

7.4 LDAR report for production facilities

8. First Measurement and Measurement After Repair Round 5

8.1 Form-07 by Round

8.2 Chemical Summary First Measurement

8.3 Chemical Summary After Repair

8.4 LDAR report for production facilities

9. First Measurement and Measurement After Repair Round 6

9.1 Form-07 by Round

9.2 Chemical Summary First Measurement

9.3 Chemical Summary After Repair

9.4 LDAR report for production facilities

Table Of Content

5

5

6

6

9

10

17

18

20

22

23

24

25

27

28

29

30

32

33

35

37

39

40

41

42

44

45

47

49

51

52

53

54

page 2 of 121

10. Graphs First Measurement Round 1

10.1 Overview by Reading Range

10.2 Comparison between count of sources & kg/year, by sources

10.3 Total overview by chemicals

11. Graphs Measurement After Repair Round 1

11.1 Overview by Reading Range

11.2 Comparison between count of sources & kg/year, by sources

11.3 Total overview by chemicals

12. Graphs First Measurement Round 2

12.1 Overview by Reading Range

12.2 Comparison between count of sources & kg/year, by sources

12.3 Total overview by chemicals

13. Graphs Measurement After Repair Round 2

13.1 Overview by Reading Range

13.2 Comparison between count of sources & kg/year, by sources

13.3 Total overview by chemicals

14. Graphs First Measurement Round 3

14.1 Overview by Reading Range

14.2 Comparison between count of sources & kg/year, by sources

14.3 Total overview by chemicals

15. Graphs Measurement After Repair Round 3

15.1 Overview by Reading Range

15.2 Comparison between count of sources & kg/year, by sources

15.3 Total overview by chemicals

16. Graphs First Measurement Round 4

16.1 Overview by Reading Range

16.2 Comparison between count of sources & kg/year, by sources

16.3 Total overview by chemicals

17. Graphs Measurement After Repair Round 4

17.1 Overview by Reading Range

17.2 Comparison between count of sources & kg/year, by sources

17.3 Total overview by chemicals

18. Graphs First Measurement Round 5

18.1 Overview by Reading Range

18.2 Comparison between count of sources & kg/year, by sources

18.3 Total overview by chemicals

19. Graphs Measurement After Repair Round 5

19.1 Overview by Reading Range

19.2 Comparison between count of sources & kg/year, by sources

19.3 Total overview by chemicals

20. Graphs First Measurement Round 6

20.1 Overview by Reading Range

20.2 Comparison between count of sources & kg/year, by sources

20.3 Total overview by chemicals

Table Of Content

56

58

57

60

62

61

64

66

65

68

70

69

72

74

73

76

78

77

80

82

81

84

86

85

88

90

89

92

94

93

96

98

97

page 3 of 121

21. Graphs Measurement After Repair Round 6

21.1 Overview by Reading Range

21.2 Comparison between count of sources & kg/year, by sources

21.3 Total overview by chemicals

22. Graphs Cumulative

22.1 Comparison between count of sources above leak definition, by quarter

22.2 Comparison between % of components above leak definition by quarter

22.3 Comparison between count of sources & kg/year, by sources Cumulative

22.4 Total overview by chemicals

23. Attachments

23.1 Calibration loglist

23.2 Calibration gas certificates

23.3 Composition list & Response Factors

23.4 Quarterly equipment check Q1

23.5 Quarterly equipment check Q2

23.6 Quarterly equipment check Q3

23.7 Quarterly equipment check Q4

23.8 Quarterly production hours

Table Of Content

100

102

101

104

105

106

107

109

110

116

117

118

119

120

121

page 4 of 121

1 Project introduction

1.1 Scope of work

6 rounds of measurements (from 01/01/2020 to 31/12/2020)

Measurements performed for following classes:

Group 1: PRD, Sampling Point

Group 2: Open End, Stem Valve

Group 3: Connection, Flange

1.2 Project phases

 Monitoring: Group 1-2-3

 Re-measurement after repair action

 Revision of equipment and production processes

 Inventorisation: adding or deleting components

 Mapping of components on P&ID's

General

1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory

Accreditation Authority).

2. ISRAC is not responsible for the test results.

Project Introduction

page 5 of 121

2 Methodology

1.1 Definitions

Chemical State:

Gas/Vapor: stream which is in process conditions under gaseous or vapor form.

Light Liquid: a liquid having a VOC content greater than 10% (by volume) hat evaporates at 150°C

Heavy Liquid: a liquid having a VOC content of 10% or less (by volume) that evaporates at 150°C

Leak definition: 1,000 ppm (all sources)

Difficult to monitor components:

Any component situated at a level higher than five meters above ground level or any component situated at a distance further than

two meters from a platform and which cannot be accessed by employees in a safe way.

Any component which access requires the elevation of a person to a level higher than two meters above regular surfaces, and which

cannot be accessed in a safe.

Registered sources:

Sources with a leak value equal or greater than 9 ppm.

Default-zero:

This equation is valid for sources with a leak value of 0 ppm.A fixed EPA emission calculation rule is used for all these sources.

Total components:

All of the existing active components.

Total measured components:

All of the components, measured in specific monitoring round.

2.2 Methodology

Formulas:

Measured ppm values are converted to emission loss (kg/year) and these calculations are based on the E.P.A. “Correlation method

Refinery”

Modified Trapezoidal Emission Calculation Method:

The modified trapezoid method assumes that the mass leak rate changes linearly between any two monitoring points, except for

periods between leak detection and repair; the leak monitor reading is used from the time the leak is detected to the time it is repaired (i.e.,

re-screened).

Cumulative data:

In "Cumulative data" tables we provide the results of all of the measurements that performed from beginning of the year till the end of

current monitoring period (quarter). We also calculate the real sum of previous emissions based on the all rounds of the measurements

(before and after repairing attempts).(US EPA "Emission Estimation Protocol for Petroleum Refineries")

Methodology

page 6 of 121

Equation Set Details Report

Equation Set

Class

Chemical State

Default Zero

Pegged 100k

Multiplier

Exponent

Avg. Factor

Refinery

Connection

Light Liquid

7.5E-06

0.03

1.53E-06

0.735

0.00025

Refinery

Flange

Light Liquid

3.1E-07

0.084

4.61E-06

0.703

0.00025

Refinery

Open End

Light Liquid

2E-06

0.079

2.2E-06

0.704

0.0023

Refinery

PRD

Light Liquid

4E-06

0.11

1.36E-05

0.589

0.16

Refinery

Sampling Point

Light Liquid

4E-06

0.11

1.36E-05

0.589

0.015

Refinery

Stem Valve

Light Liquid

7.8E-06

0.14

2.29E-06

0.746

0.0109

Equations

page 7 of 121

Project summary

The situation of TASHAN indicates there are no leaks.

0 "difficult to monitor" sources.

223 default-zero sources (0-8ppm).

0 registered sources (9-999ppm).

0 components above leak definition (1,000ppm)

The total calculated emission rate:

6.257 kg

Overview by component class

Component Class

Total components

Components 9-999ppm

count

count

Components above

leak definition (1,000

ppm)

count

% of components

9-999ppm

% of components

above leak definition

Total emission

kg

%

%

PRD

Sampling Point

Stem Valve

Open End

Flange

Connection

4

4

20

102

55

38

0

0

0

0

0

0

0

0

0

0

0

0

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

01/01/2020-31/12/2020

0.141

0.301

1.37

1.792

0.15

2.503

Total:

223

0

0

0.00%

0.00%

6.257

Overview per Unit

Unit

Total components

Total emission

kg

01/01/2020-31/12/2020

count

Alroy

223

6.257

Total:

223

6.257

Summary of Period

page 8 of 121

Summary of Period: 01/01/2020-31/12/2020

The total emissions: 6.257kg

Overview by component class

Component

Class

Total Components

count

Total Components above leak definition

% of components above leak definition

Unrepaired Components

(1,000 ppm)

(1,000 ppm)

count

%

count

Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round Round

1

2

3

4

5

6

1

2

3

4

5

6

1

2

3

4

5

6

Total Emissions

kg

01/01/2020- 31/12/2020

PRD

Sampling Point

Total Group 1:

Stem Valve

Open End

Total Group 2:

Flange

Connection

Total Group 3:

4

4

8

20

102

122

55

38

93

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.141

0.301

0.442

1.37

1.792

3.162

0.15

2.503

2.653

Total:

223

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

6.257

Overview by reading range

Total Components

Round 1

Reading Range

#

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

Total:

Cumulative Data

Round 2

%

8

0

0

0

0

0

8

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 3

%

8

0

0

0

0

0

8

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 4

%

223

0

0

0

0

0

223

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 5

%

8

0

0

0

0

0

8

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

Round 6

%

130

0

0

0

0

0

130

#

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

%

7

1

0

0

0

0

8

87.5%

12.5%

0.0%

0.0%

0.0%

0.0%

100.0%

page 9 of 121

Summary of Monitoring Period Round 1

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

0

0

0.00%

0

0.14

8

0

0

0.00%

0

0.28

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

0.28 kg/year

0 kg/year

0.28 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Summary R1

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

page 10 of 121

Summary of Monitoring Period Round 2

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

0

0

0.00%

0

0.14

8

0

0

0.00%

0

0.28

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

0.28 kg/year

0 kg/year

0.28 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Summary R2

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.28

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.28

Comments

100%

page 11 of 121

Summary of Monitoring Period Round 3

First measurement:

0 "difficult to monitor" sources.

223 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

6.063 kg/year

0 kg/year

6.063 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Stem Valve

Open End

Flange

Connection

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

223

0

0

0

0

0

Total:

223

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

4

0

0

0.00%

0

0.14

20

0

0

0.00%

0

1.363

102

0

0

0.00%

0

1.782

55

0

0

0.00%

0

0.149

38

0

0

0.00%

0

2.49

223

0

0

0.00%

0

6.064

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

6.063

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

6.063

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

223 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

6.063 kg/year

0 kg/year

6.063 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Stem Valve

20

0

0

0.00%

0

1.363

Open End

102

0

0

0.00%

0

1.782

Flange

55

0

0

0.00%

0

0.149

Connection

38

0

0

0.00%

0

2.49

223

0

0

0.00%

0

6.064

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

223

0

0

0

0

0

Total:

223

Summary R3

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

6.063

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

6.063

Comments

100%

page 12 of 121

Summary of Monitoring Period Round 4

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

0.283 kg/year

0 kg/year

0.283 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

4

0

0

0.00%

0

0.141

8

0

0

0.00%

0

0.282

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.283

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.283

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

0.283 kg/year

0 kg/year

0.283 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

Sampling Point

4

0

0

0.00%

0

0.141

Total:

8

0

0

0.00%

0

0.282

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Summary R4

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.283

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.283

Comments

100%

page 13 of 121

Summary of Monitoring Period Round 5

First measurement:

0 "difficult to monitor" sources.

130 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

3.462 kg/year

0 kg/year

3.462 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Stem Valve

Open End

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

130

0

0

0

0

0

Total:

130

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

4

0

0

0.00%

0

0.141

20

0

0

0.00%

0

1.378

102

0

0

0.00%

0

1.802

130

0

0

0.00%

0

3.462

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

3.462

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

3.462

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

130 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

3.462 kg/year

0 kg/year

3.462 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

Sampling Point

4

0

0

0.00%

0

Stem Valve

20

0

0

0.00%

0

1.378

Open End

102

0

0

0.00%

0

1.802

Total:

130

0

0

0.00%

0

3.462

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

130

0

0

0

0

0

Total:

130

Summary R5

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

3.462

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

3.462

0.141

Comments

100%

page 14 of 121

Summary of Monitoring Period Round 6

First measurement:

0 "difficult to monitor" sources.

7 default-zero sources with a calculated emission rate:

1 registered sources with a calculated emission rate:

0.247 kg/year

2.141 kg/year

2.388 kg/year

The total calculated emission rate:

Component Class

Total components

count

PRD

Sampling Point

Total:

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

7

1

0

0

0

0

Total:

8

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

4

1

0

0.00%

0

2.247

8

1

0

0.00%

0

2.388

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

87.50%

0.247

10.34%

12.50%

2.141

89.66%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

2.388

Comments

100%

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

Component Class

Total components

count

PRD

0.283 kg/year

0 kg/year

0.283 kg/year

Overview by component class

Components 9-999ppm

Components above leak

% emission rate of

Emission rate of

Total annual emission rate

definition (1,000 ppm)

components above leak

components above leak

(all components)

definition

definition

count

count

%

kg/year

kg/year

4

0

0

0.00%

0

0.141

Sampling Point

4

0

0

0.00%

0

0.141

Total:

8

0

0

0.00%

0

0.282

Reading Range

Total components

count

0-8 ppm

9-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

Total:

8

Summary R6

Overview by reading range

Percentage of Total

Annual Emission Rate

Percentage of Total

Components

Annual Emission Rate

%

kg/year

%

100.00%

0.283

100.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

0.00%

0

0.00%

100%

0.283

Comments

100%

page 15 of 121

Cumulative data for period

01-01-2020-31-12-2020

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph Cumulative

page 16 of 121

Fugitive emission component classification and emission estimation for production facilities

01/01/2018-31/12/2018 Calculation period

Monitoring

Frequency

Components above 1,000 ppm

cycles/year

Cumulative Components above

Emission

100,000 ppm

%

R6

6

6 0.00%

6

6

6 0.00%

6

0.00%

2

2 0.00%

2

2

2 0.00%

2

0.00%

1

1 0.00%

1

1

1 0.00%

1

0.00%

0.00%

R5

R4

kg

R3

R2

Count

R1

Components in

Components in

Components in

reading range

reading range 9-999 reading range 0-8 ppm

1,000-100,000 ppm

ppm

Count

Count

Count

Unrepaired

Components

Count

TASHAN Company name

22-Jan-2019 Date

Alroy Production Unit

Report Number

Total Components Difficult

Major

Total

Chemical State Component Class Group

above 1,000 ppm

to

Components Components

Monitor

Count

R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1

0

0

Count

Count

0

Count

0.00% 0.00% 0.00% 0.00% 0.00%

0.141

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

4

4

4

4

4

4 0

0

0

0

0

0 0

0

0

0

1

0.00% 0.00% 0.00% 0.00% 0.00%

0.301

0 0

0

0

0

0 0

0

0

0

0

0 1

0

0

0

0

0

3

4

4

4

4

4 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0.00% 0.00% 0.00% 0.00% 0.00%

0.442

0 0

0

0

0

0 0

0

0

0

0

0 1

0

0

0

0

0

7

8

8

8

8

8 0

0

0

0

0

0 0

0

0

0

0

0

0

1

0.00% 0.00% 0.00% 0.00% 0.00%

1.37

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

20

0

20

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

16

0.00% 0.00% 0.00% 0.00% 0.00%

1.792

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0 102

0 102

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0.00% 0.00% 0.00% 0.00% 0.00%

3.162

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0 122

0 122

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

16

0.00% 0.00% 0.00% 0.00% 0.00%

0.15

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0

55

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0.00% 0.00% 0.00% 0.00% 0.00%

2.503

0 0

0

0

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0

38

0

0 0

0

0

0

0

0 0

0

0

0

0

0

0

0

0.00% 0.00% 0.00% 0.00% 0.00%

0.00% 0.00% 0.00% 0.00% 0.00%

2.653

6.257

0 0

0 0

0

0

0

0

0

0

0 0

0 0

0

0

0

0

0

0

0

0

0 0

0 1

0

0

0

0

0

0

0

0

0

0

0

0

7 130

0 93

8 223

0

8

0 0

8 0

0

0

0

0

0

0

0

0

0 0

0 0

0

0

0

0

0

0

0

0

0

0

0

0

0

17

GV

PRD

LL

HL

GV

Sampling Point

4

LL

HL

8 Subtotal G1

GV

Stem Valve

20

LL

HL

GV

Open End

102

LL

HL

122 Subtotal G2

GV

Flange

55

LL

HL

GV

Connection

38

LL

HL

93 Subtotal G3

223 Total Components

G1

4

6.257 Total Cumulative Emission

G2

G3

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary Cumulative

Equation Set: Refinery

Units of Measurement: KG

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.007

0.0141

0.0562

0.0478

0.1406

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0301

0.003

0.015

0.0301

0.1203

0.1022

0.3007

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.137

0.0137

0.0685

0.137

0.5481

0.4659

1.3702

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1792

0.0179

0.0896

0.1792

0.7168

0.6093

1.792

Chemical CU

page 18 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary Cumulative

Equation Set: Refinery

Units of Measurement: KG

Report Date: 25.02.2021

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.015

0.0015

0.0075

0.015

0.0599

0.0509

0.1498

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.2503

0.025

0.1252

0.2503

1.0014

0.8512

2.5034

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.6257

0.0625

0.3128

0.6257

2.5027

2.1273

6.2567

Grand Total

Chemical CU

6.2567

page 19 of 121

LDAR report for production facilities

Unit

Drawing

LDAR 015

Component

Tag

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 1‐2‐3‐4‐5‐6

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 20 of 121

Round 1

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R1

page 21 of 121

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 1

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

TASHAN Company name

Round 1

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

Form-07 R1

page 22 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary First Measurement

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1118

0.095

0.2796

Grand Total

Chemical FM R1

0.2796

page 23 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary After Repair

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1118

0.095

0.2796

Grand Total

Chemical AR R1

0.2796

page 24 of 121

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R1

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 1

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 25 of 121

Round 2

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R2

page 26 of 121

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 2

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

TASHAN Company name

Round 2

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.28

0

0

0

8

0

0

1

8 Total Components

0.28 Total Annual Emission Rate

Form-07 R2

page 27 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary First Measurement

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1118

0.095

0.2796

Grand Total

Chemical FM R2

0.2796

page 28 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary After Repair

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.028

0.0028

0.014

0.028

0.1118

0.095

0.2796

Grand Total

Chemical AR R2

0.2796

page 29 of 121

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R2

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 2

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 30 of 121

Round 3

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R3

page 31 of 121

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 3

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.363

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

0.0%

1.782

0

0

0

102

0

0

0

102

LL

2

HL

0.0%

3.145

0

0

0

122

0

0

16

122

Subtotal G2

1

GV

Flange

G3

1

0.0%

0.149

0

0

0

55

0

0

0

55

LL

1

HL

1

GV

Connection

1

0.0%

2.49

0

0

0

38

0

0

0

38

LL

1

HL

0.0%

2.639

0

0

0

93

0

0

0

93

Subtotal G3

0.0%

6.064

0

0

0

223

0

0

17

223 Total Components

6.064 Total Annual Emission Rate

TASHAN Company name

Round 3

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.14

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.14

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.28

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.363

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

0.0%

1.782

0

0

0

102

0

0

0

102

LL

2

HL

0.0%

3.145

0

0

0

122

0

0

16

122

Subtotal G2

1

GV

Flange

G3

1

0.0%

0.149

0

0

0

55

0

0

0

55

LL

1

HL

1

GV

Connection

1

0.0%

2.49

0

0

0

38

0

0

0

38

LL

1

HL

0.0%

2.639

0

0

0

93

0

0

0

93

Subtotal G3

0.0%

6.064

0

0

0

223

0

0

17

223 Total Components

6.064 Total Annual Emission Rate

Form-07 R3

page 32 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary First Measurement

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1782

0.0178

0.0891

0.1782

0.7129

0.6059

1.7821

Chemical FM R3

page 33 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary First Measurement

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0149

0.0015

0.0074

0.0149

0.0596

0.0506

0.1489

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.249

0.0249

0.1245

0.249

0.9959

0.8465

2.4898

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.6064

0.0606

0.3031

0.6064

2.4253

2.0614

6.0632

Grand Total

Chemical FM R3

6.0632

page 34 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary After Repair

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.014

0.0014

0.007

0.014

0.0559

0.0475

0.1398

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1363

0.0136

0.0681

0.1363

0.5451

0.4634

1.3628

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1782

0.0178

0.0891

0.1782

0.7129

0.6059

1.7821

Chemical AR R3

page 35 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary After Repair

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

Flange

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0149

0.0015

0.0074

0.0149

0.0596

0.0506

0.1489

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.249

0.0249

0.1245

0.249

0.9959

0.8465

2.4898

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.6064

0.0606

0.3031

0.6064

2.4253

2.0614

6.0632

Grand Total

Chemical AR R3

6.0632

page 36 of 121

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R3

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 3

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 37 of 121

Round 4

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R4

page 38 of 121

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 4

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.141

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.141

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.282

0

0

0

8

0

0

1

8 Total Components

0.282 Total Annual Emission Rate

TASHAN Company name

Round 4

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.141

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.141

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.282

0

0

0

8

0

0

1

8 Total Components

0.282 Total Annual Emission Rate

Form-07 R4

page 39 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary First Measurement

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0282

0.0028

0.0142

0.0282

0.113

0.096

0.2824

Grand Total

Chemical FM R4

0.2824

page 40 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary After Repair

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0282

0.0028

0.0142

0.0282

0.113

0.096

0.2824

Grand Total

Chemical AR R4

0.2824

page 41 of 121

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R4

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 4

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 42 of 121

Round 5

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R5

page 43 of 121

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 5

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.141

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.141

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.378

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

0.0%

1.802

0

0

0

102

0

0

0

102

LL

2

HL

0.0%

3.18

0

0

0

122

0

0

16

122

Subtotal G2

0.0%

3.462

0

0

0

130

0

0

17

130 Total Components

3.462 Total Annual Emission Rate

TASHAN Company name

Round 5

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.141

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.141

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

2

GV

Stem Valve

G2

2

0.0%

1.378

0

0

0

20

0

0

16

20

LL

2

HL

2

GV

Open End

2

0.0%

1.802

0

0

0

102

0

0

0

102

LL

2

HL

0.0%

3.18

0

0

0

122

0

0

16

122

Subtotal G2

0.0%

3.462

0

0

0

130

0

0

17

130 Total Components

3.462 Total Annual Emission Rate

Form-07 R5

page 44 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary First Measurement

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1378

0.0138

0.0689

0.1378

0.5511

0.4684

1.3778

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1802

0.018

0.0901

0.1802

0.7207

0.6126

1.8018

Chemical FM R5

page 45 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary First Measurement

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

All

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.3462

0.0346

0.1732

0.3462

1.3848

1.177

3.462

Grand Total

Chemical FM R5

3.462

page 46 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary After Repair

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Stem Valve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1378

0.0138

0.0689

0.1378

0.5511

0.4684

1.3778

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.1802

0.018

0.0901

0.1802

0.7207

0.6126

1.8018

Chemical AR R5

page 47 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary After Repair

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

All

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.3462

0.0346

0.1732

0.3462

1.3848

1.177

3.462

Grand Total

Chemical AR R5

3.462

page 48 of 121

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R5

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 5

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 49 of 121

Round 6

First measurement.

Measurement after repair attempt.

Form 07: component classification and emission estimations

Correlation Equation Chemical Summary by Component Class

Form 15: LDAR report for production facilities

Paragraph By Round R6

page 50 of 121

Fugitive emission component classification and emission estimation for production facilities

TASHAN Company name

Round 6

Monitoring round

Alroy Production Unit

First measurement

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.141

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

2.247

0

0

1

3

0

0

0

4

LL

6

HL

0.0%

2.388

0

0

1

7

0

0

1

8

Subtotal G1

0.0%

2.388

0

0

1

7

0

0

1

8 Total Components

2.388 Total Annual Emission Rate

TASHAN Company name

Round 6

Monitoring round

Alroy Production Unit

Measurement after repair attempt

Monitoring Components Annual Components Components Components Components

Total

Difficult to

Major

Total

Chemical State Component Class Group

Frequency

above Leak Emission

above

in reading

in reading

in reading Components

Monitor

Components Components

Definition

Rate

100,000 ppm range 1,000- range 9-999

range 0-8

above Leak

100,000 ppm

ppm

ppm

Definition

cycles/year

%

kg/year

Count

Count

Count

Count

Count

Count

Count

Count

6

GV

PRD

G1

6

0.0%

0.141

0

0

0

4

0

0

1

4

LL

6

HL

6

GV

Sampling Point

6

0.0%

0.141

0

0

0

4

0

0

0

4

LL

6

HL

0.0%

0.282

0

0

0

8

0

0

1

8

Subtotal G1

0.0%

0.282

0

0

0

8

0

0

1

8 Total Components

0.282 Total Annual Emission Rate

Form-07 R6

page 51 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary First Measurement

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.2247

0.0225

0.1123

0.2247

0.8987

0.7639

2.2468

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.2388

0.0239

0.1194

0.2388

0.9552

0.8119

2.388

Grand Total

Chemical FM R6

2.388

page 52 of 121

Chemical Summary by Component Class

Calculation Period: 01/01/2020- 31/12/2020

Report Chemical Summary After Repair

Equation Set: SOCMI

Units of Measurement: KG/year

Report Date: 25.02.2021

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

CAS Number

106-98-9

71432

110827

1634044

111-65-9

108883

Emissions

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

Sampling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0141

0.0014

0.0071

0.0141

0.0565

0.048

0.1412

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octane

TOLUENE

106-98-9

71432

110827

1634044

111-65-9

108883

0.0282

0.0028

0.0142

0.0282

0.113

0.096

0.2824

Grand Total

Chemical AR R6

0.2824

page 53 of 121

LDAR report for production facilities

Unit

Drawing

Component

Tag

LDAR 015 R6

Plant

Unit

Monitoring Round

TASHAN

Alroy

Round 6

Component

Type

Component

Class

Location Description

ppm value, First

Measurement

Date of First

Measurement

Repair Due

Date of

repair

Repair type

Technicians

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

Date of

repair

Remarks

Repair type

date of

ppm value of

remeasurement

remeasurement

after repair attempt after repair attempt

page 54 of 121

Graphs

Round 1

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R1

page 55 of 121

Graph6.1.1 R1

page 56 of 121

Graph6.1.3 R1

page 57 of 121

Graph6.1.2 R1

page 58 of 121

Graphs

Round 1

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R1

page 59 of 121

Graph6.2.1 R1

page 60 of 121

Graph6.2.3 R1

page 61 of 121

Graph6.2.2 R1

page 62 of 121

Graphs

Round 2

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R2

page 63 of 121

Graph6.1.1 R2

page 64 of 121

Graph6.1.3 R2

page 65 of 121

Graph6.1.2 R2

page 66 of 121

Graphs

Round 2

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R2

page 67 of 121

Graph6.2.1 R2

page 68 of 121

Graph6.2.3 R2

page 69 of 121

Graph6.2.2 R2

page 70 of 121

Graphs

Round 3

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R3

page 71 of 121

Graph6.1.1 R3

page 72 of 121

Graph6.1.3 R3

page 73 of 121

Graph6.1.2 R3

page 74 of 121

Graphs

Round 3

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R3

page 75 of 121

Graph6.2.1 R3

page 76 of 121

Graph6.2.3 R3

page 77 of 121

Graph6.2.2 R3

page 78 of 121

Graphs

Round 4

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R4

page 79 of 121

Graph6.1.1 R4

page 80 of 121

Graph6.1.3 R4

page 81 of 121

Graph6.1.2 R4

page 82 of 121

Graphs

Round 4

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R4

page 83 of 121

Graph6.2.1 R4

page 84 of 121

Graph6.2.3 R4

page 85 of 121

Graph6.2.2 R4

page 86 of 121

Graphs

Round 5

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R5

page 87 of 121

Graph6.1.1 R5

page 88 of 121

Graph6.1.3 R5

page 89 of 121

Graph6.1.2 R5

page 90 of 121

Graphs

Round 5

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R5

page 91 of 121

Graph6.2.1 R5

page 92 of 121

Graph6.2.3 R5

page 93 of 121

Graph6.2.2 R5

page 94 of 121

Graphs

Round 6

First measurement.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph First R6

page 95 of 121

Graph6.1.1 R6

page 96 of 121

Graph6.1.3 R6

page 97 of 121

Graph6.1.2 R6

page 98 of 121

Graphs

Round 6

Measurement after repair attempt.

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph After R6

page 99 of 121

Graph6.2.1 R6

page 100 of 121

Graph6.2.3 R6

page 101 of 121

Graph6.2.2 R6

page 102 of 121

Graphs

Cumulative data for period

01-01-2020-31-12-2020

Comparison between count of sources & kg/year, by reading range

Comparison between count of sources & kg/year, by sources

Total overview by chemicals

Paragraph Graphs Cumul

page 103 of 121

Graph6.3.1

page 104 of 121

Graph6.3.2

page 105 of 121

Graph6.3.3

page 106 of 121

Graph6.3.4

page 107 of 121

General

Calibration loglist

Calibration gas certificates

Composition list & Response Factors

Quarterly production hours

Quarterly equipment check

Paragraph General

page 108 of 121

Calibration log list

Plant

Round Equipment Analyzer

Type

Type

Ultra-Zero

Span Gas

Span gas Cylinder

Span

Check gas Check gas Cylinder

Check gas

No

concentration

No

concentration

Date

Equipment

No

Equipment

Serial

No

Check

Calibration Result

error

1-st 2-st 3-st

check check check

(A1) (A2) (A3)

(CP)

ppm ppm ppm

(A)

ppm

ppm

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

01-Mar-2020

2

0115248185

513

513

512

1.72%

OK

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF524456

504

08-Mar-2020

2

0115248185

510

509

510

1.12%

OK

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

FF51428

1,000

Methane

FF16599

501

08-Mar-2020

3

0115248937

501

501

500

-0.27%

OK

TASHAN

2

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

31-Mar-2020

3

0115248937

507

503

501

-0.07%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

21-May-2020

5

202016061436 503

503

502

-0.26%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

21-May-2020

1

0715622657

514

514

513

1.92%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

27-May-2020

5

202016061436 504

506

506

0.26%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

27-May-2020

1

0715622657

509

509

509

0.99%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF32161

510

18-Jun-2020

2

0115248185

507

506

506

-0.72%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF32161

510

18-Jun-2020

1

0715622657

509

507

506

-0.52%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF524456

504

28-Jun-2020

5

202016061436 501

503

502

-0.40%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF524456

504

28-Jun-2020

3

0115248937

512

512

510

1.46%

OK

TASHAN

3

TVA2020

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF524456

504

05-Jul-2020

5

202016061436 502

504

501

-0.33%

OK

TASHAN

3

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF524456

504

05-Jul-2020

1

0715622657

507

508

504

0.46%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

21-Jul-2020

2

0115248185

499

510

506

0.20%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

21-Jul-2020

3

0115248937

492

497

488

-2.31%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

30-Aug-2020

8

05355151349

509

511

508

1.06%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

31-Aug-2020

3

0115248937

502

504

501

-0.33%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

31-Aug-2020

8

05355151349

509

507

507

0.73%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

01-Sep-2020

3

0115248937

487

488

487

-3.31%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

01-Sep-2020

8

05355151349

505

504

504

0.07%

OK

TASHAN

4

TVA1000B

FID

Air, THC < 0.5ppm

Methane

ET0022865

995

Methane

FF524456

504

08-Sep-2020

1

0715622657

479

480

480

-4.83%

OK

TASHAN

1

TVA2020

FID

Air, THC < 0.5ppm

Methane

ET0022842

995

Methane

FF524456

504

02-Dec-2020

5

202016061436 506

508

502

0.26%

OK

Cal-Log

page 109 of 121

Certificate

page 110 of 121

Certificate

page 111 of 121

Certificate

page 112 of 121

Certificate

page 113 of 121

Certificate

page 114 of 121

Certificate

page 115 of 121

Stream Composition Summary

Stream Name

Stream Content

Stream Content

Dates

TVA

Gasoline

TOLUENE-34 %, n-Octane-40 %, METHYL TERT-BUTYL ETHER-10 %,

CYCLOHEXANE-5 %, BENZENE-1 %, 1-Butene-10 %

A=0.42, B=0.29

Petroleum

TOLUENE-7.5 %, n-Octane-55.3 %, CYCLOHEXANE-35.2 %, BENZENE-2 %

A=0.39, B=0.31

Stream Summary

MiniRAE 10.6 MiniRAE 11.7

page 116 of 121

Quarterly Validation of LDAR Devices

Date: 29‐Dec‐2019

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Analyzer

Span Gas

Sampling Flow

Rate

1

Check

Sampling

Span Gas

Flow

Span gas

Concentration

Result Check Gas

Rate

Cylinder No

ppm

l/min

Accuracy Check

Response Time

Comparison between two Devices

90%

Check Gas

Response Response Response

Second

of

Check gas

1‐st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Time 1 Time 2 Time 3 Result

Result

Device

Result

Span

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

ET0022842

995

1.14

OK

Methane

FF524456

504

503 506 507

0.26%

OK 895.5

4

3

4

OK

2.71

2.85

‐0.14

4.91%

OK

2

0115248185

TVA1000B

FID

Methane

ET0022842

995

0.98

OK

Methane

FF524456

504

498 497 496

‐1.39%

OK 895.5

4

3

4

OK

2.01

2.15

‐0.14

6.51%

OK

3

0115248937

TVA1000B

FID

Methane

ET0022842

995

1.1

OK

Methane

FF524456

504

503 504 502

‐0.2%

OK 895.5

3

4

4

OK

1.12

1.4

‐0.28

20%

OK

5

202016061436

TVA2020

FID

Methane

ET0022842

995

1.17

OK

Methane

FF524456

504

494 497 495

‐1.72%

OK 895.5

4

3

4

OK

2.8

2.44

0.36

‐14.75%

OK

6

7

110219070002

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.51

OK

Isobutylene 995‐286088

500

505 505 504

0.79%

OK 898.2

4

4

4

OK

3

3.1

‐0.1

3.23%

OK

NEO

PID

Isobutylene

EA0009962

997

0.45

OK

Isobutylene 995‐286088

500

511 510 510

1.92%

OK 898.2

3

3

3

OK

3.1

3

0.1

‐3.33%

OK

Quarterly Validation

page 117 of 121

Quarterly Validation of LDAR Devices

Date: 02‐Apr‐2020

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Analyzer

Span Gas

Sampling Flow

Rate

Accuracy Check

Response Time

Comparison between two Devices

2

Check

Sampling

90%

Span Gas

Check Gas

Response Response Response

Second

Flow

of

Span gas

Check gas

1‐st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Concentration

Time 1 Time 2 Time 3 Result

Result Check Gas

Result

Device

Result

Rate

Span

Cylinder No

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

l/min

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

ET0022842

995

0.94

OK

Methane

FF16599

501

506 502 503

0.33%

OK 895.5

4

3

4

OK

2.35

2.01

0.34

‐16.92%

OK

2

0115248185

TVA1000B

FID

Methane

ET0022842

995

0.89

OK

Methane

FF16599

501

504 501 498

‐0.2%

OK 895.5

3

4

3

OK

1.22

1.4

‐0.18

12.86%

OK

3

0115248937

TVA1000B

FID

Methane

ET0022842

995

0.94

OK

Methane

FF16599

501

497 499 502

‐0.53%

OK 895.5

4

4

3

OK

2.15

1.9

0.25

‐13.16%

OK

5

202016061436

TVA2020

FID

Methane

ET0022842

995

1.11

OK

Methane

FF16599

501

508 501 509

0.8%

OK 895.5

4

4

4

OK

2.5

2.31

0.19

‐8.23%

OK

6

7

110219070002

MiniRAE2000

PID

Isobutylene

EA0009962

997

0.5

OK

Isobutylene 995‐286088

500

505 505 504

0.79%

OK 898.2

4

4

4

OK

2.1

2.3

‐0.2

8.7%

OK

NEO

PID

Isobutylene

EA0009962

997

0.47

OK

Isobutylene 995‐286088

500

511 510 510

1.92%

OK 898.2

3

3

3

OK

1.9

1.7

0.2

‐11.76%

OK

Quarterly Validation

page 118 of 121

Quarterly Validation of LDAR Devices

Date: 06‐Jul‐2020

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Analyzer

Span Gas

Sampling Flow

Rate

Accuracy Check

Response Time

Comparison between two Devices

3

Check

Sampling

90%

Span Gas

Check Gas

Response Response Response

Second

Flow

of

Span gas

Check gas

1‐st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Concentration

Time 1 Time 2 Time 3 Result

Result Check Gas

Result

Device

Result

Rate

Span

Cylinder No

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

l/min

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

ET0022842

995

0.93

OK

Methane

FF32161

510

504 506 507

‐0.85%

OK 895.5

4

4

3

OK

2.12

2.18

‐0.06

2.75%

OK

2

0115248185

TVA1000B

FID

Methane

ET0022842

995

0.92

OK

Methane

FF32161

510

510 512 511

0.2%

OK 895.5

3

4

4

OK

2.55

2.31

0.24

‐10.39%

OK

3

0115248937

TVA1000B

FID

Methane

ET0022842

995

1.13

OK

Methane

FF32161

510

499 501 503

‐1.76%

OK 895.5

4

4

4

OK

1.79

1.55

0.24

‐15.48%

OK

5

202016061436

TVA2020

FID

Methane

ET0022842

995

0.97

OK

Methane

FF32161

510

507 508 508

‐0.46%

OK 895.5

3

4

4

OK

2.33

2.84

‐0.51

17.96%

OK

MiniRAE2000

PID

Isobutylene

EA0010369

996

0.5

OK

Isobutylene 995‐286088

500

514 513 513

2.52%

OK 896.9

4

3

3

OK

1.5

1.4

0.1

‐7.14%

OK

6

7

110219070002

NEO

PID

Isobutylene

EA0010369

996

0.49

OK

Isobutylene 995‐286088

500

511 511 510

1.99%

OK 896.9

5

5

5

OK

1.4

1.5

‐0.1

6.67%

OK

8

05355151349

TVA1000B

FID

Methane

ET0022842

995

0.91

OK

Methane

510

511 510 510

0.07%

OK 895.5

4

4

4

OK

3.18

3.22

‐0.04

1.24%

OK

Quarterly Validation

FF32161

page 119 of 121

Quarterly Validation of LDAR Devices

Date: 23‐Sep‐2020

Equipment No Equip.Ser. No

Quarter:

Equipment

Type

Analyzer

Span Gas

Sampling Flow

Rate

Accuracy Check

Response Time

Comparison between two Devices

4

Check

Sampling

90%

Span Gas

Check Gas

Response Response Response

Second

Flow

of

Span gas

Check gas

1‐st 2nd 3rd Calibration

Instrument

Difference Difference

Concentration

Concentration

Time 1 Time 2 Time 3 Result

Result Check Gas

Result

Device

Result

Rate

Span

Cylinder No

Cylinder No

check check check error

Reading

ppm

%

Reading

ppm

l/min

ppm

ppm

sec

sec

sec

1

0715622657

TVA1000B

FID

Methane

ET0022842

995

0.92

OK

Methane

FF32161

510

507 509 511

‐0.2%

OK 895.5

4

4

4

OK

2.1

2.24

‐0.14

6.25%

OK

2

0115248185

TVA1000B

FID

Methane

ET0022842

995

0.9

OK

Methane

FF32161

510

517 515 516

1.18%

OK 895.5

4

4

4

OK

1.47

1.3

0.17

‐13.08%

OK

3

0115248937

TVA1000B

FID

Methane

ET0022842

995

1.19

OK

Methane

FF32161

510

506 506 505

‐0.85%

OK 895.5

4

4

4

OK

1.81

1.99

‐0.18

9.05%

OK

5

202016061436

TVA2020

FID

Methane

ET0022842

995

0.99

OK

Methane

FF32161

510

501 501 502

‐1.7%

OK 895.5

4

4

4

OK

2.45

2.1

0.35

‐16.67%

OK

MiniRAE2000

PID

Isobutylene

EA0010369

996

0.49

OK

Isobutylene 995‐286088

500

502 502 503

0.33%

OK 896.9

6

6

5

OK

1.3

1.44

‐0.14

9.72%

OK

6

7

110219070002

NEO

PID

Isobutylene

EA0010369

996

0.47

OK

Isobutylene 995‐286088

500

499 499 499

‐0.34%

OK 896.9

3

3

3

OK

1.44

1.3

0.14

‐10.77%

OK

8

05355151349

TVA1000B

FID

Methane

ET0022842

995

0.95

OK

Methane

FF32161

510

509 508 508

‐0.33%

OK 895.5

4

3

4

OK

2.55

2.16

0.39

‐18.06%

OK

9

33461300

TVA1000B

FID

Methane

FF51428

1,000

1.26

OK

Methane

FF32161

510

497 501 500

‐2.09%

OK

3

3

3

OK

1.58

1.68

‐0.1

5.95%

OK

Quarterly Validation

900

page 120 of 121

CUMULATIVE PRODUCTION HOURS TEMPLATE 2020

Plant

TASHAN

Unit

Drawing

Stream Name

Remark

Annual Production

Hours

Alroy

6006-100-006

Gasoline

8,784

Alroy

6006-100-007

Gasoline

8,784

Production Hours

Q1

01/01-31/03

Quarter =

Quarterly Production

hours

2,184

2,184

Q2

01/04-30/06

Quarter =

Quarterly Production

hours

2,184

2,184

Q3

01/07-30/09

Quarter =

Quarterly Production

hours

2,208

2,208

Q4

01/10-31/12

Quarter =

Quarterly Production

hours

2,208

2,208

page 121 of 121

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין

3013.17-034-T2

3013.17-025

28/02/2021

18/30

3013.17-036.doc

T2 - kerosene

External Floating roof

1. Tank data

Diameter of the tank

D

Effective height of the stock liquid (while

roof landing episode)

hle

Shell Color and condition

α

Roof color and condition

α

Tank paint solar absorptance

α

Vapor space outage (while roof landing

episode)

HVO

m

feet

m

feet

color

condition

color

condition

dimensionless

m

Tank data

--Tank data

--חום

טובה

לבן

טוב

48.77

160.01

11.00

0.58

Table 7.1-6

Brown

0.17

Table 7.1-6

0.38

Table 7.1-6

Possible to use also equation

1-15

assumption - equal to legs height

feet

11.00

Volume of the vapor space (while roof

landing episode)

Breather vent pressure setting

VV

ft

3

VV=PI()*D /4*Hvo

221,185

Equation 1-3

ΔPBP

psi

Typical value

0.50

Equation 1-11

Breather vent vacuum setting

ΔPBV

psi

Typical value

0.00

Equation 1-11

Breather vent pressure setting range

ΔPB

psi

PB  PBP  PBV

0.50

Equation 1-11

2

2. Material data - קרוסין

Stock vapor molecular weight

MV

Density of the liquid inside the tank

Wl

Vapor density

WV

True vapor pressure of the stock liquid

P

Vapor pressure at daily average liquid

surface temperature

Vapor pressure at the daily maximum

liquid surface temperature, psia

Vapor pressure at the daily minimum

liquid surface temperature

Daily vapor pressure range

3013.17-034.xls - 2

gr/gr-mole

lb/lb-mole

g/ml

lb/gal

kg/m^3

lb/ft3

msds data

130

msds data

--msds data

---

0.80

6.68

4.5

0.28

mm Hg

PEI data

0.833

psia

--הנחה:

Pv=nRT -->

P2=P1*(T2/T1)

0.02

0.02

0.02

0.00

PVA

psia

PVX

psia

PVN

psia

T1(k)=20C+273

T2(k)=37.5C+273

ΔPV

psia

 PV  PVX  PVN

1/3

0

at 20°C

0.02

Equation 1-9

28/02/2021

3. Operation data

Number of days that the tank stands idle

(on roof landing episode)

Number of degassing and cleaning

episode

Number of roof landing episode

nd

days/landing episode

site data

4

landing episode/year

site data

0.07

landing episode/year

site data

0.07

Tanks Program

--Tanks Program

---

75

34

111

50

16

T2 - B&W 2020

Tanks Program

---

59.04

27

T2 - DFloating 2019

lb per emptying

Tanks Program

61

Kg per emptying

---

28

4. Normal operation (Tanks program)

lb per year

Kg per year

lb per year

Kg per year

Kg per year

Working (withdrawal) losses

Total emissions (Breathing & Working)

Breathing (standing) losses

5. Degassing and Cleaning (Tanks program)

Degassing: emission from one turnover

Edegass-floating lb per emptying

of floating roof

Kg per emptying

Degassing: fixed roof with a height of

roof legs

Edegass-legs

Liquid fraction in sludge

Fliquid

Sludge volume

Sludge weight

Vs

Ws

Cleaning emissions

Ecleaning

Total Degassing and Cleaning emissions

Edegass-total

3013.17-034.xls - 2

0.8

m3 per emptying

Kg per emptying

lb per emptying

Kg per emptying

lb per emptying

Kg per emptying

Ecleaning = Ws * (1-Fliquid)

Edegass-total =

Edegass-floating + Edegass-legs + Ecleaning

2/3

T2 - B&W 2020

T2- DFixed 2019

(Only working losses)

Tanks FAQ - degassing and

cleaning

70

56,000

24,692

11,200

24,811

11,254

28/02/2021

6. Roof landing

Daily average liquid surface temperature

TLA

°R

Daily vapor temperature range

Daily maximum liquid surface

temperature

ΔTV

°R

TLX

Daily minimum liquid surface temperature

Liquid bulk temperature

Max standing idle losses during roof

landing

T LA  0 .44 T AA  0 .56 T B  0 .0079 *  * I

532.17

Equation 1-26

 TV  0.72 T A  0.028 *  * I

32.95

Equation 1-8

°R

TLX = TLA + 0.25*ΔTV

540.41

Figure 7.1-17

TLN

°R

TLN = TLA - 0.25*ΔTV

523.93

Figure 7.1-17

TB

°R

527.22

Equation 1-28

LSL-max

lb per landing episode

Kg per landing episode

TB = TAA + 6α - 1

LSL-max = 5.9*D2*hle*W l

--0.60 for a full liquid heel

0.50 for a partial

0.15 for drain-dry

11,093,038 Equation 2-13

5,031,769

0.50

Equation 2-26

(pages No 33,35)

1

KS 

1  0.053 * PVA * H VO

0.5

Equation 1-20

KS is assumed to be less than

or equal to the saturation

factor during filling (S) .

 TV  PV   PB

T LA

PA  PVA

0.028

Liquid stock has a true vapor

pressure greater than 0.1psia Equation 1-7.

Filling saturation factor

S

dimensionless

saturation factor

KS

dimensionless

Vapor space expansion factor

KE

dimensionless

Standing idle losses during roof landing

LSL

lb per landing episode

 PV 

L SL  n d K E  V  M V K S

 RT AA 

5

Equation 2-16

Filling losses during roof landing

LFL

lb per landing episode

 P * VV 

 M V * S

L FL  

 R * T AA 

41

Equation 2-26

Total losses during roof landing

LTL

lb per landing episode

Kg per landing episode

46

21

Equation 2-10

KE 

LTL=LSL+LFL

7. Summary

Working (withdrawal) losses

Breathing (standing) losses

Kg per year

Kg per year

34

16

Total Degassing and Cleaning emissions

Kg per year

750

Total losses during roof landing

Kg per year

1

802

3013.17-034.xls - 2

3/3

Kg per year

28/02/2021

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - B&W 2020

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.34

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Aluminum/Diffuse

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

28/02/2021

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - B&W 2020 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

All

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

76.52

65.35

87.69

Liquid

Bulk

Temp

(deg F)

68.86

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0136

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

28/02/2021

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - B&W 2020 - External Floating Roof Tank

Haifa, Israel

Annual Emission Calcaulations

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

0.0136

160.0100

130.0000

1.0000

Withdrawal Losses (lb):

Annual Net Throughput (gal/yr.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

75.2122

10,209,723.0000

0.0075

7.0000

160.0100

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

0.8398

0.0002

130.0000

1.0000

27.8819

6.2000

Total Losses (lb):

110.5526

34.5005

1.6000

0.3000

6.2000

1.6000

0.0002

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

KFa(lb-mole/yr)

1.60

6.20

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

1.20

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.94

1.00

Losses(lb)

0.1446

0.6608

0.0345

28/02/2021

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

28/02/2021

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - B&W 2020 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

34.50

75.21

0.84

0.00

110.55

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

28/02/2021

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

28/02/2021

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFixed 2019

Haifa

Israel

PEI

Vertical Fixed Roof Tank

kerosene

Tank Dimensions

Shell Height (ft):

Diameter (ft):

Liquid Height (ft) :

Avg. Liquid Height (ft):

Volume (gallons):

Turnovers:

Net Throughput(gal/yr):

Is Tank Heated (y/n):

N

Paint Characteristics

Shell Color/Shade:

Shell Condition

Roof Color/Shade:

Roof Condition:

Aluminum/Diffuse

Good

White/White

Good

Roof Characteristics

Type:

Height (ft)

Slope (ft/ft) (Cone Roof)

Breather Vent Settings

Vacuum Settings (psig):

Pressure Settings (psig)

11.00

160.01

11.00

5.50

1,654,664.74

1.00

1,654,664.74

Cone

0.00

0.00

0.00

0.50

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

Apr

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

72.10

62.74

81.45

Liquid

Bulk

Temp

(deg F)

67.57

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0118

0.0092

0.0159

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

02/02/2020

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Month:

Standing Losses (lb):

Vapor Space Volume (cu ft):

Vapor Density (lb/cu ft):

Vapor Space Expansion Factor:

Vented Vapor Saturation Factor:

January

February

March

April

May

June

July

August

September

October

November

December

Tank Vapor Space Volume:

Vapor Space Volume (cu ft):

Tank Diameter (ft):

Vapor Space Outage (ft):

Tank Shell Height (ft):

Average Liquid Height (ft):

Roof Outage (ft):

Roof Outage (Cone Roof)

Roof Outage (ft):

Roof Height (ft):

Roof Slope (ft/ft):

Shell Radius (ft):

Vapor Density

Vapor Density (lb/cu ft):

Vapor Molecular Weight (lb/lb-mole):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Daily Avg. Liquid Surface Temp. (deg. R):

Daily Average Ambient Temp. (deg. F):

Ideal Gas Constant R

(psia cuft / (lb-mol-deg R)):

Liquid Bulk Temperature (deg. R):

Tank Paint Solar Absorptance (Shell):

Tank Paint Solar Absorptance (Roof):

Daily Total Solar Insulation

Factor (Btu/sqft day):

Vapor Space Expansion Factor

Vapor Space Expansion Factor:

Daily Vapor Temperature Range (deg. R):

Daily Vapor Pressure Range (psia):

Breather Vent Press. Setting Range(psia):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Vapor Pressure at Daily Minimum Liquid

Surface Temperature (psia):

Vapor Pressure at Daily Maximum Liquid

Surface Temperature (psia):

Daily Avg. Liquid Surface Temp. (deg R):

Daily Min. Liquid Surface Temp. (deg R):

Daily Max. Liquid Surface Temp. (deg R):

Daily Ambient Temp. Range (deg. R):

Vented Vapor Saturation Factor

Vented Vapor Saturation Factor:

Vapor Pressure at Daily Average Liquid:

Surface Temperature (psia):

Vapor Space Outage (ft):

Working Losses (lb):

Vapor Molecular Weight (lb/lb-mole):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Net Throughput (gal/mo.):

Annual Turnovers:

Turnover Factor:

Maximum Liquid Volume (gal):

Maximum Liquid Height (ft):

Tank Diameter (ft):

Working Loss Product Factor:

Total Losses (lb):

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Losses(lbs)

Components

Working Loss

Breathing Loss

Total Emissions

Jet kerosene

60.63

32.78

93.41

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFloating 2019

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.00

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Aluminum/Diffuse

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

Apr

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

76.46

63.88

89.04

Liquid

Bulk

Temp

(deg F)

68.86

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0136

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

02/02/2020

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Month:

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

January

February

March

April

May

June

July

August

September

October

November

December

Withdrawal Losses (lb):

Net Throughput (gal/mo.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

Total Losses (lb):

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

KFa(lb-mole/yr)

1.60

6.20

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

1.20

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.94

1.00

Losses(lb)

0.0000

0.0000

0.0000

02/02/2020

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

2.99

55.99

0.07

0.00

59.04

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

נספח ד'

חישוב פליטות ממיכל לאיסוף תשטיפים

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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב א')

28/02/2021

24/30

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25/30

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26/30

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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב ב')

28/02/2021

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28/30

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חישובי פליטה ממיכל תשטיפים

גיליון חישוב זה הוכן על ידי "פז" הנדסה וניהול ( )1980בע"מ.

אין להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ( )1980בע"מ.

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30/30

3013.17-036.doc

מסמך 10 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 6058 KB)

תשתיות פט וא רגיה בע"מ

מסוף אלרואי

סיכום פליטות לאוויר

ש ת 2021

פרויקט3013.18 :

סימוכין3013.18-036 :

פברואר 2022

תוכן ע יי ים

.1מבוא 4.............................................................................................................................

.2תו י מסוף 5.....................................................................................................................

.2.1תו י מיכלים 5.........................................................................................................

.2.2תו ים עבור מסוף מילוי מיכליות כביש 9.....................................................................

.3חישוב פליטות 10 ..............................................................................................................

.3.1כללי10 ......................................................................................................................... ...

.3.2סוגי פליטות מחושבות 10 ..................................................................................................

.3.3בחירת חומרים בתוכ ת 11 ................................................................................... TANKS

.3.4תו ים מטאורולוגיים11 ....................................................................................................

.4סיכום פליטות לש ת 12 ............................................................................................. 2021

.4.1מיכלים 12 ........................................................................................................................

.4.2מסוף מילוי מיכליות כביש 12 .............................................................................................

.4.3מיכל איסוף תשטיפים 13 ...................................................................................................

.4.4סיכום ממצאי יטור 13 .......................................................................................... LDAR

.4.5פליטה ש תית מכלל המתקן 13 ...........................................................................................

.5פליטות לא שגרתיות במהלך ש ת 13 ............................................................................2021

.6מקורות 14 .......................................................................................................................

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3013.18-036.doc

טבלאות

טבלה :1תו י מיכלים – מידע כללי ,מידות ו תו י תפעול – ש ת 5........................................... 2021

טבלה :2תו י מעטפת וגגות – ש ת 6.................................................................................. 2021

טבלה :3תו י אביזרים – ש ת 7......................................................................................... 2021

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכ ת 8................................................... TANKS

טבלה :5תו ים עבור מסוף מילוי מיכליות כביש – ש ת 9...................................................... 2021

טבלה :6חומרים מייצגים בתוכ ת 11 ............................................................................ TANKS

טבלה :7סיכום פליטות מכלים -ש ת 12 ............................................................................ 2021

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -ש ת 12 ..................................................2021

ספחים

ספח א'

טבלה (AP-42) 1-5.2

ספח ב'

תו י יטור LDARעבור מסוף אלרואי – סיכום ש ת 2021

ספח ג'

דוגמת חישוב עבור מיכל גג חיצו י צף מס' 2המאחסן קרוסין

ספח ד'

חישוב פליטות ממיכל לאיסוף תשטיפים

מירה ליה-זיו איסקוב

שם עורך

28/02/2022

יואב פיסטי ר

שם מאשר

28.02.2022

תאריך

3/30

להערות

תיאור

0

גרסה

3013.18-036.doc

.1מבוא

חברת תשתיות פט וא רגיה בע"מ )להלן תש"ן( מפעילה את מסוף אלרואי לאחסון ושי וע

דלקים .

המסוף כולל:

מב י משרדים

חוות מכלים לאחסון דלקים מסוגים שו ים

רציפי מילוי מכליות כביש )לשימוש בעת חירום בלבד(

המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכו ת

אלרואי ומדרום לו שכו ת קרית חרושת.

באתר 9מיכלים ,מתוכם 7מכלים תפעוליים ו 2-מכלים המשמשים כמכלים אסטרטגיים

)מכלים מס' 1ו.(9-

מערכת השי וע הי ה באמצעות משאבות ובקרת מילוי וב וסף קיימות מערכות תומכות כגון

מערכות כיבוי אש ומערכות פיקוד ובקרה.

כחלק מהת אים ברישיון עסק מדצמבר ,2010בסוף כל ש ה קל דרית על תש"ן להגיש דו"ח

סיכום פליטות ש תי לגבי הש ה שחלפה.

חישובי הפליטות בוצעו בעזרת תוכ ת Tanksומסמכי EPA-AP 42על פי תו י המתק ים

הקיימים במסוף.

סיכום הפליטות הוכן על ידי חברת "פז" ה דסה ו יהול ) (1980בע"מ )להלן פז ה דסה( ,והוא

מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות יטור LDARשהוגשו לרשויות.

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.2תו י מסוף

.2.1תו י מיכלים

בטבלאות הבאות מפורט מידע טכ י של המיכלים בחוות המיכלים אלרואי.

טבלה :1תו י מיכלים – מידע כללי ,מידות ו תו י תפעול – ש ת 2021

לחץ אדים

בטמפ' ה וזל

הממוצעת

)(mmHg

405 @ 28°C

כמות

צריכה

ש תית

)מ"ק(

0

גבעה חלקית

19,692

גבעה חלקית

48.77

גבעה חלקית

48.77

32,056

48.77

32,056

28,768

56,959

51,614

15.56

51,614

15.56

14.1

15.56

14.1

11.4

18.3

18.3

15.4

9.7

סוג יקוז

בתחתית

מיכל

קוטר

מיכל

)מטר(

פח מיכל

)מ"ק(

פח מיכל

פעיל

)מ"ק(

48.77

32,056

28,768

גובה /אורך

מעטפת

מיכל

)מטר(

17.16

15.4

32,056

28,768

17.16

15.4

10

28,768

17.16

15.4

9.5

17.16

15.4

10.3

14.1

14.1

14.1

מספר

מיכל

סוג הדלק

המאוחסן

(1) 1

ב זין

2

קרוסין

0.833 @ 28°C

3

סולר

0.507 @ 28°C

23,194

4

סולר

0.507 @ 28°C

56,674

גבעה חלקית

5

סולר

0.507 @ 28°C

11,986

גבעה מלאה

68.27

(1) 6

סולר

0.507 @ 28°C

0

גבעה מלאה

68.27

56,959

(1) 7

סולר

0.507 @ 28°C

0

גבעה מלאה

68.27

56,959

51,614

(1) 8

קרוסין

0.833 @ 28°C

0

גבעה חלקית

48.8

36,547

34,228

19.54

(1) 9

קרוסין

0.833 @ 28°C

0

גבעה חלקית

48.77

32,056

28,768

17.16

367,704

332,913

111,547

סה"כ

) (1מכלים מס' 8 ,7 ,6 ,1ו 9-משמשים כמכלי מלאי ,לא היו ת ועות במכלים בש ת .2021

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גובה וזל

מירבי

)מטר(

גובה וזל

ממוצע

)מטר(

10.5

טבלה :2תו י מעטפת וגגות – ש ת 2021

מספר

מיכל

סוג גג

אטם ראשי

אטם מש י

1

גג צף

חיצו י

גג צף

חיצו י

גג צף

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גג צף

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גג צף

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גג צף

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גג צף

חיצו י

גג צף

חיצו י

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Liquid

mounted

Mechanical

Shoe

Rim

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Rim

mounted

Rim

mounted

2

3

4

5

6

7

8

9

28/02/2022

צורת גג

סוג

חיבורי

גג

צבע

גג

מצב

צבע

גג

צבע

מעטפת

חיצו ית

מצב צבע

מעטפת

חיצו ית

סוג חיבורי

מעטפת

מצב

מעטפת

פ ימית

מיכל

מחומם

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חום

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חום

ישן

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

כחול בהיר

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

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טבלה :3תו י אביזרים – ש ת 2021

מספר

מיכל

1

2

3

4

5

6

7

8

9

סה"כ

שובר ואקום

כמות

2

2

2

2

2

2

2

6

2

Vacuum

]set. [psi

0

0

0

0

0

0

0

0

0

Pressure

]set. [psi

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

רגליים מתכוו ות התומכות

בגג צף)(1

גובה כמות באזור

כמות

במרכז

)(ft

pontoon

29

43

11

29

43

11

29

43

11

29

43

11

72

107

11

72

107

11

72

107

11

36

54

9

29

43

11

כמות

מדי

מפלס

Rim

Vent

כמות בוצה

ב קיון

)מ"ק(

"גרביים" לבאר

הדיגום המחורצת

ולרגלי הגג הצף)(1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

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1

6

70

70

70

70

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150

150

70

70

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יש

יש

יש

) (1ה "ל לא לקחו בחשבון בחישוב הפליטות מתוכ ת ה TANKS-מפ י ש דגמו במסגרת יטורי ה.LDAR-

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ה חות ש לקחו לצורך החישובים

.1עבור חישוב Degassingבמיכל עם גג צף – הו ח:

גג צף ח על רגליים בגובה ) 9-11 ftבהתאם לטבלה לעיל( וזהו גם הגובה המרבי של ה וזל

במיכל.

גובה ממוצע של ה וזל במיכל הי ו 50%מגובה ה וזל המרבי.

.2הו ח כי יקיון כללי וריקון של המיכלים מתבצע אחת ל 15-ש ים .ה יקיון יארך יום אחד.

.3הו ח כי אירוע של חיתת גגות צפים מתבצע אחת ל 15-ש ים .זמן חיתת הגג במקרה זה לא

יעלה על 4ימים.

.4יחס ה וזל בבוצה הו ח כ[2] 0.8 -

.5בהתאם לטבלה 7.1-6על פי ] ,[1בחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,

לצורך חישובי פליטות לאוויר:

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכ ת Tanks

צבע מעטפת

מיכל

צבע לצורך חישובי אקסל

צבע לצורך חישובים בתוכ ת

בהתאם למסמך EPA AP-42

(*) Tanks

כחול בהיר

Gray Medium

Gray Medium

Brown

Aluminium/Diffuse

Beige/Cream

Aluminium/Specular

White

White

חום

צהוב קרם

לבן

)*( בתוכ ת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך

.[1] EPA AP-42

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.2.2תו ים עבור מסוף מילוי מיכליות כביש

טבלה :5תו ים עבור מסוף מילוי מיכליות כביש – ש ת 2021

מס'

זרוע

1

2

3

4

5

6

7

8

מוצר

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

סה"כ

מילוי

עילי /תחתי

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

פח מילוי ש תי

)מ"ק(

12

0

0

0

0

0

0

0

12

פח ממוצע של

מיכלית )מ"ק(

30

30

30

30

30

30

30

30

ה חות ש לקחו צורך החישובים

.1

מקדם (Tank paint solar absorptance) αממוצע עבור קרוסין חושב כדלקמן:

א .בשלב ראשון חושב המקדם αעבור כל אחד ממיכלי הקרוסין:

דוגמת חישוב עבור מיכל מס' :2

ב .בשלב הש י חושב מקדם αממוצע עבור הקרוסין:

.2

זמן מילוי מיכלית חושב על פי פח ממוצע של מיכלית וקצב מילוי שעתי מרבי של 1000

ליטר/דקה.

.3

Vapor collection efficiency - 70%

.4

Vapor recovery efficiency - 0%

.5

Saturation factorהו ח כ (Submerged loading, dedicated normal service) 0.6-על פי

] .[1טבלה רלוו טית מצורפת ב ספח א'.

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.3חישוב פליטות

.3.1כללי

חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכ ת Tanksובעזרת .[1] EPA-AP 42

הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ) (LDARמצורפת ב ספח ב'.

דוגמת חישוב עבור מיכל גג חיצו י צף )מיכל מס' (2המאחסן קרוסין ,מצורפת כ ספח ג' למסמך

זה.

בדוגמאות אלה יתן לראות את תו י הקלט )כולל ה חות( עליהם התבססו החישובים.

.3.2סוגי פליטות מחושבות

הערכת הפליטות ממיכלי אחסון כוללת ]:[3

פליטות בזמן אחסון )(Breathing Losses

פליטות משי ויי מפלס )(Working Losses

פליטות כתוצאה מ יקוי וריקון מיכלים )(Degassing Losses

פליטות כתוצאה מ חיתת גגות צפים )(Roof Landing Losses

פליטות כתוצאה מהפרשי לחץ )(Flash Losses

פליטות בזמן מילוי מיכלים ומיכליות

בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ

).(Flash Losses

פליטות אלה רלוו טיות לשי ויי פתאומי\מיידי בלחץ ה וזל ,תון הגורם להפרת שיווי המשקל

הקיים במיכל )בין גז ל וזל( וכתוצאה מכך וצר תהליך הבזקה ,בו מרכיבים קלים מפאזה ה וזל

עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר וזל המאוחסן בלחץ שלח

לאחסון במיכל בעל לחץ מוך יותר ].[3

פליטות אלו הוז חו כיוון שכל החומרים מוחזקים בת אים אטמוספריים בכל אחד מהשלבים

ה וגעים להובלתם ואחסו ם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.

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.3.3בחירת חומרים בתוכ ת Tanks

על פי תו י MSDSשל הדלקים במסוף ,בחרו החומרים הבאים הקיימים בתוכ ת Tanks

כמייצגים של חומרים אלו:

טבלה :6חומרים מייצגים בתוכ ת Tanks

דלק קיים במסוף

חומר מייצג בתוכ ת Tanks

סולר )תחבורה והסקה(

Distillate fuel oil no 2

פט )קרוסין(

Jet kerosene

ב זין

Gasoline RVP 10

.3.4תו ים מטאורולוגיים

לצורך חישוב ה תו ים בתוכ ת Tanksהוגדרו תו ים מטאורולוגים המתאימים למפרץ חיפה על פי

מקורות ].[4

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.4סיכום פליטות לש ת 2021

.4.1מיכלים

סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:

טבלה :7סיכום פליטות מכלים -ש ת 2021

מיכל

חומר

פליטות לאוויר

)ק"ג/ש ה(

1

ב זין

3,603

2

קרוסין

785

3

סולר

31

4

סולר

848

5

סולר

1,701

6

סולר

1,693

7

סולר

1,693

8

קרוסין

756

9

קרוסין

758

11,867

סה"כ

.4.2מסוף מילוי מיכליות כביש

להלן טבלת סיכום חישובי פליטות עבור זרועות המילוי.

טבלה :8סיכום פליטות מסוף מילוי מיכליות כביש -ש ת 2021

פליטה ש תית

)ק"ג/ש ה(

מס' זרוע

מוצר

מילוי עילי /תחתי

1

2

3

4

5

6

7

8

סה"כ

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

0.04

0

0

0

0

0

0

0

0.04

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.4.3מיכל איסוף תשטיפים

סך הפליטה ממיכל לאיסוף תשטיפים הי ה כ 1 -ק"ג/ש ה.

חישוב מצורף ב ספח ד'.

יצוין כי החישוב מתבסס על ה חה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל

בעיקר יקוז מים מהמכלים.

.4.4סיכום ממצאי יטור LDAR

טבלה :9סיכום פליטות חומרים אורג ים דיפים עבור רכיבים בש ת 2021

סה"כ פליטות )ק"ג/ש ה(

סיכום פליטות LDAR

פליטה ש תית )ק"ג/ש ה(

סה"כ

6

.4.5פליטה ש תית מכלל המתקן

טבלה :10סיכום פליטות ש תי מכלל מסוף אלרואי – ש ת 2021

סה"כ פליטות )ק"ג/ש ה(

חוות מיכלים

מסוף מילוי

מיכליות כביש

מיכל לאיסוף

תשטיפים

11,867

0.04

1

סיכום פליטות

רכיבים

סה"כ

)(LDAR

6

11,874

.5פליטות לא שגרתיות במהלך ש ת 2021

במהלך ש ת 2021לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמי ל.

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.6מקורות

[1] EPA-AP42

[2] USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version

4.0 - APPENDIX D

] [3ה חיות להגשת בקשה להיתר פליטה ושי וי הפעלה משמעותי ה חיות הממו ה לטיפול בבקשה

להיתר פליטה לפי סעיף )9א( לתק ות אוויר קי )היתרי פליטה( ,התש"ע – ,2010מהדורה ,5

ובמבר 2020

] [4האטלס האקלימי לתכ ון פיסי וסביבתי בישראל ,מהדורה ש ייה1994 ,

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ספח א'

טבלה 5.2-1

AP-42

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3013.18-036.doc

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28/02/2022

ספח ב'

תו י יטור LDARעבור אלרואי – סיכום ש ת 2021

)מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך (17.02.2022

3013.18-004A

28/02/2022

17/30

3013.18-036.doc

LDAR

Fugi ve Emission Monitoring

Report No.

RL-E I-R1-6-21

Plant: Energy Infrastructures LTD

City: Haifa

District: Haifa

Production Unit: Alroy

Report printing date:

17-Feb-2022

Report editor:

Michael Ourievsky

Approved by:

Alexey Ratner

Table of Content

1. Executive Summary

2. Project introduction

2.1 Scope of work

2.2 Project phases

3. Monitoring Results

Table 3.1 – Overview by component class

Table 3.2 – Overview by reading range

Table 3.3 – Overview per Unit

Table 3.4 – Monitoring results, last known situation

Graph 3.5 – Total overview by chemicals

4. Historical overview

Table 4.1 – Historical overview by component class

Table 4.2 – Historical Overview by Unit

5. Detailed monitoring summary

Table 5.1 - Cumulative summary, Fugitive emission component classification and emission estimation for

production facilities

Table 5.2 – Chemical Summary by Component Class

Table 5.3 - LDAR report for production facilities

Table 5.4 - Components with more than 5 significant leaks detected during last 12 months

Graph 5.6 - Comparison between count of components & kg/year, by components

Graph 5.7 - Comparison between total annual emissions (kg/year), by class & year

6. Summary by monitoring period, Round 1

Table 6.1 - First measurements, overview by component class

Table 6.2 - First measurement, overview by reading range

Table 6.3 - Measurement after repair attempt, overview by component class

Table 6.4 - Measurement after repair attempt, Overview by reading range

Table 6.5 - Form 07: First measurement and measurement after repair

Table 6.6 - Chemical Summary by Component Class, First Measurement

Table 6.7 - Chemical Summary by Component Class, After Repair

Table 6.8 - LDAR report for production facilities

Graph 6.10 - Count of components & kg/year

Graph 6.11 - Overview by reading range

Graph 6.12 - Overview by chemicals

6. Summary by monitoring period, Round 2

Table 6.1 - First measurements, overview by component class

Table 6.2 - First measurement, overview by reading range

Table 6.3 - Measurement after repair attempt, overview by component class

Table 6.4 - Measurement after repair attempt, Overview by reading range

Table 6.5 - Form 07: First measurement and measurement after repair

Table 6.6 - Chemical Summary by Component Class, First Measurement

Table 6.7 - Chemical Summary by Component Class, After Repair

Table 6.8 - LDAR report for production facilities

Graph 6.10 - Count of components & kg/year

Graph 6.11 - Overview by reading range

Graph 6.12 - Overview by chemicals

6. Summary by monitoring period, Round 3

Table 6.1 - First measurements, overview by component class

Table 6.2 - First measurement, overview by reading range

Table 6.3 - Measurement after repair attempt, overview by component class

Table 6.4 - Measurement after repair attempt, Overview by reading range

Table 6.5 - Form 07: First measurement and measurement after repair

Table 6.6 - Chemical Summary by Component Class, First Measurement

Table 6.7 - Chemical Summary by Component Class, After Repair

Table 6.8 - LDAR report for production facilities

Graph 6.10 - Count of components & kg/year

Graph 6.11 - Overview by reading range

Graph 6.12 - Overview by chemicals

6. Summary by monitoring period, Round 4

Table 6.1 - First measurements, overview by component class

Table 6.2 - First measurement, overview by reading range

Table 6.3 - Measurement after repair attempt, overview by component class

Table 6.4 - Measurement after repair attempt, Overview by reading range

Table 6.5 - Form 07: First measurement and measurement after repair

Table 6.6 - Chemical Summary by Component Class, First Measurement

5

6

6

6

7

7

7

8

8

10

10

10

10

11

12

13

15

16

17

18

19

20

21

21

21

21

22

23

24

25

26

27

28

29

30

30

30

30

31

32

33

34

35

36

37

38

39

39

39

39

40

42

44

45

46

47

48

49

50

50

50

50

51

Table 6.7 - Chemical Summary by Component Class, After Repair

Table 6.8 - LDAR report for production facilities

Graph 6.10 - Count of components & kg/year

Graph 6.11 - Overview by reading range

Graph 6.12 - Overview by chemicals

6. Summary by monitoring period, Round 5

Table 6.1 - First measurements, overview by component class

Table 6.2 - First measurement, overview by reading range

Table 6.3 - Measurement after repair attempt, overview by component class

Table 6.4 - Measurement after repair attempt, Overview by reading range

Table 6.5 - Form 07: First measurement and measurement after repair

Table 6.6 - Chemical Summary by Component Class, First Measurement

Table 6.7 - Chemical Summary by Component Class, After Repair

Table 6.8 - LDAR report for production facilities

Graph 6.10 - Count of components & kg/year

Graph 6.11 - Overview by reading range

Graph 6.12 - Overview by chemicals

6. Summary by monitoring period, Round 6

Table 6.1 - First measurements, overview by component class

Table 6.2 - First measurement, overview by reading range

Table 6.3 - Measurement after repair attempt, overview by component class

Table 6.4 - Measurement after repair attempt, Overview by reading range

Table 6.5 - Form 07: First measurement and measurement after repair

Table 6.6 - Chemical Summary by Component Class, First Measurement

Table 6.7 - Chemical Summary by Component Class, After Repair

Table 6.8 - LDAR report for production facilities

Graph 6.10 - Count of components & kg/year

Graph 6.11 - Overview by reading range

Graph 6.12 - Overview by chemicals

7. Attachments

7.1 General Remarks

Table 7.1.1 Monitored components

Table 7.1.2 Unmonitored P&IDs

Table 7.2 Project schedule

7.3 Methodology

7.4 Calibration loglist

7.5 Calibration gas certificates

7.6 Stream Composition Summary

7.7 Quarterly Validation of LDAR Devices, Quater 1

7.8 Quarterly Validation of LDAR Devices, Quater 2

7.9 Quarterly Validation of LDAR Devices, Quater 3

7.10 Quarterly Validation of LDAR Devices, Quater 4

7.11 Cumulative production hours template

52

53

54

55

56

57

58

59

59

59

59

60

62

64

65

66

67

68

69

70

70

70

70

71

72

73

74

75

76

78

78

78

78

78

79

80

81

87

88

89

90

91

92

1. Executive Summary

The total number of active components at Energy Infrastructures LTD is 223.

Six rounds of measurements have been performed in 2021.

The total calculated emission from 01/01/2021 to 31/12/2021 is 6.08 kg.

The number of components above leak definition found from the beginning of the year – 0

The number of pegged readings (above 100,000 ppm) found from the beginning of the year - 0

The last known situation of Energy Infrastructures LTD indicates there are no leaks

5/92

2 Project introduction

2.1 Scope of work

Following measurements been performed in 2021:

Round

Round 1

Round 2

Round 3

Round 4

Round 5

Round 6

Unit

G1

Monitored group

G2

G3

Alroy

Alroy

Alroy

Alroy

Alroy

Alroy

2.2 Project phases

Monitoring

Re-measurement after repair

Revision of equipment and production processes

Inventorisation: adding or deleting components

General

1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory Accreditation Authority).

2. ISRAC is not responsible for the test results.

3. The following data is provided by the customer: production hours, P&IDs, and stream information.

6/92

3. Monitoring results

The table “Overview by component class” below shows the number of active components, number of leaks above leak definitions and number of components that are still leaking in each class

(according to the monitoring round), and total calculated emissions in the specified period.

Table 3.1 Overview by component class,

Component Class

01/01/2021-31/12/2021

Total

Components

count

Total Components above

leak definition

count

% of components above

leak definition

%

Unrepaired Components

Total Emissions

count

kg

Round 1

Round 2

Round 3

Round 4

Round 5

Round 6

Round 1

Round 2

Round 3

Round 4

Round 5

Round 6

Average

Round 1

Round 2

Round 3

Round 4

Round 5

Round 6

01/01/202131/12/2021

PRD

Sampling Point

Total Group 1:

Stem Valve

Open End

Total Group 2:

Flange

Connection

Total Group 3:

4

4

8

20

102

122

55

38

93

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.14

0.14

0.28

1.367

1.787

3.154

0.149

2.497

2.646

Total:

223

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

6.08

In table “Overview by reading range” all the components divided by their reading range at first measurement according to the monitoring round.

Table 3.2 Overview by reading range

Total Components

Reading Range

Round 1

#

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above leak definition

Difficult to Monitor

Total:

Round 2

%

8

0

0

0

0

0

0

0

8

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

Round 3

%

8

0

0

0

0

0

0

0

8

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

Round 4

%

223

0

0

0

0

0

0

0

223

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

Round 5

%

8

0

0

0

0

0

0

0

8

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

Round 6

%

130

0

0

0

0

0

0

0

130

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

%

8

0

0

0

0

0

0

0

8

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

7/92

Table 3.3 Overview per Unit, 01/01/2021-31/12/2021

Unit

Total

components

Components above leak definition

count

Alroy

Total:

R1

223

223

R2

0

0

R3

R4

0

0

R5

0

0

0

0

R6

0

0

Total emission

kg

01/01/202131/12/2021

0

6.08

0

6.08

Table 3.4 – Monitoring results, 01/01/2021-31/12/2021, last known situation.

The last known situation of Energy Infrastructures LTD indicates there are no leaks.

0 "difficult to monitor" sources.

223 default-zero sources (0ppm).

0 registered sources (1-999ppm).

0 components above leak definition

Component Class

Total

components

count

PRD

Sampling Point

Stem Valve

Open End

Flange

Connection

Total:

Components 1- Components 500- Components 750499ppm

749ppm

999ppm

count

4

4

20

102

55

38

223

count

0

0

0

0

0

0

0

count

0

0

0

0

0

0

0

Components % of components

% of

above leak

1-999ppm

components

definition (1,000

above leak

ppm)

definition

count

%

%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

8/92

Graph 3-5 - Total overview by chemicals, 01/01/2021-31/12/2021.

9/92

4 . Historical overview

Table 4.1 – Historical overview by component class, 2019-2021 .

Component Class

Total Components above leak definition count, summary of all rounds

2019

2020

2021

% of components above leak definition, average of all rounds) %

2019

2020

2021

Total Emissions kg

2019

2020

2021

PRD

0

0

0

0.00%

0.00%

0.00%

0.14

0.14

0.14

Sampling Point

0

0

0

0.00%

0.00%

0.00%

1.35

0.3

0.14

Total Group 1

0

0

0

0.00%

0.00%

0.00%

1.49

0.44

0.28

Stem Valve

0

0

0

0.00%

0.00%

0.00%

1.37

1.37

1.37

Open End

0

0

0

0.00%

0.00%

0.00%

2.25

1.79

1.79

Total Group 2

0

0

0

0.00%

0.00%

0.00%

3.61

3.16

3.15

Flange

0

0

0

0.00%

0.00%

0.00%

0.15

0.15

0.15

Connection

0

0

0

0.00%

0.00%

0.00%

2.5

2.5

2.5

Total Group 3

0

0

0

0.00%

0.00%

0.00%

2.65

2.65

2.65

0

0

0

0.00%

0.00%

0.00%

7.75

6.26

6.08

Total:

Table 4.1 – Historical Overview by Unit, 2019-2021

Unit

Total emission

kg

Total Components above leak definition, summary of all rounds

2019

2020

2021

2019

2020

2021

Alroy

0

0

0

7.75

6.26

6.08

Total:

0

0

0

7.75

6.26

6.08

10/92

5. Detailed monitoring summary

01/01/2021-31/12/2021

11/92

Fugitive emission component classification and emission estimation for production facilities

01/01/2021-31/12/2021 Calculation period

Monitoring

Frequency

cycles/year

Components above 1,000 ppm

%

R6

R5

R4

R3 R2 R1

6

6 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

6

6

6 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

6

0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

2

2 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

2

2

2 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

2

0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

1

1 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

1

1

1 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

1

0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

Cumulative Components above

Components in reading

Components in reading

Emission

100,000 ppm

range 1,000-100,000 ppm

range 750-999 ppm

kg

Count

Count

Count

R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1

0.14 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

0.14 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

0.28 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

1.367 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

1.787 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

3.154 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

0.149 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

2.497 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

2.646 0 0 0 0 0 0

6.08 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Energy Infrastructures LTD Company name

17-Feb-2022 Date

Alroy Production

Report Number

Unit

Components in reading

Components in reading Components in reading

Unrepaired

Total Components Difficult to

Total

Chemical Component Class Group

range 500-749 ppm

range 1-499 ppm

range 0 ppm

Components

above 1,000 ppm

Monitor Components

State

Count

Count

Count

Count

Count

Count

R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 Count

GV

PRD

G1

0 0 0 0 0 0 0 0 0 0 0 0 4 4 4 4 4 4 0 0 0 0 0 0 0 0 0 0 0 0

0

4

LL

HL

GV

Sampling Point

0 0 0 0 0 0 0 0 0 0 0 0 4 4 4 4 4 4 0 0 0 0 0 0 0 0 0 0 0 0

0

4

LL

HL

0 0 0 0 0 0 0 0 0 0 0 0 8 8 8 8 8 8 0 0 0 0 0 0 0 0 0 0 0 0

0

8 Subtotal G1

GV

Stem Valve

G2

0 0 0 0 0 0 0 0 0 0 0 0 0 20 0 20 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

20

LL

HL

GV

Open End

0 0 0 0 0 0 0 0 0 0 0 0 0 102 0 102 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

102

LL

HL

0 0 0 0 0 0 0 0 0 0 0 0 0 122 0 122 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

122 Subtotal G2

GV

Flange

G3

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 55 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

55

LL

HL

GV

Connection

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 38 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

38

LL

HL

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 93 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

93 Subtotal G3

0 0 0 0 0 0 0 0 0 0 0 0 8 130 8 223 8 8 0 0 0 0 0 0 0 0 0 0 0 0

0

223 Total Components

6.08 Total Cumulative Emission

12/92

Table 5.2 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Cumula tive

Equa tion Set:

Refinery

Units of Mea s urement:

KG

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

Emissions

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Stem Va lve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.1367

0.0137

0.0683

0.1367

0.5466

0.4646

1.3666

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.1787

0.0179

0.0894

0.1787

0.7148

0.6076

1.7871

13/92

Table 5.2 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Cumula tive

Equa tion Set:

Refinery

Units of Mea s urement:

KG

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

Fla nge

Chemical Name (Stream Name if Not Speciated)

CAS Number

Emissions

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.0149

0.0015

0.0075

0.0149

0.0597

0.0508

0.1493

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.2497

0.025

0.1248

0.2497

0.9986

0.8488

2.4966

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.608

0.0609

0.304

0.608

2.4319

2.0672

6.08

Grand Total

6.08

14/92

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u te

D a te o f

F i rs t Me

asur

l u e , Fi r

D e s cri p

Lo ca o n

p p m va

e n t Cl a

Co m p o n

ss

e n t T yp

Co m p o n

e

e n t Ta g

a l Sta te

Ch e m i c

Co m p o n

g

D ra w i n

Un i t

Round

Table 5.3-LDAR report for production facilities

Unit

Al ro y

15/92

on

Due

re p a i r

t yp e

Re pa i r

D a te o f

Re pa i r

a s u re m

ent

u re m e n

t

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

t yp e

Unit

Al ro y

Re pa i r

Plant

En e rg y I n f ra s tru ctu re s LT D

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

D a te o f

re p a i r

F i rs t Me

s t Me a s

D a te o f

Mo re

3 d ro p s th a n

per min

u te

l u e , Fi r

D e s cri p

Lo ca o n

p p m va

e n t Cl a

Co m p o n

ss

e n t T yp

Co m p o n

e

e n t Ta g

a l Sta te

Ch e m i c

Co m p o n

g

D ra w i n

Un i t

Table 5.4-LDAR report for production facilities

In the table below we provided a list of components with more than 5 Leaks during the last 12 months as follows:≥ 10,000 ppm, or more than 3 drops per minute or ≥ 1,000 ppm for PRDs

Monitoring Round

R o u n d 1- 2- 3- 4- 5- 6

16/92

Graph 5-6 – Comparison between count of components & emissions, 01/01/2021-31/12/2021.

17/92

Graph 5-7 – Comparison between total annual emissions (kg/year) , by class & year.

18/92

6. Summary by monitoring period, Round 1

19/92

In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :

1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .

2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).

This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.

Round 1

Summary of Monitoring Period

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

Table 6.1 - First measurements, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

count

Components above leak

definition

count

count

Table 6.2 – First measurement, overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.28

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

%

kg/year

Total:

8

100%

0.28

100%

count

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate: 0.28 kg/year

0 registered sources with a calculated emission rate: 0 kg/year

The total calculated emission rate:

0.28 kg/year

Table 6.3 -Measurement after repair attempt, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

count

Components above leak

definition

count

count

Table 6.4 -Measurement after repair attempt, Overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

count

%

kg/year

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.28

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

Total:

8

100%

0.28

100%

20/92

Table 6.5 - Form 07: First Measurement and Measurement after repair

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Components above

Annual

Components

Leak Definition

Emission Rate above

100,000 ppm

%

kg/year

Count

Components in

reading range

1,000- 100,000

ppm

Count

Components in

reading range

750-999 ppm

Components in

reading range

500-749 ppm

Count

Count

Energy Infrastructures LTD Company name

Alroy Production Unit

Components in

Components in Total Components above

reading range

reading range

Leak Definition

1-499 ppm

0 ppm

Count

Count

Round 1 Monitoring round

First measurement

Difficult to

Total

Chemical Component Class Group

Monitor Components State

Count

Count

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.0%

0.28

0.28

0

0

0

0

0

0

0

0

8

8

8

8

0

0

0

0

Energy Infrastructures LTD Company name

Alroy Production Unit

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Count

Components

above Leak

Definition

%

Annual

Emission

Rate

kg/year

Components

above 100,000

ppm

Count

Components in reading

range 1,000- 100,000

ppm

Count

Components in

reading range 750999 ppm

Count

Components in

reading range 500749 ppm

Count

Components in

reading range 1-499

ppm

Count

Components in

reading range 0

ppm

Count

Total Components

above Leak

Definition

Count

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.0%

0.28

0.28

0

0

0

0

0

0

0

0

0

0

8

8

0

0

GV

PRD

LL

HL

GV

Sampling Point

4

LL

HL

8 Subtotal G1

8 Total Components

0.28 Total Annual Emission Rate

G1

4

Round 1 Monitoring round

Measurement after

repair attempt

Difficult

Total

Chemical Component Class Group

to

Components State

Monitor

Count

Count

GV

PRD

G1

0

4

LL

HL

GV

Sampling Point

0

4

LL

HL

0

8 Subtotal G1

0

8 Total Components

0.28 Total Annual Emission Rate

21/92

Table 6.6 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Firs t Mea s urement

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.02

0

0.02

0.02

0.12

0.1

0.28

Grand Total

0.28

22/92

Table 6.7 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry After Repa ir

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.02

0

0.02

0.02

0.12

0.1

0.28

Grand Total

0.28

23/92

on

Due

re p a i r

t yp e

Re pa i r

D a te o f

Re pa i r

a s u re m

ent

u re m e n

t

t yp e

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

Re pa i r

Plant

En e rg y I n f ra s tru ctu re s LT D

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

D a te o f

re p a i r

F i rs t Me

s t Me a s

D a te o f

Mo re

3 d ro p s th a n

per min

u te

l u e , Fi r

D e s cri p

Lo ca o n

p p m va

e n t Cl a

Co m p o n

ss

e n t T yp

Co m p o n

e

e n t Ta g

a l Sta te

Ch e m i c

Co m p o n

g

D ra w i n

Un i t

Table 6.8-LDAR report for production facilities

Unit

Al ro y

24/92

Graph 6.10 – Round 1, overview by component class, kg/year.

25/92

Graph 6-11 – Round 1, overview by reading range.

26/92

Graph 6-12 – Round 1, overview by chemicals.

27/92

6. Summary by monitoring period, Round 2

28/92

In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :

1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .

2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).

This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.

Round 2

Summary of Monitoring Period

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

Table 6.1 - First measurements, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

count

Components above leak

definition

count

count

Table 6.2 – First measurement, overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.28

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

%

kg/year

Total:

8

100%

0.28

100%

count

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate: 0.28 kg/year

0 registered sources with a calculated emission rate: 0 kg/year

The total calculated emission rate:

0.28 kg/year

Table 6.3 -Measurement after repair attempt, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

count

Components above leak

definition

count

count

Table 6.4 -Measurement after repair attempt, Overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

count

%

kg/year

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.28

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

Total:

8

100%

0.28

100%

29/92

Table 6.5 - Form 07: First Measurement and Measurement after repair

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Components above

Annual

Components

Leak Definition

Emission Rate above

100,000 ppm

%

kg/year

Count

Components in

reading range

1,000- 100,000

ppm

Count

Components in

reading range

750-999 ppm

Components in

reading range

500-749 ppm

Count

Count

Energy Infrastructures LTD Company name

Alroy Production Unit

Components in

Components in Total Components above

reading range

reading range

Leak Definition

1-499 ppm

0 ppm

Count

Count

Round 2 Monitoring round

First measurement

Difficult to

Total

Chemical Component Class Group

Monitor Components State

Count

Count

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.0%

0.28

0.28

0

0

0

0

0

0

0

0

8

8

8

8

0

0

0

0

Energy Infrastructures LTD Company name

Alroy Production Unit

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Count

Components

above Leak

Definition

%

Annual

Emission

Rate

kg/year

Components

above 100,000

ppm

Count

Components in reading

range 1,000- 100,000

ppm

Count

Components in

reading range 750999 ppm

Count

Components in

reading range 500749 ppm

Count

Components in

reading range 1-499

ppm

Count

Components in

reading range 0

ppm

Count

Total Components

above Leak

Definition

Count

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.0%

0.28

0.28

0

0

0

0

0

0

0

0

0

0

8

8

0

0

GV

PRD

LL

HL

GV

Sampling Point

4

LL

HL

8 Subtotal G1

8 Total Components

0.28 Total Annual Emission Rate

G1

4

Round 2 Monitoring round

Measurement after

repair attempt

Difficult

Total

Chemical Component Class Group

to

Components State

Monitor

Count

Count

GV

PRD

G1

0

4

LL

HL

GV

Sampling Point

0

4

LL

HL

0

8 Subtotal G1

0

8 Total Components

0.28 Total Annual Emission Rate

30/92

Table 6.6 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Firs t Mea s urement

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.02

0

0.02

0.02

0.12

0.1

0.28

Grand Total

0.28

31/92

Table 6.7 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry After Repa ir

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.02

0

0.02

0.02

0.12

0.1

0.28

Grand Total

0.28

32/92

on

Due

re p a i r

t yp e

Re pa i r

D a te o f

Re pa i r

a s u re m

ent

u re m e n

t

t yp e

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

Re pa i r

Plant

En e rg y I n f ra s tru ctu re s LT D

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

D a te o f

re p a i r

F i rs t Me

s t Me a s

D a te o f

Mo re

3 d ro p s th a n

per min

u te

l u e , Fi r

D e s cri p

Lo ca o n

p p m va

e n t Cl a

Co m p o n

ss

e n t T yp

Co m p o n

e

e n t Ta g

a l Sta te

Ch e m i c

Co m p o n

g

D ra w i n

Un i t

Table 6.8-LDAR report for production facilities

Unit

Al ro y

33/92

Graph 6.10 – Round 2, overview by component class, kg/year.

34/92

Graph 6-11 – Round 2, overview by reading range.

35/92

Graph 6-12 – Round 2, overview by chemicals.

36/92

6. Summary by monitoring period, Round 3

37/92

In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :

1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .

2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).

This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.

Round 3

Summary of Monitoring Period

First measurement:

0 "difficult to monitor" sources.

223 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

6.06 kg/year

0 kg/year

6.06 kg/year

Table 6.1 - First measurements, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Stem Valve

20

0

0

0.00%

0

1.36

Open End

102

0

0

0.00%

0

1.78

Flange

55

0

0

0.00%

0

0.15

Connection

38

0

0

0.00%

0

2.49

Total:

223

0

0

0.00%

0

6.06

count

Components above leak

definition

count

count

Table 6.2 – First measurement, overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

223

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

6.06

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

%

kg/year

Total:

223

100%

6.06

100%

count

Measurement after repair attempt:

0 "difficult to monitor" sources.

223 default-zero sources with a calculated emission rate: 6.06 kg/year

0 registered sources with a calculated emission rate: 0 kg/year

The total calculated emission rate:

6.06 kg/year

Table 6.3 -Measurement after repair attempt, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Stem Valve

20

0

0

0.00%

0

1.36

Open End

102

0

0

0.00%

0

1.78

Flange

55

0

0

0.00%

0

0.15

Connection

38

0

0

0.00%

0

2.49

Total:

223

0

0

0.00%

0

6.06

count

Components above leak

definition

count

count

Table 6.4 -Measurement after repair attempt, Overview by reading range

Reading Range

Total components

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

223

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

6.06

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

Total:

223

100%

6.06

100%

count

Percentage of Total Components

Annual Emission Rate

%

kg/year

38/92

Table 6.5 - Form 07: First Measurement and Measurement after repair

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Components above

Annual

Components

Leak Definition

Emission Rate above

100,000 ppm

%

2

2

2

2

2

2

1

1

1

1

1

1

kg/year

Count

Components in

reading range

1,000- 100,000

ppm

Count

Components in

reading range

750-999 ppm

Components in

reading range

500-749 ppm

Count

Count

Energy Infrastructures LTD Company name

Alroy Production Unit

Components in

Components in Total Components above

reading range

reading range

Leak Definition

1-499 ppm

0 ppm

Count

Count

Round 3 Monitoring round

First measurement

Difficult to

Total

Chemical Component Class Group

Monitor Components State

Count

Count

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.28

0

0

0

0

8

8

0

0

0.0%

1.36

0

0

0

0

20

20

0

0

0.0%

1.78

0

0

0

0

102

102

0

0

0.0%

3.14

0

0

0

0

122

122

0

0

0.0%

0.15

0

0

0

0

55

55

0

0

0.0%

2.49

0

0

0

0

38

38

0

0

0.0%

0.0%

2.64

6.06

0

0

0

0

0

0

0

0

93

223

93

223

0

0

0

0

Energy Infrastructures LTD Company name

Alroy Production Unit

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

2

2

2

2

2

2

1

1

1

1

1

1

Count

Components

above Leak

Definition

%

Annual

Emission

Rate

kg/year

Components

above 100,000

ppm

Count

Components in reading

range 1,000- 100,000

ppm

Count

Components in

reading range 750999 ppm

Count

Components in

reading range 500749 ppm

Count

Components in

reading range 1-499

ppm

Count

Components in

reading range 0

ppm

Count

Total Components

above Leak

Definition

Count

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.28

0

0

0

0

0

8

0

0.0%

1.36

0

0

0

0

0

20

0

0.0%

1.78

0

0

0

0

0

102

0

0.0%

3.14

0

0

0

0

0

122

0

0.0%

0.15

0

0

0

0

0

55

0

0.0%

2.49

0

0

0

0

0

38

0

0.0%

0.0%

2.64

6.06

0

0

0

0

0

0

0

0

0

0

93

223

0

0

GV

PRD

LL

HL

GV

Sampling Point

4

LL

HL

8 Subtotal G1

GV

Stem Valve

20

LL

HL

GV

Open End

102

LL

HL

122 Subtotal G2

GV

Flange

55

LL

HL

GV

Connection

38

LL

HL

93 Subtotal G3

223 Total Components

6.06 Total Annual Emission Rate

G1

4

G2

G3

Round 3 Monitoring round

Measurement after

repair attempt

Difficult

Total

Chemical Component Class Group

to

Components State

Monitor

Count

Count

GV

PRD

G1

0

4

LL

HL

GV

Sampling Point

0

4

LL

HL

0

8 Subtotal G1

GV

Stem Valve

G2

0

20

LL

HL

GV

Open End

0

102

LL

HL

0

122 Subtotal G2

GV

Flange

G3

0

55

LL

HL

GV

Connection

0

38

LL

HL

0

93 Subtotal G3

0

223 Total Components

6.06 Total Annual Emission Rate

39/92

Table 6.6 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Firs t Mea s urement

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Stem Va lve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.14

0.01

0.07

0.14

0.55

0.46

1.37

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.18

0.02

0.09

0.18

0.71

0.61

1.79

40/92

Table 6.6 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Firs t Mea s urement

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

Fla nge

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.25

0.02

0.12

0.25

1

0.85

2.49

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.6

0.05

0.31

0.6

2.44

2.07

6.07

Grand Total

6.07

41/92

Table 6.7 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry After Repa ir

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Stem Va lve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.14

0.01

0.07

0.14

0.55

0.46

1.37

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.18

0.02

0.09

0.18

0.71

0.61

1.79

42/92

Table 6.7 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry After Repa ir

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

Fla nge

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.25

0.02

0.12

0.25

1

0.85

2.49

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.6

0.05

0.31

0.6

2.44

2.07

6.07

Grand Total

6.07

43/92

on

Due

re p a i r

t yp e

Re pa i r

D a te o f

Re pa i r

a s u re m

ent

u re m e n

t

t yp e

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

Re pa i r

Plant

En e rg y I n f ra s tru ctu re s LT D

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

D a te o f

re p a i r

F i rs t Me

s t Me a s

D a te o f

Mo re

3 d ro p s th a n

per min

u te

l u e , Fi r

D e s cri p

Lo ca o n

p p m va

e n t Cl a

Co m p o n

ss

e n t T yp

Co m p o n

e

e n t Ta g

a l Sta te

Ch e m i c

Co m p o n

g

D ra w i n

Un i t

Table 6.8-LDAR report for production facilities

Unit

Al ro y

44/92

Graph 6.10 – Round 3, overview by component class, kg/year.

45/92

Graph 6-11 – Round 3, overview by reading range.

46/92

Graph 6-12 – Round 3, overview by chemicals.

47/92

6. Summary by monitoring period, Round 4

48/92

In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :

1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .

2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).

This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.

Round 4

Summary of Monitoring Period

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

Table 6.1 - First measurements, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

count

Components above leak

definition

count

count

Table 6.2 – First measurement, overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.28

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

%

kg/year

Total:

8

100%

0.28

100%

count

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate: 0.28 kg/year

0 registered sources with a calculated emission rate: 0 kg/year

The total calculated emission rate:

0.28 kg/year

Table 6.3 -Measurement after repair attempt, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

count

Components above leak

definition

count

count

Table 6.4 -Measurement after repair attempt, Overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

count

%

kg/year

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.28

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

Total:

8

100%

0.28

100%

49/92

Table 6.5 - Form 07: First Measurement and Measurement after repair

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Components above

Annual

Components

Leak Definition

Emission Rate above

100,000 ppm

%

kg/year

Count

Components in

reading range

1,000- 100,000

ppm

Count

Components in

reading range

750-999 ppm

Components in

reading range

500-749 ppm

Count

Count

Energy Infrastructures LTD Company name

Alroy Production Unit

Components in

Components in Total Components above

reading range

reading range

Leak Definition

1-499 ppm

0 ppm

Count

Count

Round 4 Monitoring round

First measurement

Difficult to

Total

Chemical Component Class Group

Monitor Components State

Count

Count

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.0%

0.28

0.28

0

0

0

0

0

0

0

0

8

8

8

8

0

0

0

0

Energy Infrastructures LTD Company name

Alroy Production Unit

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Count

Components

above Leak

Definition

%

Annual

Emission

Rate

kg/year

Components

above 100,000

ppm

Count

Components in reading

range 1,000- 100,000

ppm

Count

Components in

reading range 750999 ppm

Count

Components in

reading range 500749 ppm

Count

Components in

reading range 1-499

ppm

Count

Components in

reading range 0

ppm

Count

Total Components

above Leak

Definition

Count

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.0%

0.28

0.28

0

0

0

0

0

0

0

0

0

0

8

8

0

0

GV

PRD

LL

HL

GV

Sampling Point

4

LL

HL

8 Subtotal G1

8 Total Components

0.28 Total Annual Emission Rate

G1

4

Round 4 Monitoring round

Measurement after

repair attempt

Difficult

Total

Chemical Component Class Group

to

Components State

Monitor

Count

Count

GV

PRD

G1

0

4

LL

HL

GV

Sampling Point

0

4

LL

HL

0

8 Subtotal G1

0

8 Total Components

0.28 Total Annual Emission Rate

50/92

Table 6.6 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Firs t Mea s urement

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.02

0

0.02

0.02

0.12

0.1

0.28

Grand Total

0.28

51/92

Table 6.7 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry After Repa ir

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.02

0

0.02

0.02

0.12

0.1

0.28

Grand Total

0.28

52/92

on

Due

re p a i r

t yp e

Re pa i r

D a te o f

Re pa i r

a s u re m

ent

u re m e n

t

t yp e

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

Re pa i r

Plant

En e rg y I n f ra s tru ctu re s LT D

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

D a te o f

re p a i r

F i rs t Me

s t Me a s

D a te o f

Mo re

3 d ro p s th a n

per min

u te

l u e , Fi r

D e s cri p

Lo ca o n

p p m va

e n t Cl a

Co m p o n

ss

e n t T yp

Co m p o n

e

e n t Ta g

a l Sta te

Ch e m i c

Co m p o n

g

D ra w i n

Un i t

Table 6.8-LDAR report for production facilities

Unit

Al ro y

53/92

Graph 6.10 – Round 4, overview by component class, kg/year.

54/92

Graph 6-11 – Round 4, overview by reading range.

55/92

Graph 6-12 – Round 4, overview by chemicals.

56/92

6. Summary by monitoring period, Round 5

57/92

In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :

1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .

2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).

This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.

Round 5

Summary of Monitoring Period

First measurement:

0 "difficult to monitor" sources.

130 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

3.46 kg/year

0 kg/year

3.46 kg/year

Table 6.1 - First measurements, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Stem Valve

20

0

0

0.00%

0

1.38

Open End

102

0

0

0.00%

0

1.8

Total:

130

0

0

0.00%

0

3.46

count

Components above leak

definition

count

count

Table 6.2 – First measurement, overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

130

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

3.46

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

%

kg/year

Total:

130

100%

3.46

100%

count

Measurement after repair attempt:

0 "difficult to monitor" sources.

130 default-zero sources with a calculated emission rate: 3.46 kg/year

0 registered sources with a calculated emission rate: 0 kg/year

The total calculated emission rate:

3.46 kg/year

Table 6.3 -Measurement after repair attempt, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Stem Valve

20

0

0

0.00%

0

1.38

Open End

102

0

0

0.00%

0

1.8

Total:

130

0

0

0.00%

0

3.46

count

Components above leak

definition

count

count

Table 6.4 -Measurement after repair attempt, Overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

count

%

kg/year

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

130

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

3.46

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

Total:

130

100%

3.46

100%

58/92

Table 6.5 - Form 07: First Measurement and Measurement after repair

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Components above

Annual

Components

Leak Definition

Emission Rate above

100,000 ppm

%

2

2

2

2

2

2

kg/year

Count

Components in

reading range

1,000- 100,000

ppm

Count

Components in

reading range

750-999 ppm

Components in

reading range

500-749 ppm

Count

Count

Energy Infrastructures LTD Company name

Alroy Production Unit

Components in

Components in Total Components above

reading range

reading range

Leak Definition

1-499 ppm

0 ppm

Count

Count

Round 5 Monitoring round

First measurement

Difficult to

Total

Chemical Component Class Group

Monitor Components State

Count

Count

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.28

0

0

0

0

8

8

0

0

0.0%

1.38

0

0

0

0

20

20

0

0

0.0%

1.8

0

0

0

0

102

102

0

0

0.0%

0.0%

3.18

3.46

0

0

0

0

0

0

0

0

122

130

122

130

0

0

0

0

Energy Infrastructures LTD Company name

Alroy Production Unit

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

2

2

2

2

2

2

Count

Components

above Leak

Definition

%

Annual

Emission

Rate

kg/year

Components

above 100,000

ppm

Count

Components in reading

range 1,000- 100,000

ppm

Count

Components in

reading range 750999 ppm

Count

Components in

reading range 500749 ppm

Count

Components in

reading range 1-499

ppm

Count

Components in

reading range 0

ppm

Count

Total Components

above Leak

Definition

Count

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.28

0

0

0

0

0

8

0

0.0%

1.38

0

0

0

0

0

20

0

0.0%

1.8

0

0

0

0

0

102

0

0.0%

0.0%

3.18

3.46

0

0

0

0

0

0

0

0

0

0

122

130

0

0

GV

PRD

LL

HL

GV

Sampling Point

4

LL

HL

8 Subtotal G1

GV

Stem Valve

20

LL

HL

GV

Open End

102

LL

HL

122 Subtotal G2

130 Total Components

3.46 Total Annual Emission Rate

G1

4

G2

Round 5 Monitoring round

Measurement after

repair attempt

Difficult

Total

Chemical Component Class Group

to

Components State

Monitor

Count

Count

GV

PRD

G1

0

4

LL

HL

GV

Sampling Point

0

4

LL

HL

0

8 Subtotal G1

GV

Stem Valve

G2

0

20

LL

HL

GV

Open End

0

102

LL

HL

0

122 Subtotal G2

0

130 Total Components

3.46 Total Annual Emission Rate

59/92

Table 6.6 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Firs t Mea s urement

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Stem Va lve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.14

0.01

0.07

0.14

0.55

0.47

1.38

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.18

0.02

0.09

0.18

0.72

0.61

1.8

60/92

Table 6.6 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Firs t Mea s urement

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

All

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.34

0.03

0.18

0.34

1.39

1.18

3.46

Grand Total

3.46

61/92

Table 6.7 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry After Repa ir

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Stem Va lve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.14

0.01

0.07

0.14

0.55

0.47

1.38

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.18

0.02

0.09

0.18

0.72

0.61

1.8

62/92

Table 6.7 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry After Repa ir

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

All

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.34

0.03

0.18

0.34

1.39

1.18

3.46

Grand Total

3.46

63/92

on

Due

re p a i r

t yp e

Re pa i r

D a te o f

Re pa i r

a s u re m

ent

u re m e n

t

t yp e

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

Re pa i r

Plant

En e rg y I n f ra s tru ctu re s LT D

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

D a te o f

re p a i r

F i rs t Me

s t Me a s

D a te o f

Mo re

3 d ro p s th a n

per min

u te

l u e , Fi r

D e s cri p

Lo ca o n

p p m va

e n t Cl a

Co m p o n

ss

e n t T yp

Co m p o n

e

e n t Ta g

a l Sta te

Ch e m i c

Co m p o n

g

D ra w i n

Un i t

Table 6.8-LDAR report for production facilities

Unit

Al ro y

64/92

Graph 6.10 – Round 5, overview by component class, kg/year.

65/92

Graph 6-11 – Round 5, overview by reading range.

66/92

Graph 6-12 – Round 5, overview by chemicals.

67/92

6. Summary by monitoring period, Round 6

68/92

In the cha pter "Summa ry by monitoring period" we pres ent two s cena rios :

1. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined by the firs t mea s urement without reference to a round of repa irs .

2. Es tima ted a nnua l emis s ion ra te, ca lcula ted a ccording to hourly emis s ion ra te obta ined a t the end of the la s t round of repa irs (if performed).

This da ta ma y help unders ta nd the effectivenes s of the round of repa irs a nd its effect on the full-yea r emis s ion ra te.

Round 6

Summary of Monitoring Period

First measurement:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate:

0 registered sources with a calculated emission rate:

The total calculated emission rate:

0.28 kg/year

0 kg/year

0.28 kg/year

Table 6.1 - First measurements, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

count

Components above leak

definition

count

count

Table 6.2 – First measurement, overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.28

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

%

kg/year

Total:

8

100%

0.28

100%

count

Measurement after repair attempt:

0 "difficult to monitor" sources.

8 default-zero sources with a calculated emission rate: 0.28 kg/year

0 registered sources with a calculated emission rate: 0 kg/year

The total calculated emission rate:

0.28 kg/year

Table 6.3 -Measurement after repair attempt, overview by component class

Component Class

Total components

Components 1-999ppm

PRD

4

0

% emission rate of components Emission rate of components Total annual emission rate (all

above leak definition

above leak definition

components)

%

kg/year

kg/year

0

0.00%

0

0.14

Sampling Point

4

0

0

0.00%

0

0.14

Total:

8

0

0

0.00%

0

0.28

count

Components above leak

definition

count

count

Table 6.4 -Measurement after repair attempt, Overview by reading range

Reading Range

Total components

Percentage of Total Components

Annual Emission Rate

count

%

kg/year

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above 1,000 ppm

Difficult to Monitor

8

0

0

0

0

0

0

0

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.28

0

0

0

0

0

0

0

Percentage of

Total Annual Emission Rate

%

100.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

0.00%

Total:

8

100%

0.28

100%

69/92

Table 6.5 - Form 07: First Measurement and Measurement after repair

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Components above

Annual

Components

Leak Definition

Emission Rate above

100,000 ppm

%

kg/year

Count

Components in

reading range

1,000- 100,000

ppm

Count

Components in

reading range

750-999 ppm

Components in

reading range

500-749 ppm

Count

Count

Energy Infrastructures LTD Company name

Alroy Production Unit

Components in

Components in Total Components above

reading range

reading range

Leak Definition

1-499 ppm

0 ppm

Count

Count

Round 6 Monitoring round

First measurement

Difficult to

Total

Chemical Component Class Group

Monitor Components State

Count

Count

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.14

0

0

0

0

4

4

0

0

0.0%

0.0%

0.28

0.28

0

0

0

0

0

0

0

0

8

8

8

8

0

0

0

0

Energy Infrastructures LTD Company name

Alroy Production Unit

Monitoring

Frequency

cycles/year

6

6

6

6

6

6

Count

Components

above Leak

Definition

%

Annual

Emission

Rate

kg/year

Components

above 100,000

ppm

Count

Components in reading

range 1,000- 100,000

ppm

Count

Components in

reading range 750999 ppm

Count

Components in

reading range 500749 ppm

Count

Components in

reading range 1-499

ppm

Count

Components in

reading range 0

ppm

Count

Total Components

above Leak

Definition

Count

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.14

0

0

0

0

0

4

0

0.0%

0.0%

0.28

0.28

0

0

0

0

0

0

0

0

0

0

8

8

0

0

GV

PRD

LL

HL

GV

Sampling Point

4

LL

HL

8 Subtotal G1

8 Total Components

0.28 Total Annual Emission Rate

G1

4

Round 6 Monitoring round

Measurement after

repair attempt

Difficult

Total

Chemical Component Class Group

to

Components State

Monitor

Count

Count

GV

PRD

G1

0

4

LL

HL

GV

Sampling Point

0

4

LL

HL

0

8 Subtotal G1

0

8 Total Components

0.28 Total Annual Emission Rate

70/92

Table 6.6 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry Firs t Mea s urement

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.02

0

0.02

0.02

0.12

0.1

0.28

Grand Total

0.28

71/92

Table 6.7 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2021- 31/12/2021

Report Chemica l Summa ry After Repa ir

Equa tion Set:

SOCMI

Units of Mea s urement:

KG/yea r

Report Da te: 17.02.2022

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

Emissions

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.01

0

0.01

0.01

0.06

0.05

0.14

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.02

0

0.02

0.02

0.12

0.1

0.28

Grand Total

0.28

72/92

on

Due

re p a i r

t yp e

Re pa i r

D a te o f

Re pa i r

a s u re m

ent

u re m e n

t

t yp e

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

Re pa i r

Plant

En e rg y I n f ra s tru ctu re s LT D

d a te

a e r r eo f r e m e a s u r e

pair a

m

empt ent

ppm

a e r r ev a l u e o f r e m e

pair a

a

e m p t s u re m e n t

D a te o f

re p a i r

F i rs t Me

s t Me a s

D a te o f

Mo re

3 d ro p s th a n

per min

u te

l u e , Fi r

D e s cri p

Lo ca o n

p p m va

e n t Cl a

Co m p o n

ss

e n t T yp

Co m p o n

e

e n t Ta g

a l Sta te

Ch e m i c

Co m p o n

g

D ra w i n

Un i t

Table 6.8-LDAR report for production facilities

Unit

Al ro y

73/92

Graph 6.10 – Round 6, overview by component class, kg/year.

74/92

Graph 6-11 – Round 6, overview by reading range.

75/92

Graph 6-12 – Round 6, overview by chemicals.

76/92

Attachments

77/92

7.1 General remarks

Table 7-1-1 - Monitored components

Unit

Round 1

In scope

Alroy

Total

Round 2

Measured

In scope

Round 3

Measured

In scope

Round 4

Measured

In scope

Round 5

Measured

In scope

Round 6

Measured

In scope

Measured

8

8

8

8

223

223

8

8

130

130

8

8

8

8

8

8

223

223

8

8

130

130

8

8

7.2 Project schedule (excluding measurements after repair)

Unit

Alroy

Start date

Round 1

End date

06/01/2021

06/01/2021

Start date

Round 2

End date

21/02/2021

21/02/2021

Start date

Round 3

End date

07/06/2021

07/06/2021

Start date

Round 4

End date

23/08/2021

23/08/2021

Start date

Round 5

End date

20/10/2021

20/10/2021

Start date

Round 6

End date

12/12/2021

12/12/2021

78/92

7.3 Methodology

Definitions

Chemical State:

Gas/Vapor:

Light Liquid:

stream which is in process conditions under gaseous or vapor form.

a liquid having a VOC content greater than 10% (by volume)

that evaporates at 150°C

Heavy Liquid:

a liquid having a VOC content of 10% or less (by volume)

that evaporates at 150°C

Leak definition:

1,000 ppm (all sources)

Difficult to monitor components:

Any component positioned at a level higher than five meters above ground level or any

component situated at a distance further than two meters from a platform and which

cannot be accessed by employees in a safe way.

Any component which access requires the elevation of a person to a level higher

than two meters above regular surfaces, and which cannot be accessed safetly.

Registered components:

Components with a leak value greater than 0 ppm.

Default-zero:

This equation is valid for sources with a leak value of 0 ppm.

A fixed EPA emission calculation rule is used for all these components.

Total components:

All of the existing active components.

Total measured components:

All of the components, measured in specific monitoring round.

Methodology

Formulas:

Measured ppm values are converted to emission loss (kg/year) and these

calculations are based on the E.P.A. “Correlation method”

Modified Trapezoidal Emission Calculation Method:

The modified trapezoid method assumes that the mass leak rate changes

linearly between any two monitoring points, except for periods between leak

leak detection and repair; the leak monitor reading is used from the time the

leak is detected to the time it is repaired (i.e., re-screened).

Cumulative data:

In "Cumulative data" tables we provide the results of all of the measurements

that performed from the beginning of the year till the end of current monitoring

period (quarter). We also calculate the real sum of previous emissions based on

the all rounds of the measurements (before and after repairing attempts).

(US EPA "Emission Estimation Protocol for Petroleum Refineries")

79/92

Table 7.4 - Calibration log list

Plant

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Round

1

2

2

2

3

3

3

3

3

3

3

3

3

4

4

5

5

5

5

5

5

5

5

Equipment Type

TVA2020

TVA2020

TVA1000B

TVA1000B

TVA1000B

TVA2020

TVA1000B

TVA2020

TVA2020

TVA1000B

TVA1000B

TVA2020

TVA2020

TVA2020

TVA1000B

TVA1000B

TVA2020

TVA1000B

TVA1000B

TVA2020

TVA2020

TVA2020

TVA2020

Analyzer Type

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

Ultra-Zero

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Span Gas

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Span gas Cylinder No

ET0022865

ET0022865

ET0022842

ET0022842

ET0022865

ET0022865

ET0022865

ET0022865

ET0022842

ET0022842

ET0022842

ET0022842

ET0022842

ET0022842

ET0022842

ET0022842

ET0022842

ET0022842

12663

12663

12663

12663

12663

Span concentration

ppm

995

995

995

995

995

995

995

995

995

995

995

995

995

995

995

995

995

995

1,000

1,000

1,000

1,000

1,000

Check gas

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Check gas Cylinder No

FF524456

FF524456

FF524456

FF524456

FF524456

FF524456

FF524456

FF524456

FF32161

FF32161

FF32161

FF32161

FF32161

FF32161

FF32161

FF32161

FF32161

FF32161

93531

93531

93531

93531

93531

Check gas

concentration

(A)

ppm

504

504

504

504

504

504

504

504

510

510

510

510

510

510

510

510

510

510

500

500

500

500

500

Date

06-Jan-2021

21-Feb-2021

02-Mar-2021

02-Mar-2021

06-Jun-2021

06-Jun-2021

07-Jun-2021

07-Jun-2021

08-Jun-2021

08-Jun-2021

15-Jun-2021

15-Jun-2021

20-Jun-2021

23-Aug-2021

19-Sep-2021

20-Oct-2021

20-Oct-2021

07-Nov-2021

12-Dec-2021

30-Dec-2021

20-Jan-2022

03-Feb-2022

06-Feb-2022

Equipment No

5

5

3

1

9

5

9

5

5

3

3

5

5

5

2

9

5

9

9

5

5

5

5

Equipment Serial

No

202016061436

202016061436

0115248937

0715622657

33461300

202016061436

33461300

202016061436

202016061436

0115248937

0115248937

202016061436

202016061436

202016061436

0115248185

33461300

202016061436

33461300

33461300

202016061436

202016061436

202016061436

202016061436

Check

1-st check 2-st check

(A1)

(A2)

ppm

ppm

512

513

501

507

503

505

549

496

507

509

512

510

494

491

503

496

507

506

508

507

481

481

495

491

512

510

490

488

510

514

509

507

496

504

510

512

490

488

509

512

513

509

509

504

514

514

Calibration error

3-st check

(A3)

ppm

511

496

505

495

504

507

498

507

506

508

480

503

511

495

508

503

508

506

499

506

506

506

515

Result

(CP)

1.59%

-0.53%

0.07%

1.85%

0.53%

1.12%

-1.92%

-0.40%

-0.72%

-0.46%

-5.75%

-2.68%

0.20%

-3.73%

0.13%

-0.72%

-1.44%

-0.13%

-1.53%

1.80%

1.87%

1.27%

2.87%

80/92

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

81/92

82/92

83/92

84/92

85/92

86/92

Table 7.6 - Stream Composition Summary

Stream Name

Gasoline

Petroleum

Stream Content

TOLUENE-34 %, n-Octane-40 %, METHYL TERT-BUTYL ETHER-10 %, CYCLOHEXANE-5 %, BENZENE-1 %, 1-Butene-10 %

TOLUENE-7.5 %, n-Octane-55.3 %, CYCLOHEXANE-35.2 %, BENZENE-2 %

Stream Content Dates

TVA

A=0.42, B=0.29

A=0.39, B=0.31

MiniRAE 10.6

MiniRAE 11.7

87/92

Table 7.7 - Quarterly Validation of LDAR Devices

Date: 30-Dec-2020

Equipment

Equip.Ser. No

No

1

2

3

5

6

7

8

9

Quarter:

Equipment

Analyzer Span Gas

Type

0715622657 TVA1000B

0115248185 TVA1000B

0115248937 TVA1000B

202016061436 TVA2020

MiniRAE2000

110219070002

NEO

05355151349 TVA1000B

33461300

TVA1000B

Qua rterly Va lida tion Qua ter 1

FID

FID

FID

FID

PID

PID

FID

FID

Sampling Flow Rate

Check

1

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Span gas

Cylinder No

ET0022842

ET0022842

ET0022842

ET0022842

EA0010369

EA0010369

ET0022842

ET0022842

Span Gas

Concentration

Sampling

Flow Rate

ppm

l/min

995

995

995

995

996

996

995

995

0.94

0.9

0.91

1.13

0.51

0.52

0.98

1.11

Accuracy Check

Result Check Gas

Check gas

Cylinder No

OK Methane

OK Methane

OK Methane

OK Methane

OK Isobutylene

OK Isobutylene

OK Methane

OK Methane

FF16599

FF16599

FF16599

FF16599

995-286088

995-286088

FF16599

FF16599

Check Gas

Concentration

Response Time

90% of Response

1-st

2nd

3rd Calibration

Time 1

Result Span

check check check

error

ppm

501

501

501

501

500

500

501

501

504

502

498

501

510

519

499

501

503

505

501

502

510

517

501

502

506

505

502

503

511

520

502

502

0.46%

0.4%

-0.33%

0%

1.92%

3.59%

-0.27%

-0.07%

OK

OK

OK

OK

OK

OK

OK

OK

Response

Time 2

Response

Time 3 Result

ppm

sec

sec

sec

895.5

895.5

895.5

895.5

896.9

896.9

895.5

895.5

4

4

4

4

6

6

4

4

4

4

4

4

5

6

4

4

4

4

4

4

5

6

4

4

88/92

OK

OK

OK

OK

OK

OK

OK

OK

Table 7.8 - Quarterly Validation of LDAR Devices

Date: 30-Mar-2021

Equipment

Equip.Ser. No

No

1

2

3

5

6

7

8

9

Quarter:

Equipment

Analyzer Span Gas

Type

0715622657 TVA1000B

0115248185 TVA1000B

0115248937 TVA1000B

202016061436 TVA2020

MiniRAE2000

110219070002

NEO

05355151349 TVA1000B

33461300

TVA1000B

Qua rterly Va lida tion Qua ter 2

FID

FID

FID

FID

PID

PID

FID

FID

Sampling Flow Rate

Check

2

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Span gas

Cylinder No

ET0022842

ET0022842

ET0022842

ET0022842

EA0010369

EA0010369

ET0022842

ET0022842

Span Gas

Concentration

Sampling

Flow Rate

ppm

l/min

995

995

995

995

996

996

995

995

1.1

0.92

1.36

1.2

0.49

0.44

1.24

1.36

Accuracy Check

Result Check Gas

Check gas

Cylinder No

OK Methane

OK Methane

OK Methane

OK Methane

OK Isobutylene

OK Isobutylene

OK Methane

OK Methane

FF16599

FF16599

FF16599

FF16599

995-286088

995-286088

FF16599

FF16599

Check Gas

Concentration

Response Time

90% of Response

1-st

2nd

3rd Calibration

Time 1

Result Span

check check check

error

ppm

501

501

501

501

500

500

501

501

507

505

506

499

504

491

504

501

509

503

504

502

504

492

509

502

506

504

504

501

504

492

508

501

1.06%

0.4%

0.53%

-0.27%

0.66%

-1.8%

1%

-0.13%

OK

OK

OK

OK

OK

OK

OK

OK

Response

Time 2

Response

Time 3 Result

ppm

sec

sec

sec

895.5

895.5

895.5

895.5

896.9

896.9

895.5

895.5

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

4

89/92

OK

OK

OK

OK

OK

OK

OK

OK

Table 7.9 - Quarterly Validation of LDAR Devices

Date: 30-Jun-2021

Equipment

Equip.Ser. No

No

1

2

3

5

6

7

8

9

Quarter:

Equipment

Analyzer Span Gas

Type

0715622657 TVA1000B

0115248185 TVA1000B

0115248937 TVA1000B

202016061436 TVA2020

MiniRAE2000

110219070002

NEO

05355151349 TVA1000B

33461300

TVA1000B

Qua rterly Va lida tion Qua ter 3

FID

FID

FID

FID

PID

PID

FID

FID

Sampling Flow Rate

Check

3

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Span gas

Cylinder No

ET0022842

ET0022842

ET0022842

ET0022842

EA0010369

EA0010369

ET0022842

ET0022842

Span Gas

Concentration

Sampling

Flow Rate

ppm

l/min

995

995

995

995

996

996

995

995

1.07

0.92

1.13

1.08

0.49

0.53

1.12

1.21

Accuracy Check

Result Check Gas

Check gas

Cylinder No

OK Methane

OK Methane

OK Methane

OK Methane

OK Isobutylene

OK Isobutylene

OK Methane

OK Methane

FF16599

FF16599

FF16599

FF16599

995-286088

995-286088

FF16599

FF16599

Check Gas

Concentration

Response Time

90% of Response

1-st

2nd

3rd Calibration

Time 1

Result Span

check check check

error

ppm

501

501

501

501

500

500

501

501

511

501

501

507

510

511

508

501

510

502

499

506

509

512

508

503

510

498

498

504

509

512

507

501

1.66%

-0.33%

-0.53%

0.73%

1.72%

2.19%

1.13%

-0.07%

OK

OK

OK

OK

OK

OK

OK

OK

Response

Time 2

Response

Time 3 Result

ppm

sec

sec

sec

895.5

895.5

895.5

895.5

896.9

896.9

895.5

895.5

4

4

4

4

5

5

4

4

4

4

4

4

5

4

4

4

4

4

4

4

5

5

4

4

90/92

OK

OK

OK

OK

OK

OK

OK

OK

Table 7.10 - Quarterly Validation of LDAR Devices

Date: 30-Sep-2021

Equipment

Equip.Ser. No

No

1

2

3

5

6

7

8

9

Quarter:

Equipment

Analyzer Span Gas

Type

0715622657 TVA1000B

0115248185 TVA1000B

0115248937 TVA1000B

202016061436 TVA2020

MiniRAE2000

110219070002

NEO

05355151349 TVA1000B

33461300

TVA1000B

Qua rterly Va lida tion Qua ter 4

FID

FID

FID

FID

PID

PID

FID

FID

Sampling Flow Rate

Check

4

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Span gas

Cylinder No

ET0022865

ET0022865

ET0022865

ET0022865

EA0010369

EA0010369

ET0022865

ET0022865

Span Gas

Concentration

Sampling

Flow Rate

ppm

l/min

995

995

995

995

996

996

995

995

0.91

1

1.22

1.15

0.51

0.54

0.96

1.26

Accuracy Check

Result Check Gas

Check gas

Cylinder No

OK Methane

OK Methane

OK Methane

OK Methane

OK Isobutylene

OK Isobutylene

OK Methane

OK Methane

FF16599

FF16599

FF16599

FF16599

995-286088

995-286088

FF16599

FF16599

Check Gas

Concentration

Response Time

90% of Response

1-st

2nd

3rd Calibration

Time 1

Result Span

check check check

error

ppm

501

501

501

501

500

500

501

501

506

502

504

503

500

501

498

507

505

503

501

501

599

500

497

504

503

501

499

504

500

501

501

505

0.53%

0%

-0.13%

0.13%

6.45%

-0.01%

-0.66%

0.66%

OK

OK

OK

OK

OK

OK

OK

OK

Response

Time 2

Response

Time 3 Result

ppm

sec

sec

sec

895.5

895.5

895.5

895.5

896.9

896.9

895.5

895.5

4

4

4

3

4

5

5

4

3

4

3

4

4

5

5

4

4

4

4

4

4

4

5

4

91/92

OK

OK

OK

OK

OK

OK

OK

OK

Table 7.11 - PRODUCTION HOURS TEMPLATE

Plant

Energy Infrastructures LTD

Unit

Alroy

Alroy

Drawing

6006-100-006

6006-100-007

Stream Name

Gasoline

Gasoline

Remark

Annual Production Hours

8,760

8,760

Q1

01/01-31/03

Quarter =

Quarterly Production hours

2,160

2,160

Q2

01/04-30/06

Quarter =

Quarterly Production hours

2,184

2,184

Q3

01/07-30/09

Quarter =

Quarterly Production hours

2,208

2,208

Q4

01/10-31/12

Quarter =

Quarterly Production hours

2,208

2,208

92/92

ספח ג'

דוגמת חישוב עבור מיכל גג חיצו י צף מס' 2המאחסן קרוסין

3013.18-034-T2

3013.18-025

28/02/2022

18/30

3013.18-036.doc

T2 - kerosene

External Floating roof

1. Tank data

Diameter of the tank

D

Effective height of the stock liquid (while

roof landing episode)

hle

Shell Color and condition

α

Roof color and condition

α

Tank paint solar absorptance

α

Vapor space outage (while roof landing

episode)

HVO

m

feet

m

feet

color

condition

color

condition

dimensionless

m

Tank data

--Tank data

--חום

טובה

לבן

טוב

48.77

160.01

11.00

0.58

Table 7.1-6

Brown

0.17

Table 7.1-6

0.38

Table 7.1-6

Possible to use also equation

1-15

assumption - equal to legs height

feet

11.00

Volume of the vapor space (while roof

landing episode)

Breather vent pressure setting

VV

ft

3

VV=PI()*D /4*Hvo

221,185

Equation 1-3

ΔPBP

psi

Typical value

0.50

Equation 1-11

Breather vent vacuum setting

ΔPBV

psi

Typical value

0.00

Equation 1-11

Breather vent pressure setting range

ΔPB

psi

PB  PBP  PBV

0.50

Equation 1-11

2

2. Material data - קרוסין

Stock vapor molecular weight

MV

Density of the liquid inside the tank

Wl

Vapor density

WV

True vapor pressure of the stock liquid

P

Vapor pressure at daily average liquid

surface temperature

Vapor pressure at the daily maximum

liquid surface temperature, psia

Vapor pressure at the daily minimum

liquid surface temperature

Daily vapor pressure range

3013.18-034.xls - 2

gr/gr-mole

lb/lb-mole

g/ml

lb/gal

kg/m^3

lb/ft3

msds data

130

msds data

--msds data

---

0.80

6.68

4.5

0.28

mm Hg

PEI data

0.833

psia

--הנחה:

Pv=nRT -->

P2=P1*(T2/T1)

0.02

0.02

0.02

0.00

PVA

psia

PVX

psia

PVN

psia

T1(k)=20C+273

T2(k)=37.5C+273

ΔPV

psia

 PV  PVX  PVN

1/3

0

at 20°C

0.02

Equation 1-9

28/02/2022

3. Operation data

Number of days that the tank stands idle

(on roof landing episode)

Number of degassing and cleaning

episode

Number of roof landing episode

nd

days/landing episode

site data

4

landing episode/year

site data

0.07

landing episode/year

site data

0.07

Tanks Program

--Tanks Program

---

38

17

74

33

16

T2 - B&W 2021

Tanks Program

---

59

27

T2 - DFloating 2019

lb per emptying

Tanks Program

61

Kg per emptying

---

28

4. Normal operation (Tanks program)

lb per year

Kg per year

lb per year

Kg per year

Kg per year

Working (withdrawal) losses

Total emissions (Breathing & Working)

Breathing (standing) losses

5. Degassing and Cleaning (Tanks program)

Degassing: emission from one turnover

Edegass-floating lb per emptying

of floating roof

Kg per emptying

Degassing: fixed roof with a height of

roof legs

Edegass-legs

Liquid fraction in sludge

Fliquid

Sludge volume

Sludge weight

Vs

Ws

Cleaning emissions

Ecleaning

Total Degassing and Cleaning emissions

Edegass-total

3013.18-034.xls - 2

0.8

m3 per emptying

Kg per emptying

lb per emptying

Kg per emptying

lb per emptying

Kg per emptying

Ecleaning = Ws * (1-Fliquid)

Edegass-total =

Edegass-floating + Edegass-legs + Ecleaning

2/3

T2 - B&W 2021

T2- DFixed 2019

(Only working losses)

Tanks FAQ - degassing and

cleaning

70

56,000

24,692

11,200

24,811

11,254

28/02/2022

6. Roof landing

Daily average liquid surface temperature

TLA

°R

Daily vapor temperature range

Daily maximum liquid surface

temperature

ΔTV

°R

TLX

Daily minimum liquid surface temperature

Liquid bulk temperature

Max standing idle losses during roof

landing

T LA  0 .44 T AA  0 .56 T B  0 .0079 *  * I

532.17

Equation 1-26

 TV  0.72 T A  0.028 *  * I

32.95

Equation 1-8

°R

TLX = TLA + 0.25*ΔTV

540.41

Figure 7.1-17

TLN

°R

TLN = TLA - 0.25*ΔTV

523.93

Figure 7.1-17

TB

°R

527.22

Equation 1-28

LSL-max

lb per landing episode

Kg per landing episode

TB = TAA + 6α - 1

LSL-max = 5.9*D2*hle*W l

--0.60 for a full liquid heel

0.50 for a partial

0.15 for drain-dry

11,093,038 Equation 2-13

5,031,769

0.50

Equation 2-26

(pages No 33,35)

1

KS 

1  0.053 * PVA * H VO

0.5

Equation 1-20

KS is assumed to be less than

or equal to the saturation

factor during filling (S) .

 TV  PV   PB

T LA

PA  PVA

0.028

Liquid stock has a true vapor

pressure greater than 0.1psia Equation 1-7.

Filling saturation factor

S

dimensionless

saturation factor

KS

dimensionless

Vapor space expansion factor

KE

dimensionless

Standing idle losses during roof landing

LSL

lb per landing episode

 PV 

L SL  n d K E  V  M V K S

 RT AA 

5

Equation 2-16

Filling losses during roof landing

LFL

lb per landing episode

 P * VV 

 M V * S

L FL  

 R * T AA 

41

Equation 2-26

Total losses during roof landing

LTL

lb per landing episode

Kg per landing episode

46

21

Equation 2-10

KE 

LTL=LSL+LFL

7. Summary

Working (withdrawal) losses

Breathing (standing) losses

Kg per year

Kg per year

17

16

Total Degassing and Cleaning emissions

Kg per year

750

Total losses during roof landing

Kg per year

1

785

3013.18-034.xls - 2

3/3

Kg per year

28/02/2022

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - B&W 2021

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

0.68

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Aluminum/Diffuse

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

20/02/2022

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - B&W 2021 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

All

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

76.52

65.35

87.69

Liquid

Bulk

Temp

(deg F)

68.86

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0136

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

20/02/2022

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - B&W 2021 - External Floating Roof Tank

Haifa, Israel

Annual Emission Calcaulations

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

0.0136

160.0100

130.0000

1.0000

Withdrawal Losses (lb):

Annual Net Throughput (gal/yr.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

38.3228

5,202,143.0000

0.0075

7.0000

160.0100

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

0.8398

0.0002

130.0000

1.0000

27.8819

6.2000

Total Losses (lb):

73.6631

34.5005

1.6000

0.3000

6.2000

1.6000

0.0002

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

KFa(lb-mole/yr)

1.60

6.20

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

1.20

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.94

1.00

Losses(lb)

0.1446

0.6608

0.0345

20/02/2022

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

20/02/2022

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - B&W 2021 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

34.50

38.32

0.84

0.00

73.66

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

20/02/2022

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

20/02/2022

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFixed 2019

Haifa

Israel

PEI

Vertical Fixed Roof Tank

kerosene

Tank Dimensions

Shell Height (ft):

Diameter (ft):

Liquid Height (ft) :

Avg. Liquid Height (ft):

Volume (gallons):

Turnovers:

Net Throughput(gal/yr):

Is Tank Heated (y/n):

N

Paint Characteristics

Shell Color/Shade:

Shell Condition

Roof Color/Shade:

Roof Condition:

Aluminum/Diffuse

Good

White/White

Good

Roof Characteristics

Type:

Height (ft)

Slope (ft/ft) (Cone Roof)

Breather Vent Settings

Vacuum Settings (psig):

Pressure Settings (psig)

11.00

160.01

11.00

5.50

1,654,664.74

1.00

1,654,664.74

Cone

0.00

0.00

0.00

0.50

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

Apr

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

72.10

62.74

81.45

Liquid

Bulk

Temp

(deg F)

67.57

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0118

0.0092

0.0159

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

02/02/2020

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Month:

Standing Losses (lb):

Vapor Space Volume (cu ft):

Vapor Density (lb/cu ft):

Vapor Space Expansion Factor:

Vented Vapor Saturation Factor:

January

February

March

April

May

June

July

August

September

October

November

December

Tank Vapor Space Volume:

Vapor Space Volume (cu ft):

Tank Diameter (ft):

Vapor Space Outage (ft):

Tank Shell Height (ft):

Average Liquid Height (ft):

Roof Outage (ft):

Roof Outage (Cone Roof)

Roof Outage (ft):

Roof Height (ft):

Roof Slope (ft/ft):

Shell Radius (ft):

Vapor Density

Vapor Density (lb/cu ft):

Vapor Molecular Weight (lb/lb-mole):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Daily Avg. Liquid Surface Temp. (deg. R):

Daily Average Ambient Temp. (deg. F):

Ideal Gas Constant R

(psia cuft / (lb-mol-deg R)):

Liquid Bulk Temperature (deg. R):

Tank Paint Solar Absorptance (Shell):

Tank Paint Solar Absorptance (Roof):

Daily Total Solar Insulation

Factor (Btu/sqft day):

Vapor Space Expansion Factor

Vapor Space Expansion Factor:

Daily Vapor Temperature Range (deg. R):

Daily Vapor Pressure Range (psia):

Breather Vent Press. Setting Range(psia):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Vapor Pressure at Daily Minimum Liquid

Surface Temperature (psia):

Vapor Pressure at Daily Maximum Liquid

Surface Temperature (psia):

Daily Avg. Liquid Surface Temp. (deg R):

Daily Min. Liquid Surface Temp. (deg R):

Daily Max. Liquid Surface Temp. (deg R):

Daily Ambient Temp. Range (deg. R):

Vented Vapor Saturation Factor

Vented Vapor Saturation Factor:

Vapor Pressure at Daily Average Liquid:

Surface Temperature (psia):

Vapor Space Outage (ft):

Working Losses (lb):

Vapor Molecular Weight (lb/lb-mole):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Net Throughput (gal/mo.):

Annual Turnovers:

Turnover Factor:

Maximum Liquid Volume (gal):

Maximum Liquid Height (ft):

Tank Diameter (ft):

Working Loss Product Factor:

Total Losses (lb):

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Losses(lbs)

Components

Working Loss

Breathing Loss

Total Emissions

Jet kerosene

60.63

32.78

93.41

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFloating 2019

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.00

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Aluminum/Diffuse

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

Apr

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

76.46

63.88

89.04

Liquid

Bulk

Temp

(deg F)

68.86

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0136

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

02/02/2020

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Month:

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

January

February

March

April

May

June

July

August

September

October

November

December

Withdrawal Losses (lb):

Net Throughput (gal/mo.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

Total Losses (lb):

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

KFa(lb-mole/yr)

1.60

6.20

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

1.20

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.94

1.00

Losses(lb)

0.0000

0.0000

0.0000

02/02/2020

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

2.99

55.99

0.07

0.00

59.04

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חישובי פליטה ממיכל תשטיפים

גיליון חישוב זה הוכן על ידי "פז" ה דסה ו יהול ) (1980בע"מ.

אין להעתיק ו\או לעשות שימוש כלשהו במידע ה "ל ללא הרשאה כתובה מ"פז" ה דסה ו יהול ) (1980בע"מ.

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מסמך 11 מתוך 11

פתיחת הקובץ באתר הממשלה (pdf, 2696 KB)

תשתיות אנרגיה בע"מ

מסוף אלרואי

סיכום פליטות לאוויר

שנת 2022

פרויקט3013.19 :

סימוכין3013.19-036 :

פברואר 2023

תוכן עניינים

.1מבוא 4.............................................................................................................................

.2נתוני מסוף 5.....................................................................................................................

.2.1נתוני מיכלים 5.........................................................................................................

.2.2נתונים עבור מסוף מילוי מיכליות כביש 9.....................................................................

.3חישוב פליטות 10 ..............................................................................................................

.3.1כללי10 ........................................................................................................................ ....

.3.2סוגי פליטות מחושבות 10 ..................................................................................................

.3.3בחירת חומרים בתוכנת 11 ................................................................................... TANKS

.3.4נתונים מטאורולוגיים11 ....................................................................................................

.4סיכום פליטות לשנת 12 ............................................................................................. 2022

.4.1מיכלים 12 ........................................................................................................................

.4.2מסוף מילוי מיכליות כביש 12 .............................................................................................

.4.3מיכל איסוף תשטיפים 12 ...................................................................................................

.4.4סיכום ממצאי ניטור 12 .......................................................................................... LDAR

.4.5פליטה שנתית מכלל המתקן 13 ...........................................................................................

.5פליטות לא שגרתיות במהלך שנת 13 ............................................................................2022

.6מקורות 14 .......................................................................................................................

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טבלאות

טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 5........................................... 2022

טבלה :2נתוני מעטפת וגגות – שנת 6.................................................................................. 2022

טבלה :3נתוני אביזרים – שנת 7......................................................................................... 2022

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת 8................................................... TANKS

טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 9...................................................... 2022

טבלה :6חומרים מייצגים בתוכנת 11 ............................................................................ TANKS

טבלה :7סיכום פליטות מכלים -שנת 12 ............................................................................ 2022

טבלה :8סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 12 .................................. 2022

טבלה :9סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 13 .................................................. 2022

נספחים

נספח א'

טבלה )AP-42( 1-5.2

נספח ב'

נתוני ניטור LDARעבור מסוף אלרואי – סיכום שנת 2022

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין

נספח ד'

חישוב פליטות ממיכל לאיסוף תשטיפים

מירה ליה-זיו איסקוב

שם עורך

26/02/2023

יואב פיסטינר

שם מאשר

26.02.2023

תאריך

3/30

להערות

תיאור

0

גרסה

3013.19-036.doc

.1מבוא

חברת תשתיות נפט ואנרגיה בע"מ (להלן תש"א) מפעילה את מסוף אלרואי לאחסון ושינוע

דלקים .

המסוף כולל:

•

מבני משרדים

•

חוות מכלים לאחסון דלקים מסוגים שונים

•

רציפי מילוי מכליות כביש (לשימוש בעת חירום בלבד)

המסוף ממוקם בשוליים הדרום מערביים של קריית טבעון ,בצמוד לו וממערב ממוקמת שכונת

אלרואי ומדרום לו שכונת קרית חרושת.

באתר 9מיכלים ,מתוכם 7מכלים תפעוליים ו 2-מכלים המשמשים כמכלים אסטרטגיים

(מכלים מס' 1ו.)9-

מערכת השינוע הינה באמצעות משאבות ובקרת מילוי ובנוסף קיימות מערכות תומכות כגון

מערכות כיבוי אש ומערכות פיקוד ובקרה.

כחלק מהתנאים ברישיון עסק מדצמבר ,2010בסוף כל שנה קלנדרית על תש"א להגיש דו"ח

סיכום פליטות שנתי לגבי השנה שחלפה.

חישובי הפליטות בוצעו בעזרת תוכנת Tanksומסמכי EPA-AP 42על פי נתוני המתקנים

הקיימים במסוף.

סיכום הפליטות הוכן על ידי חברת "פז" הנדסה וניהול ( )1980בע"מ (להלן פז הנדסה) ,והוא

מבוסס על סקר תהליכים ופליטות לאוויר ודו"חות ניטור LDARשהוגשו לרשויות.

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.2נתוני מסוף

.2.1נתוני מיכלים

בטבלאות הבאות מפורט מידע טכני של המיכלים בחוות המיכלים אלרואי.

טבלה :1נתוני מיכלים – מידע כללי ,מידות ונתוני תפעול – שנת 2022

לחץ אדים

בטמפ' הנוזל

הממוצעת

)(mmHg

405 @ 28°C

כמות

צריכה

שנתית

(מ"ק)

0

גבעה חלקית

77,083

גבעה חלקית

48.77

גבעה חלקית

48.77

32,056

48.77

32,056

28,768

56,959

51,614

15.56

51,614

15.56

14.1

15.56

14.1

11.4

18.3

18.3

15.4

9.7

סוג ניקוז

בתחתית

מיכל

קוטר

מיכל

(מטר)

נפח מיכל

(מ"ק)

נפח מיכל

פעיל

(מ"ק)

48.77

32,056

28,768

גובה /אורך

מעטפת

מיכל

(מטר)

17.16

15.4

32,056

28,768

17.16

15.4

10

28,768

17.16

15.4

9.5

17.16

15.4

10.3

14.1

14.1

14.1

מספר

מיכל

סוג הדלק

המאוחסן

)1( 1

בנזין

2

קרוסין

0.833 @ 28°C

3

סולר

0.507 @ 28°C

14,641

4

סולר

0.507 @ 28°C

127,061

גבעה חלקית

5

סולר

0.507 @ 28°C

111,041

גבעה מלאה

68.27

)1( 6

סולר

0.507 @ 28°C

0

גבעה מלאה

68.27

56,959

)1( 7

סולר

0.507 @ 28°C

0

גבעה מלאה

68.27

56,959

51,614

8

קרוסין

0.833 @ 28°C

4,675

גבעה חלקית

48.8

36,547

34,228

19.54

)1( 9

קרוסין

0.833 @ 28°C

0

גבעה חלקית

48.77

32,056

28,768

17.16

367,704

332,913

334,501

סה"כ

( )1מכלים מס' 7 ,6 ,1ו 9-משמשים כמכלי מלאי ,לא היו תנועות במכלים בשנת .2022

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גובה נוזל

מירבי

(מטר)

גובה נוזל

ממוצע

(מטר)

10.5

טבלה :2נתוני מעטפת וגגות – שנת 2022

מספר

מיכל

סוג גג

אטם ראשי

אטם משני

1

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

גג צף

חיצוני

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Mechanical

Shoe

Liquid

mounted

Mechanical

Shoe

Rim

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Shoe

mounted

Rim

mounted

Rim

mounted

2

3

4

5

6

7

8

9

26/02/2023

צורת גג

סוג

חיבורי

גג

צבע

גג

מצב

צבע

גג

צבע

מעטפת

חיצונית

מצב צבע

מעטפת

חיצונית

סוג חיבורי

מעטפת

מצב

מעטפת

פנימית

מיכל

מחומם

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חום

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

לבן

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

חום

ישן

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

כחול בהיר

טוב

מרותך

חלוד הרבה

לא

Pontoon

מרותך

לבן

טוב

צהוב קרם

טוב

מרותך

חלוד הרבה

לא

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טבלה :3נתוני אביזרים – שנת 2022

מספר

מיכל

1

2

3

4

5

6

7

8

9

סה"כ

שובר ואקום

כמות

2

2

2

2

2

2

2

6

2

Vacuum

]set. [psi

0

0

0

0

0

0

0

0

0

Pressure

]set. [psi

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

0.5

רגליים מתכווננות התומכות

בגג צף()1

גובה כמות באזור

כמות

במרכז

()ft

pontoon

29

43

11

29

43

11

29

43

11

29

43

11

72

107

11

72

107

11

72

107

11

36

54

9

29

43

11

כמות

מדי

מפלס

Rim

Vent

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

6

כמות בוצה

בנקיון

(מ"ק)

"גרביים" לבאר

הדיגום המחורצת

ולרגלי הגג הצף()1

70

70

70

70

150

150

150

70

70

870

יש

יש

יש

יש

יש

יש

יש

יש

יש

( )1הנ"ל לא נלקחו בחשבון בחישוב הפליטות מתוכנת ה TANKS-מפני שנדגמו במסגרת ניטורי ה.LDAR-

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הנחות שנלקחו לצורך החישובים

.1עבור חישוב Degassingבמיכל עם גג צף – הונח:

•

גג צף נח על רגליים בגובה ( 9-11 ftבהתאם לטבלה לעיל) וזהו גם הגובה המרבי של הנוזל

במיכל.

•

גובה ממוצע של הנוזל במיכל הינו 50%מגובה הנוזל המרבי.

.2הונח כי ניקיון כללי וריקון של המיכלים מתבצע אחת ל 15-שנים .הניקיון יארך יום אחד.

.3הונח כי אירוע של נחיתת גגות צפים מתבצע אחת ל 15-שנים .זמן נחיתת הגג במקרה זה לא

יעלה על 4ימים.

.4יחס הנוזל בבוצה הונח כ]2[ 0.8 -

.5בהתאם לטבלה 7.1-6על פי [ ,]1נבחרו הצבעים הבאים כמייצגים את צבע מעטפת המיכלים,

לצורך חישובי פליטות לאוויר:

טבלה :4צבעים מייצגים לצורך חישובי אקסל ותוכנת Tanks

צבע מעטפת

מיכל

צבע לצורך חישובי אקסל

צבע לצורך חישובים בתוכנת

בהתאם למסמך EPA AP-42

)*( Tanks

כחול בהיר

Gray Medium

Gray Medium

Brown

Aluminium/Diffuse

Beige/Cream

Aluminium/Specular

White

White

חום

צהוב קרם

לבן

(*) בתוכנת Tanksמבחר הצבעים מצומצם יותר מאשר בטבלה 7.1-6אשר במסמך

.]1[ EPA AP-42

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.2.2נתונים עבור מסוף מילוי מיכליות כביש

טבלה :5נתונים עבור מסוף מילוי מיכליות כביש – שנת 2022

מס'

זרוע

1

2

3

4

5

6

7

8

מוצר

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

קרוסין

סה"כ

מילוי

עילי /תחתי

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

עילי טבול

נפח מילוי שנתי

(מ"ק)

0

0

0

0

0

0

0

0

0

נפח ממוצע של

מיכלית (מ"ק)

30

30

30

30

30

30

30

30

לא התקיימה פעילות מיכליות כביש בשנת .2022

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.3חישוב פליטות

.3.1כללי

חישובי הפליטות עבור מיכלי האחסון בוצעו בתוכנת Tanksובעזרת .]1[ EPA-AP 42

הערכת פליטות כתוצאה מדליפות ציוד ואביזרים ( )LDARמצורפת בנספח ב'.

דוגמת חישוב עבור מיכל גג חיצוני צף (מיכל מס' )2המאחסן קרוסין ,מצורפת כנספח ג' למסמך

זה.

בדוגמאות אלה ניתן לראות את נתוני הקלט (כולל הנחות) עליהם התבססו החישובים.

.3.2סוגי פליטות מחושבות

הערכת הפליטות ממיכלי אחסון כוללת [:]3

• פליטות בזמן אחסון )(Breathing Losses

• פליטות משינויי מפלס )(Working Losses

• פליטות כתוצאה מניקוי וריקון מיכלים )(Degassing Losses

• פליטות כתוצאה מנחיתת גגות צפים )(Roof Landing Losses

• פליטות כתוצאה מהפרשי לחץ )(Flash Losses

• פליטות בזמן מילוי מיכלים ומיכליות

בסקר הפליטות חושבו כל הפליטות המפורטות לעיל ,למעט פליטות כתוצאה מהפרשי לחץ

).(Flash Losses

פליטות אלה רלוונטיות לשינויי פתאומי\מיידי בלחץ הנוזל ,נתון הגורם להפרת שיווי המשקל

הקיים במיכל (בין גז לנוזל) וכתוצאה מכך נוצר תהליך הבזקה ,בו מרכיבים קלים מפאזה הנוזל

עוברים לפאזה הגזית .תופעות אלה מתרחשות ,בדרך כלל ,כאשר נוזל המאוחסן בלחץ נשלח

לאחסון במיכל בעל לחץ נמוך יותר [.]3

פליטות אלו הוזנחו כיוון שכל החומרים מוחזקים בתנאים אטמוספריים בכל אחד מהשלבים

הנוגעים להובלתם ואחסונם ,ולפיכך לא צפויה פליטת אדים כתוצאה מתהליך זה.

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.3.3בחירת חומרים בתוכנת Tanks

על פי נתוני MSDSשל הדלקים במסוף ,נבחרו החומרים הבאים הקיימים בתוכנת Tanks

כמייצגים של חומרים אלו:

טבלה :6חומרים מייצגים בתוכנת Tanks

דלק קיים במסוף

חומר מייצג בתוכנת Tanks

סולר (תחבורה והסקה)

Distillate fuel oil no 2

נפט (קרוסין)

Jet kerosene

בנזין

Gasoline RVP 10

.3.4נתונים מטאורולוגיים

לצורך חישוב הנתונים בתוכנת Tanksהוגדרו נתונים מטאורולוגים המתאימים למפרץ חיפה על פי

מקורות [.]4

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.4סיכום פליטות לשנת 2022

.4.1מיכלים

סיכום חישובי פליטה עבור כל אחד ממיכלי האחסון מפורט בטבלה להלן:

טבלה :7סיכום פליטות מכלים -שנת 2022

מיכל

חומר

1

בנזין

פליטות לאוויר

(ק"ג/שנה)

3,603

2

קרוסין

836

3

סולר

23

4

סולר

911

5

סולר

1,764

6

סולר

1,693

7

סולר

1,693

8

קרוסין

760

9

קרוסין

758

12,041

סה"כ

.4.2מסוף מילוי מיכליות כביש

לא התקיימה פעילות מיכליות כביש בשנת ,2022ועל כן אין פליטות ממסוף מילוי מיכליות כביש.

.4.3מיכל איסוף תשטיפים

סך הפליטה ממיכל לאיסוף תשטיפים הינה כ 1 -ק"ג/שנה.

חישוב מצורף בנספח ד'.

יצוין כי החישוב מתבסס על הנחה מחמירה שהמכל מכיל קרוסין בלבד .מעשית ,המיכל מכיל

בעיקר ניקוז מים מהמכלים.

.4.4סיכום ממצאי ניטור LDAR

טבלה :8סיכום פליטות חומרים אורגנים נדיפים עבור רכיבים בשנת 2022

סה"כ פליטות (ק"ג/שנה)

סיכום פליטות LDAR

פליטה שנתית (ק"ג/שנה)

סה"כ

6

26/02/2023

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3013.19-036.doc

.4.5פליטה שנתית מכלל המתקן

טבלה :9סיכום פליטות שנתי מכלל מסוף אלרואי – שנת 2022

סה"כ פליטות (ק"ג/שנה)

חוות מיכלים

מסוף מילוי

מיכליות כביש

מיכל לאיסוף

תשטיפים

12,041

0

1

סיכום פליטות

רכיבים

סה"כ

()LDAR

6

12,048

.5פליטות לא שגרתיות במהלך שנת 2022

במהלך שנת 2022לא התרחשו פליטות לא שגרתיות כתוצאה מפעילות הטרמינל.

26/02/2023

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3013.19-036.doc

.6מקורות

]1[ EPA-AP42

]2[ USER’S GUIDE to TANKS - Storage Tank Emissions Calculation Software Version

4.0 - APPENDIX D

[ ]3הנחיות להגשת בקשה להיתר פליטה ושינוי הפעלה משמעותי הנחיות הממונה לטיפול בבקשה

להיתר פליטה לפי סעיף (9א) לתקנות אוויר נקי (היתרי פליטה) ,התש"ע – ,2010מהדורה ,5

נובמבר 2020

[ ]4האטלס האקלימי לתכנון פיסי וסביבתי בישראל ,מהדורה שנייה1994 ,

26/02/2023

14/30

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נספח א'

טבלה 5.2-1

AP-42

26/02/2023

15/30

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3013.19-036.doc

16/30

26/02/2023

נספח ב'

נתוני ניטור LDARעבור אלרואי – סיכום שנת 2022

(מתוך דיווח שהתקבל ממעבדות אקולוגיה מתאריך )12.01.2023

3013.19-003A

26/02/2023

17/30

3013.19-036.doc

LDAR

Fugi ve Emission Monitoring

Report No.

RL-EI-R1-6-22

Plant: Energy Infrastructures LTD

City: Haifa

District: Haifa

Production Unit: Alroy

Reporting period: Annual Summary

Report printing date:

12-Jan-2023

Report editor:

Michael Ourievsky

Approved by:

Alexey Ratner

Table of Content

1. Executive Summary

2. Project introduction

2.1 Scope of work

2.2 Project phases

3. Monitoring Results

Table 3.1 – Overview by component class

Table 3.2 – Overview by reading range

Table 3.3 – Overview per Unit

Table 3.4 – Monitoring results, last known situation

Graph 3.5 – Total overview by chemicals

4. Detailed monitoring summary

Table 4.1 - Cumulative summary, Fugitive emission component classification and emission estimation for

production facilities

Table 4.2 – Chemical Summary by Component Class

Table 4.3 - LDAR report for production facilities

Table 4.4 - Components with more than 5 significant leaks detected during last 12 months

Graph 4.5 - Comparison between count of components & kg/year, by components

5. Attachments

5.1 General Remarks

Table 5.1.1 Monitored components

Table 5.1.2 Unmonitored P&IDs

Table 5.2 Project schedule

5.3 Methodology

5.4 Calibration Log list

5.5 Calibration gas certificates

5.6 Stream Composition Summary

5.6 Quarterly Validation of LDAR Devices, Quarter 1

5.7 Quarterly Validation of LDAR Devices, Quarter 2

5.8 Quarterly Validation of LDAR Devices, Quarter 3

5.9 Quarterly Validation of LDAR Devices, Quarter 4

5.10 Cumulative production hours template

4

5

5

5

6

6

6

7

7

9

9

10

11

13

14

15

17

17

17

17

17

18

19

20

22

23

24

25

26

27

1. Executive Summary

The total number of active components at Energy Infrastructures LTD is 223.

Six rounds of measurements have been performed in the Quarter 1-4 of 2022.

The total calculated emission from 01/01/2022 to 31/12/2022 is 6.08 kg.

The number of components above leak definition found from the beginning of the year – 0

The number of pegged readings (above 100,000 ppm) found from the beginning of the year - 0

The last known situation of Energy Infrastructures LTD indicates there are no leaks

4/27

2 Project introduction

2.1 Scope of work

Following measurements have been performed in 2022:

Round

Round 1, Quarter 1

Round 2, Quarter 1

Round 3, Quarter 2

Round 4, Quarter 3

Round 5, Quarter 4

Round 6, Quarter 4

Unit

G1

Monitored group

G2

G3

Alroy

Alroy

Alroy

Alroy

Alroy

Alroy

2.2 Project phases

Monitoring

Re-measurement after repair

Revision of equipment and production processes

Inventory: adding or deleting components

General

1. LDAR tests were performed under ISO-17025 accreditation of ISRAC (Israel Laboratory Accreditation Authority).

2. ISRAC is not responsible for the test results.

3. The following data is provided by the customer: production hours, P&IDs, and stream information.

5/27

3. Monitoring results

The table “Overview by component class” below shows the number of active components, number of leaks above leak definitions and number of components that are still leaking in each class

(according to the monitoring round), and total calculated emissions in the specified period.

Table 3.1 Overview by component class,

Component Class

01/01/2022-31/12/2022

Total

Components

count

Total Components above

leak definition

count

% of components above

leak definition

%

Unrepaired Components

Total

Emissions

kg

count

Round 1

Round 2

Round 3

Round 4

Round 5

Round 6

Round 1

Round 2

Round 3

Round 4

Round 5

Round 6

Average

Round 1

Round 2

Round 3

Round 4

Round 5

Round 6

01/01/202231/12/2022

PRD

Sampling Point

Total Group 1:

Stem Valve

Open End

Total Group 2:

Flange

Connection

Total Group 3:

4

4

8

20

102

122

55

38

93

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0.14

0.14

0.28

1.367

1.787

3.154

0.149

2.497

2.646

Total:

223

0

0

0

0

0

0

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0

0

0

0

0

0

6.08

In table “Overview by reading range” all the components divided by their reading range at first measurement according to the monitoring round.

Table 3.2 Overview by reading range

Total Components

Reading Range

Round 1

#

0 ppm

1-499 ppm

500-749 ppm

750-999 ppm

1,000-100,000 ppm

Above 100,000 ppm

Total above leak definition

Difficult to Monitor

Total:

Round 2

%

8

0

0

0

0

0

0

0

8

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

Round 3

%

8

0

0

0

0

0

0

0

8

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

Round 4

%

223

0

0

0

0

0

0

0

223

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

Round 5

%

8

0

0

0

0

0

0

0

8

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

Round 6

%

130

0

0

0

0

0

0

0

130

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

#

%

8

0

0

0

0

0

0

0

8

100.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

0.0%

100.0%

6/27

Table 3.3 Overview per Unit, Group 1-3

Unit

Total

components

Components above leak definition

count

Alroy

Total:

R1

223

223

R2

0

0

R3

R4

0

0

R5

0

0

0

0

R6

0

0

Total emission

kg

01/01/202231/12/2022

0

6.08

0

6.08

Table 3.4 – Monitoring results, Group 1-3, last known situation.

The last known situation of Energy Infrastructures LTD indicates there are no leaks.

0 "difficult to monitor" sources.

223 default-zero sources (0ppm).

0 registered sources (1-999ppm).

0 components above leak definition

Component Class

Total

components

count

PRD

Sampling Point

Stem Valve

Open End

Flange

Connection

Total:

Components 1- Components 500- Components 750499ppm

749ppm

999ppm

count

4

4

20

102

55

38

223

count

0

0

0

0

0

0

0

count

0

0

0

0

0

0

0

Components % of components

% of

above leak

1-999ppm

components

definition (1,000

above leak

ppm)

definition

count

%

%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

0

0

0.00%

0.00%

7/27

Graph 3-5 - Total overview by chemicals, 01/01/2022-31/12/2022.

8/27

4. Detailed monitoring summary

01/01/2022-31/12/2022

9/27

Fugitive emission component classification and emission estimation for production facilities

01/01/2022-31/12/2022 Calculation period

Monitoring

Frequency

cycles/year

Components above 1,000 ppm

%

R6

R5

R4

R3 R2 R1

6

6 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

6

6

6 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

6

0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

2

2 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

2

2

2 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

2

0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

1

1 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

1

1

1 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

1

0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

0.00% 0.00% 0.00% 0.00% 0.00% 0.00%

Cumulative Components above

Components in reading

Components in reading

Emission

100,000 ppm

range 1,000-100,000 ppm

range 750-999 ppm

kg

Count

Count

Count

R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1

0.14 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

0.14 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

0.28 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

1.367 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

1.787 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

3.154 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

0.149 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

2.497 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

2.646 0 0 0 0 0 0

6.08 0 0 0 0 0 0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

Energy Infrastructures LTD Company name

12-Jan-2023 Date

Alroy Production

Report Number

Unit

Components in reading

Components in reading Components in reading

Unrepaired

Total Components Difficult to

Total

Chemical Component Class Group

range 500-749 ppm

range 1-499 ppm

range 0 ppm

Components

above 1,000 ppm

Monitor Components

State

Count

Count

Count

Count

Count

Count

R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 R6 R5 R4 R3 R2 R1 Count

GV

PRD

G1

0 0 0 0 0 0 0 0 0 0 0 0 4 4 4 4 4 4 0 0 0 0 0 0 0 0 0 0 0 0

0

4

LL

HL

GV

Sampling Point

0 0 0 0 0 0 0 0 0 0 0 0 4 4 4 4 4 4 0 0 0 0 0 0 0 0 0 0 0 0

0

4

LL

HL

0 0 0 0 0 0 0 0 0 0 0 0 8 8 8 8 8 8 0 0 0 0 0 0 0 0 0 0 0 0

0

8 Subtotal G1

GV

Stem Valve

G2

0 0 0 0 0 0 0 0 0 0 0 0 0 20 0 20 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

20

LL

HL

GV

Open End

0 0 0 0 0 0 0 0 0 0 0 0 0 102 0 102 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

102

LL

HL

0 0 0 0 0 0 0 0 0 0 0 0 0 122 0 122 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

122 Subtotal G2

GV

Flange

G3

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 55 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

55

LL

HL

GV

Connection

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 38 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

38

LL

HL

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 93 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

93 Subtotal G3

0 0 0 0 0 0 0 0 0 0 0 0 8 130 8 223 8 8 0 0 0 0 0 0 0 0 0 0 0 0

0

223 Total Components

6.08 Total Cumulative Emission

10/27

Table 4.2 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2022- 31/12/2022

Report Chemica l Summa ry Cumula tive

Equa tion Set:

Refinery

Units of Mea s urement:

KG

Report Da te: 12.01.2023

Alroy

Unit

Component Class:

PRD

Chemical Name (Stream Name if Not Speciated)

CAS Number

Emissions

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Sa mpling Point

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.014

0.0014

0.007

0.014

0.0561

0.0477

0.1402

Component Class:

Stem Va lve

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.1367

0.0137

0.0683

0.1367

0.5466

0.4646

1.3666

Component Class:

Open End

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.1787

0.0179

0.0894

0.1787

0.7148

0.6076

1.7871

11/27

Table 4.2 Chemical Summary by Component Class

Ca lcula tion Period:

01/01/2022- 31/12/2022

Report Chemica l Summa ry Cumula tive

Equa tion Set:

Refinery

Units of Mea s urement:

KG

Report Da te: 12.01.2023

Alroy

Unit

Component Class:

Fla nge

Chemical Name (Stream Name if Not Speciated)

CAS Number

Emissions

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.0149

0.0015

0.0075

0.0149

0.0597

0.0508

0.1493

Component Class:

Connection

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.2497

0.025

0.1248

0.2497

0.9986

0.8488

2.4966

Component Class:

All

1-Butene

BENZENE

CYCLOHEXANE

METHYL TERT-BUTYL ETHER

n-Octa ne

TOLUENE

106-98-9

71-43-2

110-82-7

1634-04-4

111-65-9

108-88-3

0.608

0.0609

0.304

0.608

2.4319

2.0672

6.08

Grand Total

6.08

12/27

n t Typ e

n t Cla s s

Co m p o n e

Co m p o n e

t

e nt

p a ir

d a te

a e r re op f re m e a s u re m e

a ir a e m n t

pt

p p m va lu

a e r re p e o f re m e a s u

a ir a e m

re m e n t

pt

Re p a ir ty

pe

D a te o f re

Plant

Energy Infra s tructures LTD

d a te

a e r re op f re m e a s u re m e

a ir a e m n t

pt

p p m va lu

a e r re p e o f re m e a s u

a ir a e m

re m e n t

pt

Re p a ir ty

pe

p a ir

ue

irs t Me a

D a te o f re

Re p a ir D

D a te o f F

e a s u re m

n

s u re m e n

e , Firs t M

Mo re

3 d ro p s th a n

p e r m in u

te

p p m va lu

e s cri p o

n t Ta g

Co m p o n e

Lo ca o n

D

Sta te

Ch e m ica

l

D ra w in g

Un it

Ro u n d

Table 4.3-LDAR report for production facilities

Unit

Alroy

13/27

n t Typ e

n t Cla s s

Co m p o n e

Co m p o n e

t

p a ir

d a te

a e r re op f re m e a s u re m e

a ir a e m n t

pt

ppm v

a e r re pa lu e o f re m e a s u

a ir a e m

re m e n t

pt

Unit

Alroy

Re p a ir ty

pe

D a te o f re

d a te

a e r re op f re m e a s u re m e

a ir a e m n t

pt

ppm v

a e r re pa lu e o f re m e a s u

a ir a e m

re m e n t

pt

Re p a ir ty

pe

p a ir

ue

irs t Me a

e nt

Plant

Energy Infra s tructures LTD

D a te o f re

Re p a ir D

D a te o f F

e a s u re m

n

s u re m e n

e , Firs t M

Mo re

3 d ro p s th a n

p e r m in u

te

p p m va lu

e s cri p o

n t Ta g

Co m p o n e

Lo ca o n

D

Sta te

Ch e m ica

l

D ra w in g

Un it

Table 4.4-Components with more than 5 significant leaks detected in the last 12 months

In the table below we provided a list of components with more than 5 Leaks during the last 12 months as follows: ≥ 10,000 ppm, or more than 3 drops per minute or ≥ 1,000 ppm for PRDs

Monitoring Round

Round 1-2-3-4-5-6

14/27

Graph 4-5 – Comparison between count of components & emissions, 01/01/2022-31/12/2022.

15/27

Attachments

16/27

5.1 General remarks

Table 5-1-1 - Monitored components

Unit

Round 1

In scope

Round 2

Measured

In scope

Round 3

Measured

In scope

Round 4

Measured

In scope

Round 5

Measured

In scope

Round 6

Measured

In scope

Measured

Alroy

8

8

8

8

223

223

8

8

130

130

8

8

Total

8

8

8

8

223

223

8

8

130

130

8

8

5.2 Project schedule (excluding measurements after repair)

Unit

Alroy

Start date

Round 1

End date

03/02/2022

03/02/2022

Start date

Round 2

End date

06/03/2022

06/03/2022

Start date

Round 3

End date

05/07/2022

05/07/2022

Start date

Round 4

End date

30/08/2022

30/08/2022

Start date

Round 5

End date

18/10/2022

18/10/2022

Start date

Round 6

End date

20/12/2022

20/12/2022

17/27

5.3 Methodology

Definitions

Chemical State:

Gas/Vapor:

Light Liquid:

stream which is in process conditions under gaseous or vapor form.

a liquid having a VOC content greater than 10% (by volume)

that evaporates at 150°C

Heavy Liquid:

a liquid having a VOC content of 10% or less (by volume)

that evaporates at 150°C

Leak definition:

1,000 ppm (all sources)

Difficult to monitor components:

Any component positioned at a level higher than five meters above ground level or any

component situated at a distance further than two meters from a platform and which

cannot be accessed by employees in a safe way.

Any component which access requires the elevation of a person to a level higher

than two meters above regular surfaces, and which cannot be accessed safetly.

Registered components:

Components with a leak value greater than 0 ppm.

Default-zero:

This equation is valid for sources with a leak value of 0 ppm.

A fixed EPA emission calculation rule is used for all these components.

Total components:

All of the existing active components.

Total measured components:

All of the components, measured in specific monitoring round.

Methodology

Formulas:

Measured ppm values are converted to emission loss (kg/year) and these

calculations are based on the E.P.A. “Correlation method”

Modified Trapezoidal Emission Calculation Method:

The modified trapezoid method assumes that the mass leak rate changes

linearly between any two monitoring points, except for periods between leak

leak detection and repair; the leak monitor reading is used from the time the

leak is detected to the time it is repaired (i.e., re-screened).

Cumulative data:

In "Cumulative data" tables we provide the results of all of the measurements

that performed from the beginning of the year till the end of current monitoring

period (quarter). We also calculate the real sum of previous emissions based on

the all rounds of the measurements (before and after repairing attempts).

(US EPA "Emission Estimation Protocol for Petroleum Refineries")

18/27

Table 5.4 - Calibration log list

Plant

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Energy Infrastructures LTD

Round

1

2

2

2

2

3

3

3

3

3

3

3

3

4

4

4

4

4

5

5

5

5

5

6

Equipment Type

TVA2020

TVA2020

TVA1000B

TVA2020

TVA2020

TVA2020

TVA1000B

TVA2020

TVA2020

TVA2020

TVA1000B

TVA2020

TVA1000B

TVA2020

TVA1000B

TVA1000B

TVA2020

TVA1000B

TVA2020

TVA1000B

TVA2020

TVA1000B

TVA2020

TVA2020

Analyzer Type

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

FID

Ultra-Zero

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Air, THC < 0.5ppm

Span Gas

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Span gas Cylinder No

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

12663

Span concentration

ppm

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

1,000

Check gas

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Methane

Check gas Cylinder No

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

93531

Check gas

concentration

(A)

ppm

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

500

Date

03-Feb-2022

14-Feb-2022

14-Feb-2022

06-Mar-2022

07-Mar-2022

12-May-2022

12-May-2022

19-May-2022

06-Jun-2022

13-Jun-2022

13-Jun-2022

14-Jun-2022

14-Jun-2022

05-Jul-2022

05-Jul-2022

30-Aug-2022

30-Aug-2022

15-Sep-2022

13-Oct-2022

13-Oct-2022

18-Oct-2022

18-Oct-2022

07-Nov-2022

20-Dec-2022

Equipment No

5

5

9

5

5

5

9

5

5

5

9

5

9

5

8

9

5

9

5

9

5

9

5

5

Equipment Serial

No

202016061436

202016061436

33461300

202016061436

202016061436

202016061436

33461300

202016061436

202016061436

202016061436

33461300

202016061436

33461300

202016061436

05355151349

33461300

202016061436

33461300

202016061436

33461300

202016061436

33461300

202016061436

202016061436

Check

1-st check 2-st check

(A1)

(A2)

ppm

ppm

509

507

512

510

495

493

501

506

490

492

499

507

497

495

490

491

492

490

507

503

502

507

495

493

490

488

508

499

499

485

493

490

497

500

501

503

501

494

499

505

504

506

498

496

514

515

502

506

Calibration error

3-st check

(A3)

ppm

504

510

499

499

488

503

490

488

488

499

510

499

487

502

483

495

499

501

490

502

501

499

515

504

Result

(CP)

1.33%

2.13%

-0.87%

0.40%

-2.00%

0.60%

-1.20%

-2.07%

-2.00%

0.60%

1.27%

-0.87%

-2.33%

0.60%

-2.20%

-1.47%

-0.27%

0.33%

-1.00%

0.40%

0.73%

-0.47%

2.93%

0.80%

19/27

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

20/27

21/27

Table 5.6 - Stream Composition Summary

Stream Name

Gasoline

Petroleum

Stream Content

1-Butene-10 %, BENZENE-1 %, CYCLOHEXANE-5 %, METHYL TERT-BUTYL ETHER-10 %, n-Octane-40 %, TOLUENE-34 %

BENZENE-2 %, CYCLOHEXANE-35.2 %, n-Octane-55.3 %, TOLUENE-7.5 %

Stream Content Dates

TVA

MiniRAE 10.6

MiniRAE 11.7

22/27

Table 5.6 - Quarterly Validation of LDAR Devices

Date: 04-Jan-2022

Equipment

Equip.Ser. No

No

1

2

3

5

6

7

8

9

1

2

3

5

6

7

8

9

Quarter:

Equipment

Analyzer Span Gas

Type

0715622657 TVA1000B

0115248185 TVA1000B

0115248937 TVA1000B

202016061436 TVA2020

MiniRAE2000

110219070002

NEO

05355151349 TVA1000B

33461300

TVA1000B

0715622657 TVA1000B

0115248185 TVA1000B

0115248937 TVA1000B

202016061436 TVA2020

MiniRAE2000

110219070002

NEO

05355151349 TVA1000B

33461300

TVA1000B

Qua rterly Va lida tion Qua rter 1

FID

FID

FID

FID

PID

PID

FID

FID

FID

FID

FID

FID

PID

PID

FID

FID

Sampling Flow Rate

Check

1

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Span gas

Cylinder No

ET0022865

ET0022865

ET0022865

ET0022865

EA0010369

EA0010369

ET0022865

ET0022865

ET0022865

ET0022865

ET0022865

ET0022865

EA0010369

EA0010369

ET0022865

ET0022865

Span Gas

Concentration

Sampling

Flow Rate

ppm

l/min

995

995

995

995

996

996

995

995

995

995

995

995

996

996

995

995

0.91

1.02

1.26

1.15

0.41

0.51

0.99

1.31

0.91

1.02

1.26

1.15

0.41

0.51

0.99

1.31

Accuracy Check

Result Check Gas

Check gas

Cylinder No

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

FF16599

FF16599

FF16599

FF16599

995-286088

995-286088

FF16599

FF16599

FF16599

FF16599

FF16599

FF16599

995-286088

995-286088

FF16599

FF16599

Check Gas

Concentration

Response Time

90% of Response

1-st

2nd

3rd Calibration

Time 1

Result Span

check check check

error

ppm

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

501

501

501

501

500

500

501

501

501

501

501

501

500

500

501

501

510

505

495

497

490

511

509

503

510

505

495

497

490

511

509

503

506

499

493

502

488

509

501

508

506

499

493

502

488

509

501

508

513

501

490

507

493

510

507

496

513

501

490

507

493

510

507

496

1.53%

-0.07%

-1.86%

0%

-2.07%

1.86%

0.73%

0.07%

1.53%

-0.07%

-1.86%

0%

-2.07%

1.86%

0.73%

0.07%

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

Response

Time 2

Response

Time 3 Result

ppm

sec

sec

sec

895.5

895.5

895.5

895.5

896.9

896.9

895.5

895.5

895.5

895.5

895.5

895.5

896.9

896.9

895.5

895.5

4

4

4

3

5

5

4

3

4

4

4

3

5

5

4

3

4

4

3

4

5

5

4

4

4

4

3

4

5

5

4

4

4

4

4

4

5

5

4

4

4

4

4

4

5

5

4

4

23/27

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

OK

Table 5.7 - Quarterly Validation of LDAR Devices

Date: 01-Apr-2022

Quarter:

Equipment

Equip.Ser. No

No

Equipment

Analyzer Span Gas

Type

1

2

3

5

6

7

8

9

0715622657 TVA1000B

0115248185 TVA1000B

0115248937 TVA1000B

202016061436 TVA2020

MiniRAE2000

110219070002

NEO

05355151349 TVA1000B

33461300

TVA1000B

Qua rterly Va lida tion Qua rter 2

FID

FID

FID

FID

PID

PID

FID

FID

Sampling Flow Rate

Check

2

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Span gas

Cylinder No

ET0022865

ET0022865

ET0022865

ET0022865

EA0010369

EA0010369

ET0022865

ET0022865

Span Gas

Concentration

Sampling

Flow Rate

ppm

l/min

995

995

995

995

996

996

995

995

1.08

1.1

1.21

1.09

0.47

0.51

0.96

1.28

Accuracy Check

Result Check Gas

Check gas

Cylinder No

OK Methane

OK Methane

OK Methane

OK Methane

OK Isobutylene

OK Isobutylene

OK Methane

OK Methane

FF16599

FF16599

FF16599

FF16599

995-286088

995-286088

FF16599

FF16599

Check Gas

Concentration

Response Time

90% of Response

1-st

2nd

3rd Calibration

Time 1

Result Span

check check check

error

ppm

501

501

501

501

500

500

501

501

501

510

490

492

488

515

501

510

502

514

491

492

488

513

501

510

502

513

488

493

493

512

502

508

-0.07%

2.06%

-2.46%

-1.93%

-2.2%

2.52%

-0.13%

1.46%

OK

OK

OK

OK

OK

OK

OK

OK

Response

Time 2

Response

Time 3 Result

ppm

sec

sec

sec

895.5

895.5

895.5

895.5

896.9

896.9

895.5

895.5

4

4

4

3

6

5

4

4

4

4

4

4

5

5

4

4

4

4

4

4

5

6

4

4

24/27

OK

OK

OK

OK

OK

OK

OK

OK

Table 5.8 - Quarterly Validation of LDAR Devices

Date: 01-Jul-2022

Quarter:

Equipment

Equip.Ser. No

No

Equipment

Analyzer Span Gas

Type

1

2

3

5

6

7

8

9

0715622657 TVA1000B

0115248185 TVA1000B

0115248937 TVA1000B

202016061436 TVA2020

MiniRAE2000

110219070002

NEO

05355151349 TVA1000B

33461300

TVA1000B

Qua rterly Va lida tion Qua rter 3

FID

FID

FID

FID

PID

PID

FID

FID

Sampling Flow Rate

Check

3

Methane

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Span gas

Cylinder No

ET0022865

ET0022865

ET0022865

ET0022865

EA0010369

EA0010369

ET0022865

ET0022865

Span Gas

Concentration

Sampling

Flow Rate

ppm

l/min

995

995

995

995

996

996

995

995

1.16

1.11

1.25

1.12

0.49

0.52

0.93

1.21

Accuracy Check

Result Check Gas

Check gas

Cylinder No

OK Methane

OK Methane

OK Methane

OK Methane

OK Isobutylene

OK Isobutylene

OK Methane

OK Methane

FF16599

FF16599

FF16599

FF16599

995-286088

995-286088

FF16599

FF16599

Check Gas

Concentration

Response Time

90% of Response

1-st

2nd

3rd Calibration

Time 1

Result Span

check check check

error

ppm

501

501

501

501

500

500

501

501

512

502

475

491

482

517

505

515

512

503

477

491

482

515

505

516

511

503

477

491

48

516

504

516

1.93%

0.13%

-5.11%

-2.19%

-32.63%

3.06%

0.53%

2.72%

OK

OK

OK

OK

FAIL

OK

OK

OK

Response

Time 2

Response

Time 3 Result

ppm

sec

sec

sec

895.5

895.5

895.5

895.5

896.9

896.9

895.5

895.5

4

4

4

4

5

5

4

4

3

4

4

4

5

6

4

4

4

4

4

4

5

5

4

4

25/27

OK

OK

OK

OK

OK

OK

OK

OK

Table 5.9 - Quarterly Validation of LDAR Devices

Date: 30-Sep-2022

Equipment

Equip.Ser. No

No

1

2

5

6

7

8

9

10

Quarter:

Equipment

Analyzer Span Gas

Type

0715622657 TVA1000B

0115248185 TVA1000B

202016061436 TVA2020

MiniRAE2000

110219070002

NEO

05355151349 TVA1000B

33461300

TVA1000B

0115248463 TVA1000B

Qua rterly Va lida tion Qua rter 4

FID

FID

FID

PID

PID

FID

FID

FID

Sampling Flow Rate

Check

4

Methane

Methane

Methane

Isobutylene

Isobutylene

Methane

Methane

Methane

Span gas

Cylinder No

ET0022865

ET0022865

ET0022865

EA0010369

EA0010369

ET0022865

ET0022865

ET0022865

Span Gas

Concentration

Sampling

Flow Rate

ppm

l/min

995

995

995

996

996

995

995

995

0.86

1.14

1.26

0.5

0.92

0.98

1.18

1.39

Accuracy Check

Result Check Gas

Check gas

Cylinder No

OK Methane

OK Methane

OK Methane

OK Isobutylene

OK Isobutylene

OK Methane

OK Methane

OK Methane

FF16599

FF16599

FF16599

995-286088

995-286088

FF16599

FF16599

FF16599

Check Gas

Concentration

Response Time

90% of Response

1-st

2nd

3rd Calibration

Time 1

Result Span

check check check

error

ppm

501

501

501

500

500

501

501

501

508

503

499

506

504

497

501

501

509

506

501

506

503

494

502

499

507

501

502

507

501

501

502

502

1.2%

0.27%

-0.27%

1.13%

0.39%

-0.93%

-0.07%

-0.27%

OK

OK

OK

OK

OK

OK

OK

OK

Response

Time 2

Response

Time 3 Result

ppm

sec

sec

sec

895.5

895.5

895.5

896.9

896.9

895.5

895.5

895.5

4

4

4

6

4

4

4

4

4

4

4

6

4

4

4

4

4

4

4

6

4

4

4

4

26/27

OK

OK

OK

OK

OK

OK

OK

OK

Table 5.10 - PRODUCTION HOURS TEMPLATE

Plant

Energy Infrastructures LTD

Unit

Alroy

Alroy

Drawing

6006-100-006

6006-100-007

Stream Name

Gasoline

Gasoline

Remark

Annual Production Hours

8,760

8,760

Q1

01/01-31/03

Quarter =

Quarterly Production hours

2,160

2,160

Q2

01/04-30/06

Quarter =

Quarterly Production hours

2,184

2,184

Q3

01/07-30/09

Quarter =

Quarterly Production hours

2,208

2,208

Q4

01/10-31/12

Quarter =

Quarterly Production hours

2,208

2,208

27/27

נספח ג'

דוגמת חישוב עבור מיכל גג חיצוני צף מס' 2המאחסן קרוסין

3013.19-034-T2

3013.19-025

26/02/2023

18/30

3013.19-036.doc

T2 - kerosene

External Floating roof

1. Tank data

Diameter of the tank

D

Effective height of the stock liquid (while

roof landing episode)

hle

Shell Color and condition

α

Roof color and condition

α

Tank paint solar absorptance

α

Vapor space outage (while roof landing

episode)

HVO

m

feet

m

feet

color

condition

color

condition

dimensionless

m

Tank data

--Tank data

--חום

טובה

לבן

טוב

VV

ft

3

ΔPBP

Breather vent vacuum setting

ΔPBV

Breather vent pressure setting range

ΔPB

11.00

0.58

Table 7.1-6

Brown

0.17

Table 7.1-6

0.38

Table 7.1-6

Possible to use also equation

1-15

assumption - equal to legs height

feet

Volume of the vapor space (while roof

landing episode)

Breather vent pressure setting

48.77

160.01

11.00

2

VV=PI()*D /4*Hvo

221,185

Equation 1-3

psi

Typical value

0.50

Equation 1-11

psi

Typical value

0.00

Equation 1-11

psi

PB = PBP − PBV

0.50

Equation 1-11

msds data

130

msds data

--msds data

---

0.80

6.68

4.5

0.28

mm Hg

PEI data

0.833

psia

--הנחה:

Pv=nRT -->

P2=P1*(T2/T1)

0.02

2. Material data - קרוסין

Stock vapor molecular weight

MV

Density of the liquid inside the tank

Wl

Vapor density

WV

True vapor pressure of the stock liquid

P

Vapor pressure at daily average liquid

surface temperature

Vapor pressure at the daily maximum

liquid surface temperature, psia

Vapor pressure at the daily minimum

liquid surface temperature

Daily vapor pressure range

3013.19-034.xls - 2

gr/gr-mole

lb/lb-mole

g/ml

lb/gal

kg/m^3

lb/ft3

PVA

psia

PVX

psia

PVN

psia

T1(k)=20C+273

T2(k)=37.5C+273

0.02

ΔPV

psia

PV = PVX − PVN

0.00

1/3

0

at 20°C

0.02

0.02

Equation 1-9

26/02/2023

3. Operation data

Number of days that the tank stands idle

(on roof landing episode)

Number of degassing and cleaning

episode

Number of roof landing episode

nd

days/landing episode

site data

4

landing episode/year

site data

0.07

landing episode/year

site data

0.07

Tanks Program

--Tanks Program

---

150

68

185

84

16

T2 - B&W 2022

Tanks Program

---

59

27

T2 - DFloating 2019

lb per emptying

Tanks Program

61

Kg per emptying

---

28

4. Normal operation (Tanks program)

lb per year

Kg per year

lb per year

Kg per year

Kg per year

Working (withdrawal) losses

Total emissions (Breathing & Working)

Breathing (standing) losses

5. Degassing and Cleaning (Tanks program)

Degassing: emission from one turnover of

Edegass-floating lb per emptying

floating roof

Kg per emptying

Degassing: fixed roof with a height of roof

legs

Edegass-legs

Liquid fraction in sludge

Fliquid

Sludge volume

Sludge weight

Vs

Ws

Cleaning emissions

Ecleaning

Total Degassing and Cleaning emissions

Edegass-total

3013.19-034.xls - 2

0.8

m3 per emptying

Kg per emptying

lb per emptying

Kg per emptying

lb per emptying

Kg per emptying

Ecleaning = Ws * (1-Fliquid)

Edegass-total =

Edegass-floating + Edegass-legs + Ecleaning

2/3

T2 - B&W 2022

T2- DFixed 2019

(Only working losses)

Tanks FAQ - degassing and

cleaning

70

56,000

24,692

11,200

24,811

11,254

26/02/2023

6. Roof landing

Daily average liquid surface temperature

TLA

°R

Daily vapor temperature range

ΔTV

°R

Daily maximum liquid surface temperature

TLX

Daily minimum liquid surface temperature

Liquid bulk temperature

Max standing idle losses during roof

landing

Filling saturation factor

TLA = 0.44 TAA + 0.56 TB + 0.0079 *  * I

532.17

Equation 1-26

TV = 0.72TA + 0.028 *  * I

32.95

Equation 1-8

°R

TLX = TLA + 0.25*ΔTV

540.41

Figure 7.1-17

TLN

°R

TLN = TLA - 0.25*ΔTV

523.93

Figure 7.1-17

TB

°R

527.22

Equation 1-28

LSL-max

S

lb per landing episode

Kg per landing episode

dimensionless

TB = TAA + 6α - 1

2

LSL-max = 5.9*D *hle*W l

--0.60 for a full liquid heel

0.50 for a partial

0.15 for drain-dry

11,093,038 Equation 2-13

5,031,769

0.50

Equation 2-26

(pages No 33,35)

1

KS =

1 + 0.053 * PVA * H VO

0.5

Equation 1-20

KS is assumed to be less than

or equal to the saturation factor

during filling (S) .

TV PV − PB

+

TLA

PA − PVA

0.028

Liquid stock has a true vapor

pressure greater than 0.1psia Equation 1-7.

saturation factor

KS

dimensionless

Vapor space expansion factor

KE

dimensionless

Standing idle losses during roof landing

LSL

lb per landing episode

 PV 

L SL = n d K E  V  M V K S

 RT AA 

5

Equation 2-16

Filling losses during roof landing

LFL

lb per landing episode

 P * VV 

 M V * S

LFL = 

 R * T AA 

41

Equation 2-26

Total losses during roof landing

LTL

lb per landing episode

Kg per landing episode

46

21

Equation 2-10

KE =

LTL=LSL+LFL

7. Summary

Working (withdrawal) losses

Breathing (standing) losses

Kg per year

Kg per year

68

16

Total Degassing and Cleaning emissions

Kg per year

750

Total losses during roof landing

Kg per year

1

836

3013.19-034.xls - 2

3/3

Kg per year

26/02/2023

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - B&W 2022

Haifa-2

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

2.68

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Aluminum/Diffuse

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

Meterological Data used in Emissions Calculations: Haifa-2, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

23/02/2023

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - B&W 2022 - External Floating Roof Tank

Haifa-2, Israel

Mixture/Component

Jet kerosene

Month

All

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

76.52

65.35

87.69

Liquid

Bulk

Temp

(deg F)

68.86

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0136

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

23/02/2023

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - B&W 2022 - External Floating Roof Tank

Haifa-2, Israel

Annual Emission Calcaulations

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

0.0136

160.0100

130.0000

1.0000

Withdrawal Losses (lb):

Annual Net Throughput (gal/yr.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

150.0107

20,363,275.0000

0.0075

7.0000

160.0100

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

0.8398

0.0002

130.0000

1.0000

27.8819

6.2000

Total Losses (lb):

185.3510

34.5005

1.6000

0.3000

6.2000

1.6000

0.0002

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

KFa(lb-mole/yr)

1.60

6.20

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

1.20

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.94

1.00

Losses(lb)

0.1446

0.6608

0.0345

23/02/2023

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

23/02/2023

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - B&W 2022 - External Floating Roof Tank

Haifa-2, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

34.50

150.01

0.84

0.00

185.35

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

23/02/2023

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

23/02/2023

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFixed 2019

Haifa

Israel

PEI

Vertical Fixed Roof Tank

kerosene

Tank Dimensions

Shell Height (ft):

Diameter (ft):

Liquid Height (ft) :

Avg. Liquid Height (ft):

Volume (gallons):

Turnovers:

Net Throughput(gal/yr):

Is Tank Heated (y/n):

N

Paint Characteristics

Shell Color/Shade:

Shell Condition

Roof Color/Shade:

Roof Condition:

Aluminum/Diffuse

Good

White/White

Good

Roof Characteristics

Type:

Height (ft)

Slope (ft/ft) (Cone Roof)

Breather Vent Settings

Vacuum Settings (psig):

Pressure Settings (psig)

11.00

160.01

11.00

5.50

1,654,664.74

1.00

1,654,664.74

Cone

0.00

0.00

0.00

0.50

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

Apr

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

72.10

62.74

81.45

Liquid

Bulk

Temp

(deg F)

67.57

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0118

0.0092

0.0159

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

02/02/2020

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Month:

Standing Losses (lb):

Vapor Space Volume (cu ft):

Vapor Density (lb/cu ft):

Vapor Space Expansion Factor:

Vented Vapor Saturation Factor:

January

February

March

April

May

June

July

August

September

October

November

December

Tank Vapor Space Volume:

Vapor Space Volume (cu ft):

Tank Diameter (ft):

Vapor Space Outage (ft):

Tank Shell Height (ft):

Average Liquid Height (ft):

Roof Outage (ft):

Roof Outage (Cone Roof)

Roof Outage (ft):

Roof Height (ft):

Roof Slope (ft/ft):

Shell Radius (ft):

Vapor Density

Vapor Density (lb/cu ft):

Vapor Molecular Weight (lb/lb-mole):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Daily Avg. Liquid Surface Temp. (deg. R):

Daily Average Ambient Temp. (deg. F):

Ideal Gas Constant R

(psia cuft / (lb-mol-deg R)):

Liquid Bulk Temperature (deg. R):

Tank Paint Solar Absorptance (Shell):

Tank Paint Solar Absorptance (Roof):

Daily Total Solar Insulation

Factor (Btu/sqft day):

Vapor Space Expansion Factor

Vapor Space Expansion Factor:

Daily Vapor Temperature Range (deg. R):

Daily Vapor Pressure Range (psia):

Breather Vent Press. Setting Range(psia):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Vapor Pressure at Daily Minimum Liquid

Surface Temperature (psia):

Vapor Pressure at Daily Maximum Liquid

Surface Temperature (psia):

Daily Avg. Liquid Surface Temp. (deg R):

Daily Min. Liquid Surface Temp. (deg R):

Daily Max. Liquid Surface Temp. (deg R):

Daily Ambient Temp. Range (deg. R):

Vented Vapor Saturation Factor

Vented Vapor Saturation Factor:

Vapor Pressure at Daily Average Liquid:

Surface Temperature (psia):

Vapor Space Outage (ft):

Working Losses (lb):

Vapor Molecular Weight (lb/lb-mole):

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Net Throughput (gal/mo.):

Annual Turnovers:

Turnover Factor:

Maximum Liquid Volume (gal):

Maximum Liquid Height (ft):

Tank Diameter (ft):

Working Loss Product Factor:

Total Losses (lb):

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFixed 2019 - Vertical Fixed Roof Tank

Haifa, Israel

Losses(lbs)

Components

Working Loss

Breathing Loss

Total Emissions

Jet kerosene

60.63

32.78

93.41

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 1 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Tank Indentification and Physical Characteristics

Identification

User Identification:

City:

State:

Company:

Type of Tank:

Description:

T2 - DFloating 2019

Haifa

Israel

PEI

External Floating Roof Tank

kerosene

Tank Dimensions

Diameter (ft):

Volume (gallons):

Turnovers:

160.01

7,599,816.00

1.00

Paint Characteristics

Internal Shell Condition:

Shell Color/Shade:

Shell Condition

Dense Rust

Aluminum/Diffuse

Good

Roof Characteristics

Type:

Fitting Category

Pontoon

Detail

Tank Construction and Rim-Seal System

Construction:

Welded

Primary Seal:

Mechanical Shoe

Secondary Seal

Shoe-mounted

Deck Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

Meterological Data used in Emissions Calculations: Haifa, Israel (Avg Atmospheric Pressure = 14.69 psia)

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 2 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Liquid Contents of Storage Tank

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Mixture/Component

Jet kerosene

Month

Apr

Daily Liquid Surf.

Temperature (deg F)

Avg.

Min.

Max.

76.46

63.88

89.04

Liquid

Bulk

Temp

(deg F)

68.86

Vapor Pressure (psia)

Avg.

Min.

Max.

0.0136

N/A

N/A

Vapor

Mol.

Weight.

Liquid

Mass

Fract.

Vapor

Mass

Fract.

130.0000

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

Mol.

Weight

Basis for Vapor Pressure

Calculations

162.00

Option 1: VP70 = .011 VP80 = .015

02/02/2020

TANKS 4.0 Report

Page 3 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Detail Calculations (AP-42)

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Month:

Rim Seal Losses (lb):

Seal Factor A (lb-mole/ft-yr):

Seal Factor B (lb-mole/ft-yr (mph)^n):

Average Wind Speed (mph):

Seal-related Wind Speed Exponent:

Value of Vapor Pressure Function:

Vapor Pressure at Daily Average Liquid

Surface Temperature (psia):

Tank Diameter (ft):

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

January

February

March

April

May

June

July

August

September

October

November

December

Withdrawal Losses (lb):

Net Throughput (gal/mo.):

Shell Clingage Factor (bbl/1000 sqft):

Average Organic Liquid Density (lb/gal):

Tank Diameter (ft):

Roof Fitting Losses (lb):

Value of Vapor Pressure Function:

Vapor Molecular Weight (lb/lb-mole):

Product Factor:

Tot. Roof Fitting Loss Fact.(lb-mole/yr):

Average Wind Speed (mph):

Total Losses (lb):

Roof Fitting/Status

Access Hatch (24-in. Diam.)/Bolted Cover, Gasketed

Vacuum Breaker (10-in. Diam.)/Weighted Mech. Actuation, Gask.

Rim Vent (6-in. Diameter)/Weighted Mech. Actuation, Gask.

Quantity

3

2

1

KFa(lb-mole/yr)

1.60

6.20

0.71

Roof Fitting Loss Factors

KFb(lb-mole/(yr mph^n))

0.00

1.20

0.10

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

m

0.00

0.94

1.00

Losses(lb)

0.0000

0.0000

0.0000

02/02/2020

TANKS 4.0 Report

Page 4 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 5 of 6

TANKS 4.0.9d

Emissions Report - Detail Format

Individual Tank Emission Totals

Emissions Report for: Annual

T2 - DFloating 2019 - External Floating Roof Tank

Haifa, Israel

Losses(lbs)

Components

Rim Seal Loss

Withdrawl Loss

Deck Fitting Loss

Deck Seam Loss

Total Emissions

Jet kerosene

2.99

55.99

0.07

0.00

59.04

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

TANKS 4.0 Report

Page 6 of 6

file:///C:/Program%20Files%20(x86)/Tanks409d/summarydisplay.htm

02/02/2020

נספח ד'

חישוב פליטות ממיכל לאיסוף תשטיפים

26/02/2023

19/30

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תוכנת :Tanksחישוב פליטה כתוצאה מניקוי וריקון מיכל (שלב א')

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חישובי פליטה ממיכל תשטיפים

גיליון חישוב זה הוכן על ידי "פז" הנדסה וניהול ( )1980בע"מ.

אין להעתיק ו\או לעשות שימוש כלשהו במידע הנ"ל ללא הרשאה כתובה מ"פז" הנדסה וניהול ( )1980בע"מ.

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